Abstract: The present invention relates to a method for producing an object in an additive manufacturing process from a precursor and comprises the following steps: I) depositing a layer of a radically cross-linkable construction material, which corresponds to a first selected cross-section of the precursor, on a carrier; II) depositing a layer of a radically cross-linkable construction material, which corresponds to a further selected cross-section of the precursor, on a previously applied layer of the radically cross-linked construction material; III) repeating step II) until the precursor is formed. The radically cross-linkable construction material comprises a thermoplastic radically cross-linkable polyurethane with a urethane group content of ?5% by weight and a photoinitiator. The radically cross-linkable construction material is also heated to a processing temperature that is greater than the melting point of the radically cross-linkable polyurethane. After step III) the precursor having a temperature of 20° C.

Abstract: The present invention relates to the use of polyisocyanate compositions and trimerization catalysts for production of coatings by reaction injection molding. The present disclosure also describes the coatings obtained by the use. The correspondingly coated workpieces are also described in this disclosure. A method for coating workpieces by reaction injection molding is also described herein.

Abstract: The invention relates to storage-stable pigmented formulations containing isocyanate groups, comprising at least one pigment a., at least one component b. containing isocyanate groups, at least one wetting agent and/or dispersant c., at least one grind resin d. and optionally solvents, wherein the formulation has a viscosity increase of less than 500% after storage at 50° C. over a period of at least 3 days. The invention also relates to the production of such formulations and to the use thereof.

Abstract: A method of manufacturing a particulate composition includes providing an aqueous dispersion, the dispersion including polymer particles, where the polymer of the particles has a glass transition temperature as determined by differential scanning calorimetry according to ISO 11357, second heating, at a heating and cooling rate of 20 K/min; and storing the dispersion of step I) at a temperature of ?0° C. until a polymer including precipitate is formed. The method further includes grinding the precipitate at a temperature above the glass transition temperature of the polymer to obtain a particulate composition, where the precipitate subject to grinding has a water content of at least 5 wt.-%.

Abstract: The invention relates to potting compounds which cure to polyisocyanurate plastics, to the production of said potting compounds and to the use of the potting compounds for manufacturing electrical components.

Abstract: The present invention relates to novel anisotropic composite materials and processes for production thereof. The composite materials are based on the crosslinking of polyisocyanates and feature good weathering stability.

Abstract: The invention relates to the use of an aqueous dispersion containing at least one polyurethane-polyurea polymer formed from (a) at least one difunctional polyester polyol having a number-average molecular weight of 400 to 5000 g/mol, (b) at least one difunctional polyol component having a number-average molecular weight of 762 to 399 g/mol, c) at least one diisocyanate and (d) at least one chain extender optionally having at least one ionic group, for the bonding of at least two substrates by application of the aqueous dispersion to at least one of the substrates to be bonded, subsequent drying of the dispersion present on the at least one substrate in order to obtain at least one adhesive layer, and contacting of the at least one adhesive layer with a further substrate or with an adhesive layer present on a further substrate at a pressure of from 0.1 to 5 bar(a) and a temperature of less than 40° C.

Abstract: The invention relates to a method for modifying an object comprising the step of: I) providing an object which is made at least partially of a construction material comprising a thermoplastic polyurethane. The method also comprises the following steps: II) contacting, at least in part, the construction material, for a first predetermined period of time, with a first liquid comprising ?80% by weight, based on the total weight of the first liquid, of a polar aprotic solvent; III) contacting, for a second predetermined period of time, the areas of the construction material that were in contact with the liquid in step II) with a second liquid comprising ?80% by weight, based on the total weight of the second liquid, of a polar protic solvent. Preferably, the first liquid is DMSO or acetone and the second liquid is water.

Abstract: An adhesive composition includes a polyurethane polymer, a solvent and a co-solvent. The polyurethane polymer is an internally and/or externally hydrophilized thermoplastic polyurethane having an Mw of ?50000 g/mol. The solvent is a polar-aprotic solvent. The co-solvent is selected from water, a primary alcohol having ?10 carbon atoms, a vicinal diol or a mixture of at least two of the aforementioned compounds. The solvent and the co-solvent are present in such amounts that they form a homogenous mixture without the formation of a second phase when combined together at 20° C. The hydroxyl group content is ?1 weight-%, based on the total weight of the composition. The polyurethane polymer content is ?10 weight-%, based on the total weight of the composition and the composition forms a single continuous liquid phase. Examples for solvent/co-solvent combinations are methylethyl ketone (MEK) and water or MEK and ethanol.

Abstract: The present invention relates to adhesives which are characterized in that they cure in the absence of water and at room temperature with the formation of isocyanurate groups.

Abstract: A method for producing an object comprises the step of producing the object by means of an additive manufacturing process from a construction material. The construction material comprises a first polyurethane polymer which has: a weight percentage ratio of O to N of ?2 to ?2.5, determined by elementary analysis; a weight percentage ratio of N to C of ?0.1 to ?0.25, determined by elementary analysis; a full-width at half maximum of the melting peak of ?20 K, determined by dynamic differential scanning calorimetry DSC (2nd heating at heating rate 20 k/min); and a difference between the melting temperature and the recrystallisation temperature of ?5 K and ?100 K, determined by dynamic differential scanning calorimetry DSC (2nd heating) at a heating and cooling rate of 20 K/min.

