Patents by Inventor David Shepard
David Shepard has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20250118862Abstract: A cell for use in an electrochemical cell, that includes a positive electrode, a negative electrode, an electrolyte, and a separator in the form of a zeolite-based material comprising one or more naturally occurring or synthetically synthesized zeolites applied directly to at least one of the positive electrode and the negative electrode. The positive electrode configured so that non-reactive metal ions are reversibly extracted there from and inserted therein. The negative electrode configured to reversibly accept and release the non-reactive metal ions. The electrolyte positioned between and in contact with the negative electrode and the positive electrode, such that the electrolyte supports a reversible flow of the non-reactive metal ions between the positive electrode and the negative electrode. The separator being configured to electrically isolate the positive electrode from the negative electrode, while being permeable to the reversible flow of the non-reactive metal ions there through.Type: ApplicationFiled: September 28, 2022Publication date: April 10, 2025Inventors: Bing Tan, Wei Wu, David Shepard, Ashwin Sankaran, Yunkui Li
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Patent number: 12227428Abstract: A nanocrystal-sized cerium-zirconium-aluminum mixed oxide material includes at least 20% by mass zirconium oxide; between 5% to 55% by mass cerium oxide; between 5% to 60% by mass aluminum oxide; and a total of 25% or less by mass of at least one oxide of a rare earth metal selected from the group of lanthanum, neodymium, praseodymium, or yttrium. The nanocrystal-sized cerium-zirconium-aluminum mixed oxide exhibits hierarchically ordered aggregates having a dso particle size less than 1.5 ?m, and retains at least 80% of surface area and pore volume after ageing at temperature higher than 1000° C. for at least 6 hours. The nanocrystal-sized cerium-zirconium-aluminum mixed oxide material is prepared using a co-precipitation method followed by milling the dried and calcined oxide material. The nanocrystal-sized cerium-zirconium-aluminum mixed oxide material forms a particulate filter that may be used in an exhaust system arising from a gas or diesel engine.Type: GrantFiled: December 19, 2019Date of Patent: February 18, 2025Assignee: Pacific Industrial Development CorporationInventors: Anatoly Bortun, Jin Cho, Yunkui Li, David Shepard, Mila Bortun
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Patent number: 12129182Abstract: A nanocrystal-sized cerium-zirconium mixed oxide material includes at least 30% by mass zirconium oxide; between 5% to 55% by mass cerium oxide; and a total of 25% or less by mass of at least one oxide of a rare earth metal selected from the group of lanthanum, neodymium, praseodymium, or yttrium. The nanocrystal-sized cerium-zirconium mixed oxide exhibits hierarchically ordered aggregates having a d50 particle size less than 1.5 ?m and a total pore volume after calcination at a temperature of 600° C. or more that is at least 0.7 cm3/g with a fraction of pores between 2 nm to 10 nm being less than 15%. The nanocrystal-sized cerium-zirconium mixed oxide material is prepared using a co-precipitation method followed by milling the dried and calcined oxide material. The nanocrystal-sized cerium-zirconium mixed oxide material forms a particulate filter that may be used in an exhaust system arising from a gas or diesel engine.Type: GrantFiled: June 11, 2021Date of Patent: October 29, 2024Assignee: Pacific Industrial Development CorporationInventors: Anatoly Bortun, David Shepard, Jin Cho, Mila Bortun, Yunkui Li, Wei Wu, Jeffery Lachapelle
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Patent number: 12060280Abstract: A method of forming an AEI-type zeolite in a hydrothermal synthesis without the use of hydrogen fluoride (HF) and in the absence of any FAU zeolite Y. A gel composition formed upon using this method includes one or more sources of silica; one or more sources of alumina, one or more organic structure directing agents (OSDA); a source of alkali metal ions; and water. This gel composition is defined by the molar ratios of: SiO2/AI2O3 16:1 to 100:1; M2O/SiO2 0.15:1 to 0.30:1; ROH/SiO2 0.05:1 to 0.20:1; and H2O/SiO2 5:1 to 20:1; wherein M is the alkali metal ion and R is an organic moiety derived from the OSDA. This gel composition, after reacting at a temperature between 135° C. to about 180° C. for 15 hours to 168 hours forms the crystalline AEI-type zeolite having a silica to alumina ratio (SiO2:AI2O3) that is greater than 8:1.Type: GrantFiled: August 23, 2019Date of Patent: August 13, 2024Assignee: Pacific Industrial Development CorporationInventors: Yunkui Li, David Shepard, De Gao, Wei Wu, Jeffery Lachapelle, Geng Zhang
