Patents by Inventor Carlos Cruz

Carlos Cruz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11499040
    Abstract: Provided is a dispersion of composite particles in an aqueous medium, wherein the composite particles comprise (I) a crosslinked polyolefin core, and (II) a full or partial shell comprising polymerized units of one of more vinyl monomers.
    Type: Grant
    Filed: November 29, 2018
    Date of Patent: November 15, 2022
    Assignees: Rohm and Haas Company, Dow Global Technologies LLC
    Inventors: Liang Chen, Andy Jun Li, Matthew Carter, Robert S. Moglia, Ralph C. Even, John F. Kohn, Carlos A. Cruz, Yannick Saint-Gerard, Douglas J. Hasso, Miroslav Janco
  • Publication number: 20220359352
    Abstract: An electronic package includes an electronic component including terminals, a plurality of leads, at least some of the leads being electrically coupled to the terminals within the electronic package, and a mold compound covering the electronic component and partially covering the leads. Each of the leads include an exposed bottom face coplanar with a bottom surface of the mold compound and an exposed end face coplanar with one of a plurality of side surfaces of the mold compound. For at least some of the leads, the exposed end face includes a narrow portion forming a concave recess, the narrow portion being between top and bottom edges of the exposed end face.
    Type: Application
    Filed: May 10, 2021
    Publication date: November 10, 2022
    Inventors: Dolores Babaran Milo, Ernesto Pentecostes Rafael, JR., John Carlo Cruz Molina
  • Publication number: 20220356135
    Abstract: Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed, and these processes include the steps of irradiating the hydrocarbon reactant and a supported chromium catalyst comprising chromium in a hexavalent oxidation state with a light beam at a wavelength in the UV-visible spectrum to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the alcohol compound and/or the carbonyl compound. In addition, these processes can further comprise a step of calcining all or a portion of the reduced chromium catalyst to regenerate the supported chromium catalyst.
    Type: Application
    Filed: July 14, 2022
    Publication date: November 10, 2022
    Inventors: Max P. McDaniel, Carlos A. Cruz, Masud M. Monwar, Jared L. Barr, William C. Ellis
  • Patent number: 11492430
    Abstract: Catalyst compositions containing a metallocene compound, a solid activator, and a co-catalyst, in which the solid activator or the supported metallocene catalyst has a d50 average particle size of 15 to 50 ?m and a particle size distribution of 0.5 to 1.5, can be contacted with an olefin in a loop slurry reactor to produce an olefin polymer. A representative ethylene-based polymer produced using the catalyst composition has excellent dart impact strength and low gels, and can be characterized by a HLMI from 4 to 10 g/10 min, a density from 0.944 to 0.955 g/cm3, a higher molecular weight component with a Mn from 280,000 to 440,000 g/mol, and a lower molecular weight component with a Mw from 30,000 to 45,000 g/mol and a ratio of Mz/Mw ranging from 2.3 to 3.4.
    Type: Grant
    Filed: February 3, 2022
    Date of Patent: November 8, 2022
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Max P. McDaniel, Carlton E. Ash, Kathy S. Clear, Eric D. Schwerdtfeger, Carlos A. Cruz, Jeremy M. Praetorius
  • Publication number: 20220348527
    Abstract: Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed, and these processes include the steps of forming a supported chromium catalyst comprising chromium in a hexavalent oxidation state, irradiating the hydrocarbon reactant and the supported chromium catalyst with a light beam at a wavelength in the UV-visible spectrum to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the alcohol compound and/or the carbonyl compound. The supported chromium catalyst can be formed by heat treating a supported chromium precursor, contacting a chromium precursor with a solid support while heat treating, or heat treating a solid support and then contacting a chromium precursor with the solid support.
