Abstract: A method of determining an API gravity of a crude oil includes obtaining a reservoir sample containing the crude oil, separating an aromatic fraction from the reservoir sample, analyzing the aromatic fraction using a gas chromatography mass spectrometry (GC-MS) instrument, determining peak areas and a ratio of 4-methyldibenzothiophene and 1-methyldibenzothiophene, and determining the API gravity of the crude oil in the reservoir sample using an empirical correlation between API gravity and the ratio of 4-methyldibenzothiophene to 1-methyldibenzothiophene. A method of determining productivity of a region of a reservoir includes determining an API gravity of a crude oil in the sample from the region of the reservoir using an empirical correlation between API gravity and the ratio of 4-methyldibenzothiophene to 1-methyldibenzothiophene, and based on the API gravity of the sample, determining the productivity of the region of the reservoir.

Abstract: Methods and systems for determining a hydrocarbon type for a source sample are disclosed. The method includes obtaining a thermal maturity relationship and the source sample from a geological region of interest. The method further includes separating aromatic fraction from the source sample, and separating, measuring, and identifying responses of the aromatic fraction using gas chromatography-mass spectrometry (GC-MS) and determining a thermal maturity ratio using the responses. The method still further includes determining a thermal maturity indicator using the thermal maturity ratio and the thermal maturity relationship and determining the hydrocarbon type based on the thermal maturity indicator. The system includes a ball mill, a pipette column, a GC-MS system, and a computer processor.

Abstract: A system and method for measuring a source rock sample's maturity by a static high field resolution nuclear magnetic resonance (NMR) spectroscopy is disclosed. Kerogen, a part of the source rock matrix is studied, to quantify the amount of hydrogen (H) and carbon (C) present. This technique is non-destructive and non-invasive to the sample. The method further includes determining the H/C ratio of the kerogen in the source rock sample by integrating the H/C ratio of a known external reference sample.

Abstract: A process for monitoring and quantifying anthropogenic carbon retained within a reservoir includes, measuring ?13C and ?18O of in situ reservoir CO2 and calculating endpoint values of the in situ CO2 using ?13C and ?18O, measuring ?13C, and ?18O of anthropogenic CO2 and calculating endpoint value of the anthropogenic CO2 using ?13C and ?18O, injecting anthropogenic CO2 into the reservoir, obtaining volume or mass of anthropogenic CO2, collecting a produced sample from the reservoir after a period of time, measuring ?13C, and ?18O of a mixed in situ and anthropogenic CO2, and calculating the anthropogenic CO2 sequestered in the reservoir by using the endpoint values. A anthropogenic CO2 monitoring and quantifying system includes, injection wells, production wells, measurement devices for measuring an amount of CO2 injected and produced, and a measurement collection and analysis system for receiving gas samples and for measuring an amount of CO2 sequestered within the reservoir.

Abstract: A method of determining an API gravity of a crude oil includes obtaining a reservoir sample containing the crude oil, separating an aromatic fraction from the reservoir sample, analyzing the aromatic fraction using a gas chromatography mass spectrometry (GC-MS) instrument, determining peak areas and a ratio of 4-methyldibenzothiophene and 1-methyldibenzothiophene, and determining the API gravity of the crude oil in the reservoir sample using an empirical correlation between API gravity and the ratio of 4-methyldibenzothiophene to 1-methyldibenzothiophene. A method of determining productivity of a region of a reservoir includes determining an API gravity of a crude oil in the sample from the region of the reservoir using an empirical correlation between API gravity and the ratio of 4-methyldibenzothiophene to 1-methyldibenzothiophene, and based on the API gravity of the sample, determining the productivity of the region of the reservoir.

Abstract: A method for subsurface sequestration of carbon dioxide includes placing into a subterranean zone an oxidizer having a redox potential of at least 0.5 volts. The subterranean zone has an average total organic content of at least three weight percent. Carbon dioxide is injected into the subterranean zone via one or a plurality of wells. A total volume of all fluids injected into the subterranean zone via the one or the plurality of wells includes, on average per well per month, at least sixty-five weight percent carbon dioxide and less than thirty weight percent water.

Abstract: A pyrolysis system for evaluating a source rock sample from a subterranean reservoir and methods are described. The pyrolysis system includes a reactor vessel including a body with an open end, a cover attachable to the body, a heating system, a collector assembly. The body and the cover define a sealable chamber; a source rock sample holder sized to be received inside the sealable chamber; and a sensor system. The sensor system includes a direct sensor assembly associated with the source rock sample holder, sized to be received inside the sealable chamber, and operable to measure properties of the source rock sample in the source rock sample holder; and a pyrolysis products sensor assembly in fluid communication with the collector assembly of the reactor vessel.

Abstract: A method for subsurface sequestration of carbon includes injecting a treatment composition comprising a mineralization accelerant into a subterranean zone at least partially saturated with saline water. The mineralization accelerant is reactive with carbon dioxide to form bicarbonate. The method further includes injecting carbon in the form of carbon dioxide into the subterranean zone and sequestering at least a portion of the carbon in the subterranean zone by precipitation in the subterranean zone of a carbonate mineral formed from reaction of the bicarbonate with metal cations dissolved in the saline water. At least a portion of the bicarbonate is formed by reaction of the mineralization accelerant with the carbon dioxide.

