Abstract: Multi-layered golf balls containing a two or three-layered cover assembly are provided. In one embodiment, the cover assembly includes a relatively hard inner cover and relatively soft outer cover. Alternatively, the cover assembly may include a relatively soft inner cover with a relatively hard outer cover. Three-layered covers comprising an inner cover, intermediate cover, and outer cover layer also may be prepared. Preferably, at least one of the layers is formed from a thermoplastic composition that preferably comprises: a) ethylene acid copolymer, b) plasticizer, and c) cation source. A fatty acid ester such as ethyl oleate is preferably used as the plasticizer. The cover assembly has good impact durability and helps provide the ball with relatively high resiliency at given compressions.

Abstract: Multi-layered golf balls containing a three-layered core assembly are provided. Preferably, at least one of the core layers is formed from a thermoplastic composition that comprises: a) thermoplastic non-acid polymer, and b) plasticizer. In one preferred embodiment, the inner core is made of a first thermoset composition, for example, polybutadiene rubber; and the intermediate core layer is made of a thermoplastic composition; and the outer core is made of a second thermoset composition. A fatty acid ester such as ethyl oleate is preferably used as the plasticizer. Suitable non-acid polymers include, for example, polyesters, polyamides, polyolefins, and polyurethanes. The core assembly has a relatively high resiliency at given compressions.

Abstract: Disclosed herein are multilayer golf balls having a layer with a higher Shore C hardness and a lower Shore D hardness than another layer.

Abstract: Multi-layered golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) made from a foam or metal-containing composition, or it has a hollow shell construction, and the outer core layer is made of a thermoplastic composition. Preferably, the thermoplastic composition comprises: a) ethylene acid copolymer, b) plasticizer, and c) cation source. A fatty acid ester such as ethyl oleate is preferably used as the plasticizer. The core assembly preferably may have a positive hardness gradient extending across the entire assembly. The core structure and resulting ball have relatively good resiliency at given compressions.

Abstract: Multi-piece golf balls having at least one layer made from a polyamide non-ionomeric composition are provided. The polyamide composition consists essentially of about 40 to about 99% by weight polyamide; about 1 to about 60% by weight of an acid anhydride-modified polyolefin; and about 1 to about 60% of a fatty acid additive selected from the group consisting of fatty acid salts, fatty acid amides, and mixtures thereof. The ball includes a core, preferably a dual core construction; and a cover of at least one layer. In another preferred construction, a multi-layered core containing an inner, intermediate, and outer core layer is made. For example, the intermediate core layer may be made of a rubber composition; and each of the inner core and outer core layers may be made of the polyamide composition. The resulting ball has high resiliency along with a soft feel.

Abstract: Multi-layered golf balls containing a two layered cover assembly are provided. In one embodiment, the cover assembly includes a relatively soft inner cover and relatively hard outer cover. Preferably, at least one of the cover layers is formed from a thermoplastic composition that preferably comprises: a) thermoplastic non-acid polymer, and b) plasticizer. A fatty acid ester such as ethyl oleate is preferably used as the plasticizer. Suitable non-acid polymers include, for example, polyesters, polyamides, polyolefins, and polyurethanes. The cover assembly has good impact durability and helps provide the ball with relatively high resiliency at given compressions.

Abstract: Multi-layered golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) comprising a thermoplastic composition, preferably including: a) ethylene acid copolymer, b) plasticizer, and c) cation source. Preferably, a fatty acid ester such as ethyl oleate is used as the plasticizer. The outer core layer is preferably formed from a thermoset composition such as polybutadiene rubber. The core layers have different hardness levels. The core assembly preferably has a positive hardness gradient extending across the entire assembly. The core structure and resulting ball have relatively good resiliency at given compressions.

Abstract: A golf ball includes a thermoplastic inner core and a thermoset outer core layer. The inner core has a surface hardness of about 40 to 80 Shore C and a center hardness of about 30 to 75 Shore C, the center hardness being less than the surface hardness to define a first positive hardness gradient. The cover includes an inner cover layer and an outer cover layer. The thermoplastic inner core comprises a highly-neutralized ionomer including an acid copolymer of ethylene and an ?,?-unsaturated carboxylic acid; a plasticizer; an organic acid or salt thereof; and a cation source present in an amount sufficient to neutralize from about 70 to 100% of the acid groups present.

Abstract: A golf ball includes a thermoplastic HNP inner core layer having a center hardness less than the surface hardness to define a positive hardness gradient. An outer core layer is disposed about the inner core and is formed from a thermoset rubber composition. The core layer has an inner surface hardness less than the outer surface hardness to define a positive hardness gradient. Inner and outer cover layers are disposed about the outer core layer. The HNP composition includes an acid copolymer of ethylene and an ?,?-unsaturated carboxylic acid; a non-acid polymer comprising polyolefins, polyamides, polyesters, polyethers, polyurethanes, metallocene-catalyzed polymers, single-site catalyst polymerized polymers, ethylene propylene rubber, ethylene propylene diene rubber, styrenic block copolymer rubbers, alkyl acrylate rubbers, or functionalized derivatives thereof; an organic acid or salt thereof; and a cation source in an amount sufficient to neutralize at least about 80% of the acid groups.

