Patents by Inventor Daniel F. White
Daniel F. White has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20240132425Abstract: Catalytic compositions and processes for depolymerizing polyolefin-based feed into useful petrochemical products are described. The compositions are a composite of a zeolite catalyst component and a co-catalyst comprising an activated clay component and/or a solid base component. These catalyst systems, along with heat, are used to both increase the depolymerization reaction rate of the feed streams and suppress poisoning effects of impurities that may be present in the polyolefin-based feed. This results in a shorter residence time in the depolymerization unit and more efficient process.Type: ApplicationFiled: October 23, 2023Publication date: April 25, 2024Applicant: Basell Poliolefine Italia S.r.l.Inventors: Sandor Nagy, Christopher D. Smith, Daniel F. White, Diego Brita, Simona Guidotti, Dario Liguori, Francesco Menichelli, Paolo Ruzzi
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Patent number: 11926587Abstract: Disclosed herein is a process for upgrading a raffinate butene (C4 Raffinate) stream to propylene which can produce polymer grade propylene (PGP) by a metathesis process, without consuming fresh ethylene as a feedstock. By recycling ethylene byproduct in the metathesis equilibrium, propylene selectivity can be further improved without negatively impacting butene conversion. Additionally, upon PGP separation, this technology can provide an effluent acceptable for alkylate production by achieving a balanced butene conversion and heavies coproduction. The disclosed process is a relatively low temperature process which can be deployed as a drop-in option for conventional ethylene/butene metathesis unit and provide additional flexibility to existing operations to balance the supply and demand of C2-C4 light olefins.Type: GrantFiled: September 14, 2021Date of Patent: March 12, 2024Assignee: Lyondell Chemical Technology, L.P.Inventors: Lei Zhang, Pranit S. Metkar, Majid Keyvani, Daniel F. White
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Publication number: 20240076467Abstract: Catalytic compositions for depolymerizing polyolefin-based waste material into useful petrochemical products and methods of use are described. The catalytic compositions are mixed metal oxides demonstrating equal or higher conversion than noncatalytic pyrolysis. These mixed metal oxide catalysts and a polyolefin-based material are heated in the presence of oxygen to form a product comprising one or more olefin monomers.Type: ApplicationFiled: August 24, 2023Publication date: March 7, 2024Applicant: Basell Poliolefine Italia S.r.l.Inventors: Daniel F. White, Sandor Nagy, Christopher D. Smith, David L. Ramage, Noel C. Hallinan
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Patent number: 11872545Abstract: Catalytic compositions for depolymerizing polyolefin-based waste material into useful petrochemical products and methods of use are described. The compositions are a composite of at least one zeolite catalyst with one or more co-catalyst(s) that is a solid inorganic material. These composite catalysts, along with heat, are used to both increase the depolymerization reaction rate of the feed streams and suppress poisoning effects of non-polyolefin polymers that may be present. This results in a shorter residence time in the depolymerization unit and more efficient process.Type: GrantFiled: December 3, 2021Date of Patent: January 16, 2024Assignee: Basell Poliolefine Italia SrlInventors: Sandor Nagy, Daniel F. White, Christopher D. Smith, David L. Ramage, Diego Brita, Noel C. Hallinan
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Patent number: 11827589Abstract: Methods of converting isobutylene to C5+ compounds. The methods may include contacting isobutylene with a skeletal isomerization catalyst to provide a mixture of C4 olefins, and then contacting the mixture of C4 olefins with a metathesis catalyst to convert the mixture of C4 olefins to a product mixture. The product mixture may include C5+ olefins.Type: GrantFiled: September 23, 2022Date of Patent: November 28, 2023Assignee: Lyondell Chemical Technology, L.P.Inventors: Linn Fang, Daniel F. White, Lei Zhang
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Patent number: 11767408Abstract: Methods of depolymerizing polyolefin-based material into useful petrochemical products using supported metal oxides and heat are described. The supported metal oxides improve the depolymerization reaction by decreasing the half time for the depolymerization, which results in a higher depolymerization rate and a shorter residence time in the depolymerization unit, allowing for a predictable depolymerization reaction, and decreasing the branching or aromatic formations in the product.Type: GrantFiled: October 29, 2021Date of Patent: September 26, 2023Assignee: Basell Poliolefine Italia S.r.l.Inventors: Sandor Nagy, Daniel F. White, Christopher D. Smith, Xueyong Yang, David L. Ramage
