Patents by Inventor Francois Ledoux
Francois Ledoux has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20240132421Abstract: An explosive emulsion composition of the water-in-oil type, comprising between 80 wt. % and 95 wt. % of an oxidizer phase composition comprising at least 40 wt. % of ammonium nitrate (AN), and at least 15 wt. % of calcium nitrate (CN), and optionally one or more other secondary nitrate salts, between 5 wt. % and 20 wt. % of an organic phase comprising between 12 wt. % and 50 wt. % of one or more emulsifiers, between 50 wt. % and 88 wt. % of a fuel composition, in view of the total weight of the organic phase composition, characterized in that the fuel composition comprises between 20 wt. % and 100 wt. % of a straight vegetable oil (SVO), and wherein the explosive emulsion composition is stable and has a viscosity between 25,000 cP and 125,000 cP, as measured with a Brookfield viscometer with spindle size 7 at a frequency of 20 rpm at 30° C.Type: ApplicationFiled: March 8, 2022Publication date: April 25, 2024Inventors: Francois LEDOUX, Petr CHLADEK
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Publication number: 20240076247Abstract: An explosive emulsion composition of the water-in-oil type, comprising: between 80 wt. % and 95 wt. % of an oxidizer phase in view of the total weight of the emulsion composition, comprising at least 40 wt. % of ammonium nitrate (AN), and at least 5 wt. % of a secondary nitrate salt, in view of the total weight of the oxidizer phase composition, and between 5 wt. % and 20 wt. % of an organic phase in view of the total weight of the emulsion composition, the organic phase comprising: between 12 wt. % and 50 wt. % of one or more emulsifiers, between 50 wt. % and 88 wt. % of a fuel composition, in view of the total weight of the organic phase composition, characterized in that the fuel composition comprises between 20 wt. % and 100 wt. % of a hydrotreated vegetable oil (HVO), in view of the total weight of the fuel composition.Type: ApplicationFiled: March 8, 2022Publication date: March 7, 2024Inventors: Francois LEDOUX, Petr CHLADEK
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Publication number: 20240051888Abstract: A method is disclosed for the manufacture of a homogeneous, solid, particulate, urea-based composition comprising urea and an additive in a urea production plant comprising at least an evaporator section and a particulation section, further comprising one or more of a mixing section, an effluent gas treatment section and a scrubber solution storage section, comprising the steps of: (i) concentrating a urea melt of about 80 weight % to about 95 to 99 weight % of urea; (ii) particulating a urea or urea-based melt into a urea or urea-based composition; (iii) mixing the urea melt of about 95 to 99 weight % with other fertilizer components to produce a urea-based melt; (iv) treating the effluent gas from the particulation section comprising urea-based dust particles and ammonia gas with water to produce a scrubber solution; and (v) storing the scrubber solution from the effluent gas treatment section.Type: ApplicationFiled: December 21, 2021Publication date: February 15, 2024Inventors: Ruud VAN BELZEN, Filip COLPAERT, Francois LEDOUX
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Patent number: 11572318Abstract: This invention relates to a method for the manufacture of a homogeneous, solid, particulate, urea-based material comprising elemental sulphur. The invention further relates to a homogeneous, solid, particulate urea-based material comprising small elemental sulphur phases in a urea-based base material and formed by an accretion process. The product is in particular suitable as a fertilizer.Type: GrantFiled: March 23, 2021Date of Patent: February 7, 2023Assignee: Yara International ASAInventors: Francois Ledoux, Filip Colpaert
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Patent number: 11135559Abstract: The present application relates to a closed container containing ammonium nitrate (AN) particles in an amount of 91 to 99.75 weight % and desiccant in an amount of 0.25 and 9 weight %, wherein the AN particles have a water content of between 0 and 0.7 weight %, and the desiccant particles comprise between 50 and 95 weight % of AN and between 5 and 50 weight % of magnesium nitrate dispersed in the AN. The application furthermore relates to a method for producing of ammonium nitrate particles that are stored in a closed container and having improved anti-caking properties.Type: GrantFiled: June 22, 2018Date of Patent: October 5, 2021Assignee: YARA INIERNATIONAL ASAInventor: Francois Ledoux
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Patent number: 11072567Abstract: The invention relates to a solid, particulate, urea-based blend composition comprising a urea-based compound in particulate form, one or more components in particulate form, selected from the group of nitrates, phosphates, sulphates and chlorides, and a urease inhibitor of the type phosphoric triamide, in particular N-(n-butyl) thiophosphoric triamide (nBTPT), wherein the urea-based blend composition is further characterized in that it comprises one or more reactive alkaline or alkaline-forming inorganic or organic compounds. The composition according to the invention has been stabilized against the degradation of a urease inhibitor of the type phosphoric triamide, in particular N-(n-butyl) thiophosphoric triamide (nBTPT). The invention further relates to a method for the manufacture of the claimed solid, particulate, urea-based blend composition.Type: GrantFiled: November 10, 2016Date of Patent: July 27, 2021Assignee: YARA INTERNATIONAL ASAInventors: Francois Ledoux, Filip Colpaert, Ruud Van Belzen
