Patents by Inventor Arthur J. Epstein

Arthur J. Epstein has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5294694
    Abstract: A method is provided for absorbing electromagnetic radiation using a polyaniline composition, wherein the radiation is infrared, visible light, ultraviolet, radar, or microwave radiation. Also provided is a method for reducing the detectability by radar of an object by increasing the absorption of radar waves and thereby decrease the reflection of the radar waves by applying to the object a polyaniline composition or a partially protonated salt thereof.
    Type: Grant
    Filed: July 27, 1992
    Date of Patent: March 15, 1994
    Assignee: The Ohio State University Research Foundation
    Inventors: Arthur J. Epstein, John M. Ginder, Mitchell G. Roe, Hamid Hajiseyedjavdi
  • Patent number: 5250163
    Abstract: Broadly, the present invention takes advantage of the ability of self-protonated sulfonated polyaniline (SPAN) to sense and/or modulate pH of a medium in the vicinity of a SPAN electrode. Accordingly, one aspect of the present invention is directed to a method for sensing pH of a medium in the vicinity of a sensing electrode wherein a SPAN electrode and a counter-electrode are placed in a medium and an indicia of said SAN correlative with the pH of said medium is monitored. As another aspect of the present invention, the pH of a medium in the vicinity of a sensing electrode is modulated by placing a SPAN electrode in the medium and applying a voltage to the electrode to controllably emit or absorb protons from said electrode to modulate the pH of the medium in the vicinity of the electrode. As a further aspect of the present invention, the activity/state of a biosensor/catalyst is sensed for the activity/state correlative with pH.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: October 5, 1993
    Assignee: The Ohio State University Research Foundation
    Inventors: Arthur J. Epstein, Jiang Yue, David R. Burley
  • Patent number: 5208301
    Abstract: Sulfonic acid-substituted polyaniline compositions, ammonium salts thereof, and uses therefor are disclosed. The ammonium salts of the sulfonic acid-substituted polyaniline compositions are used as interim materials in the processing of conducting sulfonated polyaniline compositions. The ammonium salts of the sulfonic acid-substituted polyaniline compositions are also used to either reversible or irreversible NH.sub.3 filters, sensors, temperature indicators and the like.
    Type: Grant
    Filed: May 25, 1990
    Date of Patent: May 4, 1993
    Assignee: Ohio State University Research Foundation
    Inventors: Arthur J. Epstein, Jiang Yue
  • Patent number: 5164465
    Abstract: Sulfonic acid-substituted polyaniline salt compositions, processes for their preparation and uses therefor are disclosed. The sulfonated polyaniline salt compositions have fast electronic and optical responses to electrochemical potentials, improved environmental stability, and improved solubility. A process for producing the sulfonated polyaniline salt compositions comprises reacting a sulfonated polyaniline polymer with an aqueous basic solution. The sulfonated polyaniline compositions are useful for absorption of electromagnetic radiation, as a high density erasable data storage medium for use in information storage and processing applications, and to provide electronic, chemical, electrochemical, and optical microelectronic devices which use and control the chemical and physical properties of the sulfonated polyaniline salt compositions.
    Type: Grant
    Filed: October 24, 1989
    Date of Patent: November 17, 1992
    Assignee: Ohio State University Research Foundation
    Inventors: Arthur J. Epstein, Jiang Yue
  • Patent number: 5159031
    Abstract: Sulfonic acid-substituted polyaniline salt compositions and uses therefor are disclosed. The sulfonated polyaniline salt compositions have fast electronic and optical responses to electrochemical potentials, improved environmental stability, and improved solubility. The sulfonated polyaniline salt compositions are useful as an ionic electrolyte polymer.
