Abstract: A polymer comprising an optionally substituted first repeat unit off formula (1): wherein F is a divalent residue; each G in each occurrence is independently a divalent residue; r is at least 1; each p is independently 0 or 1 and each corresponding q is the other of 0 or 1; and G comprises a heteroatom in the case where n is 1.

Abstract: A crosslinking monomer for making a crosslinked polymer, said monomer comprising reactive leaving groups Y and Y1 located on the same or different aryl or heteroaryl groups of the monomer and a structural unit of general formula I: where Ar represents an aryl or heteroaryl group; Ar1 and Ar2 each independently represents a substituted or unsubstituted aryl or heteroaryl group and where any two of Ar, Ar1 and Ar2 may optionally be linked; Sp represents an optional spacer group; and X represents a crosslinkable group.

Abstract: A monomer having general Formula (I) which may be substituted or unsubstituted: where E and E are the same or different and are reactive groups capable of undergoing chain extension; X is O, S, NR5, R5C—CR6 or R5?CR6; Y is O, S, NR7, R7C—CR8 or R7C?CR8; R5, R6 R7 and R8 are the same or different and each is independently H or a substituent group; and each Ar is the same or different and is independently a substituted or unsubstituted aryl or heteroaryl group.

Abstract: A method of manufacturing an electroluminescent device which has an anode and a cathode and arranged between the anode and the cathode a light emissive layer, also includes an anode protection layer which protects the anode against the effects of converting a precursor polymer to a semiconductive conjugated polymer which constitutes the light emissive layer. This has been found to increase the brightness and half-life of devices.

Abstract: An optionally substituted oligomer or polymer comprising a repeat unit of formula (I); wherein each Ar1 and Ar3 is the same or different and independently represents an optionally substituted aryl or heteroaryl; n is at least 1; Ar2 represents an optionally substituted aryl or heteroaryl comprising a linking ring to which the two nitrogen atoms are both directly linked; and at least one of Ar2 and either or both of Ar1 is substituted with at least one substituent.

Abstract: An electroluminescent device comprising:—a first electrode for injection of positive charge carriers;—a second electrode for injection of negative charge carriers; and—an electroluminescent layer located between the first and second electrodes comprising a host material and a metal complex, wherein the host material comprises a polymer having a first repeat unit of formula (I): wherein each Ar is the same or different and independently represents an optionally substituted aryl or heteroaryl and any two Ar groups may be directly linked by a single bond.

Abstract: The instant invention relates to a new method for the synthesis of monomers and their use inter alia in the manufacture of semiconductive polymers. Monomers, in particular, asymmetric monomers, such as asymmetric fluorene compounds, are valuable material in the manufacture of semiconductive polymers. The know methods for producing asymmetric monomers, such as asymmetric fluorene compounds, are expensive due to the formation of by-products. The method according to the present invention avoids the formation of such by-products and is described in more detail in claims 1 to 14.

Abstract: A method for making a polymer containing a first repeat unit having formula: —Ar—N(R)—Ar(N(R?)—Ar)x— which may be substituted or unsubstituted where x or 0 or 1; each Ar is the same or different and independently is a substituted or unsubstituted aryl or heteroaryl group and R and R? each is hydrogen or a substituent group and a second repeat unit that is the same or different from the first repeat unit and comprises a substituted or unsubstituted, aryl or heteroaryl group.

Abstract: Monomers having the formula X1—Ar1-[triarylamine]—Ar2-X2 wherein the triarylamine unit comprises at least one nitrogen atom in the backbone of the monomer and at least three substituted or unsubstituted aryl or heteroaryl groups and wherein X1 and X2 are the same or different polymerizable groups and wherein Ar1 and Ar2 are the same or different substituted or unsubstituted aryl or heteroaryl groups. Polymers and copolymers comprising such monomers are also described. The polymers have particular application in organic optoelectronic devices such as organic electroluminescent devices and organic photovoltaic devices.

Abstract: A luminescent polymer comprising a triarylene repeat unit which comprises a triarylene of general formula (I) which is substituted or unsubstituted and an arylene repeat unit -[-Ar-]- that is different from the triarylene repeat unit wherein X, Y, and Z are each independently O, S, CR2, SiR2 or NR and each R is independently alkyl, aryl or H.

