Abstract: A vulcanizate of a rubber mixture for a vehicle tire, the rubber mixture containing at least one filler and 10 to 100 phr of at least one polymer A of the following formula: PS—R1—S—R2)n where S is a sulfur atom, and P is a polymer chain which is obtainable by anionic polymerization of at least one conjugated diene and optionally one or more vinylaromatic compounds and which has optionally been chain end-modified, R1 is most preferably C1-C8-alkyl, R2 is preferably selected from H and —SiR3R4R5 in which R3, R4 and R5 are independently selected from H, C1-C16-alkyl, C6-C16-aryl and C7-C16-aralkyl, and n is an integer selected from 1 to 200, where the —S—R1—S—R2 group(s) are bonded to the backbone of the polymer chain P.

Abstract: Modified thermoplastic hydrocarbon thermoplastic resins are provided, as well as methods of their manufacture and uses thereof in rubber compositions. The modified thermoplastic resins are modified by decreasing the relative quantity of the dimer, trimer, tetramer, and pentamer oligomers as compared to the corresponding unmodified thermoplastic resin polymers, resulting in a product that exhibits a greater shift in the glass transition temperature of the elastomer(s) used in tire formulations. This translates to better viscoelastic predictors of tire tread performance, such as wet grip and rolling resistance. The modified thermoplastic resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the modified thermoplastic resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, snow performance, and wet braking performance.

Abstract: Disclosed are monomers for copolymerization with alkenes, dienes, vinyl compounds, and/or vinylidene compounds, a process for preparing a copolymer, a copolymer prepared by the process, a sulfur-crosslinkable rubber mixture, and the use of the sulfur-crosslinkable rubber mixture for production of motor vehicle tires. In one embodiment, the monomer has the formula A-S—P, wherein A is a chemical group containing at least one C?C aliphatic double bond, S is a sulfur atom, and P is a protecting group.

Abstract: Disclosed are RAFT agents, a method of polymerizing alkenes, dienes, vinyl compounds, and/or vinylidene compounds using at least one RAFT agent, polymers prepared by the methods, sulfur-crosslinkable rubber mixtures prepared by the methods, and motor vehicle tires, cords, belts, or hoses incorporating the sulfur-crosslinkable rubber mixtures. In one embodiment, the RAFT agent has the formula Z—C(?S)—S—R—S—P or P—S—Z—C(?S)—S—R—S—P, wherein P is a protecting group, and Z and R are typical RAFT Z and R groups.

Abstract: The invention relates to a sulfur-crosslinkable rubber mixture, in particular for rubber-coating reinforcements in elastomer products, especially in vehicle tires, or inner components of vehicle tires, as well as to a vehicle tire.

Abstract: The invention relates to a sulfur-crosslinkable rubber mixture, containing: a rubber blend of at least one high-molecular-weight, solution-polymerized diene polymer A and at least one low-molecular-weight, solution-polymerized polymer B, wherein at least one of the polymers A or B is functionalized at the chain end and/or along the polymer chain and/or in a coupling center with at least one group selected from epoxy groups, hydroxy groups, carboxy groups, silane-sulfide groups, amino groups, siloxane groups, organosilicon groups, phthalocyanine groups, and from alkoxysilyl groups containing amino groups, and as a filler, at least one silicic acid and/or at least one carbon black in an amount of 25 to 300 phr, wherein the ratio of carbon black to silicic acid in the mixture is 100:0 to 3:97.

Abstract: The invention relates to a rubber blend, to a sulfur-crosslinkable rubber mixture comprising the rubber blend and to a vehicle tire comprising such a rubber mixture. The rubber blend comprises at least one solution-polymerized diene polymer A of high molecular weight and at least one solution-polymerized polymer B of low molecular weight, wherein at least one of polymers A and B has been functionalized at the chain end and/or along the polymer chain and/or at a coupling site with at least one group selected from epoxy groups, hydroxyl groups, carboxyl groups, silane sulfide groups, amino groups, siloxane groups, organosilicon groups, phthalocyanine groups and amino group-containing alkoxysilyl groups and wherein the rubber blend includes 35 to 100 phr (based on the at least one solution-polymerized diene polymer A of high molecular weight), preferably 35 to 70 phr, of the at least one solution-polymerized polymer B of low molecular weight.