    Type: Application
    Filed: July 19, 2022
    Publication date: November 3, 2022
    Inventors: Carlos A. Cruz, Masud M. Monwar, Max P. McDaniel, Jared Barr, Kathy S. Clear, William C. Ellis
  • Patent number: 11482132
    Abstract: A device for providing a tactile feedback includes an imaging device configured to capture an image of a face of a subject, a tactile feedback device, and a controller communicatively coupled to the imaging device and the tactile feedback device. The controller comprising at least one processor and at least one memory storing computer readable and executable instructions that, when executed by the processor, causes the controller to: process the image, determine a type of a facial expression based on the processed image, determine a level of a facial expression of the type based on the processed image, determine a tactile feedback intensity of the tactile feedback device based on the level of the facial expression, and control the tactile feedback device to provide a tactile feedback having the tactile feedback intensity.
    Type: Grant
    Filed: February 1, 2017
    Date of Patent: October 25, 2022
    Assignee: Toyota Motor Engineering & Manufacturing North America, Inc.
    Inventor: Carlo Cruz
  • Publication number: 20220324776
    Abstract: Processes for cracking an alkane reactant to form a lower aliphatic hydrocarbon product and for converting an alkane reactant into a higher aliphatic hydrocarbon product are disclosed, and these processes include a step of contacting the alkane reactant with a supported chromium (II) catalyst. In addition to the formation of various aliphatic hydrocarbons, such as linear alkanes, branched alkanes, 1-alkenes, and internal alkenes, aromatic hydrocarbons and hydrogen also can be produced.
    Type: Application
    Filed: June 23, 2022
    Publication date: October 13, 2022
    Inventors: Carlos A. Cruz, Max P. McDaniel, Masud M. Monwar, Jared Barr
  • Publication number: 20220320038
    Abstract: In a described example, a method includes: forming cavities in a die mount surface of a package substrate, the cavities extending into the die mount surface of the package substrate at locations corresponding to post connects on a semiconductor die to be flip-chip mounted to the package substrate; placing flux in the cavities; placing solder balls on the flux; and performing a thermal reflow process and melting the solder balls to form solder pads in the cavities on the package substrate.
    Type: Application
    Filed: March 31, 2021
    Publication date: October 6, 2022
    Inventors: Rafael Jose Lizares Guevara, Juan Carlo Cruz Molina, Steffany Ann Lacierda Moreno
  • Publication number: 20220289880
    Abstract: Ethylene-based polymers are generally characterized by a high load melt index of less than 12 g/10 min, a weight-average molecular weight from 200,000 to 550,000 g/mol, a number-average molecular weight from 18,000 to 48,000 g/mol, a CY-a parameter of less than 0.12, a tan ? at 0.1 sec?1 from 0.5 to 0.9 degrees, a tan ? at 100 sec?1 from 0.5 to 0.75 degrees, and a viscosity at 0.001 sec?1 from 1.3×106 to 1×107 Pa-sec. These ethylene polymers can be produced by peroxide-treating a bimodal molecular weight distribution dual metallocene-catalyzed resin, and can be used to produce blow molded bottles and other blow molded products.
    Type: Application
    Filed: March 15, 2021
    Publication date: September 15, 2022
    Inventors: Carlos A. Cruz, Yongwoo Inn, John R. Rathman, Youlu Yu, Ashish M. Sukhadia, Jay M. Chaffin
  • Patent number: 11440864
    Abstract: Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed, and these processes include the steps of irradiating the hydrocarbon reactant and a supported chromium catalyst comprising chromium in a hexavalent oxidation state with a light beam at a wavelength in the UV-visible spectrum to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the alcohol compound and/or the carbonyl compound. In addition, these processes can further comprise a step of calcining all or a portion of the reduced chromium catalyst to regenerate the supported chromium catalyst.
    Type: Grant
    Filed: July 12, 2021
    Date of Patent: September 13, 2022
    Assignee: Chevron Phillips Chemical Company, LP
    Inventors: Max P. McDaniel, Carlos A. Cruz, Masud M. Monwar, Jared L. Barr, William C. Ellis
  • Patent number: 11440865
    Abstract: Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed, and these processes include the steps of forming a supported chromium catalyst comprising chromium in a hexavalent oxidation state, irradiating the hydrocarbon reactant and the supported chromium catalyst with a light beam at a wavelength in the UV-visible spectrum to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the alcohol compound and/or the carbonyl compound. The supported chromium catalyst can be formed by heat treating a supported chromium precursor, contacting a chromium precursor with a solid support while heat treating, or heat treating a solid support and then contacting a chromium precursor with the solid support.
