Patents by Inventor Daniel E. Resasco

Daniel E. Resasco has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20090062785
    Abstract: The present invention is a method for detecting and destroying cancer tumors. The method is based on the concept of associating a linking protein or linking peptide such as, but not limited to, annexin V or other annexins to single-walled carbon nanotubes (SWNT) to form a protein-SWNT complex. Said linking protein or peptide can selectively bind to cancerous cells, especially tumor vasculature endothelial cells, rather than to healthy ones by binding to cancer-specific external receptors such as anionic phospholipids including phosphatidylserine expressed on the outer surfaces of cancer cells only. Irradiation of bound SWNTs with one or more specific electromagnetic wavelengths is then used to detect and destroy those cells to which the SWNTs are bound via the linking protein or peptide thereby destroying the tumor or cancer cells and preferably an immunostimulant is provided to the patient to enhance the immune response against antigens released from the tumor or cancer cells.
    Type: Application
    Filed: May 30, 2008
    Publication date: March 5, 2009
    Inventors: Roger G. Harrison, JR., Daniel E. Resasco
  • Patent number: 7459138
    Abstract: A process and apparatus for catalytic production of single walled carbon nanotubes. Catalytic particles are exposed to different process conditions at successive stages wherein the catalytic particles do not come in contact with reactive (catalytic) gases until preferred process conditions have been attained, thereby controlling the quantity and form of carbon nanotubes produced. The reaction gas is preferably provided at a high space velocity to minimize CO2 build-up. The process also contemplates processes and apparatus which recycle and reuse the gases and catalytic particulate materials, thereby maximizing cost efficiency, reducing wastes, reducing the need for additional raw materials, and producing the carbon nanotubes, especially SWNTs, in greater quantities and for lower costs.
    Type: Grant
    Filed: October 28, 2004
    Date of Patent: December 2, 2008
    Assignee: The Board of Regents of the University of Oklahoma
    Inventors: Daniel E. Resasco, Boonyarach Kitiyanan, Walter E. Alvarez, Leandro Balzano
  • Publication number: 20080274036
    Abstract: Methods for producing microstructured catalytic substrates and microstructured catalytic substrates produced by the methods, and methods for growing single-walled carbon nanotubes on the microstructured catalytic substrates wherein the single-walled carbon nanotubes are preferably of a highly specific chirality.
    Type: Application
    Filed: April 29, 2008
    Publication date: November 6, 2008
    Inventors: Daniel E. Resasco, Yongqiang Tan
  • Publication number: 20080227687
    Abstract: The present invention is a method for detecting and destroying cancer tumors. The method is based on the concept of associating a linking protein or linking peptide such as, but not limited to, annexin V or other annexins to single-walled carbon nanotubes (SWNT) to form a protein-SWNT complex. Said linking protein or peptide can selectively bind to cancerous cells, especially tumor vasculature endothelial cells, rather than to healthy ones by binding to cancer-specific external receptors such as anionic phospholipids including phosphatidylserine expressed on the outer surfaces of cancer cells only. Irradiation of bound SWNTs with specific wavelength is then used to detect and destroy those cells to which the SWNTs are bound via the linking protein or peptide thereby destroying the tumor or cancer cells.
    Type: Application
    Filed: February 19, 2008
    Publication date: September 18, 2008
    Inventors: Roger G. Harrison, Daniel E. Resasco
  • Publication number: 20080213161
    Abstract: Discernable pastes comprising single-walled carbon nanotubes (SWNT) in water or in an organic solvent are prepared. The method of preparing the Discernable pastes comprises in general the following steps: a) removal of the catalyst used during the synthesis of SWNT; b) while the SWNT are still wet, addition of the appropriate amount of solvent, in a solvent/SWNT ratio which preferably varies between 30:1 and 100:1, depending on the desired viscosity of the paste; and c) high-energy horn sonication with a dismembrator probe. The resulting pastes are suitable for easy redispersion in solvents and surfactants and incorporation in various matrices such as polymers. They are also suitable to be impregnated with metal precursors such as noble metal compounds for example, Pt. Appropriate drying and thermal treatments of the impregnated material produce metal-SWNT composites in which small metal clusters can be uniformly dispersed over the nanotube surface.