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Patent number: 12021237Abstract: A negative electrode for use in an electrochemical cell, such as a lithium-ion secondary battery that includes a positive electrode with an active material that acts as a cathode and a current collector; a negative electrode with an active material that acts as an anode and a current collector; a non-aqueous electrolyte; and a separator placed between the positive and negative electrodes. The negative electrode, includes an inorganic additive dispersed therein or applied as a coating thereon, the inorganic additive being in the form of one or more zeolites having a Si:Al ratio ranging from 1-50 that absorbs one or more of moisture, free transition metal ions, or hydrogen fluoride that become present in the cell. One or more of the cells may be combined in a housing to form a lithium-ion secondary battery.Type: GrantFiled: March 24, 2021Date of Patent: June 25, 2024Assignee: Pacific Industrial Development CorporationInventors: Shuang Gao, David Shepard, Yunkui Li, Anatoly Bortun
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Patent number: 11918453Abstract: The present disclosure describes methods of treating an injury in a subject using placental tissue streamers, engineered tissue placental tissue hybrids, suture placental tissue hybrids, placental tissue patch hybrids, and tissue hybrids, and the use of these compositions to repair, treat, or support an injury or degenerative process in a subject.Type: GrantFiled: March 12, 2021Date of Patent: March 5, 2024Assignee: Arthrex, Inc.Inventors: David Shepard, John Tokish, Brian Dorn
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Patent number: 11904303Abstract: A method of forming an AFX zeolite in a hydrothermal synthesis that exhibits a silica to alumina (SiO2AI2O3) molar ratio (SAR) that is between 8:1 and 26:1; has a morphology that includes one or more of cubic, spheroidal, or rhombic particles with a crystal size that is in the range of about 0.1 micrometer (?m) to 10 ?m. This AFX zeolite also exhibits a Brönsted acidity that is in the range of 1.2 mmol/g to 3.6 mmol/g as measured by ammonia temperature programmed desorption. A catalyst formed by substituting a metal into the framework of the zeolite exhibits about a 100% conversion of NO emissions over the temperature range of 300° C. to 650° C.Type: GrantFiled: November 8, 2019Date of Patent: February 20, 2024Assignee: Pacific Industrial Development CorporationInventors: De Gao, Yunkui Li, David Shepard, Jeffery Lachapelle, Wei Wu
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Publication number: 20240047823Abstract: A separator for use in an electrochemical cell, such as a lithium-ion secondary battery, that includes a plurality of first inorganic particles, one or more second inorganic particles, a polymeric binder, wherein the weight ratio of the first inorganic particles to the second inorganic particles is in the range from 1:99 to 99:1 and the weight ratio of the combined first and second inorganic particles to the polymeric binder is in the range from 50:50 to 99:1. The inorganic particles being a type of Li-exchanged zeolite having a lithium (Li) concentration in the range of 0.1 wt. % to 20 wt. % and a sodium (Na) concentration that is lower than 5 wt. %, based on the overall weight of the Li-exchanged zeolite. The second inorganic particles being different in composition than the first inorganic particles and having a sodium (Na) concentration in the range of 0.005 wt. % to 1.0 wt. %.Type: ApplicationFiled: December 21, 2021Publication date: February 8, 2024Inventors: Shuang Gao, Yunkui Li, David Shepard, Ashwin Sankaran
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Patent number: 11883804Abstract: A method of forming an SSZ-13 zeolite in a hydrothermal synthesis yields an SSZ-13 zeolite that exhibits a silica to alumina (SiO2:Al2O3) molar ratio (SAR) that is less than 16:1; has a morphology that includes one or more of cubic, spheroidal, or rhombic particles with a crystal size that is in the range of about 0.1 micrometer (?m) to 10 ?m. This SSZ-13 also exhibits a Brönsted acidity that is in the range of 2.0 mmol/g to 3.4 mmol/g as measured by ammonia temperature programmed desorption. A catalyst formed by substituting a metal into the framework of the zeolite provides for low temperature light-off of the NOx conversion reactions, while maintaining substantial performance at higher temperatures demonstrating hydrothermal stability.Type: GrantFiled: October 24, 2019Date of Patent: January 30, 2024Assignee: Pacific Industrial Development CorporationInventors: De Gao, Yunkui Li, David Shepard, Jeffery Lachapelle, Wei Wu
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Patent number: 11760564Abstract: An apparatus, system and method for securing wheeled shipping carts within a shipping container. The apparatus, system and method for securing wheeled shipping carts within a shipping container secures the shipping racks across the width of the container and vertically, and then end-to-end inside the length of the container from the fixed end of the container to the doors as the container is loaded. In addition, the system and method secures wheeled shipping carts within a shipping container using a securing apparatus installed within the shipping container to constrain the wheeled shipping carts both vertically and horizontally in location during transport.Type: GrantFiled: December 21, 2022Date of Patent: September 19, 2023Assignee: Globe Composite Solutions, LLCInventors: Brian Charles Evans, David Shepard Farnsworth
