Patents by Inventor Bilge Yilmaz

Bilge Yilmaz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9181145
    Abstract: The present invention relates to a process for the alkylation of an organic compound comprising: (a) providing a catalyst comprising one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and optionally comprises X2O3, wherein Y is a tetravalent element, and X is a trivalent element, (b) contacting the catalyst with one or more alkylatable organic compounds in the presence of one or more alkylating agents in one or more reactors for obtaining one or more alkylated organic compounds, wherein the one or more zeolitic materials is obtainable from a synthetic process which does not employ an organotemplate as structure directing agent.
    Type: Grant
    Filed: April 3, 2012
    Date of Patent: November 10, 2015
    Assignees: BASF SE, Tokyo Institute of Technology
    Inventors: Bilge Yilmaz, Ulrich Müller, Faruk Özkirim, Dirk de Vos, Feng-Shou Xiao, Takashi Tatsumi, Xinhe Bao, Weiping Zhang, Hermann Gies, Hiroyuki Imai, Bart Tijsebaert
  • Patent number: 9114991
    Abstract: Described is an organotemplate-free synthetic process for the production of a zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises: (1) preparing a mixture comprising seed crystals and one or more sources for YO2; and (2) crystallizing the mixture obtained in step (1); wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises one or more alkali metals M, and wherein the seed crystals comprise zeolitic material having an LEV-type framework structure.
    Type: Grant
    Filed: June 17, 2011
    Date of Patent: August 25, 2015
    Assignee: BASF SE
    Inventors: Bilge Yilmaz, Ulrich Müller, Meike Pfaff, Feng-Shou Xiao, Bin Xie, Haiyan Zhang
  • Publication number: 20150174559
    Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise catalytic microspheres containing a zeolite, a non-zeolitic component, and a rare earth component. The microspheres are modified with phosphorus. The FCC catalyst composition can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.
    Type: Application
    Filed: December 19, 2013
    Publication date: June 25, 2015
    Applicant: BASF Corporation
    Inventors: Gary M. Smith, Robert McGuire, JR., Bilge Yilmaz
  • Publication number: 20150174560
    Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles containing a non-zeolitic component and one or more boron oxide components. In embodiments, the FCC catalyst composition contains a zeolite component and optionally a rare earth component and a transition alumina. FCC catalytic compositions may comprise a first particle type containing one or more boron oxide components and a first matrix component mixed with a second particle type containing a second matrix component, and a zeolite. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.
    Type: Application
    Filed: December 19, 2013
    Publication date: June 25, 2015
    Applicant: BASF Corporation
    Inventors: Robert McGuire, JR., Gary M. Smith, Bilge Yilmaz
  • Publication number: 20150175899
    Abstract: Fluid catalytic cracking (FCC) processes are described, the processes utilizing one or more boron oxide components. Also described are FCC compositions and methods of manufacture. One or more boron oxide components on FCC compatible inorganic particles are added to a FCC unit to crack hydrocarbon feeds, resulting in lower hydrogen and coke yields.
    Type: Application
    Filed: December 19, 2013
    Publication date: June 25, 2015
    Applicant: BASF Corporation
    Inventors: Robert McGuire, JR., Gary M. Smith, Bilge Yilmaz
  • Publication number: 20150175900
    Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles first particle type comprising one or more boron oxide components and a first matrix component and a second particle type having a composition different from the first particle type, the second particle type comprising a second matrix component, a phosphorus component and 20% to 95% by weight of a zeolite component. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.
    Type: Application
    Filed: December 19, 2013
    Publication date: June 25, 2015
    Applicant: BASF Corporation
    Inventors: Gary M. Smith, Robert McGuire, JR., Bilge Yilmaz
  • Patent number: 9028795
    Abstract: The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material comprising YO2 and X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals, one or more sources for YO2, one or more sources for X2O3, and one or more solvents; (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material comprising YO2 and X2O3 as a crystallization product; wherein Y is a tetravalent element, and X is a trivalent element, and wherein at least a portion of the mother liquor obtained in step (2) is recycled to step (1) as a source for YO2, optionally after concentration of the mother liquor.
