Abstract: The disclosure describes a one reactor process for making a bio-based polyester resin and the polyester polymer thereof The bio-based polymer is the product of a condensation reaction of (a) a rosin diol, (b) neopentyl glycol, (c) succinic acid, (d) an aromatic dicarboxylic acid and (e) dipropylene glycol or tripropvlene glycol, wherein the rosin diol is a reaction product between a rosin acid and a cyclic alkylene glycol and comprises only one rosin moiety. The resultant polyester resin retains thermal properties as compared to a similar resin but made using previous multi-step processes conducted in separate vessels.

Abstract: Incorporation of organic amines as neutralization agents in based phase inversion emulsification (PIE) processes to provide emulsification of high molecular amorphous and high molecular branch amorphous polyester resins, which are traditionally difficult to emulsify. The organic amines facilitate emulsification of these resins to achieve desired particle size with a narrow size distribution.

Abstract: The disclosure provides a toner composition comprising toner particles with a core and a shell, wherein the core comprises a polyester polymer and a styrene acrylate polymer, and the shell comprises a polyester polymer and, optionally, a styrene acrylate polymer, either or both of which can be the same or different from that in the core.

Abstract: The disclosure describes a one reaction process for making a bio-based polyester resin. The resultant polyester resin retains thermal properties as compared to a similar resin but made using previous multi-step processes conducted in separate vessels.

Abstract: Disclosed herein are sacrificial coating compositions comprising at least one hydrophilic polymer; at least one hygroscopic agent; at least one surfactant; at least one non-reactive silicone release agent; and water. In certain embodiments, the at least one non-reactive silicone release agent is chosen from polyether modified polysiloxane and nonreactive silicone glycol copolymers. In certain embodiments, the at least one non-reactive silicone release agent may be present in an amount ranging from about 0.001% to about 2%, based on the total weight of the composition, such as from about 0.03% to about 0.06%. Also disclosed herein is a blanket material suitable for transfix printing comprising a sacrificial coating composition, as well as an indirect printing process comprising a step of applying a sacrificial coating composition to a blanket material.

Abstract: A toner includes a polymeric resin, a colorant, and a small molecule crystalline aromatic monoester having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline aromatic monoester may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline aromatic monoester as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline aromatic monoester in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline aromatic monoester in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline aromatic monoesters may include 2-Naphthyl benzoate.

Abstract: A toner includes a polymeric resin, a colorant, and a small molecule crystalline aromatic monoester having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline aromatic monoester may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline aromatic monoester as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline aromatic monoester in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline aromatic monoester in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline aromatic monoesters may include 2-Naphthyl benzoate.

Abstract: An emulsion aggregation toner composition includes toner particles including: an unsaturated polymeric resin, such as amorphous resins, crystalline resins, and combinations thereof; an optional colorant; an optional wax; an optional coagulant; and a photoinitiator. By optimizing the particle size of the emulsion, the aggregant concentration utilized in the emulsion aggregation process, and the solids content of the emulsion, toners may be produced capable of generating images with non-contact fusing that have high gloss.

Abstract: There is provided a homogenous composite dispersion. The composite dispersion is made from ingredients comprising: a first dispersion comprising a filler dispersed in a liquid continuous phase, the filler selected from the group consisting of nanotubes, graphene or a combination thereof, the liquid continuous phase comprising an acid copolymer and a first solvent, the acid copolymer comprising at least one carboxyl functionalized polymeric unit and at least one carboxylate ester functionalized polymeric unit having an alkyl or fluorinated alkyl attached to an oxygen atom of the carboxylate ester; a second dispersion comprising a fluoroplastic dispersed in a second solvent; and a sacrificial polymeric binder material.

Abstract: Incorporation of organic amines as neutralization agents in based phase inversion emulsification (PIE) processes to provide emulsification of high molecular amorphous and high molecular branch amorphous polyester resins, which are traditionally difficult to emulsify. The organic amines facilitate emulsification of these resins to achieve desired particle size with a narrow size distribution.

