Patents by Inventor Barry B. Fish
Barry B. Fish has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9475739Abstract: Processes for the production of chlorinated propenes are provided. The present processes make use of a feedstock comprising 1,2,3-trichloropropane and chlorinates the 1,1,2,3-tetrachloropropane generated by the process prior to a dehydrochlorination step. Production of the less desirable pentachloropropane isomer, 1,1,2,3,3-pentachloropropane, is thus minimized. The present processes provide better reaction yield as compared to conventional processes that require dehydrochlorination of 1,1,2,3-tetrachloropropane prior to chlorinating the same. The present process can also generate anhydrous HCl as a byproduct that can be removed from the process and used as a feedstock for other processes, while limiting the production of waste water, thus providing further time and cost savings.Type: GrantFiled: August 1, 2012Date of Patent: October 25, 2016Assignee: BLUE CUBE IP LLCInventors: Max M. Tirtowidjojo, Barry B. Fish, David S. Laitar
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Patent number: 9475740Abstract: Processes for the production of chlorinated propenes are provided. The present processes make use of 1,2-dichloropropane, a by-product in the production of chlorohydrin, as a low cost starting material. 1,1,1,2,2-pentachloropropane produced by the process is subjected to catalytic dehydrochlorination and build-up of the same within the process is avoided.Type: GrantFiled: December 17, 2013Date of Patent: October 25, 2016Assignee: BLUE CUBE IP LLCInventors: Max M. Tirtowidjojo, David S. Laitar, Barry B. Fish, William J. Kruper, Jr.
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Publication number: 20160009624Abstract: A salt-splitting liquid and a process that uses the salt-splitting liquid to “split” ammonium propionate salts into ammonia (or amines) and propionic acid that minimizes increases in the viscosity.Type: ApplicationFiled: February 17, 2014Publication date: January 14, 2016Applicant: Dow Global Technologies LLCInventors: Sanjib Biswas, Barry B. Fish, Viet Pham, Binghe Gu, Brandon A. Rodriguez
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Patent number: 9233896Abstract: Processes for the production of chlorinated propenes are provided wherein a dehydrochlorination reaction occurs prior to a first chlorination reaction. The present processes make use of at least one reactor twice, i.e., at least two reactions occur in the same reactor. Cost and time savings are thus provided. Additional savings can be achieved by conducting more than two chlorination reactions, or all chlorination reactions, in one chlorination reactor, and/or by conducting more than two dehydrochlorination reactions, or all dehydrochlorination reactions, within a single dehydrochlorination reactor.Type: GrantFiled: August 4, 2012Date of Patent: January 12, 2016Assignee: Blue Cube IP LLCInventors: Max M. Tirtowidjojo, Barry B. Fish, David S. Laitar
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Patent number: 9233908Abstract: The instant invention provides cycloaliphatic diamines and a method of making the same. The cycloaliphatic diamines according to the instant invention comprise the reaction product of one or more cycloaliphatic cyanoaldehydes selected from the group consisting of 1,3-cyanocyclohexane carboxaldehyde, 1,4-cyanocyclohexane carboxaldehyde, mixtures thereof, and combinations thereof, hydrogen, and ammonia fed into a continuous reductive amination reactor system; wherein the one or more cycloaliphatic cyanoaldehydes, hydrogen, and ammonia are contacted with each other in the presence of one or more heterogeneous metal based catalyst systems at a temperature in the range of from 80° C. to about 160° C. and a pressure in the range of from 700 to 3500 psig; and wherein one or more cycloaliphatic diamines are formed; and wherein said one or more cycloaliphatic diamines are selected from the group consisting of 1,3-bis(aminomethyl)cyclohexane, 1,4-bis(aminomethyl)cyclohexane, combinations thereof, and mixtures thereof.Type: GrantFiled: July 30, 2010Date of Patent: January 12, 2016Assignee: Dow Global Technologies LLCInventors: Abraham D. Schuitman, Shawn D. Feist, Barry B. Fish, Daniel A. Hickman, Erich J. Molitor, Michael L. Tulchinsky
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Publication number: 20150344386Abstract: Processes for the production of chlorinated propenes are provided. The processes make use of 1,2-dichloropropane as a starting material and subject a feedstream comprising the same to an ionic chlorination process. At least a portion of any tri- and tetrachlorinated propanes not amenable to ionic chlorination conditions are removed from the ionic chlorination product stream, or, are subjected to chemical base dehydrochlorination step. In this way, recycle of intermediates not amenable to ionic chlorination reactions is reduced or avoided, as is the buildup of these intermediates within the process. Selectivity and, in some embodiments, yield of the process is thus enhanced.Type: ApplicationFiled: December 18, 2013Publication date: December 3, 2015Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: MAX M. TIRTOWIDJOJO, DAVID S. LAITAR, BARRY B. FISH, MATTHEW L. GRANDBOIS
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Publication number: 20150344387Abstract: Processes for the production of chlorinated propenes are provided. The present processes make use of 1,2-dichloropropane, a by-product in the production of chlorohydrin, as a low cost starting material. 1,1,1,2,2-pentachloropropane produced by the process is subjected to catalytic dehydrochlorination and build-up of the same within the process is avoided.Type: ApplicationFiled: December 17, 2013Publication date: December 3, 2015Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: MAX M. TIRTOWIDJOJO, DAVID S. LAITAR, BARRY B. FISH, WILLIAM J. KRUPER, Jr.
