Patents by Inventor Antoine Hernandez

Antoine Hernandez has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20180282159
    Abstract: A process and a plant for the continuous conversion of a hydrocarbonaceous feed gas into a synthesis gas comprising carbon monoxide and hydrogen, wherein the H2/CO molar ratio of the product gases can be varied within a wide range. This is achieved in that at least a part of a methane-rich gas obtained during the fractionation of the raw synthesis gas is admixed to the feed gas mixture, and that in the alternative at least a part of the H2 product gas and/or a fraction of a hydrogen-rich gas increased with respect to the normal operation of the process is admixed to the heating gas mixture, in order to lower the H2/CO ratio, or at least a part of the CO product gas and/or a fraction of a carbon monoxide-rich gas increased with respect to the normal operation of the process is admixed to the heating gas mixture, in order to increase the H2/CO ratio.
    Type: Application
    Filed: September 23, 2016
    Publication date: October 4, 2018
    Applicant: L'Air Liquide, Societe Anonyme Pour I'Etude et I'Exploitation des Procedes Georges Claude
    Inventors: Bernd POLSTER, Antoine HERNANDEZ
  • Publication number: 20180251373
    Abstract: In a method for producing a gaseous mixture of CO and H2, a first gas comprising at least 50% CO is compressed in a first compressor to form a first compressed gas cooled to a first temperature and mixes with a second gas comprising at least 50% hydrogen in order to form the gaseous mixture, at least one of the first and second gases originating from a cryogenic distillation separation unit in which a feed gas containing H2 and CO cools in a first heat exchanger and is separated in at least one distillation column and at least one part of the second gas heats in the separation unit to a third temperature lower than the first temperature and is then sent to mix with the first gas.
    Type: Application
    Filed: July 20, 2016
    Publication date: September 6, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour I'Etude et I'Etude et I'Exploitation des Procedes Georges Cla
    Inventors: Angela FERNANDEZ, Antoine HERNANDEZ, Jean-Marc TSEVERY
  • Publication number: 20180100696
    Abstract: The invention relates to a facility for producing liquid helium from a source gas mixture substantially comprising nitrogen and helium. The facility includes a cryogenic purifier including a system for separating the nitrogen from the source gas mixture with a view to producing helium at a temperature lower than the temperature of the source gas. The facility also includes a helium liquefier that subjects the helium to a work cycle including, in series: compressing the helium, cooling and decompressing the compressed helium, and reheating the cooled, decompressed helium. The facility includes a helium transfer pipe connecting an outlet of the purifier to an inlet of the liquefier in order to transfer helium produced by the purifier into the work cycle of the liquefier. The facility is characterized in that the cryogenic purifier includes a decompression system that includes an inlet to be connected to a source of pressurized nitrogen gas.
    Type: Application
    Filed: April 13, 2016
    Publication date: April 12, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour I'Etude et I'Exploitation des Procedes Georges Claude
    Inventors: Bertrand DEMOLLIENS, Jean-Marc BERNHARDT, Rawia ALI SAID, Delphine PICHOT, Antoine HERNANDEZ, Jean-Marc TSEVERY, Jean-Marc PEYRON
  • Publication number: 20180094854
    Abstract: A plant for producing an argon-rich stream from a mixture formed by a purge fluid from a plant for producing ammonia comprises at least two methane scrubbing columns upstream of a methane separation column and, downstream therefrom, a nitrogen/argon separation column.
    Type: Application
    Filed: September 29, 2017
    Publication date: April 5, 2018
    Applicant: L'Air Liquide, Societe Anonyme pour I'Etude et I'Exploitation des Procedes Georges Claude
    Inventors: Bertrand Demolliens, Antoine Hernandez
  • Patent number: 9625209
    Abstract: A method for separating a feed gas, containing nitrogen and carbon monoxide as main components, in a distillation column: the feed gas is cooled in a heat exchanger; at least a portion of the feed gas, or at least a portion of a gas derived from the feed gas, is sent to a reboiler of the distillation column so as to condense the gas while producing a liquid, and optionally a gas; at least a portion of the liquid is sent to the distillation column; a nitrogen gas-rich flow is extracted from the distillation column; a carbon monoxide-rich flow is extracted from the distillation column, heated in the heat exchanger, and compressed so as to provide a carbon monoxide-rich material at production pressure.
