Patents by Inventor Daisuke Endo

Daisuke Endo has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8551659
    Abstract: The active material for a lithium secondary battery includes a solid solution of a lithium transition metal composite oxide having an ?-NaFeO2 type crystal structure, in which the composition ratio of Li, Co, Ni, and Mn contained in the solid solution satisfies Li1+(1/3)xCo1?x?yNi(1/2)yMn(2/3)x+(1/2)y (x+y?1, 0?y and 1?x?y=z); in an Li[Li1/3Mn2/3]O2(x)-LiNi1/2Mn1/2O2(y)-LiCoO2(z) type ternary phase diagram, (x, y, z) is represented by values in a range present on or within a line of a heptagon (ABCDEFG) defined by the vertexes; point A(0.45, 0.55, 0), point B(0.63, 0.37, 0), point C(0.7, 0.25, 0.05), point D(0.67, 0.18, 0.15), point E(0.75, 0, 0.25), point F(0.55, 0, 0.45), and point G(0.45, 0.2, 0.35); and the intensity ratio between the diffraction peaks on (003) plane and (104) plane measured by X-ray diffractometry before charge-discharge is I(003)/I(104)?1.56 and at the end of discharge is I(003)/I(104)>1.
    Type: Grant
    Filed: November 11, 2008
    Date of Patent: October 8, 2013
    Assignee: GS Yuasa International Ltd.
    Inventors: Daisuke Endo, Miki Yasutomi, Yoshihiro Katayama, Toshiyuki Nukuda
  • Publication number: 20130230775
    Abstract: There is provided an active material for a nonaqueous electrolyte secondary battery, including a lithium-transition metal composite oxide which has an ?-NaFeO2-type crystal structure and of which the average composition is represented by the composition formula of Li1+?Me1??O2 (Me is a transition metal containing Co, Ni and Mn; and ?>0), wherein the lithium-transition metal composite oxide is a particle having a core and a coated part, the cobalt concentration of the coated part is higher than the cobalt concentration of the core, the manganese concentration of the coated part is lower than the manganese concentration of the core, and the ratio of cobalt present in the coated part is 3 to 10% in terms of a molar ratio based on the amount of the transition metal present in the core.
    Type: Application
    Filed: February 27, 2013
    Publication date: September 5, 2013
    Applicant: GS YUASA INTERNATIONAL LTD.
    Inventor: Daisuke Endo
  • Publication number: 20130146808
    Abstract: [Object] There is provided an active material for a lithium secondary battery, which has a high initial efficiency and a high discharge capacity, and particularly has a high discharge capacity at a low temperature (excellent low-temperature characteristic), and a lithium secondary battery using the active material. [Solution] An active material for a lithium secondary battery, which contains a solid solution of a lithium transition metal composite oxide having an ?-NaFeO2 crystal structure, wherein the composition ratio of metal elements contained in the solid solution satisfies, Li1+x?yNayCoaNibMncO2+d (0<y?0.1, 0.4?c?0.7, x+a+b+c=1, 0.1?x?0.25, ?0.2?d?0.2), the active material has an X-ray diffraction pattern attributable to a space group R3-m (P3112), and in the Miller index hkl, the half width of the diffraction peak of the (003) is 0.30° or less and the half width of the diffraction peak of the (114) plane is 0.50° or less.
    Type: Application
    Filed: September 21, 2011
    Publication date: June 13, 2013
    Applicant: GS YUASA INTERNATIONAL LTD.
    Inventors: Daisuke Endo, Yoshihiro Katayama
  • Patent number: 8382860
    Abstract: A process for producing a lithium secondary battery employs a charging method where a positive electrode upon charging has a maximum achieved potential of 4.3 V (vs. Li/Li+) or lower. The process includes charging the lithium secondary battery to reach at least a region with relatively flat fluctuation of potential appearing in a positive electrode potential region exceeding 4.3 V (vs. Li/Li+) and 4.8V (vs. Li/Li+) or lower. The lithium secondary battery includes an active material having a solid solution of a lithium transition metal composite oxide having an ?-NaFeO2 type crystal structure. The composition ratio of Li, Co, Ni, and Mn contained in the solid solution satisfies Li1+1/3xCo1?x?yNiy/2Mn2x/3+y/2(x+y?1, 0?y and 1?x?y=z).
    Type: Grant
    Filed: October 12, 2010
    Date of Patent: February 26, 2013
    Assignee: GS Yuasa International Ltd.
    Inventors: Daisuke Endo, Miki Yasutomi, Yoshihiro Katayama, Toshiyuki Nukuda
  • Publication number: 20120145954
    Abstract: It is an object of the present invention to provide an active material for a lithium secondary battery having high discharge capacity and excellent in high rate discharge characteristics and a lithium secondary battery using the same. The active material for a lithium secondary battery containing a solid solution of a lithium-transition metal composite oxide having an ?-NaFeO2 type crystal structure and the lithium secondary battery using the same have features that the composition ratios of the metal elements contained in the solid solution satisfy Li1+(x/3)Co1?x?y?zNiy/2Mgz/2Mn(2x/3)+(y/2)+(z/2) (x>0; y>0; z>0; x+y+z<1); the active material has an X-ray diffraction pattern capable of belonging to space group P3112; and the active material has discharge capacity exceeding 200 mAh/g.