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Patent number: 9187403Abstract: The instant invention provides a process for separating one or more aliphatic diamines from reductive amination reaction solvents and impurities, and aliphatic diamines obtained via such a process. The process for separating one or more aliphatic diamines from reductive amination reaction solvents and impurities according to the instant invention comprises the steps of: (1) feeding one or more cycloaliphatic cyanoaldehydes, hydrogen, ammonia, and optionally one or more solvents into a continuous reductive amination reactor system; (2) contacting said one or more cycloaliphatic cyanoaldehydes, hydrogen, and ammonia with each other in the presence of one or more heterogeneous metal based catalyst systems at a temperature in the range of from 80° C. to about 160° C.Type: GrantFiled: July 30, 2010Date of Patent: November 17, 2015Assignee: Dow Global Technologies LLCInventors: Stacie Santhany, Patrick Ho Sing Au-Yeung, Gerald W. Dare, Shawn D. Feist, Barry B. Fish, Daniel A. Hickman, David Jean, Erich J. Molitor, Abraham D. Schuitman, Todd William Toyzan
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Patent number: 9056808Abstract: Processes for the production of chlorinated propenes are provided. The present processes make use of 1,2-dichloropropane, a by-product in the production of chlorohydrin, as a low cost starting material, alone or in combination with 1,2,3-trichloropropane. The present processes can also generate anhydrous HCl as a byproduct that can be removed from the process and used as a feedstock for other processes, providing further time and cost savings. Finally, the processes are advantageously conducted in the liquid phase, thereby presenting additional savings as compared to conventional, gas phase processes.Type: GrantFiled: May 18, 2012Date of Patent: June 16, 2015Assignee: Dow Global Technologies, LLCInventors: Max M. Tirtowidjojo, William J. Kruper, Jr., Barry B. Fish, David S. Laitar
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Patent number: 8907148Abstract: Processes for the production of chlorinated propenes are provided. The present processes make use of a feedstock comprising 1,2,3-trichloropropane and chlorinates the 1,1,2,3-tetrachloropropane generated by the process prior to a dehydrochlorination step. Production of the less desirable pentachloropropane isomer, 1,1,2,3,3-pentachloropropane, is thus minimized. The present processes provide better reaction yield as compared to conventional processes that require dehydrochlorination of 1,1,2,3-tetrachloropropane prior to chlorinating the same. The present process can also generate anhydrous HCl as a byproduct that can be removed from the process and used as a feedstock for other processes, while limiting the production of waste water, thus providing further time and cost savings.Type: GrantFiled: August 1, 2012Date of Patent: December 9, 2014Assignee: Dow Global Technologies LLCInventors: Max M. Tirtowidjojo, Barry B. Fish, David S. Laitar
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Patent number: 8907149Abstract: Processes for the production of chlorinated propenes are provided. The present processes make use of a feedstream comprising 1,2-dichloropropane, a by-product in the production of chlorohydrin, as a low cost starting material, alone or in combination with 1,2,3-trichloropropane. Selectivity of the process is enhanced over conventional processes employing successive chlorinations and/or dehydrochlorinations, by conducting at least one chlorination in the presence of an ionic chlorination catalyst. The present processes may also generate anhydrous HCl as a byproduct that can be removed from the process and used as a feedstock for other processes, providing further time and cost savings.Type: GrantFiled: May 18, 2012Date of Patent: December 9, 2014Assignee: Dow Global Technologies LLCInventors: Max M. Tirtowidjojo, William J. Kruper, Jr., Barry B. Fish, David S. Laitar
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Publication number: 20140179962Abstract: Processes for the production of chlorinated propenes are provided wherein a dehydrochlorination reaction occurs prior to a first chlorination reaction. The present processes make use of at least one reactor twice, i.e., at least two reactions occur in the same reactor. Cost and time savings are thus provided. Additional savings can be achieved by conducting more than two chlorination reactions, or all chlorination reactions, in one chlorination reactor, and/or by conducting more than two dehydrochlorination reactions, or all dehydrochlorination reactions, within a single dehydrochlorination reactor.Type: ApplicationFiled: August 4, 2012Publication date: June 26, 2014Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Max M. Tirtowidjojo, Barry B. Fish, David S. Laitar