    Type: Grant
    Filed: November 4, 2010
    Date of Patent: April 18, 2017
    Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Arthur Darde, Antoine Hernandez, Bernard Saulnier
  • Publication number: 20160282044
    Abstract: A process to produce at least carbon dioxide and carbon monoxide from a feed gas containing carbon dioxide, hydrogen and carbon monoxide; comprises separating at least part of the carbon dioxide from the compressed feed gas by partial condensation and/or distillation producing a carbon dioxide product and a carbon dioxide depleted stream, treating the carbon dioxide depleted stream in a treatment unit to produce a feed stream containing carbon monoxide and hydrogen, less rich in carbon dioxide than the carbon dioxide depleted stream and feeding at least part of the feed stream containing carbon monoxide and hydrogen to a separation unit operating at cryogenic temperatures to produce a carbon monoxide product.
    Type: Application
    Filed: November 19, 2014
    Publication date: September 29, 2016
    Applicant: l'Air Liquide, Societe Anonyme pour I'Etude et l'Explotation des Procedes Georges Claude
    Inventors: Antoine HERNANDEZ, Paul TERRIEN
  • Patent number: 8966937
    Abstract: A process and to an apparatus for the generation and separation of a mixture of hydrogen and carbon monoxide is provided.
    Type: Grant
    Filed: July 20, 2009
    Date of Patent: March 3, 2015
    Assignee: L'Air Liquide Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Natacha Haik-Beraud, Antoine Hernandez, Pascal Marty, Bernd Polster
  • Patent number: 8959952
    Abstract: The invention relates to a method for separating a mixture comprising at least carbon monoxide, hydrogen, and methane. According to said method, the mixture is separated by a first separating means, at least one liquid fraction of the chamber of the separating means is sent to a product stripper, and at least part of the liquid fraction is sent from the product stripper to a CO/CH4 separating column in order to produce a methane-enriched liquid flow and a gaseous flow enriched with carbon monoxide. The process is carried out under cold conditions at least partially as a result of a carbon monoxide cycle, said cycle at least partially ensuring the condensation at the top of the CO/CH4 separating column and/or the reboiling in the chamber of the product stripper and/or the reboiling in the chamber of the CO/CH4 separating column and/or the cooling of the mixture for the first separating means.
    Type: Grant
    Filed: December 14, 2007
    Date of Patent: February 24, 2015
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Arthur Darde, Natacha Haik-Beraud, Antoine Hernandez, Guillaume Teixeira
  • Patent number: 8888873
    Abstract: A method for generating and purifying syngas and to an apparatus for generating and purifying syngas is presented.
    Type: Grant
    Filed: July 23, 2009
    Date of Patent: November 18, 2014
    Assignee: L'air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Natacha Haik-Beraud, Antoine Hernandez, Pascal Marty, Bernd Polster
  • Patent number: 8869553
    Abstract: A process and a device for the cryogenic separation of a mixture of hydrogen and carbon monoxide, in particular of a mixture having, as main components, hydrogen and carbon monoxide is presented.
    Type: Grant
    Filed: March 20, 2009
    Date of Patent: October 28, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Philippe Court, Antoine Hernandez
  • Publication number: 20140305162
    Abstract: Process for the purification and separation of a synthesis gas stream containing hydrogen, carbon monoxide and carbon dioxide in which synthesis gas is purified in a purification unit (W) involving a methanol washing step to remove carbon dioxide, the carbon dioxide depleted synthesis gas is purified by adsorption (P) to produce a purified synthesis gas stream and the purified gas stream is sent to a cryogenic separation unit (C) where it is cooled and separated by cryogenic separation in a column of a column system, at least one stream (13) enriched in carbon monoxide is removed from a column of the column system, warmed and divided in two, one part of the stream being removed from the cryogenic separation unit as a first stream, the other part of the stream forming a second stream (13B, 15B) and being sent to the purification unit wherein it is warmed and the warmed second stream is mixed with the first stream.
    Type: Application
    Filed: November 13, 2012
    Publication date: October 16, 2014
    Inventors: Guylaine Callens, Antoine Hernandez, Pascal Marty, Manfred Meyer, Denis Prost, Alexander Schriefl, Jean-Marc Tsevery, Marie-Pascal Victor
  • Patent number: 8783062
    Abstract: A storage enclosure and an apparatus and method for producing carbon monoxide and/or hydrogen by means of cryogenic separation, including one such enclosure is provided.