Abstract: A polymer comprising an optionally substituted first repeal unit off formula (1): wherein F is a divalent residue; each Gin each occurrence is independently a divalent residue; r is at least 1; each p is independently 0 or 1 and each corresponding q is the other of 0 or 1: and G comprises a het-eroatom in the case where n is 1.

Abstract: A polymer containing an optionally substituted repeat unit of formula (I) wherein each R is the same or different and represents H or an electron withdrawing group, and each R1 is the same or different and represents a substituent.

Abstract: A polymer for use in an optical device comprising one or more regions, where each region comprises (i) a first structural unit having general formula I: where m=1 or 2 and which contains at least one substituent selected from the group consisting of alkyl, alkoxy, aryl, aryloxy, heteroaryl, and heteroaryloxy groups, each of which may be further substituted; and (ii) a second structural unit Ar selected from the group consisting of heteroaryl, triarylamine and 2,7-fluorenyl; such that where m=1 each region comprises a unit having general formula II: wherein, the substituent has a molecular weight of less than 300.

Abstract: An oligomer or polymer comprising a first repeat unit and a second repeat unit that may be the same or different, the first repeat unit having formula (I): wherein each E independently represents optionally substituted nitrogen or optionally substituted phosphorus, with the proviso that at least one E is optionally substituted phosphorus; each Ar1, Ar2 and Ar3 is the same or different and independently represents an optionally substituted aryl or heteroaryl; n is 0-3; and in the case of unsubstituted nitrogen and phosphorus, the second repeat unit is directly conjugated to the first repeat unit.

Abstract: A process for preparing high molecular weight polymers or copolymers by Suzuki coupling. The catalyst used in the process comprises a source of palladium and a source of a phosphine characterized in that at least one substituent on the phosphine is an ortho substituted aryl group. The process is suitable for the preparation of polymers for use in electronic and optoelectronic applications.

Abstract: An electroluminescent device which has an anode (4) and a cathode (10) and arranged between the anode (4) and the cathode (10) a light emissive layer (8). Also included between the light emissive layer and the anode is a dielectric layer, a carbon or amorphous silicon layer, or a layer of conductive oxide such as tin oxide, vanadium oxide, molybdenum oxide and nickel oxide.

Abstract: A polymer for use in an optical device comprising one or more regions, where each region comprises (i) a first structural unit having general formula I: where m=1 or 2 and which contains at least one substituent selected from the group consisting of alkyl, alkoxy, aryl, aryloxy, heteroaryl, and heteroaryloxy groups, each of which may be further substituted; and (ii) a second structural unit Ar selected from the group consisting of heteroaryl, triarylamine and 2,7-fluorenyl; such that where m=1 each region comprises a unit having general formula II: first structural unit—Ar??(II) wherein, the substituent has a molecular weight of less than 300.

Abstract: A method of manufacturing an electroluminescent device which has an anode and a cathode and arranged between the anode and the cathode a light emissive layer, also includes an anode protection layer which protects the anode against the effects of converting a precursor polymer to a semiconductive conjugated polymer which constitutes the light emissive layer. This has been found to increase the brightness and half-life of devices.

Abstract: A process for preparing a conjugated polymer, which comprises polymerizing in a reaction mixture (a) an aromatic monomer having at least two boron derivative functional groups selected from the group consisting of boronic acid groups, boronic ester groups, and borane groups, and an aromatic monomer having at least two reactive halide functional groups, or (b) an aromatic monomer having one reactive halide functional group and one boron derivative functional group selected from the group consisting of boronic acid groups, boronic ester groups, and borane groups, an amount of a catalyst suitable for catalyzing the polymerization of the aromatic monomers, and a base in an amount sufficient to convert the boron derivative functional groups into boron anionic groups, characterized in that the reaction mixture further comprises a first solvent and a second solvent with which said first solvent is substantially immiscible and an emulsifier in an amount sufficient to form an emulsion of the reaction mixture.

Abstract: The present invention relates to new semiconductive oligomers and polymers, a process for their manufacture and their use in thin film electronic and optical devices, such as organic light emitting diodes (OLED) and photovoltaic devices, eg. solar cells and photodetectors.