Abstract: Some variations provide a composition for reducing a metal ore, the composition comprising a carbon-metal ore particulate, wherein the carbon-metal ore particulate comprises at least about 0.1 wt % to at most about 50 wt % fixed carbon on a moisture-free and ash-free basis, and wherein the carbon is at least 50% renewable carbon as determined from a measurement of the 14C/12C isotopic ratio. Some variations provide a process for reducing a metal ore, comprising: providing a biomass feedstock; pyrolyzing the feedstock to generate a biogenic reagent comprising carbon and a pyrolysis off-gas comprising hydrogen or carbon monoxide; obtaining a metal ore comprising a metal oxide; combining the carbon with the metal ore, to generate a carbon-metal ore particulate; optionally pelletizing the carbon-metal ore particulate; and utilizing the pyrolysis off-gas to chemically reduce the metal oxide to elemental metal, such as iron.

Abstract: Water-resistant, high-durability, and high-density biocarbon pellets are described. In some variations, a process for producing biocarbon pellets comprises: pyrolyzing a biomass-containing feedstock in a pyrolysis reactor, thereby generating a solid biocarbon-containing material and a pyrolysis vapor; introducing the pyrolysis vapor to a separation system configured to recover a pyrolysis condensate in liquid form separated from non-condensable gases; capturing pyrolysis condensate as a polyphenolic material; contacting the solid biocarbon-containing material with the polyphenolic material, thereby generating an intermediate mixture; introducing the intermediate mixture to a densification unit, thereby generating a biocarbon pellet precursor; and at least partially drying the biocarbon pellet precursor, thereby generating biocarbon pellets characterized by a 24-hour water uptake of about 20 wt % or less, measured at 25° C. and 1 bar.

Abstract: Water-resistant, high-durability, and high-density biocarbon pellets are described. In some variations, a process for producing biocarbon pellets comprises: pyrolyzing a biomass-containing feedstock in a pyrolysis reactor, thereby generating a solid biocarbon-containing material and a pyrolysis vapor; introducing the pyrolysis vapor to a separation system configured to recover a pyrolysis condensate in liquid form separated from non-condensable gases; capturing pyrolysis condensate as a polyphenolic material; contacting the solid biocarbon-containing material with the polyphenolic material, thereby generating an intermediate mixture; introducing the intermediate mixture to a densification unit, thereby generating a biocarbon pellet precursor; and at least partially drying the biocarbon pellet precursor, thereby generating biocarbon pellets characterized by a 24-hour water uptake of about 20 wt % or less, measured at 25° C. and 1 bar.

Abstract: Some variations provide a carbon-negative carbon product that is characterized by a carbon intensity less than 0 kg CO2e per metric ton of the carbon-negative carbon product, wherein the carbon-negative carbon product contains at least about 50 wt % carbon. In some embodiments, the carbon intensity is less than ?500 kg CO2e per metric ton of the carbon-negative carbon product. Other variations provide a carbon-negative metal product (e.g., a steel product) that is characterized by a carbon intensity less than 0 kg CO2e per metric ton of the carbon-negative metal product, wherein the metal product contains from 50 wt % to 100 wt % of one or more metals and optionally one or more alloying elements. In some embodiments, the carbon-negative metal product is characterized by a carbon intensity less than ?200 kg CO2e per metric ton of the carbon-negative metal product. The carbon-negative metal product can contain a wide variety of metals.

Abstract: Provided are biogenic porous carbon silicon dioxide compositions, as well as related compositions, and methods of making and using such compositions. Exemplary biogenic porous carbon silicon dioxide compositions include a high-carbon biogenic reagent composition that contains at least about 50 wt % total carbon, at most about 5 wt % hydrogen, at most about 1 wt % nitrogen, at most about 0.5 wt % phosphorus, at most about 0.2 wt % sulfur, at most about 0.02 wt % titanium, at most about 0.5% calcium, at most about 0.1% aluminum, and silicon dioxide. The total carbon can be biogenic carbon, and the silicon dioxide can be contained within river rock or silica fume. Also provided are processes for producing such compositions, where the processes can include: preheating a renewable feedstock, pyrolyzing the renewable feedstock, separating certain pyrolysis products, cooling solid pyrolysis products, and introducing silicon dioxide at a certain point in process.