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Publication number: 20140163266Abstract: Processes for the production of chlorinated propenes are provided. The present processes make use of a feedstock comprising 1,2,3-trichloropropane and chlorinates the 1,1,2,3-tetrachloropropane generated by the process prior to a dehydrochlorination step. Production of the less desirable pentachloropropane isomer, 1,1,2,3,3-pentachloropropane, is thus minimized. The present processes provide better reaction yield as compared to conventional processes that require dehydrochlorination of 1,1,2,3-tetrachloropropane prior to chlorinating the same. The present process can also generate anhydrous HCl as a byproduct that can be removed from the process and used as a feedstock for other processes, while limiting the production of waste water, thus providing further time and cost savings.Type: ApplicationFiled: August 1, 2012Publication date: June 12, 2014Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Max M. Tirtowidjojo, Barry B. Fish, David S. Laitar
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Publication number: 20140163265Abstract: Processes for the production of chlorinated propenes are provided. The present processes make use of a feedstock comprising 1,2,3-trichloropropane and chlorinates the 1,1,2,3-tetrachloropropane generated by the process prior to a dehydrochlorination step. Production of the less desirable pentachloropropane isomer, 1,1,2,3,3-pentachloropropane, is thus minimized. The present processes provide better reaction yield as compared to conventional processes that require dehydrochlorination of 1,1,2,3-tetrachloropropane prior to chlorinating the same. The present process can also generate anhydrous HCl as a byproduct that can be removed from the process and used as a feedstock for other processes, while limiting the production of waste water, thus providing further time and cost savings.Type: ApplicationFiled: August 1, 2012Publication date: June 12, 2014Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Max M. Tirtowidjojo, Barry B. Fish, David S. Laitar
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Publication number: 20140100394Abstract: Processes for the production of chlorinated propenes are provided. The present processes make use of a feedstream comprising 1,2-dichloropropane, a by-product in the production of chlorohydrin, as a low cost starting material, alone or in combination with 1,2,3-trichloropropane. Selectivity of the process is enhanced over conventional processes employing successive chlorinations and/or dehydrochlorinations, by conducting at least one chlorination in the presence of an ionic chlorination catalyst. The present processes may also generate anhydrous HCl as a byproduct that can be removed from the process and used as a feedstock for other processes, providing further time and cost savings.Type: ApplicationFiled: May 18, 2012Publication date: April 10, 2014Applicant: DOW GLOBAL TECHNOLOGIES, LLCInventors: Max M. Tirtowidjojo, William J. Kruper, JR., Barry B. Fish, David S. Laitar
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Publication number: 20140081055Abstract: Processes for the production of chlorinated propenes are provided. The present processes make use of 1,2-dichloropropane, a by-product in the production of chlorohydrin, as a low cost starting material, alone or in combination with 1,2,3-trichloropropane. The present processes can also generate anhydrous HCl as a byproduct that can be removed from the process and used as a feedstock for other processes, providing further time and cost savings. Finally, the processes are advantageously conducted in the liquid phase, thereby presenting additional savings as compared to conventional, gas phase processes.Type: ApplicationFiled: May 18, 2012Publication date: March 20, 2014Applicant: DOW GLOBAL TECHNOLOGIES, LLCInventors: Max M. Tirtowidjojo, William J. Kruper, JR., Barry B. Fish, David S. Laitar