Abstract: A resin comprises: A) a multifunctional (meth)acrylate; B) an NCO-functional polyurethane; C) a radical starter and D) a catalyst. The multifunctional (meth)acrylate A) has a viscosity at 23° C. as determined according to DIN EN ISO 2884-1 of ?10000 mPa·s, the NCO-functional polyurethane B) has an average NCO group functionality of ?2 and an equivalent molecular weight with respect to NCO groups of >300 g/mol, the catalyst D) is an isocyanate trimerization catalyst and the resin is free from NCO-reactive compounds or, if NCO-reactive compounds are present in the resin, the molar ratio of NCO groups to NCO-reactive groups is ?5:1.

Abstract: The invention relates to a method for applying a material containing a meltable polymer comprising the step of applying a filament of the at least partially molten material from a discharge opening of a discharge element onto a substrate. The meltable polymer has the following properties: —a melting point (DSC, differential scanning calorimetry; second heating with a heating rate of 5° C./min) in a range from ?40° C. to ?120° C.; —a glass transition temperature (DMA, dynamic mechanical analysis in accordance with DIN EN ISO 6721-1:2011) in a range from ??70° C. to ?30° C.; —a storage modulus G? (parallel plate oscillation viscometer in accordance with ISO 6721-10:2015 at a frequency of 1/s) at 20° C. above the melting point of ?1·104 Pa; —a storage modulus G? (parallel plate oscillation viscometer in accordance with ISO 6721-10:2015 at a frequency of 1/s) at 10° C. below the melting point with prior heating to a temperature of 20° C. above the melting point and subsequent cooling with a cooling rate of 1° C.

Abstract: A resin comprises: A) a multifunctional (meth)acrylate; B) an NCO-functional polyurethane; C) a radical starter and D) a catalyst. The multifunctional (meth)acrylate A) has a viscosity at 23° C. as determined according to DIN EN ISO 2884-1 of ?10000 mPa·s, the NCO-functional polyurethane B) has an average NCO group functionality of ?2 and an equivalent molecular weight with respect to NCO groups of >300 g/mol. The resin is free from isocyanate trimerization catalysts and the resin is free from NCO-reactive compounds or, if NCO-reactive compounds are present in the resin, the molar ratio of NCO groups to NCO-reactive groups is ?5:1.

Abstract: The invention relates to reaction mixtures having a high ratio of isocyanate groups to isocyanate-reactive groups, which reaction mixtures mostly cure through the formation of isocyanurate groups, and to the use of such reaction mixtures for producing semifinished materials.

Abstract: The present invention relates to an orthodontic splint made of a crosslinked polymer, wherein the crosslinked polymer has a glass transition temperature Tg, determined by means of dynamic-mechanical analysis at a frequency of 1/s DMA as peak tan ?, of ?25° C. and ?60° C., a modulus of elasticity, determined by means of dynamic-mechanical analysis as the storage modulus E? at a frequency of 1/s at 35° C., of ?500 MPa and ?4000 MPa, and a loss factor tan ?, determined by means of dynamic-mechanical analysis at a frequency of 1/s at 35° C., of ?0.08. The invention further relates to a process for producing such splints.

Abstract: A resin comprises: A) a (meth)acrylate-functional compound; B) a polyisocyanate; C) a radical starter and D) a catalyst. The compound A) has an equivalent molecular weight with respect to (meth)acrylate C?C double bonds of ?500 g/mol and an average number of (meth)acrylate groups per molecule of ?1.8 to ?2.2, the polyisocyanate B) has an average NCO group functionality of ?2 and an equivalent molecular weight with respect to NCO groups of ?300 g/mol, the catalyst D) is an isocyanate trimerization catalyst and the resin is free from NCO-reactive compounds or, if NCO-reactive compounds are present in the resin, the molar ratio of NCO groups to NCO-reactive groups is ?5:1. Such resins may form hybrid polymer networks.

Abstract: The present invention relates to a method for functionalizing a workpiece surface, comprising the following steps: a) providing a workpiece; b) providing a film; c) functionalizing at least one film side by the location-selective application of a functionalization composition comprising a polymer material onto part of the film side in one or more layers by means of a 3D printing process; d) creating an integrally bonded or interlocking connection between the workpiece surface and the film functionalized in step c) by bringing the film into contact with at least part of the workpiece surface, wherein the integrally bonded or interlocking connection to the workpiece surface is achieved with a functionalized film side. The invention further relates to workpieces having a surface functionalized according to the invention.

Abstract: The present invention relates to a process for producing translucent polyurethane and polyisocyanurate foams by reaction of a component A, comprising A1 at least one polyol reactive with component B; A2 optionally at least one amine; A3 water and optionally formic acid or at least one physical blowing agent or mixtures thereof; A4 at least one foam stabilizer; A5 optionally auxiliary and/or additive substances; A6 optionally at least one flame retardant; A7 at least one catalyst; and a component B, comprising B1 at least one aliphatic or cycloaliphatic polyisocyanate component or a combination thereof; and B2 optionally at least one hydrophilized isocyanate; and B3 more than or equal to 10 parts by weight and up to 70 parts by weight of an aromatic polyisocyanate component, wherein the parts by weight of B3 are based on the sum of the parts by weight of B1 to B3 which are normalized to 100 parts by weight.

Abstract: The invention relates to a 2K coating formulation that is printed without a mask using a valve jet printer.