Patent number: 6200654
Abstract: 1,4-disubstituted 2,6-difluorobenzene compound of formula I
wherein
R is an alkyl or alkenyl radical,
A1 and A2, in each case independently of one another, are
(a) a trans-1,4-cyclohexylene radical in which a CH2 group may be replaced by —O— and/or —S,
(b) a 1,4-phenylene radical in which a CH group may be replaced by N,
(c) 1,4-cyclohexenylene, 1,4-bicyclo(2,2,2)octylene, piperidine-1,4-diyl, naphthalene-2,6-diyl, decahydronaphthalene-2,6-diyl or 1,2,3,4-tetrahydronaphthalene-2,6-diyl,
Z1 and Z2 are —CO—O—, —O—CO—, —CH2—O—, —OCH2—, —CH2CH2—, —CH═CH—, —C≡C— or a single bond
m and n are 0, 1, 2 or 3,
(m+n) is 1, 2 or 3,
X is R or F, Cl, CF3, —OCF3, or —OCHF2, —OCF5, —CN or —NCS
with the proviso that at least one of the radicals A1 and A2 present in the molecule is
are suitable as components of liquid-c
Type:
Grant
Filed:
August 25, 1997
Date of Patent:
March 13, 2001
Assignee:
Merck Patent Gesellschaft mit beschrankter Haftung
Inventors:
Eike Poetsch, Volker Meyer, Volker Reiffenrath, Andreas Wachtler, Ulrich Finkenzeller, Hans Adolf Kurmeier, Reinhard Hittich, Bernhard Rieger, David Coates, Simon Greenfield, Robert William Clemitson
Patent number: 5891360
Abstract: Novel phenylcyclohexanes of the formula I ##STR1## in which n is 0 to 7, Q.sup.1 and Q.sup.2 are H, or one of these radicals is alternatively CH.sub.3, r is 0, 1, 2, 3, 4 or 5, A is trans-1,4-cyclohexylene, 1,4-phenylene, 3-fluoro-1,4-phenylene or a single bond, X is F, Cl, --CF.sub.3, --CN, --OCF.sub.3 or --OCHF.sub.2, and Y and Z are each, independently of one another, H or F, with the proviso that, in the case where A is a single bond, Q.sup.1 =Q.sup.2 =H and simultaneously X=CN, Y and/or Z are F.
Type:
Grant
Filed:
April 15, 1993
Date of Patent:
April 6, 1999
Assignee:
Merck Patent Gesellschaft MIT Beschrankter
Inventors:
Andreas Wachtler, Reinhard Hittich, Eike Poetsch, Herbert Plach, David Coates, Bernhard Rieger, Joachim Krause
Patent number: 5837162
Abstract: Liquid-crystalline compounds of the formula I ##STR1## R is H, an alkyl or alkylene radical, Z.sup.1 and Z are each, independently of one another, --CH.sub.2 CH.sub.2 --, --CH.dbd.CH--,--C.tbd.C-- or a single bond, and one of the radicals Z.sup.1 and Z is alternatively --(CH.sub.2).sub.4 -- or --CH.dbd.CH--CH.sub.2 CH.sub.2 --,A is trans-1,4-cyclohexylene in which, in addition, one or two non-adjacent CH.sub.2 groups may be replaced by --O--,A.sup.1 is trans-1,4-cyclohexylene in which, in addition, one or two non-adjacent CH.sub.2 groups may be replaced by --O--, or is 1,4-phenylene which is unsubstituted or monosubstituted or disubstituted by fluorine and/or Cl atoms and in which, in addition, one or two CH groups may be replaced by N,W is --O--,Q is a single bond,m, o, s, r and t are as defined below,Y is F, Cl, OCF.sub.3, CHF.sub.2, OCHF.sub.2 or OCHF, and can be CF.sub.3,are suitable as components for liquid-crystalline media.
Type:
Grant
Filed:
January 30, 1997
Date of Patent:
November 17, 1998
Assignee:
Merck Patent Gesellschaft mit Beschrankter Haftung
Inventors:
Volker Reiffenrath, Herbert Plach, Detlef Pauluth, Reinhard Hittich, Eike Poetsch, Thomas Geelhaar, Georg Weber, Ekkehard Bartmann