Abstract: A method of preparing an amorphous film of lithiated metal sulfide or oxysulfide of formula Li?M(O1-?S?)? using a lithiated target material: M being advantageously selected from the group comprising Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ge, Zr, Nb, Mo, Ag, Cd, In, Sn, Sb, Ta, W, Pb, Bi, and mixtures thereof; and ??0.5; 1????; 2??/???.

Abstract: The method for producing a stack of films provided with at least one 3D-structured pattern including providing a first mold having a textured front face including a first 3D pattern, depositing a first layer of the stack on the textured front face so as to cover the first 3D pattern by a continuous layer, the first layer having a first face in contact with the front face of the mold, removing the first mold so as to release the first face of the first layer having a second 3D pattern complementary to the first 3D pattern and depositing a second layer of the stack on the first face of the first layer so as to cover the second 3D pattern by a continuous layer.

Abstract: A method for producing lithium-ion batteries comprising the steps of (a) forming, on a substrate, a cathode current collector layer and a stack of a cathode layer made from a material capable of inserting lithium ions, an electrolyte layer and an anode layer, (b) depositing a lithium layer on the anode layer in order to form a lithium alloy, (c) short-circuiting the anode and cathode layers by depositing an anode current collector layer on the anode layer, thereby causing the diffusion of the lithium ions from the anode layer to the cathode layer, and (d) separating the batteries, resulting in the opening of the short-circuit between the anode and cathode layers in all the batteries. The method simplifies and improves the method for producing lithium-ion microbatteries and improves the diffusion of the lithium ions from the anode layer to the cathode layer after short-circuiting these two layers.

Abstract: A method for determining the self-discharge current of a lithium-ion battery provided with a positive electrode, a negative electrode, and an electrolyte arranged between the positive and negative electrodes includes charging the battery until a metal lithium layer is formed between the electrolyte and the negative electrode, measuring the open-circuit voltage of the battery at two moments, and determining the self-discharge current from the variation of the voltage measured between the two moments.

Abstract: A method of preparing an amorphous film of lithiated metal sulfide or oxysulfide of formula Li?M(O1-?S?)? using a lithiated target material: M being advantageously selected from the group comprising Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ge, Zr, Nb, Mo, Ag, Cd, In, Sn, Sb, Ta, W, Pb, Bi, and mixtures thereof; and ??0.5; 1????; 2??/???.

Abstract: The method for producing a stack of films provided with at least one 3D-structured pattern including providing a first mould having a textured front face including a first 3D pattern, depositing a first layer of the stack on the textured front face so as to cover the first 3D pattern by a continuous layer, the first layer having a first face in contact with the front face of the mould, removing the first mould so as to release the first face of the first layer having a second 3D pattern complementary to the first 3D pattern and depositing a second layer of the stack on the first face of the first layer so as to cover the second 3D pattern by a continuous layer.

Abstract: A method for producing lithium-ion batteries comprising the steps of (a) forming, on a substrate, a cathode current collector layer and a stack of a cathode layer made from a material capable of inserting lithium ions, an electrolyte layer and an anode layer, (b) depositing a lithium layer on the anode layer in order to form a lithium alloy, (c) short-circuiting the anode and cathode layers by depositing an anode current collector layer on the anode layer, thereby causing the diffusion of the lithium ions from the anode layer to the cathode layer, and (d) separating the batteries, resulting in the opening of the short-circuit between the anode and cathode layers in all the batteries. The method simplifies and improves the method for producing lithium-ion microbatteries and improves the diffusion of the lithium ions from the anode layer to the cathode layer after short-circuiting these two layers.

Abstract: The invention relates to an all-solid-state lithium battery and to a method for producing such a battery. The all-solid-state lithium battery includes first and second electrodes separated by a solid electrolyte. The second electrode is formed by a composite material including an electrochemically-active material made of a lithium-ion insertion material, and an amorphous lithium-based material which is an ionic conductor for the lithium ions and which is inert relative to the electrochemically active material.

Abstract: The invention relates to a material comprising carbon nanotubes, deposited at the surface of each of which is a substantially continuous film of nanoscale silicon particles, that can be used in negative electrodes for a lithium battery.

Abstract: A method for determining the self-discharge current of a lithium-ion battery provided with a positive electrode, a negative electrode, and an electrolyte arranged between the positive and negative electrodes includes charging the battery until a metal lithium layer is formed between the electrolyte and the negative electrode, measuring the open-circuit voltage of the battery at two moments, and determining the self-discharge current from the variation of the voltage measured between the two moments.