Abstract: The invention relates to a sulfur-crosslinkable rubber mixture comprising a rubber blend composed of at least one solution-polymerized diene polymer A of high molecular weight and at least one solution-polymerized polymer B of low molecular weight, wherein at least one of polymers A and B has been functionalized at the chain end and/or along the polymer chain and/or at a coupling site with at least one group selected from epoxy groups, hydroxyl groups, carboxyl groups, silane sulfide groups, amino groups, siloxane groups, organosilicon groups, phthalocyanine groups and amino group-containing alkoxysilyl groups, 30 to 300 phr of at least one silica and 1 to 20 phf of at least one substance of formula I) as silane coupling agent (R1R2R3)Si—S4—Si(R3R2R1)??II) where R1, R2, R3 in the structure may be the same or different and may be selected from linear or branched alkoxy, cycloalkoxy, alkyl, cycloalkyl or aryl groups having 1 to 20 carbon atoms.

Abstract: A sulfur-crosslinkable rubber mixture includes from 40 to 100 phr of at least one natural and/or synthetic polyisoprene, and 15 phr or more of at least one hydrocarbon resin which is built up to the extent of 50 to 100 wt. % from aliphatic C5 monomers and to the extent of 0 to 50 wt. % from further monomers, where the hydrocarbon resin according to formula I) has a Q of from 0.015 [° C.·mol/g] to 0.050 [° C.·mol/g]. Formula I) is defined as Q=softening point [° C.]/centrifuge average Mc [g/mol]. In some aspects, the sulfur-crosslinkable rubber mixture includes 15 to 300 phr of the hydrocarbon resin, or even from 36 to 100 phr of the hydrocarbon resin. The further monomer(s) is or are selected from the group of unsaturated compounds, which can be polymerized cationically, which includes aromatics and/or unsaturated terpenes and/or alkenes and/or cycloalkenes.

Abstract: The invention relates to a sulfur-crosslinkable rubber mixture, in particular for treads of vehicle tires, and to a vehicle tire. The rubber mixture contains at least the following components: at least one diene rubber and 10 to 200 phr of at least one silicic acid and 2 to 20 phf of at least one silane having general empirical formula I) [(R1)3Si—X]mSn(R2)2-m, wherein the residues R1 within a molecule can be the same or different and are alkoxy groups having 1 to 10 carbon atoms or cyclic dialkoxy groups having 2 to 10 carbon atoms or cycloalkoxy groups having 4 to 10 carbon atoms or phenoxy groups or aryl groups having 6 to 20 carbon atoms or alkyl groups having 1 to 10 carbon atoms or alkenyl groups having 2 to 20 carbon atoms or aralkyl groups having 7 to 20 carbon atoms or halides and wherein X is a polar organic group containing urea and wherein m assumes the value 1 or 2 and wherein n is an integer from 1 to 8 and wherein R2 is a hydrogen atom or an acyl group having 1 to 20 carbon atoms.

Abstract: Polar silane linkers are provided that attach to resins to form silane-functionalized resins. The functionalized resins can be bound to hydroxyl groups on the surface of silica particles to improve the dispersibility of the silica particles in rubber mixtures. Further disclosed are synthetic routes to provide the silane-functionalized resins, as well as various uses and end products that benefit from the unexpected properties of the silane-functionalized resins. Silane-functionalized resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the silane-functionalized resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, and wet braking performance.

Abstract: Polar silane linkers are provided that attach to resins to form silane-functionalized resins. The functionalized resins can be bound to hydroxyl groups on the surface of silica particles to improve the dispersibility of the silica particles in rubber mixtures. Further disclosed are synthetic routes to provide the silane-functionalized resins, as well as various uses and end products that benefit from the unexpected properties of the silane-functionalized resins. Silane-functionalized resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the silane-functionalized resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, and wet braking performance.