    Type: Grant
    Filed: October 14, 2021
    Date of Patent: September 13, 2022
    Assignee: Chevron Phillips Chemical Company, LP
    Inventors: Carlos A. Cruz, Masud M. Monwar, Max P. McDaniel, Jared L. Barr, Kathy S. Clear, William C. Ellis
  • Publication number: 20220275183
    Abstract: Ethylene-based polymers having a density of 0.952 to 0.965 g/cm3, a high load melt index (HLMI) from 5 to 25 g/10 min, a weight-average molecular weight from 275,000 to 450,000 g/mol, a number-average molecular weight from 15,000 to 40,000 g/mol, a viscosity at HLMI from 1400 to 4000 Pa-sec, and a tangent delta at 0.1 sec?1 from 0.65 to 0.98 degrees. These polymers have the processability of chromium-based resins, but with improved stress crack resistance, and can be used in large-part blow molding applications.
    Type: Application
    Filed: May 17, 2022
    Publication date: September 1, 2022
    Inventors: Carlos A. Cruz, Yongwoo Inn, Justin Lumbley, Brandy Rutledge-Ryal, John R. Rathman, Jennifer L. Hicks, Jay M. Chaffin
  • Publication number: 20220266231
    Abstract: Supported chromium catalysts with an average valence less than +6 and having a hydrocarbon-containing or halogenated hydrocarbon-containing ligand attached to at least one bonding site on the chromium are disclosed, as well as ethylene-based polymers with terminal alkane, aromatic, or halogenated hydrocarbon chain ends. Another ethylene polymer characterized by at least 2 wt. % of the polymer having a molecular weight greater than 1,000,000 g/mol and at least 1.5 wt. % of the polymer having a molecular weight less than 1000 g/mol is provided, as well as an ethylene homopolymer with at least 3.5 methyl short chain branches and less than 0.6 butyl short chain branches per 1000 total carbon atoms.
    Type: Application
    Filed: May 5, 2022
    Publication date: August 25, 2022
    Inventors: Masud M. Monwar, Carlos A. Cruz, Jared L. Barr, Max P. McDaniel
  • Patent number: 11414540
    Abstract: Provided is a method of modifying a blend of polycarbonate and acrylonitrile/butadiene/styrene copolymer comprising adding composite particles to the blend, wherein the composite particles comprise (I) a partially crosslinked polyolefin core and (II) a full or partial shell comprising polymerized units of one or more vinyl monomer, and the resulting modified blend.
    Type: Grant
    Filed: December 4, 2018
    Date of Patent: August 16, 2022
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Liang Chen, Carlos A. Cruz, Yannick Saint-Gerard, Jessica Ye Huang, Matthew J. Crimmins, Douglas J. Hasso
  • Patent number: 11401404
    Abstract: Provided is a process for making a dispersion of composite particles comprising (i) providing a dispersion of crosslinked polyolefin particles in an aqueous medium, (ii) performing emulsion polymerization on one or more vinyl monomers in the presence of the crosslinked polyolefin particles to produce the dispersion of composite particles.
    Type: Grant
    Filed: November 29, 2018
    Date of Patent: August 2, 2022
    Assignees: Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Liang Chen, Andy Jun Li, Matthew Carter, Robert S. Moglia, Ralph C. Even, Miroslav Janco, Carlos A. Cruz, Yannick Saint-Gerard
  • Patent number: 11396485
    Abstract: Processes for cracking an alkane reactant to form a lower aliphatic hydrocarbon product and for converting an alkane reactant into a higher aliphatic hydrocarbon product are disclosed, and these processes include a step of contacting the alkane reactant with a supported chromium (II) catalyst. In addition to the formation of various aliphatic hydrocarbons, such as linear alkanes, branched alkanes, 1-alkenes, and internal alkenes, aromatic hydrocarbons and hydrogen also can be produced.