    Type: Application
    Filed: August 20, 2010
    Publication date: June 14, 2012
    Applicant: GS YUASA INTERNATIONAL LTD.
    Inventors: Daisuke Endo, Yoshihiro Katayama, Toshiyuki Nukuda
  • Patent number: 8153295
    Abstract: A positive active material is provided which can inhibit side reactions between the positive electrode and an electrolyte even at a high potential and which, when applied to a battery, can improve charge/discharge cycle performance without impairing battery performances even in storage in a charged state. Also provided are: a process for producing the active material; a positive electrode for lithium secondary batteries which employs the active material; and a lithium secondary battery which has improved charge/discharge cycle performance while retaining intact battery performances even after storage in a charged state and which can exhibit excellent charge/discharge cycle performance even when used at a high upper-limit voltage. The positive active material comprises: base particles able to dope and release lithium ions; and an element in Group 3 of the periodic table present on at least part of that part of the base particles which is able to come into contact with an electrolyte. It is produced by, e.g.
    Type: Grant
    Filed: July 13, 2004
    Date of Patent: April 10, 2012
    Assignee: GS Yuasa International Ltd.
    Inventors: Daisuke Endo, Akihiro Fujii, Ryuji Shiozaki, Tokuo Inamasu, Hiroe Nakagawa, Toshiyuki Nukuda
  • Patent number: 8053115
    Abstract: It is an object of the present invention to provide an active material for lithium ion battery having an excellent discharge capacity in the potential flat part and a high-performance and long-life lithium ion battery, and particularly to provide a technology of improving voltage flatness. The present invention provides an active material for lithium ion battery represented by a composition formula: Li[Li(1-2x)/3MgxTi(5-x)/3]O4 (0<x<1/2) in which a part of the element of lithium titanate is substituted with Mg, and a lithium ion battery using this active material as a negative electrode active material.
    Type: Grant
    Filed: March 22, 2006
    Date of Patent: November 8, 2011
    Assignee: GS Yuasa International Ltd.
    Inventors: Daisuke Endo, Tokuo Inamasu, Toshiyuki Nukuda, Yoshihiro Katayama
  • Publication number: 20110037440
    Abstract: A process for producing a lithium secondary battery employs a charging method where a positive electrode upon charging has a maximum achieved potential of 4.3 V (vs. Li/Li+) or lower. The process includes charging the lithium secondary battery to reach at least a region with relatively flat fluctuation of potential appearing in a positive electrode potential region exceeding 4.3 V (vs. Li/Li+) and 4.8V (vs. Li/Li+) or lower. The lithium secondary battery includes an active material having a solid solution of a lithium transition metal composite oxide having an ?-NaFeO2 type crystal structure. The composition ratio of Li, Co, Ni, and Mn contained in the solid solution satisfies Li1?1/3xCo1?x?yNiy/2Mn2x/3+y/2(x+y?1, 0?y and 1?x?y=z).
    Type: Application
    Filed: October 12, 2010
    Publication date: February 17, 2011
    Applicant: GS YUASA INTERNATIONAL LTD.
    Inventors: Daisuke Endo, Miki Yasutomi, Yoshihiro Katayama, Toshiyuki Nukuda
  • Patent number: 7879265
    Abstract: It is an object of the present invention to provide an active material for lithium ion battery capable of producing a lithium ion battery having an excellent high rate charge and discharge performance and a lithium ion battery having an excellent high rate charge and discharge performance. The present invention provides an active material for lithium ion battery represented by a composition formula: Li[Li(1-x)/3AlxTi(5-2x)/3]O4 (??x<1) lithium titanate is substituted with Al, and a lithium ion battery using this active material as a negative electrode active material.
    Type: Grant
    Filed: March 22, 2006
    Date of Patent: February 1, 2011
    Assignee: GS Yuasa Corporation
    Inventors: Daisuke Endo, Tokuo Inamasu, Toshiyuki Nukuda, Yoshihiro Katayama
  • Publication number: 20100233542
    Abstract: The present invention provides an active material for a lithium secondary battery with a high discharge capacity, particularly for a lithium secondary battery that can increase the discharge capacity in a potential region of 4.3 V or lower, a method for producing the same, a lithium secondary battery having a high discharge capacity, and a method for producing the same. The active material for a lithium secondary battery includes a solid solution of a lithium transition metal composite oxide having an ?-NaFeO2 type crystal structure, in which the composition ratio of Li, Co, Ni, and Mn contained in the solid solution satisfies Li1+(1/3)xCo1?x?yNi(1/2)yMn(2/3)x+(1/2)y (x+y?1, 0?y and 1?x?y=z); in an Li[Li1/3Mn2/3]O2(x)-LiNi1/2Mn1/2O2(y)-LiCoO2(z) type ternary phase diagram, (x, y, z) is represented by values in a range present on or within a line of a heptagon (ABCDEFG) defined by the vertexes; point A(0.45, 0.55, 0), point B(0.63, 0.37, 0), point C(0.7, 0.25, 0.05), point D(0.67, 0.18, 0.15), point E(0.