    Type: Grant
    Filed: May 25, 1990
    Date of Patent: October 27, 1992
    Assignee: Ohio State University Research Foundation
    Inventors: Arthur J. Epstein, Jiang Yue
  • Patent number: 5147968
    Abstract: A composition for absorbing electromagnetic radiation (such as microwave, infrared, visible light radiation ultraviolet radiation), wherein said electromagnetic radiation possesses a wavelength generally in the range of from about 1000 Angstroms to about 50 meters, wherein said composition comprises a polyaniline composition of the formula ##STR1## where y can be equal to or greater than zero and R' and R.sub.2 are independently selected from the group consisting of --H, --OCH.sub.3, --CH.sub.3, --F, --Cl, --Br, --I, --NR.sup.3.sub.2, --NHCOR.sub.3, --OH, --O, --SR.sup.3, --OR.sup.3, --OCOR.sup.3, --NO.sub.2, --COOH, --COOR.sup.3, --COR.sup.3, --CHO, and --CN, where R.sup.3 is a C.sub.1 to C.sub.a alkyl, aryl or aralkyl group.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: September 15, 1992
    Assignee: The Ohio State University Research Foundation
    Inventors: Arthur J. Epstein, John M. Ginder, Mitchell G. Roe, Hamid Hajiseyedjavadi
  • Patent number: 5137991
    Abstract: Self-prontonated sulfonic acid-substituted polyaniline compositions, processes for their preparation and uses therefor are disclosed. The sulfonated polyaniline compositions have faster electronic and optical responses to electrochemical potentials comparing to its parent polyaniline, improved environmental stability, and improved solubility than the parent polymer, polyaniline. A process for producing the sulfonated polyaniline compositions comprises reacting the polyaniline polymer with concentrated sulfuric acid. The sulfonated polyaniline compositions are useful for switching an electrochemical response between a conducting and a nonconducting state. The sulfonated polyaniline compositions are also useful for conduction of electricity, absorption of electromagnetic radiation, modulation of electromagnetic beams and modification of the electromagnetic response of sulfonated polyaniline compositions by chemical or electrochemical means.
    Type: Grant
    Filed: October 19, 1989
    Date of Patent: August 11, 1992
    Assignee: The Ohio State University Research Foundation
    Inventors: Arthur J. Epstein, Jiang Yue
  • Patent number: 5135696
    Abstract: Methods for producing fibers of self-protonated sulfonic acid-substituted polyaniline compositions. The sulfonated polyaniline compositions have faster electronic and optical responses to electrochemical potentials comparing to its parent polyaniline, improved environmental stability, and improved solubility than the parent polymer, polyaniline.
    Type: Grant
    Filed: May 25, 1990
    Date of Patent: August 4, 1992
    Assignee: Ohio State University Research Foundation
    Inventors: Arthur J. Epstein, Jiang Yue
  • Patent number: 5109070
    Abstract: Multicomponent polymeric compositions comprising self-prontonated sulfonic acid-substituted polyaniline compositions or derivatives thereof and at least one insulating polymer are disclosed. The sulfonated polyaniline compositions have faster electronic and optical responses to electrochemical potentials, improved environmental stability, and improved solubility than the parent polymer, polyaniline. The multicomponent sulfonated polyaniline/insulating polymer compositions are useful in electronic, chemical, electrochemical, and optical microelectric applications which use and control the chemical and physical properties of the sulfonated polyaniline compositions.
    Type: Grant
    Filed: May 25, 1990
    Date of Patent: April 28, 1992
    Assignee: Ohio State University Research Foundation
    Inventors: Arthur J. Epstein, Jiang Yue
  • Patent number: 5093439
    Abstract: Sulfonic acid-substituted polyaniline compositions and their derivatives are produced by reacting a polyaniline polymer with SO.sub.3 gas. The sulfonated polyaniline compositions have faster electronic and optical responses to electrochemical potentials and improved environmental stability solubility than the parent polyaniline polymer.
    Type: Grant
    Filed: May 25, 1990
    Date of Patent: March 3, 1992
    Assignee: Ohio State University Research Foundation
    Inventors: Arthur J. Epstein, Jiang Yue
  • Patent number: 5079334
    Abstract: A composition for absorbing electromagnetic radiation, wherein said electromagnetic radiation possesses a wavelength generally in the range of from about 1000 Angstroms to about 50 meters, wherein said composition comprises a polyaniline composition of the formula ##STR1## where y can be equal to or greater than zero, and R.sup.1 and R.sup.2 are independently selected from the group containing of H, --OCH.sub.3, --CH.sub.3, --F, --Cl, --Br, --I, NR.sup.3 .sub.2, --NHCOR.sup.3, --OH, --O.sup.-, SR.sup.3, --OCOR.sup.3, --NO.sub.2, --COOH, --COOR.sup.3, --COR.sup.3, --CHO, and --CN, where R.sup.3 is a C.sub.1 to C.sub.8 alkyl, aryl or aralkyl group.