Abstract: Process for the preparation of an insertion compound of an alkali metal in which the following successive stages are carried out: a) an organic complex of a transition metal or of a mixture of transition metals M in an oxidation state of greater than 2 is brought into contact with an alkali metal A in the ionic form and with an entity of formula Hb(XO4), where X is chosen from Si, S, Al, P, Ge, As or Mo and b has a value from 0 to 5, in a liquid medium in a closed chamber; the chamber is brought to a temperature T which makes possible the decomposition of the organic complex in the said liquid medium; the temperature and the pressure in the chamber are brought back to ambient temperature and atmospheric pressure and the insertion compound for an alkali metal of formula AMXO4, in which M is in the +2 oxidation state, is recovered.

Abstract: The invention relates to an all-solid-state lithium battery and to a method for producing such a battery. The all-solid-state lithium battery includes first and second electrodes separated by a solid electrolyte. The second electrode is formed by a composite material including an electrochemically-active material made of a lithium-ion insertion material, and an amorphous lithium-based material which is an ionic conductor for the lithium ions and which is inert relative to the electrochemically active material.

Abstract: The LiMPO4 compound is synthesized by reacting a compound of general formula XMPO4, nH2O where X represents a radical selected from —NH4 and —H and M is a transition metal selected from Co, Ni and Mn, with a lithium source such as lithium nitrate, at a temperature lower than or equal to 350° C. The XMPO4, nH2O compound further exhibits a particular morphology in the form of platelets that is preserved during the reaction between the two precursors. The LiMPO4 compound thus synthesized is advantageously used as active material of an electrode for a lithium storage battery.

Abstract: A material or compound is provided having a spinel structure and corresponding to the formula LiyNi0.5Mn1.5?xIVMnxIIIAzO4?d, where: 0.02?x?0.35; d>0; A is selected from the group comprising Na, K, Mg, Nb, Al, Ni, Co, Zr, Cr, Fe, Cu, Ti, Zn, Si and Mo; 0.8?y?1.2; 0?z?0.1; and has a mesh parameter of between 8.174 and 8.179 ?.

Abstract: The lithium-ion microbattery comprises a positive electrode having a first Li+ ion storage capacity and a first thickness made from a first lithium insertion material, an electrolyte and a negative electrode having a second storage capacity and a second thickness made from a second insertion material. The thicknesses are such that the ratio of the first storage capacity over the second storage capacity is greater than or equal to 10 and lower than or equal to 1000. During the first charging of the micro-battery, the Li+ ions are inserted in the negative electrode and completely saturate the second insertion material. When initial charging is continued, they form a metallic lithium layer between the electrolyte and the lithium-saturated negative electrode by electroplating. During the subsequent charging and discharging cycles, only the metallic lithium layer participates in transfer of lithium ions.

Abstract: A non-volatile electrochemical memory cell formed of a stack of thin films comprising at least one first active layer, suited to releasing and accepting, in a reversible manner, at least one ion species, at least one second active layer, suited to releasing and accepting said ion species, in a reversible manner, the active layers being based on materials having different compositions and electrochemical potential profiles.

Abstract: A material or compound is provided having a spinel structure and corresponding to the formula LiyNi0.5Mn1.5?xIVMnxIIIAzO4?d, where: 0.02?x?0.35; d>0; A is selected from the group comprising Na, K, Mg, Nb, Al, Ni, Co, Zr, Cr, Fe, Cu, Ti, Zn, Si and Mo; 0.8?y?1.2; 0?z?0.1; and has a mesh parameter of between 8.174 and 8.179 ?.

Abstract: The present invention relates to a method of chemically modifying a lithium-based oxide comprising at least one transition metal, which comprises, in succession: a step of bringing said oxide into contact with an aqueous solution comprising phosphate ions; a step of separating said oxide from the aqueous solution; and a step of drying said oxide. Use of the modified lithium transition metal oxide as active positive electrode material for a lithium secondary battery.

Abstract: Process for preparing composite silicon/carbon material composed of carbon-coated silicon particles, wherein the following successive steps are carried out: silicon particles are mixed with a solution of an oxygen-free polymer in a solvent, whereby a dispersion of silicon particles in the polymer solution is obtained; the dispersion obtained in step a) is subjected to a spray-drying operation whereby a composite silicon/polymer material consisting of silicon particles coated with the polymer is obtained; the material obtained in step a) is pyrolyzed whereby the composite silicon/carbon material composed of carbon-coated silicon particles is obtained.

Abstract: The invention relates to a lithium battery, comprising at least one lithium intercalation compound, made up of crystallites and obtained by a production method, comprising at least the following steps: formation of a homogeneous mixture of at least one precursor for the lithium intercalation compound with a given adjunct, chemically stable with relation to crystallites and designed to limit the growth of crystallites or crystallite precursors during the formation thereof, thermal treatment of the homogeneous mixture for the synthesis of the lithium intercalation compound in the form of crystallites and to give a composite material comprising at least two phases formed respectively by the lithium intercalation compound and the adjunct and forming of the composite material to give said electrode. The invention further relates to an electrode obtained by said method and lithium battery comprising such an electrode.