Patents by Inventor Frederick L. Schmitt
Frederick L. Schmitt has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 4532361Abstract: Described are methods for augmenting or enhancing the aroma of perfumes and perfumed articles by adding thereto perfume aroma augmenting or enhancing quantities of novel methyl substituted-2-oxohexane derivatives produced by dimerizing isoamylene (2-methyl-2-butene) and then oxidizing the resulting product using formic acid and hydrogen peroxide; and optionally reacting the resulting product with a methyl Grignard reagent such as methyl magnesium chloride followed by hydrolysis; as well as perfume compositions, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, hair preparations, perfumed polymers and deodorant compositions as well as bleaching compositions containing same.Also covered is the genus of compounds defined according to the structure: ##STR1## wherein R.sub.1 and R.sub.2 taken together represent oxygen; or wherein, taken separately, R.sub.1 is hydroxyl and R.sub.2 is methyl or R.sub.Type: GrantFiled: June 13, 1984Date of Patent: July 30, 1985Assignee: International Flavors & Fragrances Inc.Inventors: Richard M. Boden, Lambert Dekker, Frederick L. Schmitt, Augustinus G. Van Loveren
-
Patent number: 4503259Abstract: Described are methods for augmenting or enhancing the aroma of perfumes and perfumed articles by adding thereto perfume aroma augmenting or enhancing quantities of novel methyl substituted-2-oxohexane derivatives produced by dimerizing isoamylene (2-methyl-2-butene) and then oxidizing the resulting product using formic acid and hydrogen peroxide; and optionally reacting the resulting product with a methyl Grignard reagent such as methyl magnesium chloride followed by hydrolysis; as well as perfume compositions, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, hair preparations, perfumed polymers and deodorant compositions as well as bleaching compositions containing same.Also covered is the genus of compounds defined according to the structure: ##STR1## wherein R.sub.1 and R.sub.2 taken together represent oxygen; or wherein, taken separately, R.sub.1 is hydroxyl and R.sub.2 is methyl or R.sub.Type: GrantFiled: May 24, 1983Date of Patent: March 5, 1985Assignee: International Flavors & Fragrances Inc.Inventors: Richard M. Boden, Lambert Dekker, Frederick L. Schmitt, Augustinus G. Van Loveren
-
Patent number: 4495091Abstract: Described are methods for augmenting or enhancing the aroma of perfumes and perfumed articles by adding thereto perfume aroma augmenting or enhancing quantities of novel methyl substituted-2-oxohexane derivatives produced by dimerizing isoamylene (2-methyl-2-butene); then oxidizing the resulting product using formic acid and hydrogen peroxide; then reducing the resulting ketone(s) with an alkali metal borohydride; and then, optionally, reacting the resulting alcohol(s) with acetic anhydride to form one or more esters; as well as perfume compositions, colognes and perfumed articles including solid or liquid anionic cationic nonionic or zwitterionic detergents, fabric softener compositions, hair preparations, perfumed polymers and deodorant compositions as well as bleaching compositions containing same.Also covered is the genus of compounds defined according to the structure: ##STR1## wherein R.sub.12 represents hydroxyl:--OH]or acetoxy having the structure: ##STR2## and wherein R.sub.3, R.sub.4, R.sub.5, R.Type: GrantFiled: May 24, 1983Date of Patent: January 22, 1985Assignee: International Flavors & Fragrances Inc.Inventors: Richard M. Boden, Lambert Dekker, Frederick L. Schmitt, Augustinus G. van Loveren
-
Patent number: 4431577Abstract: Described are compounds defined according to the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; and one of R.sub.1 and R.sub.2 is methyl and the other of R.sub.1 and R.sub.2 is hydrogen. In addition, organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, chewing tobaccos, medicinal products, toothpastes, perfumes, perfumed articles (such as liquid or solid, anionic, cationic, nonionic or zwitterionic detergents), fabric softeners and dryer-added fabric softener articles.Type: GrantFiled: May 20, 1982Date of Patent: February 14, 1984Assignee: International Flavors & Fragrances Inc.Inventors: Philip T. Klemarczyk, James M. Sanders, Manfred H. Vock, Joaquin F. Vinals, Frederick L. Schmitt, Edward J. Granda
-
