Abstract: An electronic writing instrument for rewritable electronic writing surfaces. A self-powered, untethered, pencil-like instrument uses a perpendicular fringe field for changing the orientation of pixels composed of bistable, bichromal colorant elements. An appendix hereto describes bistable, bichromal, molecular colorant.

Abstract: Optical properties of a screen on which an image is being projected are considered. A patterned surface is given a predetermined pattern of color pixels whereby a degree of wavelength selectivity is employed to improve the color qualities of the projected image. A system is provided wherein there is a matching of emission characteristics of a projector to the screen's reflective characteristics.

Abstract: A bistable molecular switch can have a highly conjugated first state and a less conjugated second state. The bistable molecular switch can be configured such that application of an electric field reversibly switches the molecular switch from the first state to the second state. Additionally, the bistable molecular switch can include a hydrophobic moiety and a hydrophilic moiety. Such molecular switches can be incorporated into a thin film as part of a molecular switch system which can include a layer of molecular switches between a first electrode layer and a second electrode layer. The layer of molecular switches can have substantially all of the molecular switches having their hydrophilic moiety oriented in the same direction. An electric potential can then be induced between the first and second electrode layers sufficient to switch the molecular switches from the first or second state to the second or first state, respectively.

Abstract: A composition of matter is provided that results in a change of electrical properties through intra-molecular charge transfer or inter-molecular charge transfer or charge transfer between a molecule and an electrode, wherein the charge transfer is induced by an electric field.

Abstract: Ceramic pigment-based, chemically-modified porous coatings can be used for enhancing image permanence of ink-jet image printing. Specifically, a porous coated media sheet, comprising a media substrate, having a porous coating coated thereon comprising a modified ceramic pigment including a fixer group and a stabilizer group, each covalently attached to the ceramic pigment is disclosed. Additionally, a method and system for preparing permanent ink-jet images is also provided.

Abstract: An electric field activated bi-stable molecular system configured within an electric field generated by a pair of electrodes is provided for use, e.g., as electronic ink or other visual displays. The molecular system has at least one rotor portion connected to at least one stator portion, wherein the rotor portion rotates with respect to the stator portion between at least two different states upon application of the electric field, thereby inducing a band gap change in the molecular system, wherein in a first state, there is extended conjugation throughout the major portion of the molecular system, resulting in a relatively smaller band gap, and wherein in a second state, the extended conjugation is destroyed, resulting in a relatively larger band gap. A primary advantage of the molecular system is improved contrast. Because the colorant of the present invention is molecular and thus effectively monoplanar, there should be no backside reflection or scattering from the colorant.

Abstract: Methods and apparatus for packing, including single pixel data strings, and playback tracking of informative data, e.g., audio signals, associated with graphics. To maximize the signal-to-noise ratio during data recovery, a Read sensor is kept substantially on-center of each data block throughout reading. A Print-and-Read ink-jet embodiment carriage mechanism in conjunction with the paper feed mechanism keeps the Read sensor on track center as misalignment information has been determined beforehand or in real time for active track servoing. Additional functionalities are incorporated in scanning ink-jet class of printers so that they can further operate as informative data recovery or retrieval systems for digitized data on graphical data images. In another embodiment, a digital camera itself is provided with additional functionalities to operate as a recovery and playback device for prints containing informative data.

Abstract: An electronic book, having a single screen, employs an electric field addressable, rewritable, colorant, preferably a bistable molecular colorant, for providing printed pages sequentially to a reader. The electronic book includes the rewritable screen coupled to an extraction-retraction device, an electrode array printer, a sheet position detector, and associated circuitry to download, store, sequence, and print images on the screen. Methods associated with document distribution are another aspect of the invention.

Abstract: The present invention provides a printer and media solution that is conducive to briefcase-compatible compactness, battery operation, and media reuse. The printer consists of a low power, electrode array that images the surface of a paper-like, rewritable sheet. The sheet is responsive to pixel-sized electric fields produced by each electrode, resulting in a pixel array that is imaged in response to field polarity. The sheet is coated with a rewritable colorant that is a highly energy efficient, bistable, bi-modal molecular layer, requiring energy only to change an image, not to hold or illuminate it.

Abstract: A molecular system is provided for nanometer-scale reversible electronic and optical switches, specifically, electric field-activated molecular switches that have an electric field induced band gap change that occurs via rotation of rotor units connected to immobile stator units. The molecular system has two branches on one side of an immobile junction unit and one or two branches on the opposite side to thereby provide “Y” and “X” configurations, respectively. The ends of the branches opposite the junction unit are connected to, or electrically associated with, other molecular systems or substrates, such as electrodes. The rotor units each rotate between two states as a function of an externally-applied field. Both multi-stable molecular mechanical devices and electric field-activated optical switches are provided.