    Type: Grant
    Filed: May 13, 1988
    Date of Patent: January 7, 1992
    Assignee: The Ohio State University Research Foundation
    Inventors: Arthur J. Epstein, John M. Ginder, Mitchell G. Roe, Hamid Hajiseyedjavadi
  • Patent number: 5079037
    Abstract: An insulating host polymer is heavily loaded with resistive short fibers to form resistive films in the resistance range of 10.sup.2 to 10.sup.8 ohms/square having thicknesses in the range of 1.0 micron to 500 microns. The particular choice of resistive short fibers and film forming binder provides specific systems of needed resistivity and mechanical properties. Fibers are chosen having a bulk resistivity lower than a required resistivity of the resulting film and are loaded in an amount above a percolation threshold of the fibers in the film. Fine tuning of the resistivity is made by adjusting the amount of fibers in the film.
    Type: Grant
    Filed: December 28, 1989
    Date of Patent: January 7, 1992
    Assignee: Xerox Corporation
    Inventors: Ian D. Morrison, Arthur J. Epstein
  • Patent number: 5039583
    Abstract: An erasable optical information storage apparatus is disclosed and the process for making such an apparatus is disclosed. The apparatus utilizes the photoabsorption and electrochemical absorption characteristics of the polyaniline class to polymers to provide an easily accessible and erasable information storage unit.
    Type: Grant
    Filed: February 2, 1989
    Date of Patent: August 13, 1991
    Assignee: Ohio State University Research Foundation
    Inventors: Arthur J. Epstein, John M. Ginder, Richard P. McCall
  • Patent number: 4913867
    Abstract: A process to produce oriented, crystalline polyaniline films using simultaneous heat treatment and stressing of polyaniline films. Films stressed while being held at elevated temperatures (T.gtoreq.110.degree. C.), showed anisotropic x-ray, IR and visible optical response.
    Type: Grant
    Filed: February 2, 1989
    Date of Patent: April 3, 1990
    Assignee: The Ohio State University Research Foundation
    Inventors: Arthur J. Epstein, Keith Cromack, Mikolaj Jozefowicz, John M. Ginder
  • Patent number: 4841099
    Abstract: An electrical component is made from an electrically insulating polymer matrix filled with electrically insulating fibrous filler which is capable of heat conversion to electrically conducting fibrous filler and has at least one continuous electrically conductive path formed in the matrix by the in situ heat conversion of the electrically insulating fibrous filler. In a preferred embodiment, the fibrous filler is thermally stabilized polyacrylonitrile fibers and the conductive path is formed by in situ heat converted thermally stabilized polyacrylonitrile fibers which have been converted by directing a laser beam through a mask having a predetermined pattern to melt the polymer and to heat convert the thermally stabilized polyacrylonitrile fibers.
    Type: Grant
    Filed: May 2, 1988
    Date of Patent: June 20, 1989
    Assignee: Xerox Corporation
    Inventors: Arthur J. Epstein, Joan R. Ewing, Joseph A. Swift
  • Patent number: 4080332
    Abstract: There are described novel charge transfer compounds having high electrical conductivity which are represented by the formula [A].sub.x.sup.+ [B].sub.y.sup.- where A is represented by the formula ##STR1## where R.sub.1 -R.sub.4 may be the same or different and may be H or CH.sub.3 and B is 7,7,8,8-tetracyanoquinodimethane, X is 1 and Y is 1 or 2.
    Type: Grant
    Filed: June 28, 1976
    Date of Patent: March 21, 1978
    Assignee: Xerox Corporation
    Inventors: Daniel J. Sandman, Arthur J. Epstein