Patents by Inventor Carlos Cruz

Carlos Cruz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11338278
    Abstract: Catalyst preparation systems and methods for preparing reduced chromium catalysts are disclosed, and can comprise irradiating a supported chromium catalyst containing hexavalent chromium with a light beam having a wavelength within the UV-visible light spectrum. Such reduced chromium catalysts have improved catalytic activity compared to chromium catalysts reduced by other means. The use of the reduced chromium catalyst in polymerization reactor systems and olefin polymerization processes also is disclosed, resulting in polymers with a higher melt index.
    Type: Grant
    Filed: September 8, 2021
    Date of Patent: May 24, 2022
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Kathy S. Clear, Max P. McDaniel, William C. Ellis, Eric D. Schwerdtfeger, Deloris R. Gagan, Carlos A. Cruz, Masud M. Monwar
  • Publication number: 20220153887
    Abstract: Catalyst compositions containing a metallocene compound, a solid activator, and a co-catalyst, in which the solid activator or the supported metallocene catalyst has a d50 average particle size of 15 to 50 ?m and a particle size distribution of 0.5 to 1.5, can be contacted with an olefin in a loop slurry reactor to produce an olefin polymer. A representative ethylene-based polymer produced using the catalyst composition has excellent dart impact strength and low gels, and can be characterized by a HLMI from 4 to 10 g/10 min, a density from 0.944 to 0.955 g/cm3, a higher molecular weight component with a Mn from 280,000 to 440,000 g/mol, and a lower molecular weight component with a Mw from 30,000 to 45,000 g/mol and a ratio of Mz/Mw ranging from 2.3 to 3.4.
    Type: Application
    Filed: February 3, 2022
    Publication date: May 19, 2022
    Inventors: Max P. McDaniel, Carlton E. Ash, Kathy S. Clear, Eric D. Schwerdtfeger, Carlos A. Cruz, Jeremy M. Praetorius, Youlu Yu
  • Publication number: 20220144985
    Abstract: Catalyst compositions containing a metallocene compound, a solid activator, and a co-catalyst, in which the solid activator or the supported metallocene catalyst has a d50 average particle size of 15 to 50 ?m and a particle size distribution of 0.5 to 1.5, can be contacted with an olefin in a loop slurry reactor to produce an olefin polymer. A representative ethylene-based polymer produced using the catalyst composition has excellent dart impact strength and low gels, and can be characterized by a HLMI from 4 to 10 g/10 min, a density from 0.944 to 0.955 g/cm3, a higher molecular weight component with a Mn from 280,000 to 440,000 g/mol, and a lower molecular weight component with a Mw from 30,000 to 45,000 g/mol and a ratio of Mz/Mw ranging from 2.3 to 3.4.
    Type: Application
    Filed: July 8, 2021
    Publication date: May 12, 2022
    Inventors: Max P. McDaniel, Carlton E. Ash, Kathy S. Clear, Eric D. Schwerdtfeger, Carlos A. Cruz, Jeremy M. Praetorius, Youlu Yu
  • Patent number: 11326005
    Abstract: Catalyst compositions containing a metallocene compound, a solid activator, and a co-catalyst, in which the solid activator or the supported metallocene catalyst has a d50 average particle size of 15 to 50 ?m and a particle size distribution of 0.5 to 1.5, can be contacted with an olefin in a loop slurry reactor to produce an olefin polymer. A representative ethylene-based polymer produced using the catalyst composition has excellent dart impact strength and low gels, and can be characterized by a HLMI from 4 to 10 g/10 min, a density from 0.944 to 0.955 g/cm3, a higher molecular weight component with a Mn from 280,000 to 440,000 g/mol, and a lower molecular weight component with a Mw from 30,000 to 45,000 g/mol and a ratio of Mz/Mw ranging from 2.3 to 3.4.