Patent number: 4421679Abstract: Described are methods for augmenting or enhancing the aroma of perfumes and perfumed articles by adding thereto perfume aroma augmenting or enhancing quantities of novel methyl substituted-2-oxohexane derivatives produced by dimerizing isoamylene (2-methyl-2-butene) and then oxidizing the resulting product using formic acid and hydrogen peroxide; and optionally reacting the resulting product with a methyl Grignard reagent such as methyl magnesium chloride followed by hydrolysis; as well as perfume compositions, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, hair preparations, perfumed polymers and deodorant compositions as well as bleaching compositions containing same.Also covered is the genus of compounds defined according to the structure: ##STR1## wherein R.sub.1 and R.sub.2 taken together represent oxygen; or wherein, taken separately, R.sub.1 is hydroxyl and R.sub.2 is methyl or R.sub.Type: GrantFiled: February 4, 1982Date of Patent: December 20, 1983Assignee: International Flavors & Fragrances Inc.Inventors: Richard M. Boden, Lambert Dekker, Frederick L. Schmitt, Augustinus G. Van Loveren
-
Patent number: 4420423Abstract: Described are methods for augmenting or enhancing the aroma of perfumes and perfumed articles by adding thereto perfume aroma augmenting or enhancing quantities of novel methyl substituted-2-oxohexane derivatives produced by dimerizing isoamylene (2-methyl-2-butene); then oxidizing the resulting product using formic acid and hydrogen peroxide; then reducing the resulting ketone(s) with an alkali metal borohydride; and then, optionally, reacting the resulting alcohol(s) with acetic anhydride to form one or more esters; as well as perfume compositions, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, hair preparations, perfumed polymers and deodorant compositions as well as bleaching compositions containing same.Also covered is the genus of compounds defined according to the structure ##STR1## wherein R.sub.12 represents hydroxyl:--OH]or acetoxy having the structure: ##STR2## and wherein R.sub.3, R.sub.4, R.sub.5, R.Type: GrantFiled: February 4, 1982Date of Patent: December 13, 1983Assignee: International Flavors & Fragrances Inc.Inventors: Richard M. Boden, Lambert Dekker, Frederick L. Schmitt, Augustinus G. Van Loveren
-
Patent number: 4395366Abstract: Described are compounds defined according to the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; and one of R.sub.1 and R.sub.2 is methyl and the other of R.sub.1 and R.sub.2 is hydrogen. In addition, organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, chewing tobaccos, medicinal products, toothpastes, perfumes, perfumed articles (such as liquid or solid, anionic, cationic, nonionic or zwitterionic detergents), fabric softeners and dryer-added fabric softener articles.Type: GrantFiled: May 20, 1982Date of Patent: July 26, 1983Assignee: International Flavors & Fragrances Inc.Inventors: Philip T. Klemarczyk, James M. Sanders, Manfred H. Vock, Joaquin F. Vinals, Frederick L. Schmitt, Edward J. Granda
-
Patent number: 4390464Abstract: Described are methyl substituted norbornane derivatives having the generic structure: ##STR1## wherein R represents the nitrile moiety having the structure: ##STR2## or the dimethoxymethyl moiety having the structure: ##STR3## and wherein one of R.sub.1, or R.sub.2 is methyl and the other of R.sub.1 or R.sub.2 is hydrogen.Also described are processes and compositions for augmenting or enhancing the flavor and/or aroma of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, perfumes, colognes and perfumed articles such as solid or liquid anionic, cationic, nonionic or zwitterionic detergents or fabric softeners or fabric softener articles using as the essential ingredient at least one of methyl substituted norbornane derivatives of our invention.Type: GrantFiled: April 6, 1982Date of Patent: June 28, 1983Assignee: International Flavors & Fragrances Inc.Inventors: Philip T. Klemarczyk, James M. Sanders, Manfred H. Vock, Joaquin F. Vinals, Frederick L. Schmitt, Edward J. Granda
-
Patent number: 4388228Abstract: Described are methods for augmenting or enhancing the aroma of perfumes and perfumed articles by adding thereto perfume aroma augmenting or enhancing quantities of novel C.sub.10 -branched olefin epoxide mixtures produced by dimerizing isoamylene, (2-methyl-2-butene) and then epoxidizing the resulting product; as well as perfume compositions, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, hair preparations and deodorant compositions as well as bleaching compositions containing same.Type: GrantFiled: February 18, 1982Date of Patent: June 14, 1983Assignee: International Flavors & Fragrances Inc.Inventors: Richard M. Boden, Lambert Dekker, Frederick L. Schmitt, Augustinus G. Van Loveren