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Patent number: 11635009Abstract: A method of making an oxygen storage material (OSM) with developed mesoporosity having a small fraction of pores <10 nm (fresh or aged), and resistance to thermal sintering is provided. This OSM is suitable for use as a catalyst and catalyst support. The method of making this oxygen storage material (OSM) includes the preparation of a solution containing pre-polymerized zirconium oligomers, cerium, rare earth and transition metal salts; the interaction of this solution with a complexing agent that has an affinity towards zirconium; the formation of a zirconium-based precursor; and the co-precipitation of all constituent metal hydroxide with abase.Type: GrantFiled: January 7, 2019Date of Patent: April 25, 2023Assignee: Pacific Industrial Development CorporationInventors: Anatoly Bortun, Mila Bortun, David Shepard, Yunkui Li, Jin Cho, Wei Wu, Jeffery Lachapelle
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Publication number: 20230124907Abstract: An apparatus, system and method for securing wheeled shipping carts within a shipping container. The apparatus, system and method for securing wheeled shipping carts within a shipping container secures the shipping racks across the width of the container and vertically, and then end-to-end inside the length of the container from the fixed end of the container to the doors as the container is loaded. In addition, the system and method secures wheeled shipping carts within a shipping container using a securing apparatus installed within the shipping container to constrain the wheeled shipping carts both vertically and horizontally in location during transport.Type: ApplicationFiled: December 21, 2022Publication date: April 20, 2023Applicant: Globe Composite Solutions, LLCInventors: Brian Charles EVANS, David Shepard FARNSWORTH
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Publication number: 20230090959Abstract: A cerium-zirconium oxide-based ionic conductor (CZOIC) material including zirconium oxide in an amount ranging from 5 wt. % up to 95 wt. %, cerium oxide in an amount ranging from 95 wt. % to 5 wt. %, and at least one oxide or a rare earth metal in an amount ranging from 30 wt. % or less, based on the overall mass of the CZOIC material. The CZOIC material exhibits a structure comprising one or more expanded unit cells and a plurality of crystallites having ordered nano-domains. The structure of the CZOIC material exhibits a crystal lattice defined by a d-value measured at multiple (hkl) locations using a SAED technique that exhibit distortions, such that the d-values for the same (hkl) location varies from about 2% to about 5% from the d-value measured for a reference cerium-zirconium material at the same (hkl) location.Type: ApplicationFiled: January 14, 2021Publication date: March 23, 2023Inventors: Anatoly Bortun, Mila Bortun, Geng Zhang, David Shepard
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Publication number: 20230031405Abstract: An electrochemical cell, such as a secondary cell of a lithium-ion battery, that includes a positive electrode with an active material that acts as a cathode; a negative electrode with an active material that acts as an anode; a non-aqueous electrolyte; and a separator placed between the positive electrode and negative electrode. The separator including an inorganic material. This inorganic material includes a mixture of a first inorganic particle and one or more second inorganic particles; wherein the inorganic material absorbs one or more of moisture, free transition metal ions, or hydrogen fluoride (HF) that become present in the electrochemical cell. One or more of the cells may be combined in a housing to form a lithium-ion secondary battery.Type: ApplicationFiled: December 21, 2020Publication date: February 2, 2023Inventors: Shuang Gao, David Shepard, Yunkui Li, Ashwin Sankaran
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Patent number: 11565875Abstract: An apparatus, system and method for securing wheeled shipping carts within a shipping container. The apparatus, system and method for securing wheeled shipping carts within a shipping container secures the shipping racks across the width of the container and vertically, and then end-to-end inside the length of the container from the fixed end of the container to the doors as the container is loaded. In addition, the system and method secures wheeled shipping carts within a shipping container using a securing apparatus installed within the shipping container to constrain the wheeled shipping carts both vertically and horizontally in location during transport.Type: GrantFiled: March 26, 2020Date of Patent: January 31, 2023Assignee: Globe Composite Solutions, LLCInventors: Brian Charles Evans, David Shepard Farnsworth