    Type: Grant
    Filed: July 8, 2021
    Date of Patent: May 10, 2022
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Max P. McDaniel, Carlton E. Ash, Kathy S. Clear, Eric D. Schwerdtfeger, Carlos A. Cruz, Jeremy M. Praetorius, Youlu Yu
  • Patent number: 11325997
    Abstract: Supported chromium catalysts containing a solid oxide and 0.1 to 15 wt. % chromium, in which the solid oxide or the supported chromium catalyst has a particle size span from 0.5 to 1.4, less than 3 wt. % has a particle size greater than 100 ?m, and less than 10 wt. % has a particle size less than 10 ?m, can be contacted with an olefin monomer in a loop slurry reactor to produce an olefin polymer. Representative ethylene-based polymers produced using the chromium catalysts have a HLMI of 4 to 70 g/10 min, a density from 0.93 to 0.96 g/cm3, from 150 to 680 ppm solid oxide (such as silica), from 1.5 to 6.8 ppm chromium, and a film gel count of less than 15 catalyst particle gels per ft2 of 25 micron thick film and/or a gel count of less than or equal to 50 catalyst particles of greater than 100 ?m per five grams of the ethylene polymer.
    Type: Grant
    Filed: December 7, 2021
    Date of Patent: May 10, 2022
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Max P. McDaniel, Carlton E. Ash, Kathy S. Clear, Eric D. Schwerdtfeger, Carlos A. Cruz, Jeremy M. Praetorius, Youlu Yu
  • Publication number: 20220119562
    Abstract: Ethylene-based polymers having a density of 0.952 to 0.968 g/cm3, a ratio of HLMI/MI from 185 to 550, an IB parameter from 1.46 to 1.80, a tan ? at 0.1 sec?1 from 1.05 to 1.75 degrees, and a slope of a plot of viscosity versus shear rate at 100 sec?1 from 0.18 to 0.28 are described, with low melt flow versions having a HLMI from 10 to 30 g/10 min and a Mw from 250,000 to 450,000 g/mol, and high melt flow versions having a HLMI from 30 to 55 g/10 min and a Mw from 200,000 to 300,000 g/mol. These polymers have the processability of chromium-based resins, but with improved stress crack resistance and topload strength for bottles and other blow molded products.
    Type: Application
    Filed: October 20, 2020
    Publication date: April 21, 2022
    Inventors: Jeremy M. Praetorius, Yongwoo Inn, Alfred E. Brown, JR., Brandy Rutledge-Ryal, Carlos A. Cruz, Jay M. Chaffin
  • Publication number: 20220101392
    Abstract: A method for generating a singularity recommendation includes receiving structured and unstructured data for a user, where the structured and unstructured data for the user provide a first context for generating a singularity recommendation. The method, responsive to identifying a location for the user, determines ecosystem data based on the location for the user, where the ecosystem data provides a second context for generating the singularity recommendation. The method determines environmental data based on the location for the user, where the environmental data provides a second context for generating the singularity recommendation. The method generates the singularity recommendation based on the first context, the second context, and the third context directed to the user. The method displays the singularity recommendation in a user interface on a client device associated with the user.
    Type: Application
    Filed: September 25, 2020
    Publication date: March 31, 2022
    Inventors: YU KIT LEE, SHANKAR SWAMINATHAN, LUIS CARLOS Cruz Huertas, Wee Siang Yeap
  • Publication number: 20220081370
    Abstract: Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed in which the hydrocarbon reactant and a supported transition metal catalyst—containing molybdenum, tungsten, or vanadium—are irradiated with a light beam at a wavelength in the UV-visible spectrum, optionally in an oxidizing atmosphere, to form a reduced transition metal catalyst, followed by hydrolyzing the reduced transition metal catalyst to form a reaction product containing the alcohol compound and/or the carbonyl compound.
    Type: Application
    Filed: September 9, 2021
    Publication date: March 17, 2022
    Inventors: Masud M. Monwar, Jared L. Barr, Carlos A. Cruz, Kathy S. Clear, Max P. McDaniel
  • Patent number: 11275793
    Abstract: The disclosure describes techniques for generating device recommendations. The techniques include registering a plurality of Internet of Things (IoT) devices in a social IoT network, where each device performs one or more tasks and the one or more tasks include a first task. The techniques include periodically receiving, with the social IoT network, a work profile from one or more of the registered devices. The work profile includes device information associated with the one or more device tasks performed by the respective registered device. The techniques include grouping devices performing the first task into groups of similar devices, identifying, based on the device information in the work profile received from one or more of the registered devices, at least one device from the group of devices for which recommendations are to be provided, generating the recommendations for the identified device, and providing the recommendations for the identified device.
    Type: Grant
    Filed: July 2, 2019
    Date of Patent: March 15, 2022
    Assignee: KYNDRYL, INC.