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Publication number: 20230106395Abstract: A method of depolymerizing polymeric material including the steps of: (a) feeding a polymeric material to a depolymerization reactor maintained at a temperature in the range of from 400° C. to 600° C. and operated under a pressure in the range of from 4 to 15 barg; and (b) depolymerizing at least a portion of the polymeric material thereby forming a first gaseous product and a first liquid product.Type: ApplicationFiled: September 28, 2022Publication date: April 6, 2023Applicant: Basell Poliolefine Italia S.r.l.Inventors: David L. Ramage, Christopher D. Smith, Xueyong Yang, Daniel F. White, Sandor Nagy
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Publication number: 20230107520Abstract: Methods of converting isobutylene to C5+ compounds. The methods may include contacting isobutylene with a skeletal isomerization catalyst to provide a mixture of C4 olefins, and then contacting the mixture of C4 olefins with a metathesis catalyst to convert the mixture of C4 olefins to a product mixture. The product mixture may include C5+ olefins.Type: ApplicationFiled: September 23, 2022Publication date: April 6, 2023Applicant: Lyondell Chemical Technology, L.P.Inventors: Linn Fang, Daniel F. White, Lei Zhang
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Patent number: 11613510Abstract: A process for the production of 4-hydroxybutyraldehyde is described. The process comprises reacting allyl alcohol with a mixture of carbon monoxide and hydrogen in the presence of methylcyclohexane as a reaction solvent and a catalyst system comprising a rhodium complex and a substituted or unsubstituted diphosphine ligand. The use of the methylcyclohexane increases the reaction rate while also giving a high yield of 4-hydroxybutyraldehyde compared to 3-hydroxy-2-methylpropionaldehyde and improving the separation of the hydroxyaldehyde products from the catalyst system.Type: GrantFiled: April 7, 2022Date of Patent: March 28, 2023Assignee: Lyondell Chemical Technology, L.P.Inventors: Daniel F. White, Beaven S. Mandimutsira, Robert J. Rebman
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Publication number: 20230009131Abstract: Pre-treatment methods for polyolefin-based feed streams before depolymerization are described. Polyolefins are separated from other material in the polyolefin-based feed stream using density differences in an aqueous solution, which allows for a pre-treatment method that does not affect the depolymerization catalyst. By removing the non-polyolefin materials from the feed stream, the depolymerization of the polyolefin material can proceed at lower temperatures for longer cycles. This results in a more efficient process with a smaller carbon footprint.Type: ApplicationFiled: July 8, 2022Publication date: January 12, 2023Applicant: Basell Poliolefine Italia S.r.l.Inventors: Sandor Nagy, Diego Brita, Christopher D. Smith, David A. Heaps, Daniel F. White, David L. Ramage
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Publication number: 20220324782Abstract: A process for the production of 4-hydroxybutyraldehyde is described. The process comprises reacting allyl alcohol with a mixture of carbon monoxide and hydrogen in the presence of methylcyclohexane as a reaction solvent and a catalyst system comprising a rhodium complex and a substituted or unsubstituted diphosphine ligand. The use of the methylcyclohexane increases the reaction rate while also giving a high yield of 4-hydroxybutyraldehyde compared to 3-hydroxy-2-methylpropionaldehyde and improving the separation of the hydroxyaldehyde products from the catalyst system.Type: ApplicationFiled: April 7, 2022Publication date: October 13, 2022Applicant: Lyondell Chemical Technology, L.P.Inventors: Daniel F. White, Beaven S. Mandimutsira, Robert J. Rebman
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Patent number: 11377534Abstract: Methods of depolymerizing polyolefin-based material into useful petrochemical products using metal oxides and heat are described. The metal oxides improve the depolymerization reaction by decreasing the onset temperature for the depolymerization, which results in a higher depolymerization rate and a shorter residence time in the depolymerization unit, allowing for a predictable depolymerization reaction, and decreasing the branching or aromatic formations in the product.Type: GrantFiled: September 9, 2020Date of Patent: July 5, 2022Assignee: Basell Poliolefine Italia S.r.l.Inventors: Diego Brita, Sheri E. Davis, Yulenty Deal, Simona Guidotti, Dario Liguori, Sandor Nagy, Christopher D. Smith, Daniel F. White, Xueyong Yang, Shahram Mihan
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Patent number: 11370737Abstract: A process of co-feeding gaseous ethylene with liquid allyl alcohol in the presence of a catalyst to produce 1,4-butanediol and n-propanol may include: introducing a gaseous mixture of ethylene, carbon monoxide and hydrogen into a reactor in the presence of a hydroformylation catalyst in a solvent; introducing liquid allyl alcohol (AA) into the reactor; and carrying out hydroformylation reaction at a temperature between 50 and 100° C. to obtain hydroformylation products.Type: GrantFiled: September 21, 2021Date of Patent: June 28, 2022Assignee: Lyondell Chemical Technology, L.P.Inventors: Daniel F. White, Beaven S. Mandimutsira, Roberto Alvarez
