Abstract: The invention relates to the field of efficient separation and recovery of bromine by full wet method, especially to a two-step separating method of bromide and recovery of lead and zinc from printed circuit board Incineration ash. It mainly includes first sodium hydroxide alkaline leaching, secondary sodium peroxide alkaline leaching, pH adjustment, separate lead and zinc, bromide evaporation and crystallization to recover crude bromide and other steps. Compared with traditional comprehensive recovery process of ash, the invention uses sodium hydroxide to dissolve bromide, lead and zinc, and uses the strong oxidation of sodium peroxide in alkaline environment, copper bromide and other bromine are oxidized and leached; through two-step method, the efficient leaching of bromine, lead and zinc is realized, silver and other precious metals are enriched at the same time. It is beneficial to subsequent recovery of precious metals and has the characteristics of short tail liquid discharge.

Abstract: The invention relates to the field of comprehensive recovery of valuable elements such as bromine, base metal and precious metal from incineration ash, especially relates to a method for enriching precious metals from printed circuit board incineration ash by bath smelting-chlorination circulation process. The process mainly comprises pretreatment of the printed circuit board Incineration ash and circulation-chlorination enrichment process for precious metals. The crude copper, crude zinc sulfate, bromine, lead chloride and precious metal enriched slag are obtained. Compared with the traditional process, it realizes the cycle enrichment of precious metals as well as avoids the loss of valuable metals and secondary pollution caused by tail liquid discharge.

Abstract: The invention relates to a method for multi-metal products recovery from pyrolytic waste integrated circuit boards. The method mainly comprises the steps of smelting and blending, atomization, acidolysis and filtration, noble metal recycling, copper extraction and back extraction, nickel extraction and back extraction. Compared with the prior art, the method has the advantages that smoke pollution and the smelting slag treatment in the process of preparing a black copper ingot through multi-metal collaborative smelting are reduced, and the problems of low anode efficiency of the black copper electrolysis process are solved. Meanwhile, the high-temperature high-oxygen atomized gas generated in the atomizing process provides a heat source and an oxygen source for subsequent acidolysis, so that the energy consumption is further reduced. The method has the advantages such as short process, remarkable energy conservation and emission reduction.

Abstract: The invention relates to a method for multi-metal products recovery from pyrolytic waste integrated circuit boards. The method mainly comprises the steps of smelting and blending, atomization, acidolysis and filtration, noble metal recycling, copper extraction and back extraction, nickel extraction and back extraction. Compared with the prior art, the method has the advantages that smoke pollution and the smelting slag treatment in the process of preparing a black copper ingot through multi-metal collaborative smelting are reduced, and the problems of low anode efficiency of the black copper electrolysis process are solved. Meanwhile, the high-temperature high-oxygen atomized gas generated in the atomizing process provides a heat source and an oxygen source for subsequent acidolysis, so that the energy consumption is further reduced. The method has the advantages such as short process, remarkable energy conservation and emission reduction.

Abstract: A green resource-based method of thermal mass synergy in waste Integrated circuit board mainly includes carbonization cracking system, crushing and separation system, gasification cracking system and heat value utilization and comprehensive recovery system. Compared with existing techniques, carbonization cracking system can realize the dry distillation cracking of organic matter in waste integrated circuit board which converts carbon, hydrogen and other elements into fuel carbonized cracking gas and cracking oil, the heat from the combustion of the carbonization cracking gas of the invention provides the energy needed for the carbonization cracking to realize self-heating carbonization cracking.

Abstract: A method of pretreatment and bromine recovery of PCB Incineration ash is disclosed that relates to the field of comprehensive recovery of valuable metals by full wet method, especially relates to a method of valuable metals and bromine recovery, precious metals enrichment in pretreatment process of PCB Incineration ash. The major steps includes alkali leaching, Cu extraction back-extraction, neutralization-precipitation to separate, Bromine evaporative crystallization, regeneration, acid pickling, Zn evaporative crystallization, removal of Zn and Cu. Compared with the traditional comprehensive recovery process of ash, the invention can separate bromine from ash and recover valuable metals such as copper, zinc and lead with the maximum extent, at the same time, the enrichment of silver and other precious metals is beneficial to the subsequent recovery of precious metals. It has high added recovery value and no tailless discharge.