    Inventors: Edgar Adolfo Zamora Duran, Radha Radha Mohan De, Luis Carlos Cruz Huertas, Roxana Monge Nunez, Barun Das
  • Publication number: 20220033332
    Abstract: Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed, and these processes include the steps of forming a supported chromium catalyst comprising chromium in a hexavalent oxidation state, irradiating the hydrocarbon reactant and the supported chromium catalyst with a light beam at a wavelength in the UV-visible spectrum to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the alcohol compound and/or the carbonyl compound. The supported chromium catalyst can be formed by heat treating a supported chromium precursor, contacting a chromium precursor with a solid support while heat treating, or heat treating a solid support and then contacting a chromium precursor with the solid support.
    Type: Application
    Filed: October 14, 2021
    Publication date: February 3, 2022
    Inventors: Carlos A. Cruz, Masud M. Monwar, Max P. McDaniel, Jared L. Barr, Kathy S. Clear, William C. Ellis
  • Patent number: 11214630
    Abstract: A process for preparing a (meth)acrylate comprising preparing an aqueous phase by combining water, one or more stabilizing agents, and one or more surfactants; preparing an oil phase by combining one or more free radical initiators, one or more monomers capable of undergoing radical polymerization, one or more crosslinking and/or graft-linking monomers, and stearyl methacrylate and/or lauryl methacrylate, wherein the free radical initiator is capable of partitioning preferentially into the oil phase; combining the aqueous and oil phases and mixing to form a suspension having oil droplets ranging in size from 1 to 10 microns; raising the temperature of the suspension to effect an initial polymerization forming a core polymer is provided.
    Type: Grant
    Filed: June 1, 2020
    Date of Patent: January 4, 2022
    Assignee: Rohm and Haas Company
    Inventors: Carlos A. Cruz, Morris C. Wills
  • Publication number: 20210402383
    Abstract: Catalyst preparation systems and methods for preparing reduced chromium catalysts are disclosed, and can comprise irradiating a supported chromium catalyst containing hexavalent chromium with a light beam having a wavelength within the UV-visible light spectrum. Such reduced chromium catalysts have improved catalytic activity compared to chromium catalysts reduced by other means. The use of the reduced chromium catalyst in polymerization reactor systems and olefin polymerization processes also is disclosed, resulting in polymers with a higher melt index.
    Type: Application
    Filed: September 8, 2021
    Publication date: December 30, 2021
    Inventors: Kathy S. Clear, Max P. McDaniel, William C. Ellis, Eric D. Schwerdtfeger, Deloris R. Gagan, Carlos A. Cruz, Masud M. Monwar
  • Publication number: 20210380511
    Abstract: Processes for converting an olefin reactant into a diol compound are disclosed, and these processes include the steps of contacting the olefin reactant and a supported chromium catalyst comprising chromium in a hexavalent oxidation state to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the diol compound. While being contacted, the olefin reactant and the supported chromium catalyst can be irradiated with a light beam at a wavelength in the UV-visible spectrum. Optionally, these processes can further comprise a step of calcining at least a portion of the reduced chromium catalyst to regenerate the supported chromium catalyst.
    Type: Application
    Filed: August 19, 2021
    Publication date: December 9, 2021
    Inventors: Jared L. Barr, Carlos A. Cruz, Masud M. Monwar, Kathy S. Clear, Max P. McDaniel
  • Patent number: 11180435
    Abstract: Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed, and these processes include the steps of forming a supported chromium catalyst comprising chromium in a hexavalent oxidation state, irradiating the hydrocarbon reactant and the supported chromium catalyst with a light beam at a wavelength in the UV-visible spectrum to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the alcohol compound and/or the carbonyl compound. The supported chromium catalyst can be formed by heat treating a supported chromium precursor, contacting a chromium precursor with a solid support while heat treating, or heat treating a solid support and then contacting a chromium precursor with the solid support.
    Type: Grant
    Filed: September 14, 2020
    Date of Patent: November 23, 2021
    Assignee: Chevron Phillips Chemical Company, LP
    Inventors: Carlos A. Cruz, Masud M. Monwar, Max P. McDaniel, Jared L. Barr, Kathy S. Clear, William C. Ellis
  • Patent number: 11173475
    Abstract: Catalyst preparation systems and methods for preparing reduced chromium catalysts are disclosed, and can comprise irradiating a supported chromium catalyst containing hexavalent chromium with a light beam having a wavelength within the UV-visible light spectrum. Such reduced chromium catalysts have improved catalytic activity compared to chromium catalysts reduced by other means. The use of the reduced chromium catalyst in polymerization reactor systems and olefin polymerization processes also is disclosed, resulting in polymers with a higher melt index.