    Type: Application
    Filed: October 9, 2007
    Publication date: September 4, 2008
    Inventors: Olga Matarredona, Leandro Balzano, Daniel E. Resasco, Siriporn Jongpatiwut
  • Publication number: 20080107588
    Abstract: A method of producing a carbon nanotube product comprising a catalytic particle and carbon nanotubes deposited thereon. The catalytic particles preferably contain Co or Ni metal from Group VIII, and Mo or W metal from Group VIb. The catalytic particle preferably comprises a support material upon which the metals are disposed. The carbon nanotube product is preferably formed by exposing the catalytic particle to a carbon-containing gas at a temperature sufficient to form the carbon nanotubes as a primary portion of a solid carbon product with minor amounts of graphite and amorphous carbon residue.
    Type: Application
    Filed: May 25, 2007
    Publication date: May 8, 2008
    Inventors: Daniel E. Resasco, Boonyarach Kitiyanan, Jeffrey H. Harwell, Walter Alvarez
  • Patent number: 7357907
    Abstract: A catalyst composition and method of use of the catalyst composition for producing single-walled carbon nanotubes (SWNTs). The catalyst is cobalt (Co) and molybdenum (Mo) on a silica support. The Mo occurs primarily as dispersed Mo oxide clusters on the support while the Co is primarily in an octahedral configuration in a CoMoO4-like phase disposed on the Mo oxide clusters. In the method, the catalyst is used and the process conditions manipulated in such a manner as to enable the diameters of the SWNTs to be substantially controlled.
    Type: Grant
    Filed: October 20, 2003
    Date of Patent: April 15, 2008
    Assignee: The Board of Regents of the University of Oklahoma
    Inventors: Daniel E. Resasco, Walter E. Alvarez, Jose E. Herrera, Leandro Balzano
  • Patent number: 7354881
    Abstract: A catalyst composition and method of use of the catalyst composition for producing single-walled carbon nanotubes (SWNTs). The catalyst is cobalt (Co) and molybdenum (Mo) on a silica support. The Mo occurs primarily as dispersed Mo oxide clusters on the support while the Co is primarily in an octahedral configuration in a CoMoO4-like phase disposed on the Mo oxide clusters. In the method, the catalyst is used and the process conditions manipulated in such a manner as to enable the diameters of the SWNTs to be substantially controlled.
    Type: Grant
    Filed: November 24, 2003
    Date of Patent: April 8, 2008
    Assignee: The Board of Regents of the University of Oklahoma
    Inventors: Daniel E. Resasco, Walter E. Alvarez, Jose E. Herrera, Leandro Balzano
  • Patent number: 7279247
    Abstract: Dispersable pastes comprising single-walled carbon nanotubes (SWNT) in water or in an organic solvent are prepared. The method of preparing the dispersable pastes comprises in general the following steps: a) removal of the catalyst used during the synthesis of SWNT; b) while the SWNT are still wet, addition of the appropriate amount of solvent, in a solvent/SWNT ratio which preferably varies between 30:1 and 100:1, depending on the desired viscosity of the paste; and c) high-energy horn sonication with a dismembrator probe. The resulting pastes are suitable for easy redispersion in solvents and incorporation in various matrices such as polymers. They are also suitable to be impregnated with metal precursors such as noble metal compounds for example, Pt. Appropriate drying and thermal treatments of the impregnated material produce metal-SWNT composites in which small metal clusters can be uniformly dispersed over the nanotube surface.
    Type: Grant
    Filed: November 15, 2004
    Date of Patent: October 9, 2007
    Assignee: The Board of Regents of the University of Oklahoma
    Inventors: Olga Matarredona, Leandro Balzano, Daniel E. Resasco, Siriporn Jongpatiwut
  • Patent number: 7153903
    Abstract: A method of forming carbon nanotube-filled composites using miniemulsion polymerization. The carbon nanotubes are preferably single-walled carbon nanotubes. The carbon nanotubes are highly dispersed within and associated with the polymer comprising the composite.