Abstract: There is provided a homogenous composite dispersion. The composite dispersion is made from ingredients comprising: a first dispersion comprising a filler dispersed in a liquid continuous phase, the filler selected from the group consisting of nanotubes, graphene or a combination thereof, the liquid continuous phase comprising an acid copolymer and a first solvent, the acid copolymer comprising at least one carboxyl functionalized polymeric unit and at least one carboxylate ester functionalized polymeric unit having an alkyl or fluorinated alkyl attached to an oxygen atom of the carboxylate ester; a second dispersion comprising a fluoroplastic dispersed in a second solvent; and a sacrificial polymeric binder material.

Abstract: A toner includes a polymeric resin, optionally a colorant, and a small molecule crystalline aromatic ether having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline aromatic ether may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline aromatic ether as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline aromatic ether in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline aromatic ether in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline aromatic ethers may include benzyl 2-naphthyl ether.

Abstract: A fuser comprises a substrate and a composite layer formed on the substrate. The composite layer comprises a fluoropolymer and at least one of (a) perfluorosulfonated polymer-treated, carbon nanotube-comprising particles, and (b) perfluorosulfonated polymer-treated, graphene-comprising particles. Methods of making a fuser and methods of fusing toner particles are also disclosed.

Abstract: A member for a fuser assembly of a printer. The member may include a support body and a composite coating disposed on an outer surface of the support body. The composite coating may include a fluororesin and a nanocarbon material dispersed within the fluororesin. The nanocarbon material may be present in a higher concentration proximate the support body and a lower concentration proximate an outer surface of the composite coating. The lower concentration may be less than or equal to about 2 wt % of the nanocarbon material.

Abstract: An indirect printing apparatus can include an intermediate transfer member, at least one jetting nozzle of a printhead positioned proximate the intermediate transfer member for jetting sacrificial coating composition droplets imagewise onto the intermediate transfer member, a drying station, at least one ink jet nozzle positioned proximate the intermediate transfer member, an ink processing station, and a substrate transfer mechanism. The drying station can be configured for drying the sacrificial coating composition to form a sacrificial coating pattern on the intermediate transfer member. The at least one ink jet nozzle can be configured for jetting ink droplets onto the sacrificial coating formed on the intermediate transfer member. The ink processing station can be configured to at least partially dry the ink on the sacrificial coating formed on the intermediate transfer member. The substrate transfer mechanism can be configured for moving a substrate into contact with the intermediate transfer member.

Abstract: Toners and processes useful in providing toners suitable for electrophotographic apparatuses, including apparatuses such as digital, image-on-image, and similar apparatuses. In particular, emulsion aggregate toner compositions that use two different emulsion aggregation (EA) technologies and which comprise a base resin composed of both styrene-acrylate and polyester resins. These toner compositions further include polyaluminum chloride (PAC) instead of the more commonly used aluminum sulfate as the flocculant or aggregating agent.

Abstract: A toner includes a polymeric resin, optionally a colorant, and a small molecule crystalline diester having an aromatic core and a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline aromatic diester may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a significant solid to liquid phase transition peak for the small molecule compound as determined by differential scanning calorimetry, the enthalpy of fusion for the small molecule compound in the mixture being measured to be less than 10% of the enthalpy of fusion of the compound in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner.

Abstract: An emulsion aggregation (EA) toner includes an amorphous polymeric resin, optionally a colorant, and a small molecule crystalline organic compound having molecular weight less than 1,000 g/mol and melting point less than the fusing temperature of the EA toner, wherein a mixture of the resin and the small molecule compound is characterized by a reduction in glass transition temperature from that of the resin and by the lack of a significant solid to liquid phase transition peak for the small molecule compound as determined by differential scanning calorimetry, the enthalpy of fusion for the small molecule compound in the mixture being measured to be less than 10% of the enthalpy of fusion of the compound in pure form. Furthermore, the EA toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner.

Abstract: There is described a fuser member comprising a substrate layer and a surface layer disposed on the substrate. The surface layer comprises a non-woven polymer fiber matrix having dispersed throughout a cross-linked fluoropolymer and a release agent. The release agent is a liquid at a temperature about 100° C.

Abstract: Disclosed is toner particles having controlled and tailorable fusing characteristics. In particular, there is provided toner particles comprising styrene acrylate which have specific shape characteristics that allow for tailorable fusing characteristics without generating a detrimental effect on the blocking characteristics of such toners.