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Patent number: 11370726Abstract: Methods of improving the selectivity of selective hydrogenation of residual 1,3-butadiene in a C4 fraction of a hydrocarbon raffinate stream in a fixed-bed reactor are described. The methods may include co-feeding a competitive chemical species that increases the mechanistic selectivity to 1- and 2-butenes while increasing isomerization selectivity to 2-butene in the product stream. The hydrogenation reactor and competitive chemical species conditions may be tailored to selectively produce butenes over butane or iso-butane, where the butenes comprise 1-butene and/or 2-butene.Type: GrantFiled: April 27, 2020Date of Patent: June 28, 2022Assignee: Lyondell Chemical Technology, L.P.Inventors: Sarthak Gaur, Daniel F. White
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Patent number: 11358920Abstract: A process of producing allyl alcohol by reacting glycerin with ReO3—Al2O3 in the presence of gamma-valerolactone (GVL) in a reactor is described. More specifically, a process to produce allyl alcohol, comprising the step of: a) reacting glycerin with ReO3—Al2O3 in the presence of an inert solvent, GVL, in a reactor, and b) collecting the product comprising allyl alcohol.Type: GrantFiled: July 30, 2021Date of Patent: June 14, 2022Assignee: Lyondell Chemical Technology, L.P.Inventors: Xueyong Yang, Daniel F. White, Chelsee A. Arceneaux, Pranit S. Metkar
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Publication number: 20220176358Abstract: Catalytic compositions for depolymerizing polyolefin-based waste material into useful petrochemical products and methods of use are described. The compositions are a composite of at least one zeolite catalyst with one or more co-catalyst(s) that is a solid inorganic material. These composite catalysts, along with heat, are used to both increase the depolymerization reaction rate of the feed streams and suppress poisoning effects of non-polyolefin polymers that may be present. This results in a shorter residence time in the depolymerization unit and more efficient process.Type: ApplicationFiled: December 3, 2021Publication date: June 9, 2022Applicant: Basell Poliolefine Italia S.r.l.Inventors: Sandor Nagy, Daniel F. White, Christopher D. Smith, David L. Ramage, Diego Brita, Noel C. Hallinan
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Publication number: 20220135760Abstract: Methods of depolymerizing polyolefin-based material into useful petrochemical products using supported metal oxides and heat are described. The supported metal oxides improve the depolymerization reaction by decreasing the half time for the depolymerization, which results in a higher depolymerization rate and a shorter residence time in the depolymerization unit, allowing for a predictable depolymerization reaction, and decreasing the branching or aromatic formations in the product.Type: ApplicationFiled: October 29, 2021Publication date: May 5, 2022Applicant: Basell Poliolefine Italia S.r.l.Inventors: Sandor Nagy, Daniel F. White, Christopher D. Smith, Xueyong Yang, David L. Ramage
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Patent number: 11319424Abstract: A method of depolymerizing plastics using a halloysite catalyst is described herein. The method reduces the energy required for the depolymerization process while achieving improved depolymerization results.Type: GrantFiled: September 9, 2020Date of Patent: May 3, 2022Assignee: Basell Poliolefine Italia S.r.l.Inventors: Diego Brita, Sheri E. Davis, Volker Fraaije, Simona Guidotti, Dario Liguori, Sandor Nagy, David L. Ramage, Shahram Mihan, Christopher D. Smith, Daniel F. White, Xueyong Yang
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Publication number: 20220112352Abstract: Methods of depolymerizing polyolefin-based material into useful petrochemical products using styrene oligomers or polymers, and heat are described. The styrene oligomers or polymers improve the depolymerization reaction by decreasing the halftime for the depolymerization, which results in a higher depolymerization rate and a shorter residence time in the depolymerization unit, allowing for a predictable depolymerization reaction, and decreasing the branching or aromatic formations in the product.Type: ApplicationFiled: October 7, 2021Publication date: April 14, 2022Applicant: Basell Poliolefine Italia S.r.l.Inventors: Sandor Nagy, Daniel F. White, Christopher D. Smith, David L. Ramage
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Publication number: 20220098138Abstract: A process of co-feeding gaseous ethylene with liquid allyl alcohol in the presence of a catalyst to produce 1,4-butanediol and n-propanol may include: introducing a gaseous mixture of ethylene, carbon monoxide and hydrogen into a reactor in the presence of a hydroformylation catalyst in a solvent; introducing liquid allyl alcohol (AA) into the reactor; and carrying out hydroformylation reaction at a temperature between 50 and 100° C. to obtain hydroformylation products.Type: ApplicationFiled: September 21, 2021Publication date: March 31, 2022Applicant: Lyondell Chemical Technology, L.P.Inventors: Daniel F. White, Beaven S. Mandimutsira, Roberto Alvarez