    Type: Grant
    Filed: September 7, 2012
    Date of Patent: May 12, 2015
    Assignee: BASF SE
    Inventors: Bilge Yilmaz, Ulrich Müller, Faruk Özkirim, Meike Pfaff, Mike Haas, Feng-Shou Xiao
  • Patent number: 9011815
    Abstract: The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material having a BEA framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals and at least one source for YO2; and (2) crystallizing the mixture; wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises at least one alkali metal M, wherein when the BEA framework additionally comprises X2O3, the mixture according to step (1) comprises at least one source for X2O3, and wherein the seed crystals comprise zeolitic material having a BEA framework structure, preferably zeolite Beta.
    Type: Grant
    Filed: October 17, 2012
    Date of Patent: April 21, 2015
    Assignee: BASF SE
    Inventors: Feng-Shou Xiao, Bin Xie, Ulrich Mueller, Bilge Yilmaz
  • Patent number: 8940652
    Abstract: A phosphorus modification of an FCC catalyst is provided by reducing the sodium content of the as formed catalyst, a first treatment with a phosphate solution, a second ammonium exchange to further reduce the sodium content of the phosphorus solution treated catalyst and a second treatment with a phosphate solution.
    Type: Grant
    Filed: November 5, 2012
    Date of Patent: January 27, 2015
    Assignee: BASF Corporation
    Inventors: Qi Fu, Chandrashekhar Pandurang Kelkar, Gary Smith, Bilge Yilmaz
  • Patent number: 8865121
    Abstract: The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material having a BEA framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals and at least one source for YO2; and (2) crystallizing the mixture; wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises at least one alkali metal M, wherein when the BEA framework additionally comprises X2O3; the mixture according to step (1) comprises at least one source for X2O3, and wherein the seed crystals comprise zeolitic material having a BEA framework structure, preferably zeolite Beta.
    Type: Grant
    Filed: June 18, 2009
    Date of Patent: October 21, 2014
    Assignee: BASF SE
    Inventors: Feng-Shou Xiao, Bin Xie, Ulrich Mueller, Bilge Yilmaz
  • Patent number: 8742189
    Abstract: The present invention relates to a catalyst for dehydroaromatizing C1-C4-aliphatics, said catalyst being obtainable by twice treating a zeolite from the group of MFI and MWW with NH4-containing mixtures, in each case with subsequent drying and calcination. The catalyst comprises molybdenum and, if appropriate, as further elements, Cu, Ni, Fe, Co, Mn, Cr, Nb, Ta, Zr, V, Zn and/or Ga. The present invention further provides a process for dehydroaromatizing a mixture comprising C1-C4-aliphatics by conversion in the presence of the catalyst.
    Type: Grant
    Filed: April 8, 2009
    Date of Patent: June 3, 2014
    Assignee: BASF SE
    Inventors: Frank Kiesslich, Joana Coelho Tsou, Bilge Yilmaz, Sebastian Ahrens, Thomas Heidemann, Veronika Will, Christian Bechtold
  • Patent number: 8710271
    Abstract: The present invention relates to a process for the preparation of a zeolitic material having a BEA framework structure comprising the steps of: (i) providing one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element; (ii) subjecting the one or more zeolitic materials provided in step (i) to a procedure for removing at least a portion of X, preferably tetrahedrally coordinated X, from the BEA framework structure; wherein the Y:X molar ratios of the one or more zeolitic materials provided in step (i) are respectively comprised in the range of from 1 to 50.