Abstract: In some variations, the disclosure provides a renewable biocarbon composition comprising from 50 wt % to 99 wt % total carbon, wherein the biocarbon composition is characterized by a base-acid ratio selected from 0.1 to 10, an iron-calcium ratio selected from 0.05 to 5, iron-plus-calcium parameter selected from 5 to 50 wt %, a slagging factor selected from 0.001 to 1, and/or a fouling factor or modified fouling factor selected from 0.1 to 10. Some variations provide a process comprising: providing a biomass feedstock; pyrolyzing the biomass feedstock to generate an intermediate biocarbon stream; washing or treating the intermediate biocarbon stream with an acid, a base, a salt, a metal, H2, H2O, CO, CO2, or a combination thereof, and/or introducing an additive in the process, to adjust a base-acid ratio or other compositional parameter; and recovering a biocarbon composition comprising from 50 wt % to 99 wt % total carbon and optimized for a compositional parameter.

Abstract: In some variations, the disclosure provides a renewable biocarbon composition comprising from 50 wt % to 99 wt % total carbon, wherein the biocarbon composition is characterized by a base-acid ratio selected from 0.1 to 10, an iron-calcium ratio selected from 0.05 to 5, iron-plus-calcium parameter selected from 5 to 50 wt %, a slagging factor selected from 0.001 to 1, and/or a fouling factor or modified fouling factor selected from 0.1 to 10. Some variations provide a process comprising: providing a biomass feedstock; pyrolyzing the biomass feedstock to generate an intermediate biocarbon stream; washing or treating the intermediate biocarbon stream with an acid, a base, a salt, a metal, H2, H2O, CO, CO2, or a combination thereof, and/or introducing an additive in the process, to adjust a base-acid ratio or other compositional parameter; and recovering a biocarbon composition comprising from 50 wt % to 99 wt % total carbon and optimized for a compositional parameter.

Abstract: Some variations provide a carbon-negative carbon product that is characterized by a carbon intensity less than 0 kg CO2e per metric ton of the carbon-negative carbon product, wherein the carbon-negative carbon product contains at least about 50 wt % carbon. In some embodiments, the carbon intensity is less than ?500 kg CO2e per metric ton of the carbon-negative carbon product. Other variations provide a carbon-negative metal product (e.g., a steel product) that is characterized by a carbon intensity less than 0 kg CO2e per metric ton of the carbon-negative metal product, wherein the metal product contains from 50 wt % to 100 wt % of one or more metals and optionally one or more alloying elements. In some embodiments, the carbon-negative metal product is characterized by a carbon intensity less than ?200 kg CO2e per metric ton of the carbon-negative metal product. The carbon-negative metal product can contain a wide variety of metals.

Abstract: Some variations provide a biomedia composition comprising: from 50 wt % to 75 wt % total carbon, on a dry basis, according to ASTM D5373, wherein the total carbon is renewable according to ASTM D6866 (14C/12C isotopic ratio); from 20 wt % to 40 wt % oxygen, on a dry basis, according ASTM D5373; from 3 wt % to 10 wt % hydrogen, on a dry basis, according to ASTM D5373; and from 0.1 wt % to 2 wt % nitrogen, on a dry basis, according to ASTM D5373, wherein the biomedia composition is characterized by volatile-matter content from 50 wt % to 75 wt %, according to ASTM D3175; wherein the biomedia composition is characterized by ash content from 1 wt % to 25 wt %, according to ASTM D3174; and wherein the biomedia composition is characterized by moisture content from 0 to 75 wt %, according to ASTM D3173. Processes are also described to make and use the biomedia compositions.