    Type: Grant
    Filed: June 18, 2003
    Date of Patent: December 26, 2006
    Assignee: The Board of Regents of the University of Oklahoma
    Inventors: Harry J. Barraza, Leandro Balzano, Francisco Pompeo, Olga Lucia Rueda, Edgar A. O'Rear, Daniel E. Resasco
  • Patent number: 7094386
    Abstract: A method of producing a carbon nanotube product comprising a catalytic particle and single-walled carbon nanotubes deposited thereon. The catalytic particles preferably contain at least one metal from Group VIII, including for example Co, Ni, Ru, Rh, Pd, Ir, and Pt, and at least one metal from Group VIb including for example Mo, W and Cr. The catalytic particle preferably further comprises a support material such as silica. The carbon nanotube product is preferably formed by exposing the catalytic particle to a carbon-containing gas at a temperature sufficient to form the single-walled nanotubes as a primary portion of a solid carbon product on the catalytic particles.
    Type: Grant
    Filed: August 25, 2004
    Date of Patent: August 22, 2006
    Assignee: The Board of Regents of the University of Oklahoma
    Inventors: Daniel E. Resasco, Boonyarach Kitiyanan, Jeffrey H. Harwell, Walter Alvarez
  • Patent number: 6994907
    Abstract: A carbon nanotube product formed from a metallic catalytic particle and single-walled carbon nanotubes deposited thereon. The catalytic particles preferably contain at least one metal from Group VIII, including for example Co, Ni, Ru, Rh, Pd, Ir, and Pt, and at least one metal from Group VIb including for example Mo, W and Cr. The metallic catalytic particle preferably further comprises a support material such as silica. The carbon nanotube product is preferably formed by exposing the metallic catalytic particle to a carbon-containing gas at a temperature sufficient to form the single-walled nanotubes as a primary portion of a solid carbon product on the metallic catalytic particles.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: February 7, 2006
    Inventors: Daniel E. Resasco, Boonyarach Kitiyanan, Jeffrey H. Harwell, Walter Alvarez
  • Patent number: 6962892
    Abstract: A metallic catalytic particle for producing single-walled carbon nanotubes. The catalytic particles contain at least one metal from Group VIII, including for example Co, Ni, Ru, Rh, Pd, Ir, and Pt, and at least one metal from Group VIb including for example Mo, W and Cr. The metal component is on a support such as silica.
    Type: Grant
    Filed: January 8, 2004
    Date of Patent: November 8, 2005
    Inventors: Daniel E. Resasco, Boonyarach Kitiyanan, Jeffrey H. Harwell, Walter Alvarez
  • Patent number: 6955800
    Abstract: A method and apparatus for catalytic production of carbon nanotubes. Catalytic particles are exposed to different process conditions at successive stages wherein the catalytic particles do not come in contact with reactive (catalytic) gases until preferred process conditions have been attained, thereby controlling the quantity and form of carbon nanotubes produced. The method also contemplates methods and apparatus which recycle and reuse the gases and catalytic particulate materials, thereby maximizing cost efficiency, reducing wastes, reducing the need for additional raw materials, and producing the carbon nanotubes, especially SWNTs, in greater quantities and for lower costs.