    Type: Grant
    Filed: April 3, 2012
    Date of Patent: April 29, 2014
    Assignees: BASF SE, Tokyo Institute of Technology
    Inventors: Bilge Yilmaz, Ulrich Müller, Faruk Özkirim, Takashi Tatsumi, Feng-Shou Xiao, Dirk de Vos, Xinhe Bao, Weiping Zhang, Hermann Gies, Hiroyuki Imai, Bart Tijsebaert
  • Publication number: 20140113981
    Abstract: Described is a process for the production of a pillared silicate. The process comprises (i) providing a layered silicate; (ii) interlayer expanding the layered silicate provided in step (i) comprising a step of treating the layered silicate with one or more swelling agents; (iii) treating the interlayer expanded silicate obtained in step (ii) with one or more hydrolyzable silicon containing compounds; (iv) treating the interlayer expanded compound obtained in step (iii) with an aqueous solution to obtain a pillared silicate; (v) removing at least a portion of the one or more swelling agents from the pillared silicate obtained in step (iv); and (vi) impregnating the pillared silicate obtained in step (v) with one or more elements selected from the group consisting of Fe, Ru, Ir, and combinations of two or more thereof. Also described is a pillared silicate optionally obtainable from said process and its use, in particular, in a process for the production of one or more olefins according to the invention.
    Type: Application
    Filed: October 17, 2013
    Publication date: April 24, 2014
    Applicant: BASF SE
    Inventors: Bilge Yilmaz, Ulrich Müller, Xinhe Bao, Weiping Zhang, Dirk de Vos, Takashi Tatsumi, Feng-Shou Xiao, Hermann Gies, Hiroyuki Imai
  • Publication number: 20130123096
    Abstract: The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material having a BEA framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals and at least one source for YO2; and (2) crystallizing the mixture; wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises at least one alkali metal M, wherein when the BEA framework additionally comprises X2O3, the mixture according to step (1) comprises at least one source for X2O3, and wherein the seed crystals comprise zeolitic material having a BEA framework structure, preferably zeolite Beta.
    Type: Application
    Filed: December 19, 2012
    Publication date: May 16, 2013
    Inventors: Feng-Shou XIAO, Bin Xie, Ulrich Mueller, Bilge Yilmaz
  • Publication number: 20130101503
    Abstract: The present invention relates to a process for the preparation of a zeolitic material having a CHA framework structure, said zeolitic material comprising zeolite crystals having a core-shell structure, wherein said process comprises the steps of (1) providing a mixture comprising one or more sources for Z2O5, one or more sources for X2O3, optionally one or more structure directing agents, and seed crystals having a CHA framework structure, wherein the CHA framework structure of the seed crystals comprises YO2, X2O3, and optionally Z2O5, and wherein the seed crystals have a diameter of 450 nm or greater; (2) crystallizing the mixture provided in (1) to afford zeolite crystals comprising a core of seed crystal provided in step (1) and a shell crystallized on the seed crystal; wherein Z is a pentavalent element, Y is a tetravalent element, and X is a trivalent element.
    Type: Application
    Filed: September 14, 2012
    Publication date: April 25, 2013
    Applicants: Tokyo Institute of Technology, BASF SE
    Inventors: Bilge Yilmaz, Ulrich Müller, Feng-Shou Xiao, Takashi Tatsumi, Dirk de Vos, Xinhe Bao, Weiping Zhang, Hermann Gies, Hiroyuki Imai, Bart Tijsebaert, Limin Ren, Chengguan Yang
  • Patent number: 8426332
    Abstract: The present invention relates to a pillared silicate compound comprising a layered silicate structure, and bridging metal atoms located between adjacent silicate layers of the silicate structure, wherein said bridging metal atoms form at least one covalent bond to each of the adjacent silicate layers, as well as a process for the preparation of a pillared silicate compound, and further includes a pillared silicate compound obtainable and or obtained according to said process, as well as a method of catalyzing a chemical reaction comprising the step of contacting one or more chemical compounds with the any of the aforementioned pillared silicate compounds.