Abstract: The disclosed technology provides processes for producing hydrogen that is renewable, has negative carbon intensity, and is associated with net water production. The hydrogen is economically, environmentally, and socially superior to conventional hydrogen via steam reforming of natural gas or electrolysis of water. Some variations provide a process for manufacturing carbon-negative hydrogen and optionally activated carbon, comprising: feeding biomass into a first heated vessel or zone to generate dried biomass and a first recovered water stream; feeding the dried biomass into a second heated vessel or zone to pyrolyze the dried biomass, generating a biocatalyst and a biogas; feeding the biocatalyst, the first recovered water stream, and biogas to a third heated vessel or zone for biocatalytic conversion, thereby generating H2, CO, and optionally activated carbon; and recovering the hydrogen. The H2 is carbon-negative hydrogen characterized by a carbon intensity less than 0 kg CO2e per metric ton H2.

Abstract: The disclosed technology provides processes for producing hydrogen that is renewable, has negative carbon intensity, and is associated with net water production. The hydrogen is economically, environmentally, and socially superior to conventional hydrogen via steam reforming of natural gas or electrolysis of water. Some variations provide a process for manufacturing carbon-negative hydrogen and optionally activated carbon, comprising: feeding biomass into a first heated vessel or zone to generate dried biomass and a first recovered water stream; feeding the dried biomass into a second heated vessel or zone to pyrolyze the dried biomass, generating a biocatalyst and a biogas; feeding the biocatalyst, the first recovered water stream, and biogas to a third heated vessel or zone for biocatalytic conversion, thereby generating H2, CO, and optionally activated carbon; and recovering the hydrogen. The H2 is carbon-negative hydrogen characterized by a carbon intensity less than 0 kg CO2e per metric ton H2.

Abstract: Some variations provide a biomedia composition comprising: from 50 wt % to 75 wt % total carbon, on a dry basis, according to ASTM D5373, wherein the total carbon is renewable according to ASTM D6866 (14C/12C isotopic ratio); from 20 wt % to 40 wt % oxygen, on a dry basis, according ASTM D5373; from 3 wt % to 10 wt % hydrogen, on a dry basis, according to ASTM D5373; and from 0.1 wt % to 2 wt % nitrogen, on a dry basis, according to ASTM D5373, wherein the biomedia composition is characterized by volatile-matter content from 50 wt % to 75 wt %, according to ASTM D3175; wherein the biomedia composition is characterized by ash content from 1 wt % to 25 wt %, according to ASTM D3174; and wherein the biomedia composition is characterized by moisture content from 0 to 75 wt %, according to ASTM D3173. Processes are also described to make and use the biomedia compositions.

Abstract: Some variations provide a process for producing biocarbon pellets, comprising: pyrolyzing a biomass-containing feedstock in a first pyrolysis reactor to generate a first biogenic reagent and a pyrolysis vapor; introducing the pyrolysis vapor to a separation unit, to generate a pyrolysis precipitate in liquid or solid form; contacting the first biogenic reagent with the pyrolysis precipitate, thereby generating an intermediate material; pelletizing the intermediate material, to generate intermediate pellets; optionally, drying the intermediate pellets; separately pyrolyzing the intermediate pellets in a second pyrolysis reactor to generate a second biogenic reagent and a pyrolysis off-gas; and recovering the second biogenic reagent as biocarbon pellets. Some variations provide a similar process that utilizes a carbon-containing condensed-matter material, which is not necessarily a pyrolysis precipitate.