    Type: Grant
    Filed: May 13, 2002
    Date of Patent: October 18, 2005
    Inventors: Daniel E. Resasco, Boonyarach Kitiyanan, Walter Alvarez, Leandro Balzano
  • Patent number: 6919064
    Abstract: A process and apparatus for catalytic production of single walled carbon nanotubes. Catalytic particles are exposed to different process conditions at successive stages wherein the catalytic particles do not come in contact with reactive (catalytic) gases until preferred process conditions have been attained, thereby controlling the quantity and form of carbon nanotubes produced. The reaction gas is preferably provided at a high space velocity to minimize CO2 build-up. The process also contemplates processes and apparatus which recycle and reuse the gases and catalytic particulate materials, thereby maximizing cost efficiency, reducing wastes, reducing the need for additional raw materials, and producing the carbon nanotubes, especially SWNTs, in greater quantities and for lower costs.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: July 19, 2005
    Inventors: Daniel E. Resasco, Boonyarach Kitiyanan, Walter E. Alvarez, Leandro Balzano
  • Patent number: 6872364
    Abstract: An apparatus for conducting an endothermic reaction of an organic' compound in the presence of molecular hydrogen and of multicomponent solids is described. The process of operating the apparatus comprises contacting the compound with a solid catalyst for the endothermic reaction and a hydrogen oxidizing solid reagent intermixed with the solid catalyst. Organic products of the endothermic reaction are produced, with evolution of molecular hydrogen. The solid catalyst becomes gradually deactivated by formation of carbonaceous deposits thereon. The evolved hydrogen undergoes an exothermic reaction with the hydrogen oxidizing solid reagent to form a reduction product which comprises deactivated hydrogen oxidizing solid reagent.
    Type: Grant
    Filed: December 30, 2002
    Date of Patent: March 29, 2005
    Assignee: Sunoco, Inc. (R&M)
    Inventors: Thomas W. Bierl, Vincent A. Durante, Lawrence H. Finkel, Daniel E. Resasco
  • Publication number: 20040197260
    Abstract: A catalyst composition and method of use of the catalyst composition for producing single-walled carbon nanotubes (SWNTs). The catalyst is cobalt (Co) and molybdenum (Mo) on a silica support. The Mo occurs primarily as dispersed Mo oxide clusters on the support while the Co is primarily in an octahedral configuration in a CoMoO4-like phase disposed on the Mo oxide clusters. In the method, the catalyst is used and the process conditions manipulated in such a manner as to enable the diameters of the SWNTs to be substantially controlled.
    Type: Application
    Filed: October 20, 2003
    Publication date: October 7, 2004
    Inventors: Daniel E. Resasco, Walter E. Alvarez, Jose E. Herrera, Leandro Balzano
  • Publication number: 20040186011
    Abstract: A metallic catalytic particle for producing single-walled carbon nanotubes. The catalytic particles contain at least one metal from Group VIII, including for example Co, Ni, Ru, Rh, Pd, Ir, and Pt, and at least one metal from Group VIb including for example Mo, W and Cr. The metal component is on a support such as silica.
    Type: Application
    Filed: January 8, 2004
    Publication date: September 23, 2004
    Inventors: Daniel E. Resasco, Boonyarach Kitiyanan, Jeffrey H. Harwell, Walter Alvarez
  • Publication number: 20040131532
    Abstract: A catalyst composition and method of use of the catalyst composition for producing single-walled carbon nanotubes (SWNTs). The catalyst is cobalt (Co) and molybdenum (Mo) on a silica support. The Mo occurs primarily as dispersed Mo oxide clusters on the support while the Co is primarily in an octahedral configuration in a CoMoO4-like phase disposed on the Mo oxide clusters. In the method, the catalyst is used and the process conditions manipulated in such a manner as to enable the diameters of the SWNTs to be substantially controlled.
    Type: Application
    Filed: November 24, 2003
    Publication date: July 8, 2004
    Inventors: Daniel E. Resasco, Walter E. Alvarez, Jose E. Herrera, Leandro Balzano
  • Publication number: 20040070009
    Abstract: A carbon nanotube product formed from a metallic catalytic particle and single-walled carbon nanotubes deposited thereon. The catalytic particles preferably contain at least one metal from Group VIII, including for example Co, Ni, Ru, Rh, Pd, Ir, and Pt, and at least one metal from Group VIb including for example Mo, W and Cr. The metallic catalytic particle preferably further comprises a support material such as silica. The carbon nanotube product is preferably formed by exposing the metallic catalytic particle to a carbon-containing gas at a temperature sufficient to form the single-walled nanotubes as a primary portion of a solid carbon product on the metallic catalytic particles.
    Type: Application
    Filed: April 25, 2003
    Publication date: April 15, 2004
    Inventors: Daniel E. Resasco, Boonyarach Kitiyanan, Jeffrey H. Harwell, Walter Alvarez