Abstract: A process for converting C2-5 alkanes to higher value C5-24 hydrocarbon fuels and blendstocks. The C2-5 alkanes are converted to olefins by thermal olefination, without the use of a dehydrogenation catalyst and without the use of steam. The product olefins are fed to an oligomerization reactor containing a zeolite catalyst to crack, oligomerize and cyclize the olens to the fuel products which are then recovered. Optionally, hydrogen and methane are removed from the product olefin stream prior to oligomerization. Further optionally, C2-5 alkanes are removed from the product olefin stream prior to oligomerization.

Abstract: A fuel additive for fuel formulations comprising calcium sulfonates in an amount effective to limit or eliminate valve seat recession in engines utilizing such fuel formulations. The fuel additive may also include a detergent, particularly in an amount to enhance the VSR limiting effect of the calcium sulfonates. Also included are fuel formulations containing calcium sulfonates in a concentration effective to limit vale seat recession in engines utilizing the fuel formulations. Methods for treating VSR in piston engines are also provided.

Abstract: A process for converting C2-5 alkanes to higher value C5-24 hydrocarbon fuels and blendstocks. The C2-5 alkanes are converted to olefins by thermal olefination, without the use of a dehydrogenation catalyst and without the use of steam. The product olefins are fed to an oligomerization reactor containing a zeolite catalyst to crack, oligomerize and cyclize the olens to the fuel products which are then recovered. Optionally, hydrogen and methane are removed from the product olefin stream prior to oligomerization. Further optionally, C2-5 alkanes are removed from the product olefin stream prior to oligomerization.

Abstract: Methods for making higher-octane fuel components from a feed stream of C8+ paraffins, including catalytically cracking the C8+ paraffins using a Zeolite catalyst to produce a reaction product of mid-chain paraffins and olefins and short-chain paraffins and olefins. The reaction product comprises liquid phase paraffins having an increased Octane Value over the feed stream paraffins. The reaction product further comprises a gas phase of short-chain paraffins which are separated from the liquid phase. In embodiments, the short chain olefins are hydrogenated to form mid-chain paraffins and a gas phase containing short-chain paraffins.

Abstract: A process for converting C2-5 alkanes to higher value C5-24 hydrocarbon fuels and blendstocks. The C2-5 alkanes are converted to olefins by thermal olefination, without the use of a dehydrogenation catalyst and without the use of steam. The product olefins are fed to an oligomerization reactor containing a zeolite catalyst to crack, oligomerize and cyclize the olens to the fuel products which are then recovered. Optionally, hydrogen and methane are removed from the product olefin stream prior to oligomerization. Further optionally, C2-5 alkanes are removed from the product olefin stream prior to oligomerization.

Abstract: Disclosed herein are processes for the production of hydrocarbon fuel products from C2-5 alkanes. Methane is converted to ethylene in a methane thermal olefination reactor operating at a temperature of at least 900° C. and a pressure of at least 150 psig, and without a dehydrogenation catalyst or steam. C2-5 alkanes are converted to olefins in a C2-5 thermal olefination reactor operating at a temperature, pressure and space velocity to convert at least 80% of the alkanes to C2-5 olefins. The ethylene and C2-5 olefins are passed through an oligomerization reactor containing a zeolite catalyst and operating at a temperature, pressure and space velocity to crack, oligomerize and cyclize the olefins. In one aspect, methane in the effluent of the oligomerization reactor is recycled through the C2-5 thermal olefination reactor. Methods for the thermal olefination of methane are also disclosed.

Abstract: Describe are preferred formulations for Avgas meeting the requirements for use in aircraft, including requirements established under ASTM standards and by the Federal Aviation Administration. In one embodiment, a binary mixture of 1,3,5-trimethyl benzene (mesitylene) and isopentane is used to provide a MON of at least 100, and more preferably at least 102. In other embodiments, the amounts of mesitylene and/or isopentane may be changed, and other fuel components are included. These various Avgas formulations are thereby adjusted to meet a variety of requirements as to octane rating, RVP, cold start, and other fuel characteristics.