    Type: Application
    Filed: November 11, 2008
    Publication date: September 16, 2010
    Applicant: GS YUASA INTERNATIONAL LTD.
    Inventors: Daisuke Endo, Miki Yasutomi, Yoshihiro Katayama, Toshiyuki Nukuda
  • Publication number: 20090269668
    Abstract: It is an object of the present invention to provide an active material for lithium ion battery having an excellent discharge capacity in the potential flat part and a high-performance and long-life lithium ion battery, and particularly to provide a technology of improving voltage flatness. The present invention provides an active material for lithium ion battery represented by a composition formula: Li[Li(1-2x)/3MgxTi(5-x)/3]O4(0<x<1/2) in which a part of the element of lithium titanate is substituted with Mg, and a lithium ion battery using this active material as a negative electrode active material.
    Type: Application
    Filed: March 22, 2006
    Publication date: October 29, 2009
    Applicant: GS YUASA CORPORATION
    Inventors: Daisuke Endo, Tokuo Inamasu, Toshiyuki Nukuda, Yoshihiro Katayama
  • Publication number: 20090127503
    Abstract: It is an object of the present invention to provide an active material for lithium ion battery capable of producing a lithium ion battery having an excellent high rate charge and discharge performance and a lithium ion battery having an excellent high rate charge and discharge performance. The present invention provides an active material for lithium ion battery represented by a composition formula: Li[Li(1-x)/3AlxTi(5-2x)/3]O4 (0<x<1) in which a part of the element of lithium titanate is substituted with Al, and a lithium ion battery using this active material as a negative electrode active material.
    Type: Application
    Filed: March 22, 2006
    Publication date: May 21, 2009
    Applicant: GS YUASA CORPORATION
    Inventors: Daisuke Endo, Tokuo Inamasu, Toshiyuki Nukuda, Yoshihiro Katayama
  • Publication number: 20080315161
    Abstract: It is an object of the present invention to provide an electrochemical device adopting lithium titanate as an active material and having a sufficient output characteristic. It is another object of the present invention to provide a production method of an electrode material, an electrode, and a production method of the electrode material, to be used for the device. There can be obtained an electrochemical device-oriented electrode material, containing 90% or more of lithium titanate, and having a bulk density of 1.5 g/cm3 or more and a volume resistivity of 16 ?·cm or less, by mixing the lithium titanate with an organic substance followed by heat treatment. Usage thereof allows for achievement of the objects.
    Type: Application
    Filed: July 27, 2005
    Publication date: December 25, 2008
    Applicant: GS YUASA CORPORATION
    Inventors: Daisuke Endo, Tokuo Inamasu, Toshiyuki Nukuda
  • Publication number: 20080216455
    Abstract: An air cleaner is provided with a housing having an opening, and a filter. The filter has a frame and an element supported to the frame. The filter is installed in the interior of the housing from the opening of the housing. A second seal surface of a seal ring of the filter is joined to a first seal surface of the housing in a state in which the filter is installed in the housing. A rib-shaped protection portion extending along the first seal surface is provided in the housing. The protection portion protrudes further toward the filter than the first seal surface. A slide protrusion protruding further toward the first seal surface than the second seal surface is provided in the frame of the filter. The slide protrusion can slide on the protection portion.
    Type: Application
    Filed: March 5, 2008
    Publication date: September 11, 2008
    Applicant: TOYOTA BOSHOKU KABUSHIKI KAISHA
    Inventors: Masao AIZAWA, Daisuke ENDO
  • Publication number: 20060177739
    Abstract: A positive active material is provided which can inhibit side reactions between the positive electrode and an electrolyte even at a high potential and which, when applied to a battery, can improve charge/discharge cycle performance without impairing battery performances even in storage in a charged state. Also provided are: a process for producing the active material; a positive electrode for lithium secondary batteries which employs the active material; and a lithium secondary battery which has improved charge/discharge cycle performance while retaining intact battery performances even after storage in a charged state and which can exhibit excellent charge/discharge cycle performance even when used at a high upper-limit voltage. The positive active material comprises: base particles able to dope and release lithium ions; and an element in Group 3 of the periodic table present on at least part of that part of the base particles which is able to come into contact with an electrolyte. It is produced by, e.g.
    Type: Application
    Filed: July 13, 2004
    Publication date: August 10, 2006
    Inventors: Daisuke Endo, Akihiro Fujii, Ryuji Shiozaki, Tokuo Inamasu, Hiroe Nakagawa, Toshiyuki Nukuda