Abstract: An article is described comprising a substrate and a plurality of layers deposited by layer-by-layer self-assembly disposed on the substrate. A portion of the layers comprise inorganic oxide nanoparticles comprising a phosphorous-containing surface treatment. Also described is an article comprising a bi-layer, the bi-layer comprises a monolayer of a polycation and a monolayer of a polyanion. The polyanion comprises inorganic oxide nanoparticles comprising a phosphorous-containing surface treatment. The polycations may be a polyelectrolyte or inorganic oxide nanoparticles.

Abstract: A method of making a coatable composition includes: providing a first composition comprising silica nanoparticles dispersed in an aqueous liquid vehicle, wherein the first composition has a pH greater than 6; acidifying the first composition to a pH of less than or equal to 4 using inorganic acid to provide a second composition; and dissolving at least one metal compound in the second composition to form the coatable composition. The silica nanoparticles have a polymodal particle size distribution, wherein the polymodal particle size distribution comprises a first mode having a first particle size in the range of from 8 to 35 nanometers, wherein the polymodal particle size distribution comprises a second mode having a second particle size in the range of from 2 to 20 nanometers, wherein the first particle size is greater than the second particle size. Coatable compositions, antistatic compositions, preparable by the method are also disclosed.

Abstract: A method of coating a plurality of sheets. A fluid is forced through gaps in the plurality of sheets. The fluid has a substantially plug flow profile and the fluid deposits a coating on at least one surface of the plurality of sheets in a self-limiting deposition process.

Abstract: Methods of protecting a substrate from light-induced degradation are described. The methods comprise providing a substrate and disposing onto the substrate a plurality of layers deposited by layer-by-layer self-assembly. At least a portion of the layers comprise an organic light absorbing compound, an organic light stabilizing compound, or a combination thereof dispersed within a polyelectrolyte. Also described are articles comprising a substrate and a plurality of layers deposited by layer-by-layer self-assembly wherein at least a portion of the layers comprise an organic light absorbing compound, an organic light stabilizing compound, or a combination thereof dispersed within a polyelectrolyte. Random copolymers suitable for use in the method and articles are also described.

Abstract: A coating composition comprising an aqueous media comprising silica nanoparticles dispersed in the aqueous media, and clay particles dispersed in the aqueous media, wherein a weight ratio of the clay particles to the silica nanoparticles is in a range from 0.01 to 0.25, and wherein the coating composition has a pH of less than or equal to 4. Articles having an outermost layer having an amorphous silica network of silica nanoparticles and clay particles dispersed in the amorphous silica network.

Abstract: Transfer films, articles made therewith, and layer-by-layer methods of making and using transfer films to form an inorganic optical stack are disclosed.

Abstract: Transfer films, articles made therewith, and methods of making and using transfer films to form an inorganic optical stack are disclosed.

Abstract: Static dissipative coatings that include a multilayer antistatic coating on a substrate, the multilayer antistatic coating including a buried clay/nanosilica layer and an overcoat layer, wherein the overcoat layer comprises a fluoropolymer, a silicone, or a hydrocarbon polymer, and methods for providing a multilayer antistatic coating on the surface of a substrate.

Abstract: Articles including bi-layers of anionic and cationic self-limited monolayers are described. One monolayer comprises titanium dioxide and the other layer comprises a fluorinated polyelectrolyte. The use of titanium dioxide nanoparticles and perfluorinated polymers such as perfluorosulfonic acid polymer are described. Layer-by-layer, self-assembled layers and processes of producing such layers are also described.

Abstract: Methods of making a multilayer optical film are described. In one embodiment, the method comprises providing a multilayer optical film and disposing onto the multilayer optical film a plurality of layers deposited by layer-by-layer self-assembly of nanoparticles, polymers, and combinations thereof. The multilayer optical film typically comprises a plurality of alternating polymeric layers of a low refractive index layer and a high refractive index layer that reflects at least one bandwidth of electromagnetic radiation ranging from ultraviolet to near infrared. Multilayer optical film articles are described comprising a plurality of layers disposed onto the multilayer optical film, wherein the plurality of layers comprises layer-by-layer self-assembled nanoparticles, polymers, and combinations thereof.

Abstract: The present invention is generally directed to new liquid-liquid extraction methods for the length-based separation of carbon nanotubes (CNTs) and other 1-dimensional nanostructures.

Abstract: A modular independent coil spring suspension for steerable/non-steerable wheel assemblies and driven/non-driven axles having a single coil spring with a low spring rate secured (a) to the lower of two vertically spaced control arms which connect the chassis to wheel assembly on one end, and (b) to the chassis at an upper location approximately level with a tire of the wheel assembly at the other end which provides maximum wheel travel, decreased rearward thrust, and tire/ground mobility.

Abstract: A retaining ring and method of installation are provided to maintain the relative position of an inner joint to an outer joint in a constant velocity joint. The outer joint has an open end, a generally spherical internal surface with a plurality of ball grooves, and an annular groove formed in the internal surface near the open end of the outer joint. An annular ring with a radially extending tab is aligned within one of the ball grooves to axially align the tab with the annular groove. The annular ring is then rotatable within the annular groove to align the tab between two of the ball grooves. The annular ring is rotationally retained within the annular groove.

Abstract: A constant velocity joint race includes a shaft and a plurality of track segments having a ball race surface formed thereon. Each of the segments is arranged circumferentially in an abutting manner with an adjacent track segment on either side. The segments are secured to the shaft and one another.

Abstract: A modular independent coil spring suspension for steerable/non-steerable wheel assemblies and driven/non-driven axles having a single coil spring with a low spring rate secured (a) to the lower of two vertically spaced control arms which connect the chassis to the wheel assembly on one end, and (b) to the chassis at an upper location approximately level with a tire of the wheel assembly at the other end which provides maximum wheel travel, decreased rearward thrust, and tire/ground mobility.

Abstract: Helmet visor support apparatus is provided which can move the visor between raised and a lowered position by the operation of one hand. The apparatus comprises a visor support arm pivotally attached to the helmet at a pivot point for moving the visor between the raised and lowered positions. A positioning means is attached to the helmet at the pivot point and has at least two bores corresponding to the raised and lowered visor positions. A locking pin retractably engages either one of the bores in the positioning means to lock the visor support arm in position. A spring coiled around the locking pin normally biases the locking pin in engagement with one of the bores. A manually activatable retracting means is attached to the locking pin for retracting the locking pin from the one of the bores upon being manually activated, thereby allowing the visor support arm to pivot.

Abstract: A goggles emergency release apparatus is disclosed wherein an actuator, ptioned adjacent the goggles latching mechanism, drives a wedge into the mechanism to push a release pin into the open position and push the goggles away from the helmet. The actuator receives its initiation power when the ejection seat movement closes a microswitch.