Abstract: Some variations provide a biomedia composition comprising: from 50 wt % to 75 wt % total carbon, on a dry basis, according to ASTM D5373, wherein the total carbon is renewable according to ASTM D6866 (14C/12C isotopic ratio); from 20 wt % to 40 wt % oxygen, on a dry basis, according ASTM D5373; from 3 wt % to 10 wt % hydrogen, on a dry basis, according to ASTM D5373; and from 0.1 wt % to 2 wt % nitrogen, on a dry basis, according to ASTM D5373, wherein the biomedia composition is characterized by volatile-matter content from 50 wt % to 75 wt %, according to ASTM D3175; wherein the biomedia composition is characterized by ash content from 1 wt % to 25 wt %, according to ASTM D3174; and wherein the biomedia composition is characterized by moisture content from 0 to 75 wt %, according to ASTM D3173. Processes are also described to make and use the biomedia compositions.

Abstract: In some variations, the invention provides a biocarbon composition comprising a low fixed carbon material with a fixed carbon concentration from 20 wt % to 55 wt %; a high fixed carbon material with a fixed carbon concentration from 50 wt % to 100 wt % (and higher than the fixed carbon concentration of the low fixed carbon material; from 0 to 30 wt % moisture; from 0 to 15 wt % ash; and from 0 to 20 wt % of one or more additives (such as a binder).

Abstract: In some variations, the invention provides a biocarbon composition comprising a low fixed carbon material with a fixed carbon concentration from 20 wt % to 55 wt %; a high fixed carbon material with a fixed carbon concentration from 50 wt % to 100 wt % (and higher than the fixed carbon concentration of the low fixed carbon material; from 0 to 30 wt % moisture; from 0 to 15 wt % ash; and from 0 to 20 wt % of one or more additives (such as a binder).

Abstract: Some variations provide a carbon-negative carbon product that is characterized by a carbon intensity less than 0 kg CO2e per metric ton of the carbon-negative carbon product, wherein the carbon-negative carbon product contains at least about 50 wt % carbon. In some embodiments, the carbon intensity is less than ?500 kg CO2e per metric ton of the carbon-negative carbon product. Other variations provide a carbon-negative metal product (e.g., a steel product) that is characterized by a carbon intensity less than 0 kg CO2e per metric ton of the carbon-negative metal product, wherein the metal product contains from 50 wt % to 100 wt % of one or more metals and optionally one or more alloying elements. In some embodiments, the carbon-negative metal product is characterized by a carbon intensity less than ?200 kg CO2e per metric ton of the carbon-negative metal product. The carbon-negative metal product can contain a wide variety of metals.

Abstract: Some variations provide a carbon-negative carbon product that is characterized by a carbon intensity less than 0 kg CO2e per metric ton of the carbon-negative carbon product, wherein the carbon-negative carbon product contains at least about 50 wt % carbon. In some embodiments, the carbon intensity is less than ?500 kg CO2e per metric ton of the carbon-negative carbon product. Other variations provide a carbon-negative metal product (e.g., a steel product) that is characterized by a carbon intensity less than 0 kg CO2e per metric ton of the carbon-negative metal product, wherein the metal product contains from 50 wt % to 100 wt % of one or more metals and optionally one or more alloying elements. In some embodiments, the carbon-negative metal product is characterized by a carbon intensity less than ?200 kg CO2e per metric ton of the carbon-negative metal product. The carbon-negative metal product can contain a wide variety of metals.

Abstract: A process for producing biocoke is provided, comprising: providing a heated biogas stream comprising carbon-containing vapors; providing a kinetic interface media, in solid form; introducing the kinetic interface media and the heated biogas stream to a kinetic interface reactor, operated to convert at least some of the carbon-containing vapors to biocoke; removing the solid biocoke-containing kinetic interface media from the kinetic interface reactor; and recovering the solid biocoke-containing kinetic interface media.

Abstract: A process for producing biocoke is provided, comprising: providing a heated biogas stream comprising carbon-containing vapors; providing a kinetic interface media, in solid form; introducing the kinetic interface media and the heated biogas stream to a kinetic interface reactor, operated to convert at least some of the carbon-containing vapors to biocoke; removing the solid biocoke-containing kinetic interface media from the kinetic interface reactor; and recovering the solid biocoke-containing kinetic interface media.