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Publication number: 20220393239Abstract: A cell for use in an electrochemical cell, such as a lithium-ion secondary battery that includes a positive electrode with an active material that acts as a cathode and a current collector; a negative electrode with an active material that acts as an anode and a current collector; a non-aqueous electrolyte; and a separator placed between the positive and negative electrodes. At least one of the cathode, the anode, the electrolyte, and the separator includes an inorganic additive in the form of a metal aluminate or a mixture of metal aluminates that absorbs one or more of moisture, free transition metal ions, or hydrogen fluoride (HF) that become present in the cell. One or more of the cells may be combined in a housing to form a lithium-ion secondary battery. The inorganic additive may also be incorporated as a coating applied to the internal wall of the housing.Type: ApplicationFiled: October 30, 2020Publication date: December 8, 2022Inventors: Shuang Gao, David Shepard, Yunkui Li, Anatoly Bortun
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Publication number: 20220393179Abstract: A cell for use in an electrochemical cell, such as a lithium-ion secondary battery that includes a positive electrode with an active material that acts as a cathode and a current collector; a negative electrode with an active material that acts as an anode and a current collector; a non-aqueous electrolyte; and a separator placed between the positive and negative electrodes. At least one of the cathode, the anode, the electrolyte, and the separator includes an inorganic additive in the form of a transition phase alumina or a type of boehmite that absorbs one or more of moisture and/or hydrogen fluoride (HF) that become present in the cell. One or more cells may be combined in a housing to form a lithium-ion secondary battery. The inorganic additive may also be incorporated as a coating applied to the internal wall of the housing.Type: ApplicationFiled: October 30, 2020Publication date: December 8, 2022Inventors: Shuang Gao, David Shepard, Yunkui Li, Anatoly Bortun
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Publication number: 20220379284Abstract: An apparatus, system, and method for removing impurities from a non-aqueous electrolyte used in an electrochemical cell. The apparatus includes a vessel having one or more chambers with an inlet and an outlet configured to allow the flow of the electrolyte through the one or more chambers; and an inorganic scavenging agent located within the one or more chambers. The inorganic scavenging agent includes one or more types of zeolite particles, at least one type of absorbent filler particles, or a combination of the zeolite and absorbent filler particles. The inorganic scavenging agent absorbs one or more of moisture, free transition metal ions, or hydrogen fluoride (HF) that is present as impurities in the non-aqueous electrolyte.Type: ApplicationFiled: May 10, 2022Publication date: December 1, 2022Inventors: Jeffery Lachapelle, David Shepard, Ashwin Sankaran, Wei Wu, Yunkui Li
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Publication number: 20220376357Abstract: An electrochemical cell that includes a positive electrode with an active material acting as a cathode; a negative electrode with an active material acting as an anode; a non-aqueous electrolyte; and a separator placed between the positive electrode and negative electrode. In one embodiment, the separator includes an inorganic material, i.e., a type of boehmite, formed of nanometer-sized particles and optionally one or more binders and/or ceramic particles. In a second embodiment, at least one of the cathode, the anode, the electrolyte, and the separator includes the boehmite particles, which absorb one or more of moisture and/or hydrogen fluoride that become present in the cell. One or more of the cells may be combined in a housing to form a lithium-ion secondary battery.Type: ApplicationFiled: October 30, 2020Publication date: November 24, 2022Inventors: Shuang Gao, David Shepard, Yunkui Li, Anatoly Bortun
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Publication number: 20220216468Abstract: A cell for use in an electrochemical cell, e.g., a lithium-ion secondary battery, that includes a positive electrode with an active material acting as a cathode and a current collector; a negative electrode with an active material acting as an anode and a current collector; a non-aqueous electrolyte; and a separator placed between the electrodes. At least one of the cathode and anode includes an inorganic additive in the form of a zeolite having a Si:Al ratio ranging from 2-50 that absorbs one or more of moisture, free transition metal ions, or hydrogen fluoride that become present in the cell. Multiple cells may be combined in a housing to form a lithium-ion secondary battery. The inorganic additive may be incorporated as part of the positive electrode, the negative electrode, or a combination thereof.Type: ApplicationFiled: December 29, 2021Publication date: July 7, 2022Inventors: Shuang Gao, Yunkui Li, David Shepard, Ashwin Sankaran