Abstract: A high-temperature solution process for making polyolefins is disclosed. Olefins polymerize at greater than about 130° C. in the presence of an activator and an organometallic complex. The complex includes a bridged indenoindolyl ligand. One part of the ligand is a second indenoindolyl group or a polymerization-stable, cyclopentadienyl-like group having an extended pi-electron system. Because the catalysts activate quickly and thoroughly, even with low levels of an alumoxane, the invention provides an efficient way to make high-molecular-weight (Mw>100K) polyolefins.

Abstract: A gas-phase process for polymerizing an olefin is disclosed. The process involves feeding the catalyst into the reactor in a stream of gas that comprises at least 75 volume % of a noble gas in order to reduce static.

Abstract: A device and method allow a dry catalyst to be delivered to a liquid-filled polymerization reactor, thus avoiding problems associated with catalyst-liquid contact or with undesired addition of gases to the reactor. A quantity of dry catalyst is transferred from a catalyst reservoir maintained under dry conditions to a catalyst chamber. An inert fluid then enters the chamber to flush the catalyst charge toward the reactor. Optional embodiments include means for precontacting the dry catalyst with a modifier and for removing gas from the fluid line.

Abstract: A device and method allow a dry catalyst to be delivered to a liquid-filled polymerization reactor, thus avoiding problems associated with catalyst-liquid contact or with undesired addition of gases to the reactor. A quantity of dry catalyst is transferred from a catalyst reservoir maintained under dry conditions to a catalyst chamber. An inert fluid then enters the chamber to flush the catalyst charge toward the reactor. Optional embodiments include means for precontacting the dry catalyst with a modifier and for removing gas from the fluid line.

Abstract: A device and method allow a dry catalyst to be delivered to a liquid-filled polymerization reactor, thus avoiding problems associated with catalyst-liquid contact or with undesired addition of gases to the reactor. A quantity of dry catalyst is transferred from a catalyst reservoir maintained under dry conditions to a catalyst chamber. An inert fluid then enters the chamber to flush the catalyst charge toward the reactor. Optional embodiments include means for precontacting the dry catalyst with a modifier and for removing gas from the fluid line.

Abstract: The present invention provides an ethylene copolymer resin that has unique melt elastic properties not observed in ethylene copolymers heretofore known. Specifically, the ethylene copolymer resin of the present invention when in pelletized form has a reduction in melt elasticity (ER) of 10% or more to a final value of 1.0 or less upon rheometric low shear modification or solution dissolution. Moreover, the resin of the present invention when in reactor-made form exhibits at least a partially reversible increase of 10% or more in ER when pelletizing the same. An ethylene polymerization catalyst, a process of preparing the ethylene copolymer resin and a high-impact film are also provided herein.