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Patent number: 8586793Abstract: Aldehyde or ketone compounds having more than one carbonyl group are reductively aminated to form a product amine compound having more than one primary amino group. The aldehyde or ketone compound is reacted with the product amine compound, to form a reaction mixture that contains one or more intermediates. The intermediate is then reductively aminated to form the desired product. This process produces the desired product in very high yields with low levels of secondary amine impurities.Type: GrantFiled: June 29, 2006Date of Patent: November 19, 2013Assignee: Dow Global Technologies LLCInventors: Michael Leo Tulchinsky, Barry B. Fish
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Publication number: 20120123165Abstract: The instant invention provides cycloaliphatic diamines and a method of making the same. The cycloaliphatic diamines according to the instant invention comprise the reaction product of one or more cycloaliphatic cyanoaldehydes selected from the group consisting of 1,3-cyanocyclohexane carboxaldehyde, 1,4-cyanocyclohexane carboxaldehyde, mixtures thereof, and combinations thereof, hydrogen, and ammonia fed into a continuous reductive amination reactor system; wherein the one or more cycloaliphatic cyanoaldehydes, hydrogen, and ammonia are contacted with each other in the presence of one or more heterogeneous metal based catalyst systems at a temperature in the range of from 80° C. to about 160° C. and a pressure in the range of from 700 to 3500 psig; and wherein one or more cycloaliphatic diamines are formed; and wherein said one or more cycloaliphatic diamines are selected from the group consisting of 1,3-bis(aminomethyl)cyclohexane, 1,4-bis(aminomethyl)cyclohexane, combinations thereof, and mixtures thereof.Type: ApplicationFiled: July 30, 2010Publication date: May 17, 2012Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Abraham D. Schuitman, Shawn D. Feist, Barry B. Fish, Daniel A. Hickman, Erich J. Molitor, Michael L. Tulchinsky
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Publication number: 20120116123Abstract: The instant invention provides a process for separating one or more aliphatic diamines from reductive amination reaction solvents and impurities, and aliphatic diamines obtained via such a process. The process for separating one or more aliphatic diamines from reductive amination reaction solvents and impurities according to the instant invention comprises the steps of: (1) feeding one or more cycloaliphatic cyanoaldehydes, hydrogen, ammonia, and optionally one or more solvents into a continuous reductive amination reactor system; (2) contacting said one or more cycloaliphatic cyanoaldehydes, hydrogen, and ammonia with each other in the presence of one or more heterogeneous metal based catalyst systems at a temperature in the range of from 80° C. to about 160° C.Type: ApplicationFiled: July 30, 2010Publication date: May 10, 2012Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Stacie Santhany, Patrick Ho Sing Au-Yeung, Gerald W. Dare, Shawn D. Feist, Barry B. Fish, Daniel A. Hickman, David Jean, Erich J. Molitor, Abraham D. Schuitman, Todd William Toyzan
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Patent number: 8129436Abstract: The present invention provides a method for simplifying manufacture of a mixed alcohol or mixed oxygenate product from synthesis gas. The mixed alcohol or mixed oxygenate product contains ethanol and other oxygenates with two or more carbon atoms per molecule. The method includes stripping a portion of carbon dioxide and inert gases contained in a mixed alcohol synthesis reaction product using a methanol-containing stream, such as one produced as part of the method, as a medium to absorb said carbon dioxide and inert gases and recycling light products and heavy products to one or more of synthesis gas generation, mixed alcohol synthesis and separation of desired mixed alcohol or mixed oxygenate products from other components of a mixed alcohol synthesis stream.Type: GrantFiled: March 21, 2007Date of Patent: March 6, 2012Assignee: Dow Global Technologies LLCInventors: Max M. Tirtowidjojo, Barry B. Fish, Hendrik L. Pelt, Dennis W. Jewell, Mark D. Bearden, John G. Pendergast, Jr., Jon H. Siddall, Brien A. Stears, Haivan D. Tran, Jan W. Verwijs, Aaltje Verwijs-van den Brink, legal representative, Lena Verwijs, legal representative, Hendrika Gerrita Verwijs, legal representative, Richard M. Wehmeyer