Abstract: The invention relates to the field of comprehensive recovery of valuable elements such as bromine, base metal and precious metal from incineration ash, especially relates to a method for enriching precious metals from printed circuit board incineration ash by bath smelting-chlorination circulation process. The process mainly comprises pretreatment of the printed circuit board Incineration ash and circulation-chlorination enrichment process for precious metals. The crude copper, crude zinc sulfate, bromine, lead chloride and precious metal enriched slag are obtained. Compared with the traditional process, it realizes the cycle enrichment of precious metals as well as avoids the loss of valuable metals and secondary pollution caused by tail liquid discharge.

Abstract: A method of recovering bromide from bromine-containing smelting ash relates to the field of high efficient separation and recovery of bromine by total wet method. It especially relates to the method of high efficiency separation of bromine salt and lead, zinc recovery of circuit board smelting ash by two-step method. It mainly comprising: sub-molten salt leaching, washing, separate Lead and zinc by adjusting the pH of industrial sulfuric acid, membrane separation and concentration, reuse of water, crude bromine salt recovery by evaporation crystallization of bromine salt. Compared with the traditional baking and recycling process of ash, the invention adopts sodium hydroxide submolten salt leaching technology and membrane separation and concentration technology, to reduce the reaction temperature and tailings discharge greatly, which has a good effect of energy saving and emission reduction.

Abstract: A method of recovering bromide from bromine-containing smelting ash relates to the field of high efficient separation and recovery of bromine by total wet method. It especially relates to the method of high efficiency separation of bromine salt and lead, zinc recovery of circuit board smelting ash by two-step method. It mainly comprising: sub-molten salt leaching, washing, separate Lead and zinc by adjusting the pH of industrial sulfuric acid, membrane separation and concentration, reuse of water, crude bromine salt recovery by evaporation crystallization of bromine salt. Compared with the traditional baking and recycling process of ash, the invention adopts sodium hydroxide submolten salt leaching technology and membrane separation and concentration technology, to reduce the reaction temperature and tailings discharge greatly, which has a good effect of energy saving and emission reduction.

Abstract: A method of pretreatment and bromine recovery of PCB Incineration ash is disclosed that relates to the field of comprehensive recovery of valuable metals by full wet method, especially relates to a method of valuable metals and bromine recovery, precious metals enrichment in pretreatment process of PCB Incineration ash. The major steps includes alkali leaching, Cu extraction back-extraction, neutralization-precipitation to separate, Bromine evaporative crystallization, regeneration, acid pickling, Zn evaporative crystallization, removal of Zn and Cu. Compared with the traditional comprehensive recovery process of ash, the invention can separate bromine from ash and recover valuable metals such as copper, zinc and lead with the maximum extent, at the same time, the enrichment of silver and other precious metals is beneficial to the subsequent recovery of precious metals. It has high added recovery value and no tailless discharge.

Abstract: A method for recovering valuable metals and simultaneously preparing ceramsite by roasting cyanide tailing belongs to the area of comprehensive recovery and high value utilization of metallurgical waste residue. In this method, cyanide tailings, bentonite, calcium chloride, coal powder and albite are mixed by ball milling according to certain weight ratio to get a mixture. After drying and roasting twice, dust is collected from the roasted ash, the obtained polymetallic ash is collected and treated. The secondary calcined material is cooled to obtain ceramsite. The invention volatilizes and recovers the valuable metal in the roasting and sintering process of cyanide tailings and directly prepares the ceramsite through reasonable batching, which achieves the effect of recycling cyanide tailings and high-value utilization, can create good economic and environmental benefits, and has significant effect of energy saving and consumption reduction.

Abstract: A method for recovering valuable metals and simultaneously preparing ceramsite by roasting cyanide tailing belongs to the area of comprehensive recovery and high value utilization of metallurgical waste residue. In this method, cyanide tailings, bentonite, calcium chloride, coal powder and albite are mixed by ball milling according to certain weight ratio to get a mixture. After drying and roasting twice, dust is collected from the roasted ash, the obtained polymetallic ash is collected and treated. The secondary calcined material is cooled to obtain ceramsite. The invention volatilizes and recovers the valuable metal in the roasting and sintering process of cyanide tailings and directly prepares the ceramsite through reasonable batching, which achieves the effect of recycling cyanide tailings and high-value utilization, can create good economic and environmental benefits, and has significant effect of energy saving and consumption reduction.

Abstract: The invention provides a pollution-free reuse method for iron-based grinding waste, involving the technology of recycling economy, with special reference to the metallurgical industry, iron-based grinding waste green recycling technology. The present invention of the iron grinding waste recycling and reuse methods includes degreasing, heat treatment, sieving, matching, and obtains iron-based alloyed powders, which can be used in SHS lined steel pipe, powder metallurgy structural component, magnetic grinding, thermal spray. More than 95% iron-based alloyed powders can be recycled from wide source of iron-based grinding waste. The invention has the advantage of low cost, no secondary pollution and wide application.