Abstract: Polar silane linkers are provided that attach to resins to form silane-functionalized resins. The functionalized resins can be bound to hydroxyl groups on the surface of silica particles to improve the dispersibility of the silica particles in rubber mixtures. Further disclosed are synthetic routes to provide the silane-functionalized resins, as well as various uses and end products that benefit from the unexpected properties of the silane-functionalized resins. Silane-functionalized resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the silane-functionalized resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, and wet braking performance.

Abstract: Modified thermoplastic hydrocarbon thermoplastic resins are provided, as well as methods of their manufacture and uses thereof in rubber compositions. The modified thermoplastic resins are modified by decreasing the relative quantity of the dimer, trimer, tetramer, and pentamer oligomers as compared to the corresponding unmodified thermoplastic resin polymers, resulting in a product that exhibits a greater shift in the glass transition temperature of the elastomer(s) used in tire formulations. This translates to better viscoelastic predictors of tire tread performance, such as wet grip and rolling resistance. The modified thermoplastic resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the modified thermoplastic resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, snow performance, and wet braking performance.

Abstract: Modified thermoplastic hydrocarbon thermoplastic resins are provided, as well as methods of their manufacture and uses thereof in rubber compositions. The modified thermoplastic resins are modified by decreasing the relative quantity of the dimer, trimer, tetramer, and pentamer oligomers as compared to the corresponding unmodified thermoplastic resin polymers, resulting in a product that exhibits a greater shift in the glass transition temperature of the elastomer(s) used in tire formulations. This translates to better viscoelastic predictors of tire tread performance, such as wet grip and rolling resistance. The modified thermoplastic resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the modified thermoplastic resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, snow performance, and wet braking performance.

Abstract: Modified thermoplastic hydrocarbon thermoplastic resins are provided, as well as methods of their manufacture and uses thereof in rubber compositions. The modified thermoplastic resins are modified by decreasing the relative quantity of the dimer, trimer, tetramer, and pentamer oligomers as compared to the corresponding unmodified thermoplastic resin polymers, resulting in a product that exhibits a greater shift in the glass transition temperature of the elastomer(s) used in tire formulations. This translates to better viscoelastic predictors of tire tread performance, such as wet grip and rolling resistance. The modified thermoplastic resins impart remarkable properties on various rubber compositions, such as tires, belts, hoses, brakes, and the like. Automobile tires incorporating the modified thermoplastic resins are shown to possess excellent results in balancing the properties of rolling resistance, tire wear, snow performance, and wet braking performance.

Abstract: A process for producing an environmentally-friendly plasticizer, which is particularly suitable for use in vehicle tires or technical rubber articles. A vulcanized and/or unvulcanized polymer material of a high molecular weight is converted into a low-molecular phase by direct thermal liquefaction. The vulcanized and/or unvulcanized high-molecular-weight polymer material is provided as a polymer powder and/or a granulated polymer and can be obtained from used tires.

Abstract: Disclosed are RAFT agents, a method of polymerizing alkenes, dienes, vinyl compounds, and/or vinylidene compounds using at least one RAFT agent, polymers prepared by the methods, sulfur-crosslinkable rubber mixtures prepared by the methods, and motor vehicle tires, cords, belts, or hoses incorporating the sulfur-crosslinkable rubber mixtures. In one embodiment, the RAFT agent has the formula Z—C(?S)—S—R—S—P or P—S—Z—C(?S)—S—R—S—P, wherein P is a protecting group, and Z and R are typical RAFT Z and R groups.

Abstract: Disclosed are processes for preparing a copolymer, a copolymer prepared by the process, a sulfur-crosslinkable rubber mixture, and the use of the sulfur-crosslinkable rubber mixture for production of motor vehicle tires. In one embodiment, the monomer has the formula: A-S—P, wherein A is a chemical group containing at least one aliphatic double bond, S is a sulfur atom, and P is a protecting group.

Abstract: Disclosed are monomers for copolymerization with alkenes, dienes, vinyl compounds, and/or vinylidene compounds, a process for preparing a copolymer, a copolymer prepared by the process, a sulfur-crosslinkable rubber mixture, and the use of the sulfur-crosslinkable rubber mixture for production of motor vehicle tires. In one embodiment, the monomer has the formula A-S-P, wherein A is a chemical group containing at least one C?C aliphatic double bond, S is a sulfur atom, and P is a protecting group.