Abstract: A molecular system is provided for electric field activated switches, such as a crossed-wire device or a pair of electrodes to which the molecular system is linked by linking moieties. The crossed-wire device comprises a pair of crossed wires that form a junction where one wire crosses another at an angle other than zero degrees and at least one connector species connecting the pair of crossed wires in the junction. The connector species comprises the molecular system, which has an electric field induced band gap change, and thus a change in its electrical conductivity, that occurs via one a molecular conformation change, based on a rotor/stator construction of the molecular system, involving a rotating portion (rotor) connected between to stationary portions (stators). Nanometer-scale reversible electronic switches are thus provided that can be assembled easily to make cross-bar circuits, which provide memory, logic, and communication functions.

Abstract: A molecular system is provided for electric field activated switches, such as optical switches. The molecular system has an electric field induced band gap change that occurs via a molecular conformation change, based on a rotor/stator construction of the molecular system, involving a rotating portion (rotor) connected between two stationary portions (stators). Nanometer-scale reversible optical switches are thus provided that can be assembled easily to make a variety of optical devices, including optical displays.

Abstract: A digital dye having an optical change resulting from an electrochemical oxidation/reduction reaction is provided for use in a molecular system. The molecular system provides two different colors based on two different oxidation states of at least one digital dye in the molecular system. Further, an optical switch comprising the molecular system configured within an electric field generated by a pair of electrodes is provided, employing the above-described digital dye. Still further, a display device including a transparent display electrode, a counter electrode, and the molecular system disposed therebetween is provided, where the molecular system comprises at least one digital dye.

Abstract: An electrochromic molecular colorant and a plurality of uses as an erasably writeable medium. Multitudinous types of substrates, such as paper, are adaptable for receiving a coating of the colorant. Electrical fringe field or through fields are used to transform targeted pixel molecules between a first, high color state and transparent state, providing information content having resolution and viewability at least equal to hard copy document print. The scope of the invention includes both the liquid coating and the combination of coating on substrate.

Abstract: Molecular systems are provided for electric field activated switches, such as optical switches. The molecular system has an electric field induced band gap change that occurs via one of the following mechanisms: (1) molecular conformation change; (2) change of extended conjugation via chemical bonding change to change the band gap; or (3) molecular folding or stretching. Nanometer-scale reversible optical switches are thus provided that can be assembled easily to make a variety of optical devices, including optical displays.

Abstract: An electrochromic molecular colorant and a plurality of uses as an erasably writeable medium. Multitudinous types of substrates, such as paper, are adaptable for receiving a coating of the colorant. Electrical fringe field or through fields are used to transform targeted pixel molecules between a first, high color state and transparent state, providing information content having resolution and viewability at least equal to hard copy document print. The scope of the invention includes both the liquid coating and the combination of coating on substrate.

Abstract: A molecular light valve mechanism is used for imaging on an adjacent pixel-patterned construct. An electrical fringe field or through field is used to transform targeted pixels by switching light valve molecules between a first non-transparent state and transparent state, providing information content on the adjacent pixel-patterned imaging layer.

Abstract: An electronic writing instrument for rewritable electronic writing surfaces. A self-powered, untethered, pencil-like instrument uses a fringe field for changing the orientation of pixels composed of molecular colorant elements. An appendix hereto describes the molecular colorant.

Abstract: Methods and apparatus for packing, including single pixel data strings, and playback tracking of informative data, e.g., audio signals, associated with graphics. To maximize the signal-to-noise ratio during data recovery, a Read sensor is kept substantially on-center of each data block throughout reading. A Print-and-Read ink-jet embodiment carriage mechanism in conjunction with the paper feed mechanism keeps the Read sensor on track center as misalignment information has been determined beforehand or in real time for active track servoing. Additional functionalities are incorporated in scanning ink-jet class of printers so that they can further operate as informative data recovery or retrieval systems for digitized data on graphical data images. In another embodiment, a digital camera itself is provided with additional functionalities to operate as a recovery and playback device for prints containing informative data.

Abstract: A three-dimensional molecular assembly and method of formation are provided. The molecular assembly is formed on a substrate. The molecular assembly comprises: a first monolayer of seed molecules for initiating self-assembled molecular growth, the first monolayer formed on the substrate; a second monolayer of active molecules comprising a plurality of rotor and stator moieties, with one rotor moiety supported between two stator moieties, the second monolayer of active molecules formed on the first monolayer of seed molecules, with a one-to-one correspondence between molecules in the first monolayer and the second monolayer; a third monolayer of spacer molecules, formed on the second monolayer of active molecules, with a one-to-one correspondence between molecules in the second monolayer and the third monolayer; and a plurality of alternating second monolayers and third monolayers having the one-to-one correspondence.