Abstract: The invention related to the recycling field of waste printed circuit boards (WPCB), and especially involved a complete non-cyanogens wet process for green recycling of WPCB, which belonged to the field of recycle economy. In the invention, the process included that WPCB were broken by the jaw crusher, and then mixed copper powders and nonmetallic powders were separated by the method of air classification, the mixed copper powders were smelted and casted to get copper anode plates, the copper was purified by electrolytion, the valuable metals (such as copper, gold, silver, platinum and palladium, lead and tin) were recycled from the copper anode slime, and the waste water was recycled. The recovery ratio of all-metal was above 98%. The purity of the cathode copper was up to 4N level. The ratio of de-coppering was above 96%. The recovery ratio of gold was above 98.

Abstract: The invention belongs to the field of recycling of resources, in particular to a method for waste rare earth luminescent material by dual hydrochloric acid. First hydrochloric acid was used to dissolve the red phosphor powder (Y2O3:Eu) priority, and yttrium-rich rare earth chloride solution and residue were obtained after filtered. Residue's major components were green and blue phosphor powder, and the removal of Ca2+ in filtrate was conducted by using Na2SO4, and CaSO4 precipitation separation was conducted to get rich rare earth chloride solution, europium and yttrium. Residue was mixed with alkali to perform alkaline fusion at high temperature to decompose green and blue powder, then sodium aluminate, magnesium, barium and rare earth oxides were obtained. Alkaline fusion products were washed with water, and filtered, and then sodium aluminate solution and residues containing rare earth oxides were obtained.

Abstract: The invention belongs to the field of recycling of resources, in particular to a method for waste rare earth luminescent material by dual hydrochloric acid. First hydrochloric acid was used to dissolve the red phosphor powder (Y2O3:Eu) priority, and yttrium-rich rare earth chloride solution and residue were obtained after filtered. Residue's major components were green and blue phosphor powder, and the removal of Ca2+ in filtrate was conducted by using Na2SO4, and CaSO4 precipitation separation was conducted to get rich rare earth chloride solution, europium and yttrium. Residue was mixed with alkali to perform alkaline fusion at high temperature to decompose green and blue powder, then sodium aluminate, magnesium, barium and rare earth oxides were obtained. Alkaline fusion products were washed with water, and filtered, and then sodium aluminate solution and residues containing rare earth oxides were obtained.

Abstract: The invention provides a pollution-free reuse method for iron-based grinding waste, involving the technology of recycling economy, with special reference to the metallurgical industry, iron-based grinding waste green recycling technology. The present invention of the iron grinding waste recycling and reuse methods includes degreasing, heat treatment, sieving, matching, and obtains iron-based alloyed powders, which can be used in SHS lined steel pipe, powder metallurgy structural component, magnetic grinding, thermal spray. More than 95% iron-based alloyed powders can be recycled from wide source of iron-based grinding waste. The invention has the advantage of low cost, no secondary pollution and wide application.

Abstract: The invention related to the recycling field of waste printed circuit boards (WPCB), and especially involved a complete non-cyanogens wet process for green recycling of WPCB, which belonged to the field of recycle economy. In the invention, the process included that WPCB were broken by the jaw crusher, and then mixed copper powders and nonmetallic powders were separated by the method of air classification, the mixed copper powders were smelted and casted to get copper anode plates, the copper was purified by electrolytion, the valuable metals (such as copper, gold, silver, platinum and palladium, lead and tin) were recycled from the copper anode slime, and the waste water was recycled. The recovery ratio of all-metal was above 98%. The purity of the cathode copper was up to 4N level. The ratio of de-coppering was above 96%. The recovery ratio of gold was above 98.

Abstract: A method of producing individual integrated circuit package units includes the steps of: providing a base which includes a leadframe, a plurality of package precursors, and a continuous encapsulating epoxy layer bonded integrally with the leadframe; and singulating the package precursors. The leadframe has a plurality of metallic connection bars and extension parts formed integrally with the connection bars. The package precursors are singulated by cutting the leadframe and the epoxy layer along first and second cutting streets. The cutting of the base is performed by cutting into the first and second cutting streets with a cutting tool, which can be a single-blade or dual-blade, thereby separating the connection bars from the inner leads.