    Type: Grant
    Filed: May 16, 2008
    Date of Patent: July 22, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Alain Briglia, Natacha Haik-Beraud, Antoine Hernandez, Arthur Darde, Guillaume Teixeira
  • Publication number: 20130298600
    Abstract: A process for the production of ammonia synthesis gas and pure methane by cryogenic separation of a feed gas containing at least 75% hydrogen as well as methane and nitrogen, the feed gas is cooled in a heat exchanger and partially condensed, the partially condensed feed is sent to a phase separator, the gas from the phase separator is sent to a nitrogen wash column, liquid nitrogen is sent to the top of the nitrogen wash column and ammonia synthesis gas is removed from the top of the nitrogen wash column, the liquid from the phase separator is expanded and sent to a separation column, a nitrogen enriched gas stream is removed from the top of the column and a nitrogen depleted liquid stream rich in methane is removed from the bottom of the column and the nitrogen depleted liquid stream rich in methane is vaporized to form a pure methane product.
    Type: Application
    Filed: January 17, 2011
    Publication date: November 14, 2013
    Applicant: L'AIR LIQUIDE SOCIETE ANONYME POUR I'ETUDE ET I'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Antoine Hernandez, Yuan-Jun Hu, Yanfang Liu, Jean-Marc Tsevery
  • Patent number: 8555673
    Abstract: The invention relates to a method and apparatus for separating a mixture containing carbon monoxide, nitrogen and hydrogen by cryogenic distillation in a separation system which includes a denitrification column and at least another column. The method can include separating the mixture in order to obtain a fluid enriched with carbon monoxide and containing nitrogen, separating the fluid in the denitrification column, pressurizing the carbon monoxide flow from the column in a compressor up to a high pressure, collecting a fraction of carbon monoxide flow to be used as a product, expanding an amount of the high-pressure carbon monoxide flow in a valve prior to supplying it to the denitrification column, and varying the flow expanded in the valve according to re-boiling needs of the denitrification column.
    Type: Grant
    Filed: December 12, 2007
    Date of Patent: October 15, 2013
    Assignee: L'Air Liquide, Société pour l'Étude et l'Éxploitation des Procédés Georges Claude
    Inventors: Arthur Darde, Antoine Hernandez
  • Publication number: 20120279254
    Abstract: A method for separating a feed gas, containing nitrogen and carbon monoxide as main components, in a distillation column: the feed gas is cooled in a heat exchanger; at least a portion of the feed gas, or at least a portion of a gas derived from the feed gas, is sent to a reboiler of the distillation column so as to condense the gas while producing a liquid, and optionally a gas; at least a portion of the liquid is sent to the distillation column; a nitrogen gas-rich flow is extracted from the distillation column; a carbon monoxide-rich flow is extracted from the distillation column, heated in the heat exchanger, and compressed so as to provide a carbon monoxide-rich material at production pressure.
    Type: Application
    Filed: November 4, 2010
    Publication date: November 8, 2012
    Applicant: L'Air Liquide Societe Annonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claud
    Inventors: Arthur Darde, Antoine Hernandez, Bernard Saulnier
  • Publication number: 20110138853
    Abstract: A process and to an apparatus for the generation and separation of a mixture of hydrogen and carbon monoxide is provided.
    Type: Application
    Filed: July 20, 2009
    Publication date: June 16, 2011
    Inventors: Natacha Haik-Beraud, Antoine Hernandez, Pascal Marty, Bernd Polster
  • Publication number: 20110126459
    Abstract: A method for generating and purifying syngas and to an apparatus for generating and purifying syngas is presented.
    Type: Application
    Filed: July 23, 2009
    Publication date: June 2, 2011
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Natacha Haik-Beraud, Antoine Hernandez, Pascal Marty, Bernd Polster
  • Publication number: 20110056239
    Abstract: A process and a device for the cryogenic separation of a mixture of hydrogen and carbon monoxide, in particular of a mixture having, as main components, hydrogen and carbon monoxide is presented.
    Type: Application
    Filed: March 20, 2009
    Publication date: March 10, 2011
    Inventors: Philippe Court, Antoine Hernandez
  • Publication number: 20100199718
    Abstract: A storage enclosure and an apparatus and method for producing carbon monoxide and/or hydrogen by means of cryogenic separation, including one such enclosure is provided.
    Type: Application
    Filed: May 16, 2008
    Publication date: August 12, 2010
    Inventors: Alain Briglia, Arthur Darde, Natacha Haik-Beraud, Antoine Hernandez, Guillaume Teixeira
  • Publication number: 20100162754
    Abstract: A method and to a device for separating a mixture of hydrogen, methane and carbon monoxide by cryogenic distillation is provided. In particular, the present invention relates to a method for producing a mixture of H2/CO with a low CH4 content, possibly combined with the production of CH4 in liquid form.
    Type: Application
    Filed: April 23, 2008
    Publication date: July 1, 2010
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation des Procedes Georges Claude
    Inventors: Jean Billy, Antoine Hernandez, Marie-Khuny Khy