-
Patent number: 4388207Abstract: Described are methyl substituted norbornane derivatives having the generic structure: ##STR1## wherein R represents the nitrile moiety having the structure:[ C.tbd.N]or the dimethoxymethyl moiety having the structure: ##STR2## and wherein one of R.sub.1, or R.sub.2 is methyl and the other of R.sub.1 or R.sub.2 is hydrogen.Also described are processes and compositions for augmenting or enhancing the flavor and/or aroma of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, perfumes, colognes and perfumed articles such as solid or liquid anionic, cationic, nonionic or zwitterionic detergents or fabric softeners or fabric softener articles using as the essential ingredient at least one of methyl substituted norbornane derivatives of our invention.Type: GrantFiled: April 6, 1982Date of Patent: June 14, 1983Assignee: International Flavors & Fragrances Inc.Inventors: Philip T. Klemarczyk, James M. Sanders, Manfred H. Vock, Joaquin F. Vinals, Frederick L. Schmitt, Edward J. Granda
-
Patent number: 4386064Abstract: Described are compounds defined according to the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; and one of R.sub.1 and R.sub.2 is methyl and the other of R.sub.1 and R.sub.2 is hydrogen. In addition, organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, chewing tobaccos, medicinal products, toothpastes, perfumes, perfumed articles (such as liquid or solid, anionic, cationic, nonionic or zwitterionic detergents), fabric softeners and dryer-added fabric softener articles.Type: GrantFiled: May 20, 1982Date of Patent: May 31, 1983Assignee: International Flavors & Fragrances Inc.Inventors: Philip T. Klemarczyk, James M. Sanders, Manfred H. Vock, Joaquin F. Vinals, Frederick L. Schmitt, Edward J. Granda
-
Patent number: 4385073Abstract: Described is the use of 4,4A,5,6-tetrahydro-7-methyl-2-(3H)-naphthalenone having the structure: ##STR1## in substantially pure liquid or pure crystalline form for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfumes, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softeners, fabric softener articles, perfumed polymers, hair preparations and the like.Type: GrantFiled: March 26, 1982Date of Patent: May 24, 1983Assignee: International Flavors & Fragrances Inc.Inventors: Alan O. Pittet, Ranya Muralidhara, Manfred H. Vock, Domenick Luccarelli, Jr., Frederick L. Schmitt, Joaquin F. Vinals, Jacob Kiwala
-
Patent number: 4385072Abstract: Described is a process for augmenting or enhancing the aroma or taste of foodstuffs and chewing gums comprising the step of adding to a foodstuff composition or chewing gum composition, an aroma or taste augmenting or enhancing quantity of at least one of the two compounds having the structures: ##STR1##Type: GrantFiled: October 22, 1981Date of Patent: May 24, 1983Assignee: International Flavors & Fragrances Inc.Inventors: Ronald P. Schreck, Kenneth K. Light, John B. Hall, Frederick L. Schmitt, Manfred H. Vock, William L. Schreiber, Joaquin F. Vinals, Jacob Kiwala
-
Patent number: 4380658Abstract: Described are methods for augmenting or enhancing the aroma of perfumes and perfumed articles by adding thereto perfume aroma augmenting or enhancing quantities of novel C.sub.10 -branched olefin epoxide mixtures produced by dimerizing isoamylene, (2-methyl-2-butene) and then epoxidizing the resulting product; as well as perfume compositions, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, hair preparations and deodorant compositions as well as bleaching compositions containing same.Type: GrantFiled: February 18, 1982Date of Patent: April 19, 1983Assignee: International Flavors & Fragrances Inc.Inventors: Richard M. Boden, Lambert Dekker, Frederick L. Schmitt, Augustinus G. Van Loveren
-
Patent number: 4376058Abstract: Described are methods for augmenting or enhancing the aroma of perfumes and perfumed articles by adding thereto perfume aroma augmenting or enhancing quantities of novel C.sub.10 -branched olefin epoxide mixtures produced by dimerizing isoamylene, (2-methyl-2-butene) and then epoxidizing the resulting product; as well as perfume compositions, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, hair preparations and deodorant compositions as well as bleaching compositions containing same.Type: GrantFiled: February 18, 1982Date of Patent: March 8, 1983Assignee: International Flavors & Fragrances Inc.Inventors: Richard M. Boden, Lambert Dekker, Frederick L. Schmitt, Augustinus G. Van Loveren