Abstract: A process for converting C2-5 alkanes to higher value C5-24 hydrocarbon fuels and blendstocks. The C2-5 alkanes are converted to olefins by thermal olefination, without the use of a dehydrogenation catalyst and without the use of steam. The product olefins are fed to an oligomerization reactor containing a zeolite catalyst to crack, oligomerize and cyclize the olefins to the fuel products which are then recovered. Optionally, hydrogen and methane are removed from the product olefin stream prior to oligomerization. Further optionally, C2-5 alkanes are removed from the product olefin stream prior to oligomerization.

Abstract: Methods for making higher-octane fuel components from a feed stream of C8+ paraffins, including catalytically cracking the C8+ paraffins using a Zeolite catalyst to produce a reaction product of mid-chain paraffins and olefins and short-chain paraffins and olefins. The reaction product comprises liquid phase paraffins having an increased Octane Value over the feed stream paraffins. The reaction product further comprises a gas phase of short-chain paraffins which are separated from the liquid phase. In embodiments, the short chain olefins are hydrogenated to form mid-chain paraffins and a gas phase containing short-chain paraffins.

Abstract: Methods for the thermal olefination of a methane feedstream involving the thermal cracking of the methane feedstream at selected temperatures and pressures in the absence of a catalyst, steam or added oxygen. The methane feedstream contains greater than 85 wt % methane, and the thermal cracking produces an effluent stream containing greater than 20 wt % ethylene. Thermal cracking is optionally performed at less than 1,100° C., and in some embodiments at 850-900° C. The methane feedstream optionally contains greater than 95 wt % methane and produces an effluent stream containing greater than 30 wt % olefins. Methane in the effluent stream may be recycled to the methane feedstream.

Abstract: A process for converting C2-5 alkanes to higher value C5-24 hydrocarbon fuels and blendstocks. The C2-5 alkanes are converted to olefins by thermal olefination, without the use of a dehydrogenation catalyst and without the use of steam. The product olefins are fed to an oligomerization reactor containing a zeolite catalyst to crack, oligomerize and cyclize the olens to the fuel products which are then recovered. Optionally, hydrogen and methane are removed from the product olefin stream prior to oligomerization. Further optionally, C2-5 alkanes are removed from the product olefin stream prior to oligomerization.

Abstract: A process for converting C2-5 alkanes to higher value C5-24 hydrocarbon fuels and blendstocks. The C2-5 alkanes are converted to olefins by thermal olefination, without the use of a dehydrogenation catalyst and without the use of steam. The product olefins are fed to an oligomerization reactor containing a zeolite catalyst to crack, oligomerize and cyclize the olefins to the fuel products which are then recovered. Optionally, hydrogen and methane are removed from the product olefin stream prior to oligomerization. Further optionally, C2-5 alkanes are removed from the product olefin stream prior to oligomerization.

Abstract: A process for converting C2-5 alkanes to higher value C5-24 hydrocarbon fuels and blendstocks. The C2-5 alkanes are converted to olefins by thermal olefination, without the use of a dehydrogenation catalyst and without the use of steam. The product olefins are fed to an oligomerization reactor containing a zeolite catalyst to crack, oligomerize and cyclize the olens to the fuel products which are then recovered. Optionally, hydrogen and methane are removed from the product olefin stream prior to oligomerization. Further optionally, C2-5 alkanes are removed from the product olefin stream prior to oligomerization.

Abstract: Methods for making higher-octane fuel components from a feed stream of C8+ paraffins, including catalytically cracking the C8+ paraffins using a Zeolite catalyst to produce a reaction product of mid-chain paraffins and olefins and short-chain paraffins and olefins. The reaction product comprises liquid phase paraffins having an increased Octane Value over the feed stream paraffins. The reaction product further comprises a gas phase of short-chain paraffins which are separated from the liquid phase. In embodiments, the short chain olefins are hydrogenated to form mid-chain paraffins and a gas phase containing short-chain paraffins.