Abstract: The present invention is directed to golf balls consisting of a multi-layer core and a cover. The multi-layer core includes at least one layer formed from a relatively soft or low modulus HNP composition and at least one layer formed from a relatively hard or high modulus HNP composition.

Abstract: Multi-piece golf balls having a solid core of at least one layer and cover of at least one layer are provided. At least one of the layers is formed from a thermoplastic polyamide composition, comprising a blend of polyamide, ethylene acid copolymer ionomer, fatty acid amide, and plasticizer. A polyamide having a transparent optical nature is preferably used in the composition. A fatty acid ester such as dipropylene glycol dibenzoate and propylene carbonate is preferably used as the plasticizer. The ball may contain an inner core and surrounding outer core layer. A rubber composition is preferably used to form the inner core and the polyamide-based composition is preferably used to form the outer core layer.

Abstract: A golf ball comprising a core and a cover layer, wherein at least one of the core or cover layer comprises a plasticized polyurethane composition comprising at least one polyurethane and at least one plasticizer.

Abstract: The present invention is directed to an improved multi-layered core golf ball wherein each core layer comprises its own specific hardness gradient (positive, negative or a combination) in addition to an overall specific hardness gradient from one core layer to the next.

Abstract: Multi-layered golf balls having at least one layer made of a polyester composition containing a polyester thermoplastic elastomer and plasticizer are provided. The plasticizers help reduce the glass transition temperature (Tg) of the composition and various plasticizers may be used. For example, the composition may include alkyl oleate plasticizers such as ethyl oleate and octyl oleate. Polyester-ether block copolymers are particularly preferred. The golf ball includes a core having at least one layer and a cover having at least one layer. The polyester composition may be used to form any core, cover, or other layer in the golf ball.

Abstract: Multi-layered golf balls containing a two or three-layered core assembly are provided. In one embodiment, the core assembly includes an inner core (center) comprising a thermoset composition, an intermediate core layer; and surrounding outer core layer. Preferably, the thermoplastic composition comprises: a) ethylene acid copolymer, b) plasticizer, and c) cation source. A fatty acid ester such as ethyl oleate is preferably used as the plasticizer. A second thermoset composition such as polybutadiene rubber may be used to form the outer core layer. The core layers have different hardness levels. In another embodiment, a two-layered core structure is provided. For example, the inner core and/or outer core layer may be made of the plasticized thermoplastic composition. The core structure and resulting ball have relatively good resiliency at given compressions.

Abstract: Methods for making multi-piece golf balls comprising at least one component made of ethylene-propylene diene copolymer (EPDM) rubber and the resulting balls are provided. The multi-piece golf ball includes a cover, preferably a dual-cover having inner and outer cover layers. The outer cover is preferably made of a liquid rubber composition based on liquid EPDM rubber. In one version, the ball sub-assembly is dipped in a bath containing liquid EPDM rubber to form the outer cover. In another version, a casting method is used and the liquid EPDM rubber is dispensed into mold cavities to form the outer cover. The inner core of the ball may be made of polybutadiene rubber and the outer core layer may be made of EPDM rubber. The resulting golf ball has high resiliency, a soft feel, and good weatherability.

Abstract: Multi-layered golf balls having at least one layer made of polyamide/acid anhydride-modified polyolefin blended compositions are provided. Preferably, a transparent polyamide is used. In one version, the composition comprises a blend of polyamide, acid anhydride-modified polyolefin, and plasticizer. The golf ball includes a core having at least one layer and a cover having at least one layer. The polyamide/acid anhydride-modified polyolefin composition may be used to form any core, cover, or other layer in the golf ball. In one preferred version, the polyamide/acid anhydride-modified polyolefin composition is used to form the inner core, and a rubber composition is used to form the outer core layer.

Abstract: A golf ball of the present invention comprises a core of one or more layers and a cover of one or more layers surrounding the core. At least one of the core layers is comprised of a surface region. The surface region is a composite of cured core material and non-reactive particles. The non-reactive particles are comprised of ground cured-rubber or ground thermoplastic polymer.

Abstract: Multi-layered golf balls having at least one layer made of a polyamide composition containing a polyamide polymer and plasticizer are provided. The plasticizers help reduce the glass transition temperature (Tg) of the composition and various plasticizers may be used. For example, the composition may include ethyl oleate or propylene carbonate as a plasticizer. Transparent polyamides, for example, polyether-amide block copolymers, preferably are used in the composition. The golf ball includes a core having at least one layer and a cover having at least one layer. The polyamide composition may be used to form any core, cover, or other layer in the golf ball. In one version, the polyamide composition is used to form the inner cover layer.

Abstract: Golf ball incorporating an HNP composition consisting of a mixture of: at least one ethylene acid copolymer; sufficient amount of cation source to neutralize greater than about 100% of all acid groups present; and a highly diverse mixture of at least four organic acids having different characteristics such as relating to: carbon chain lengths, number of double bonds on carbon chains, positioning of double bonds on carbon chains, number of branches, types of branches, positioning of branches on carbon chains, positioning of acid groups on carbon chains, configurations(cis/trans), functional groups on carbon chains, being saturated/unsaturated, being conjugated/non-conjugated; presence/absence of functional group(s) on carbon chain; being aliphatic/aromatic, or combinations thereof. No organic acid is present in highly diverse mixture in a concentration greater than 80%, or, in some embodiments, greater than 60%, or greater than 40%.