-
Patent number: 4374746Abstract: Described is the genus of compounds defined according to the structure: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and each represents methyl or hydrogen with the proviso that when one of R.sub.2, R.sub.3 and R.sub.4 is methyl, then the other two of R.sub.2, R.sub.3 and R.sub.4 are hydrogen which have been found to be useful in augmenting or enhancing the aroma of perfumes and perfumed articles as well as colognes and, in addition, in combatting tobacco beetles of the species Lasioderma serricorne (F.). Also described are novel processes for preparing such cyclohexyl phenethylether derivatives by reacting cyclohexene having the structure: ##STR2## with a phenethyl alcohol derivative having the structure: ##STR3## in the presence of an acid catalyst.Type: GrantFiled: September 25, 1981Date of Patent: February 22, 1983Assignee: International Flavors & Fragrances Inc.Inventors: Jacob Kiwala, Richard J. Tokarzewski, Frederick L. Schmitt, Mark A. Sprecker
-
Patent number: 4374054Abstract: Use in perfumery are compounds both separately and in admixture having the generic structure: ##STR1## wherein the dashed line is either a carbon-carbon single bond or a carbon-carbon double bond and each of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.6 and R.sub.7 represents hydrogen or methyl with the proviso that one of R.sub.1, R.sub.2, R.sub.6 and R.sub.7 is methyl and each of the other of R.sub.1, Rhd 2, R.sub.6 and R.sub.7 is hydrogen and R.sub.3 and R.sub.4 are not both methyl; wherein R.sub.5 represents C.sub.1 -C.sub.4 alkyl are disclosed.Type: GrantFiled: September 17, 1981Date of Patent: February 15, 1983Assignee: International Flavors & Fragrances Inc.Inventors: Philip T. Klemarczyk, James M. Sanders, Manfred H. Vock, Joaquin F. Vinals, Frederick L. Schmitt, Edward J. Granda
-
Patent number: 4374055Abstract: Described is a process for preparing several substituted or unsubstituted cycloalkyl acyl alkanoates defined according to the generic structure: ##STR1## wherein R.sub.1 and R.sub.2 taken together complete a cycloalkyl moiety or methyl, dimethyl or trimethyl substituted cycloalkyl moiety containing five or six carbon atoms in the ring and wherein R.sub.3 is C.sub.1 -C.sub.3 lower alkyl and R.sub.4 is methyl or hydrogen by reacting a compound having the generic structure: ##STR2## in an aqueous silver-ion containing solution having a weakly acidic pH at elevated temperatures.Type: GrantFiled: October 22, 1981Date of Patent: February 15, 1983Assignee: International Flavors & Fragrances Inc.Inventors: Ronald P. Schreck, Kenneth K. Light, John B. Hall, Frederick L. Schmitt, Manfred H. Vock, William L. Schreiber, Joaquin F. Vinals, Jacob Kiwala
-
Patent number: 4371715Abstract: Described is the genus of compounds defined according to the structure: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and each represents methyl or hydrogen with the proviso that one of R.sub.2, R.sub.3 and R.sub.4 is methyl and the other two of R.sub.2, R.sub.3 and R.sub.4 are hydrogen which have been found to be useful in augmenting or enhancing the aroma of perfumes and perfumed articles as well as colognes and, in addition, in combatting tobacco beetles of the species Lasioderma serricorne (F.). Also described are novel processes for preparing such cyclohexyl phenethylether derivatives by reacting cyclohexene having the structure: ##STR2## with a phenethyl alcohol derivative having the structure: ##STR3## in the presence of an acid catalyst.Type: GrantFiled: September 25, 1981Date of Patent: February 1, 1983Assignee: International Flavors & Fragrances Inc.Inventors: Jacob Kiwala, Richard J. Tokarzewski, Frederick L. Schmitt, Mark A. Sprecker
-
Patent number: 4366078Abstract: Described are methods for augmenting or enhancing the aroma of perfumes and perfumed articles by adding thereto perfume aroma augmenting or enhancing quantities of C.sub.10 -branched olefin mixtures produced by dimerizing isoamylene, (2-methyl-2-butene) as well as perfume compositions, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, hair preparations and deodorant compositions as will as bleaching compositions containing same.Type: GrantFiled: May 28, 1981Date of Patent: December 28, 1982Assignee: International Flavors & Fragrances Inc.Inventors: Richard M. Boden, Lambert Dekker, Frederick L. Schmitt, Augustinus G. Van Loveren