    Type: Grant
    Filed: September 16, 2019
    Date of Patent: November 16, 2021
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Kathy S. Clear, Max P. McDaniel, William C. Ellis, Eric D. Schwerdtfeger, Deloris R. Gagan, Carlos A. Cruz, Masud M. Monwar
  • Publication number: 20210340085
    Abstract: Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed, and these processes include the steps of irradiating the hydrocarbon reactant and a supported chromium catalyst comprising chromium in a hexavalent oxidation state with a light beam at a wavelength in the UV-visible spectrum to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the alcohol compound and/or the carbonyl compound. In addition, these processes can further comprise a step of calcining all or a portion of the reduced chromium catalyst to regenerate the supported chromium catalyst.
    Type: Application
    Filed: July 12, 2021
    Publication date: November 4, 2021
    Inventors: Max P. McDaniel, Carlos A. Cruz, Masud M. Monwar, Jared L. Barr, William C. Ellis
  • Publication number: 20210320014
    Abstract: A method of making a semiconductor device includes mounting at least two semiconductor dies to a die pad of a leadframe in spaced apart relation to each other, the leadframe having a plurality of preformed leads, electrically connecting each semiconductor die to at least one preformed lead of the leadframe, forming a molding structure including at least part of the semiconductor dies and the preformed leads of the leadframe, and forming a trench in the molding structure in a space between the at least two semiconductor dies, the trench separating the die pad into first and second die pad portions.
    Type: Application
    Filed: June 23, 2021
    Publication date: October 14, 2021
    Inventors: Bernard Kaebin Andres Ancheta, Emerson Mamaril Enipin, John Carlo Cruz Molina
  • Publication number: 20210315496
    Abstract: Disclosed are devices, components and methods associated with a body fluid analysis system, which, according to some embodiments, can be employed in at-home, clinical, medical office and outpatient settings and applications. The system can be configured to provide results within a short period of time after a body fluid sample has been acquired from a patient such as by a finger or skin prick. In some embodiments, a body fluid sample cartridge is configured for use in conjunction with a corresponding spectroscopic body fluid analysis device, where the cartridge comprises one or more body fluid dispersing sheets, layers or membranes. In some embodiments, the cartridge is configured to deliver and disperse a predetermined amount or volume of a body fluid sample taken from a human or animal onto, into, through or across the body fluid dispersing sheet, layer or membrane disposed within the cartridge for subsequent analysis of the body fluid sample by a corresponding spectroscopic device.
    Type: Application
    Filed: April 5, 2021
    Publication date: October 14, 2021
    Inventors: Nuno Jorge Carvalho de Sousa, Miguel Angelo Alves Gomes dos Santos Silva, Joao Carlos Cruz de Sousa, Antonio Cesar Cesar Silva Ferreira, Joao Alexandre Oliveira Martins, Antonio Manuel Pacheco e Murta, Vitor Manuel da Rocha Dinis Manuel da Rocha Dinis
  • Patent number: 11142491
    Abstract: Processes for converting an olefin reactant into a diol compound are disclosed, and these processes include the steps of contacting the olefin reactant and a supported chromium catalyst comprising chromium in a hexavalent oxidation state to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the diol compound. While being contacted, the olefin reactant and the supported chromium catalyst can be irradiated with a light beam at a wavelength in the UV-visible spectrum. Optionally, these processes can further comprise a step of calcining at least a portion of the reduced chromium catalyst to regenerate the supported chromium catalyst.
    Type: Grant
    Filed: September 14, 2020
    Date of Patent: October 12, 2021
    Assignee: Chevron Phillips Chemical Company, LP
    Inventors: Jared L. Barr, Carlos A. Cruz, Masud M. Monwar, Kathy S. Clear, Max P. McDaniel
  • Patent number: 11136452
    Abstract: Provided are poly(methyl methacrylate) resin compositions containing (a) a methyl methacrylate polymer, and (b) a multistage acrylic impact modifier containing (i) a core-shell polymer, and (ii) an overpolymer containing methyl methacrylate monomers and a chain transfer agent.
    Type: Grant
    Filed: July 13, 2018
    Date of Patent: October 5, 2021
    Assignee: Rohm and Haas Company
    Inventors: Steven Brown, Carlos A. Cruz, Morris Wills