    Type: Grant
    Filed: September 8, 2020
    Date of Patent: July 26, 2022
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Carlos A. Cruz, Max P. McDaniel, Masud M. Monwar, Jared L. Barr
  • Publication number: 20220227897
    Abstract: Supported chromium catalysts containing a solid oxide and 0.1 to 15 wt. % chromium, in which the solid oxide or the supported chromium catalyst has a particle size span from 0.5 to 1.4, less than 3 wt. % has a particle size greater than 100 ?m, and less than 10 wt. % has a particle size less than 10 ?m, can be contacted with an olefin monomer in a loop slurry reactor to produce an olefin polymer. Representative ethylene-based polymers produced using the chromium catalysts have a HLMI of 4 to 70 g/10 min, a density from 0.93 to 0.96 g/cm3, from 150 to 680 ppm solid oxide (such as silica), from 1.5 to 6.8 ppm chromium, and a film gel count of less than 15 catalyst particle gels per ft2 of 25 micron thick film and/or a gel count of less than or equal to 50 catalyst particles of greater than 100 ?m per five grams of the ethylene polymer.
    Type: Application
    Filed: April 8, 2022
    Publication date: July 21, 2022
    Inventors: Max P. McDaniel, Carlton E. Ash, Kathy S. Clear, Eric D. Schwerdtfeger, Carlos A. Cruz, Jeremy M. Praetorius, Youlu Yu
  • Patent number: 11376575
    Abstract: Supported chromium catalysts with an average valence less than +6 and having a hydrocarbon-containing or halogenated hydrocarbon-containing ligand attached to at least one bonding site on the chromium are disclosed, as well as ethylene-based polymers with terminal alkane, aromatic, or halogenated hydrocarbon chain ends. Another ethylene polymer characterized by at least 2 wt. % of the polymer having a molecular weight greater than 1,000,000 g/mol and at least 1.5 wt. % of the polymer having a molecular weight less than 1000 g/mol is provided, as well as an ethylene homopolymer with at least 3.5 methyl short chain branches and less than 0.6 butyl short chain branches per 1000 total carbon atoms.
    Type: Grant
    Filed: September 16, 2019
    Date of Patent: July 5, 2022
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Masud M. Monwar, Carlos A. Cruz, Jared L. Barr, Max P. McDaniel
  • Patent number: 11377541
    Abstract: Ethylene-based polymers having a density of 0.952 to 0.965 g/cm3, a high load melt index (HLMI) from 5 to 25 g/10 min, a weight-average molecular weight from 275,000 to 450,000 g/mol, a number-average molecular weight from 15,000 to 40,000 g/mol, a viscosity at HLMI from 1400 to 4000 Pa-sec, and a tangent delta at 0.1 sec?1 from 0.65 to 0.98 degrees. These polymers have the processability of chromium-based resins, but with improved stress crack resistance, and can be used in large-part blow molding applications.
    Type: Grant
    Filed: July 26, 2019
    Date of Patent: July 5, 2022
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Carlos A. Cruz, Yongwoo Inn, Justin Lumbley, Brandy Rutledge-Ryal, John R. Rathman, Jennifer L. Hicks, Jay M. Chaffin
  • Patent number: 11345649
    Abstract: Processes for converting an olefin reactant into a diol compound are disclosed, and these processes include the steps of contacting the olefin reactant and a supported chromium catalyst comprising chromium in a hexavalent oxidation state to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the diol compound. While being contacted, the olefin reactant and the supported chromium catalyst can be irradiated with a light beam at a wavelength in the UV-visible spectrum. Optionally, these processes can further comprise a step of calcining at least a portion of the reduced chromium catalyst to regenerate the supported chromium catalyst.
    Type: Grant
    Filed: August 19, 2021
    Date of Patent: May 31, 2022
    Assignee: Chevron Phillips Chemical Company, LP
    Inventors: Jared L. Barr, Carlos A. Cruz, Masud M. Monwar, Kathy S. Clear, Max P. McDaniel