Abstract: A method of determining a thermal maturity model of a subterranean region of interest is disclosed. The method includes obtaining a plurality of rock samples for the subterranean region of interest. The method further includes determining a first porosity value, a second porosity value, and a volume fraction of organic matter, for each of the plurality of rock samples. The method further includes determining, for each of the plurality of rock samples, a thermal maturity index based, at least in part, on the first porosity value, the second porosity value and the volume fraction of organic matter. The method further includes determining the thermal maturity model based, at least in part, on the thermal maturity index for each of the plurality of rock samples.

Abstract: The subject matter of this specification can be embodied in, among other things, a method for treating a geologic formation that includes providing a hydraulic fracture model, providing a first value representative of a volume of kerogen breaker in a fracturing fluid, determining a discrete fracture network (DFN) based on the hydraulic fracture model and the first value, determining a geomechanical model based on the DFN and a reservoir model based on the DFN, determining a hydrocarbon production volume based on the geomechanical model and the reservoir model, adjusting the first value based on the hydrocarbon production volume, and adjusting a volume of kerogen breaker in the fracturing fluid to a hydrocarbon reservoir based on the adjusted first value.

Abstract: A method for subsurface sequestration of carbon dioxide includes placing into a subterranean zone an oxidizer having a redox potential of at least 0.5 volts. The subterranean zone has an average total organic content of at least three weight percent. Carbon dioxide is injected into the subterranean zone via one or a plurality of wells. A total volume of all fluids injected into the subterranean zone via the one or the plurality of wells includes, on average per well per month, at least sixty-five weight percent carbon dioxide and less than thirty weight percent water.

Abstract: A method of determining a thermal maturity model of a subterranean region of interest is disclosed. The method includes obtaining a plurality of rock samples for the subterranean region of interest. The method further includes determining a first porosity value, a second porosity value, and a volume fraction of organic matter, for each of the plurality of rock samples. The method further includes determining, for each of the plurality of rock samples, a thermal maturity index based, at least in part, on the first porosity value, the second porosity value and the volume fraction of organic matter. The method further includes determining the thermal maturity model based, at least in part, on the thermal maturity index for each of the plurality of rock samples.

Abstract: The disclosure relates to a source productivity assay integrating pyrolysis data and X-ray diffraction data.

Abstract: A method for subsurface sequestration of carbon includes injecting a treatment composition comprising a mineralization accelerant into a subterranean zone at least partially saturated with saline water. The mineralization accelerant is reactive with carbon dioxide to form bicarbonate. The method further includes injecting carbon in the form of carbon dioxide into the subterranean zone and sequestering at least a portion of the carbon in the subterranean zone by precipitation in the subterranean zone of a carbonate mineral formed from reaction of the bicarbonate with metal cations dissolved in the saline water. At least a portion of the bicarbonate is formed by reaction of the mineralization accelerant with the carbon dioxide.

Abstract: Methods and systems for determining a hydrocarbon type for a source sample are disclosed. The method includes obtaining a thermal maturity relationship and the source sample from a geological region of interest. The method further includes separating aromatic fraction from the source sample, and separating, measuring, and identifying responses of the aromatic fraction using gas chromatography-mass spectrometry (GC-MS) and determining a thermal maturity ratio using the responses. The method still further includes determining a thermal maturity indicator using the thermal maturity ratio and the thermal maturity relationship and determining the hydrocarbon type based on the thermal maturity indicator. The system includes a ball mill, a pipette column, a GC-MS system, and a computer processor.

Abstract: A method for subsurface sequestration of carbon dioxide includes placing into a subterranean zone an oxidizer having a redox potential of at least 0.5 volts. The subterranean zone has an average total organic content of at least three weight percent. Carbon dioxide is injected into the subterranean zone via one or a plurality of wells. A total volume of all fluids injected into the subterranean zone via the one or the plurality of wells includes, on average per well per month, at least sixty-five weight percent carbon dioxide and less than thirty weight percent water.

Abstract: A combination of scanning electron microscope data and pyrolysis data are used to correct for solid organic matter-containing pores in a source rock sample. The methods can yield corrected sample porosity estimates and/or kerogen content estimates.

Abstract: A mounting device for holding a sample mounted to a sample holder for use in an inverted microscope. The mounting device includes a platen; a mounting located on a sample side of the platen; a sample holder removably coupled to the mounting so the sample is along an optical axis of the inverted microscope; and a spacer shaped as a hollow prism or a hollow cylinder having a height and defining a through hole. The platen is disposed on the spacer with the sample side facing toward the spacer and the sample holder positioned within the through hole. The height of the spacer arranges the sample within a focal plane of the inverted microscope.

Abstract: The disclosure relates to a source productivity assay integrating pyrolysis data and X-ray diffraction data.

Abstract: A method for subsurface sequestration of carbon dioxide includes placing into a subterranean zone an oxidizer having a redox potential of at least 0.5 volts. The subterranean zone has an average total organic content of at least three weight percent. Carbon dioxide is injected into the subterranean zone via one or a plurality of wells. A total volume of all fluids injected into the subterranean zone via the one or the plurality of wells includes, on average per well per month, at least sixty-five weight percent carbon dioxide and less than thirty weight percent water.