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Publication number: 20210214281Abstract: This invention relates to a method for the manufacture of a homogeneous, solid, particulate, urea-based material comprising elemental sulphur. The invention further relates to a homogeneous, solid, particulate urea-based material comprising small elemental sulphur phases in a urea-based base material and formed by an accretion process. The product is in particular suitable as a fertilizer.Type: ApplicationFiled: March 23, 2021Publication date: July 15, 2021Applicant: Yara International ASAInventors: Francois Ledoux, Filip Colpaert
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Patent number: 11053170Abstract: The present application generally relates to a method for the manufacture of a liquid composition essentially consisting of an organic solvent of the type glycol and a urease inhibitor of the type phosphoric triamide and products obtained therewith.Type: GrantFiled: February 24, 2017Date of Patent: July 6, 2021Assignee: YARA INTERNATIONAL ASAInventors: Filip Colpaert, Francois Ledoux, Ruud Van Belzen
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Patent number: 10974998Abstract: This invention relates to a method for the manufacture of a homogeneous, solid, particulate, urea-based material comprising elemental sulphur. The invention further relates to a homogeneous, solid, particulate urea-based material comprising small elemental sulphur phases in a urea-based base material and formed by an accretion process. The product is in particular suitable as a fertilizer.Type: GrantFiled: November 4, 2019Date of Patent: April 13, 2021Assignee: Yara International ASAInventors: Francois Ledoux, Filip Colpaert
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Patent number: 10626058Abstract: The invention relates to a homogeneous, solid, particulate, urea ammonium sulphate-based composition comprising urea ammonium sulphate and a urease inhibitor of the type phosphoric triamide, wherein the urea ammonium sulphate-based composition is further characterized in that one or more of the following measures applies: a) it comprises 5 weight % or less, relative to the total weight of the composition, of one or more alkaline or alkaline-forming inorganic or organic compounds that is able to interact with ammonium sulphate; b) the urease inhibitor of the type phosphoric triamide is in a solid particulate form; c) an anticaking and/or moisture repellent coating is applied onto the urea ammonium sulphate particulate material. The composition according to the invention has improved properties for reducing ammonia loss by urease activity in the soil and is in particular suitable as a fertilizer.Type: GrantFiled: September 7, 2016Date of Patent: April 21, 2020Assignee: Yara International ASAInventors: Filip Colpaert, Francois Ledoux, Ruud Van Belzen
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Publication number: 20200062665Abstract: This invention relates to a method for the manufacture of a homogeneous, solid, particulate, urea-based material comprising elemental sulphur. The invention further relates to a homogeneous, solid, particulate urea-based material comprising small elemental sulphur phases in a urea-based base material and formed by an accretion process. The product is in particular suitable as a fertilizer.Type: ApplicationFiled: November 4, 2019Publication date: February 27, 2020Applicant: Yara International ASAInventors: Francois Ledoux, Filip Colpaert
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Publication number: 20200016556Abstract: The present application relates to a closed container containing ammonium nitrate (AN) particles in an amount of 91 to 99.75 weight % and desiccant in an amount of 0.25 and 9 weight %, wherein the AN particles have a water content of between 0 and 0.7 weight %, and the desiccant particles comprise between 50 and 95 weight % of AN and between 5 and 50 weight % of magnesium nitrate dispersed in the AN. The application furthermore relates to a method for producing of ammonium nitrate particles that are stored in a closed container and having improved anti-caking properties.Type: ApplicationFiled: June 22, 2018Publication date: January 16, 2020Inventor: Francois LEDOUX
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Patent number: 10501380Abstract: This invention relates to a method for the manufacture of a homogeneous, solid, particulate, urea-based material comprising elemental sulphur. The invention further relates to a homogeneous, solid, particulate urea-based material comprising small elemental sulphur phases in a urea-based base material and formed by an accretion process. The product is in particular suitable as a fertilizer.Type: GrantFiled: July 4, 2016Date of Patent: December 10, 2019Assignee: Yara International ASAInventors: Francois Ledoux, Filip Colpaert
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Publication number: 20190225557Abstract: The invention relates to a homogeneous, solid, particulate, urea-based composition comprising elemental sulphur and a urease inhibitor of the type phosphoric triamide, wherein the urea-based composition comprising elemental sulphur is further characterized in that one or more of the following measures applies: a) it comprises 5 weight % or less, relative to the total weight of the composition, of one or more alkaline or alkaline-forming inorganic or organic compounds; or b) it comprises an anticaking and/or moisture-repellent coating. The composition according to the invention has improved properties for reducing ammonia loss by urease activity in the soil and is in particular suitable as a fertilizer.Type: ApplicationFiled: October 13, 2017Publication date: July 25, 2019Applicant: YARA INTERNATIONAL ASAInventors: Filip Colpaert, Francois Ledoux, Ruud Van Belzen