Abstract: Describe are preferred formulations for Avgas meeting the requirements for use in aircraft, including requirements established under ASTM standards and by the Federal Aviation Administration. In one embodiment, a binary mixture of 1,3,5-trimethyl benzene (mesitylene) and isopentane is used to provide a MON of at least 100, and more preferably at least 102. In other embodiments, the amounts of mesitylene and/or isopentane may be changed, and other fuel components are included. These various Avgas formulations are thereby adjusted to meet a variety of requirements as to octane rating, RVP, cold start, and other fuel characteristics.

Abstract: A process for converting C2-5 alkanes to higher value C5-24 hydrocarbon fuels and blendstocks. The C2-5 alkanes are converted to olefins by thermal olefination, without the use of a dehydrogenation catalyst and without the use of steam. The product olefins are fed to an oligomerization reactor containing a zeolite catalyst to crack, oligomerize and cyclize the olens to the fuel products which are then recovered. Optionally, hydrogen and methane are removed from the product olefin stream prior to oligomerization. Further optionally, C2-5 alkanes are removed from the product olefin stream prior to oligomerization.

Abstract: Disclosed is a process for converting C2-5 alkanes to higher-value C5-24+ hydrocarbon fuels and fuel blendstocks including reacting the C2-5 alkanes in a thermal olefination reactor operating at a temperature, pressure and space velocity to convent the alkanes to olefins and in the absence of both a dehydrogenation catalyst and steam. At least a portion of the product olefin stream is oligomerized using a zeolite catalyst to crack, oligomerize and cyclize the product olefins to form the fuel products, which are then recovered. The process is useful in removing sulfur and nitrogen-based compounds in a single step process, while reducing total costs of processing and eliminating the need for additives used in the field.

Abstract: Methods for making higher-octane fuel components from a feed stream of C8+ paraffins, including catalytically cracking the C8+ paraffins using a Zeolite catalyst to produce a reaction product of mid-chain paraffins and olefins and short-chain paraffins and olefins. The reaction product comprises liquid phase paraffins having an increased Octane Value over the feed stream paraffins. The reaction product further comprises a gas phase of short-chain paraffins which are separated from the liquid phase. In embodiments, the short chain olefins are hydrogenated to form mid-chain paraffins and a gas phase containing short-chain paraffins.

Abstract: Disclosed herein are processes for the production of hydrocarbon fuel products from C2-5 alkanes. Methane is converted to ethylene in a methane thermal olefination reactor operating at a temperature of at least 900° C. and a pressure of at least 150 psig, and without a dehydrogenation catalyst or steam. C2-5 alkanes are converted to olefins in a C2-5 thermal olefination reactor operating at a temperature, pressure and space velocity to convert at least 80% of the alkanes to C2-5 olefins. The ethylene and C2-5 olefins are passed through an oligomerization reactor containing a zeolite catalyst and operating at a temperature, pressure and space velocity to crack, oligomerize and cyclize the olefins. In one aspect, methane in the effluent of the oligomerization reactor is recycled through the C2-5 thermal olefination reactor. Methods for the thermal olefination of methane are also disclosed.

Abstract: Described are preferred compositions for a motor fuel. Such motor fuels may be particularly well suited for use in the motor of an aircraft. In particular, compositions of the present disclosure may comprise alicyclic alkanes, straight or branched chain alkanes, and aromatics. In a preferred embodiment, the fuel comprises cyclopentane, isooctane, and one or more aromatics selected from xylene, toluene, and trimethylbenzenes. The present disclosure describes a full spectrum of unleaded fuels with various motor octane (MON) values to address a wide range of aviation fuel needs in the global marketplace.