    Type: Grant
    Filed: July 1, 2011
    Date of Patent: April 23, 2013
    Assignee: BASF SE
    Inventors: Bilge Yilmaz, Ulrich Müller, Trees De Baerdemaeker, Hermann Gies, Feng-Shou Xiao, Takashi Tatsumi, Xinhe Bao, Weiping Zhang, Dirk de Vos
  • Publication number: 20130090234
    Abstract: Described is an organotemplate-free synthetic process for the production of a zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises: (1) preparing a mixture comprising seed crystals and one or more sources for YO2; and (2) crystallizing the mixture obtained in step (1); wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises one or more alkali metals M, and wherein the seed crystals comprise zeolitic material having an LEV-type framework structure.
    Type: Application
    Filed: June 17, 2011
    Publication date: April 11, 2013
    Applicant: BASF SE
    Inventors: Bilge Yilmaz, Ulrich Müller, Meike Pfaff, Feng-Shou Xiao, Bin Xie, Haiyan Zhang
  • Publication number: 20130064758
    Abstract: The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material comprising YO2 and X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals, one or more sources for YO2, one or more sources for X2O3, and one or more solvents; (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material comprising YO2 and X2O3 as a crystallization product; wherein Y is a tetravalent element, and X is a trivalent element, and wherein at least a portion of the mother liquor obtained in step (2) is recycled to step (1) as a source for YO2, optionally after concentration of the mother liquor.
    Type: Application
    Filed: September 7, 2012
    Publication date: March 14, 2013
    Applicant: BASF SE
    Inventors: Bilge Yilmaz, Ulrich Müller, Faruk Özkirim, Meike Pfaff, Mike Haas, Feng-Shou Xiao
  • Publication number: 20130059723
    Abstract: The present invention relates to a process for the preparation of a zeolitic material having a structure comprising YO2 and optionally comprising X2O3, preferably comprising YO2 and X2O3, wherein said process comprises the steps of (1) providing a mixture comprising one or more ammonium compounds of which the ammonium cation has the formula (I): [R1R2NR3R4]+??(I) and further comprising one or more sources for YO2 and one or more sources for X2O3; (2) crystallizing the mixture provided in (1); wherein Y is a tetravalent element, and X is a trivalent element, and wherein in formula (I) R1 and R2 are independently from one another derivatized or underivatized methyl, and R3 and R4 are independently from one another derivatized or underivatized (C3-C5)alkyl, and wherein the molar ratio of ammonium cation having the formula (I) to Y in the mixture provided in step (1) and crystallized in step (2) is equal to or greater than 0.25.
    Type: Application
    Filed: September 6, 2012
    Publication date: March 7, 2013
    Applicant: BASF SE
    Inventors: Bilge Yilmaz, Ulrich Berens, Vijay Narayanan Swaminathan, Ulrich Müller, Gabriele Iffland, Laszlo Szarvas
  • Publication number: 20130004398
    Abstract: Described is an iron-containing zeolite wherein the number of iron sites, based on the zeolite, is greater than the number of cationic positions in the zeolite. Also described is an iron-containing zeolite preparable by gas phase reaction with iron pentacarbonyl, said zeolite having a greater specific surface area than iron-containing zeolites prepared analogously by ion exchange and/or being more hydrothermally stable than iron-containing zeolites prepared analogously by ion exchange, or wherein the number of iron clusters larger than 10 nm is less than 15% by weight, based on the total amount of iron. Further described is a process for preparing an iron-containing zeolitic material, which comprises doping with iron by means of a gas phase reaction using iron pentacarbonyl. Further described is a process for catalytic reduction of nitrogen oxides using catalysts comprising said iron-containing zeolitic materials.
    Type: Application
    Filed: December 13, 2010
    Publication date: January 3, 2013
    Applicant: BASF SE
    Inventors: Dirk A. Grossschmidt, Bilge Yilmaz, Dirk Klingler, Bernd Zoels