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Publication number: 20190039962Abstract: The present application generally relates to a method for the manufacture of a liquid composition essentially consisting of an organic solvent of the type glycol and a urease inhibitor of the type phosphoric triamide and products obtained therewith.Type: ApplicationFiled: February 24, 2017Publication date: February 7, 2019Applicant: YARA INTERNAL ASAInventors: Filip Colpaert, Francois Ledoux, Ruud Van Belzen
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Patent number: 10167236Abstract: The invention relates to a method for providing an inorganic coating to ammonium nitrate (AN) based particles, in particular to ammonium nitrate-based particles for use as a fertilizer, as well as to an inorganic coating for ammonium nitrate-based particles per se. The method comprises the steps of: a) applying a liquid concentrated mineral acid with a water content of less than 50 weight %, to the particles, in order to at least solubilize ammonium nitrate at the outer surface of the particles such that an acidified particle grasping layer is obtained, and b) applying a solid mineral alkaline in powder form to the particles of step a) in order to react with the grasping layer of the particles to coat the acidified particle surface; wherein the stoichiometric ratio of solid mineral alkaline in powder form to concentrated mineral acid is equal to or more than 5:1.Type: GrantFiled: March 3, 2015Date of Patent: January 1, 2019Assignee: YARA INTERNATIONAL ASAInventor: Francois Ledoux
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Publication number: 20180370864Abstract: Additives can be added to fertilizers to impart desirable characteristics. For example, a class of additives have been disclosed to stabilize the explosive potential of AN fertilizers are desirable, however, such additives can react with the AN fertilizer during its manufacture or during its storage. This is particularly the case where the additives contain carbonates, oxides, hydroxides, contain water of hydration or water locked within the structure (e.g. within an interlayer substructure). This reaction can be avoided if the additive has a passivation layer substantially covering the surface of the additive. The passivation layer, being substantially non-reactive and substantially insoluble, protects the additive so that the additive keeps its desired properties and the fertilizer keeps its quality. In other aspects, methods of making the fertilizer are provided.Type: ApplicationFiled: December 20, 2016Publication date: December 27, 2018Applicant: YARA INTERNATIONAL ASAInventor: Francois LEDOUX
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Patent number: 10106470Abstract: The invention concerns a method for incorporating micronutrients in an outer shell of urea-based particles, characterized in that it comprises the steps of a) applying a liquid concentrated mineral acid with a water content of at most 25 weight % to urea-based particles having a water content of at most 2 weight %, in order to at least form a double salt layer at the outer surface of the urea-based particles such that an acidified particle grasping layer is obtained, and subsequently b) applying a solid mineral base in powder form to the urea-based particles of step a) in order to react with the grasping layer of the urea-based particles; wherein the mineral acid or the solid mineral base are the source of any one of the micronutrients and wherein the liquid concentrated mineral acid and the solid mineral base in powder form are applied in a non-equimolar ratio between 0.1 and 1 mol/mol mineral acid/mineral base.Type: GrantFiled: March 3, 2015Date of Patent: October 23, 2018Assignee: YARA INTERNATIONAL ASAInventor: Francois Ledoux
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Publication number: 20180297903Abstract: The invention relates to a solid, particulate, urea-based blend composition comprising a urea-based compound in particulate form, one or more components in particulate form, selected from the group of nitrates, phosphates, sulphates and chlorides, and a urease inhibitor of the type phosphoric triamide, in particular N-(n-butyl) thiophosphoric triamide (nBTPT), wherein the urea-based blend composition is further characterized in that it comprises one or more reactive alkaline or alkaline-forming inorganic or organic compounds. The composition according to the invention has been stabilized against the degradation of a urease inhibitor of the type phosphoric triamide, in particular N-(n-butyl) thiophosphoric triamide (nBTPT). The invention further relates to a method for the manufacture of the claimed solid, particulate, urea-based blend composition.Type: ApplicationFiled: November 10, 2016Publication date: October 18, 2018Applicant: YARA INTERNATIONAL ASAInventors: Francois Ledoux, Filip Colpaert, Ruud Van Belzen
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Publication number: 20180258002Abstract: The invention relates to a homogeneous, solid, particulate, urea ammonium sul¬phate-based composition comprising urea ammonium sulphate and a urease inhibitor of the type phosphoric triamide, wherein the urea ammonium sulphate-based composition is further characterized in that one or more of the following measures applies: a) it comprises 5 weight % or less, relative to the total weight of the composition, of one or more alkaline or alkaline-forming inorganic or organic compounds that is able to interact with ammonium sulphate; b) the urease inhibitor of the type phosphoric triamide is in a solid particulate form; c) an anticaking and/or moisture repellent coating is applied onto the urea am¬monium sulphate particulate material. The composition according to the invention has improved properties for reducing ammonia loss by urease activity in the soil and is in particular suitable as a ferti¬lizer.Type: ApplicationFiled: September 7, 2016Publication date: September 13, 2018Applicant: YARA INTERNATIONAL ASAInventors: Filip Colpaert, Francois Ledoux, Ruud Van Belzen