Abstract: Antiballistic armor is provided that includes a glass-ceramic component having 50 to 70 weight percent SiO2, 15 to 25 weight percent Al2O3, 0.5 to 5 weight percent ZrO2, 0.1 to 10 weight percent Li2O, 1 to 5 weight percent TiO2. The glass ceramic component has a main crystalline phase that comprises keatite mixed crystal in a compositional range of LiAlSi2O6 to LiAlSi4O10.

Abstract: The method of environmentally friendly melting and refining a glass melt of a crystallizable glass, which is used for making a lithium aluminium silicate (LAS) glass ceramic, includes the steps of providing a glass batch with a main batch composition within a lithium aluminium silicate (LAS) glass system, in which 0.1-<0.6% by weight of tin oxide has been added as main refining agent, but which does not contain arsenic oxide and/or antimony oxide as refining agent, formulating a raw material mixture for the glass batch, so that less than 40% by weight of the raw material mixture is quartz sand and then refining a glass melt formed from the glass batch at temperatures of at least 1600° C.

Abstract: The present invention describes a transparent plate of lithium aluminosilicate glass ceramic showing a high transmission, a process for producing same and transparent plate laminates comprising at least one plate of the lithium aluminosilicate glass ceramic of the invention and the use thereof as armored glass or bullet-proof vest.

Abstract: A transparent, colorless lithium-aluminosilicate glass ceramic plate with high-quartz mixed crystals as the prevailing crystal phase, which is provided on one side with an opaque, colored, temperature-stable coating over the entire surface or over the entire surface to a large extent, is described, which has a content of Nd2O3 of 40 to 4000 ppm, a Yellowness Index of less than 10% with a 4 mm glass (ceramic) layer thickness, and a variegation of colors of the glass or the glass ceramic in the CIELAB color system of C* of less than 5. The glass ceramic plate preferably has a composition (in % by weight based on oxide) of: Li2O 3.0-4.5, Na2O 0-1.5, K2O 0-1.5, ?Na2O+K2O 0.2-2.0, MgO 0-2.0, CaO 0-1.5, SrO 0-1.5, BaO 0-2.5, ZnO 0-2.5, B2O3 0-1.0, Al2O3 19-25, SiO2 55-69, TiO2 1-3, ZrO2 1-2.5, SnO2 0-0.4, ?SnO2+TiO2<3, P2O5 0-3.0, Nd2O3 0.01-0.4, CoO 0.0-0.

Abstract: An optically detectable, floatable arsenic- and antimony-free, glazable lithium-aluminosilicate glass that can be prestressed and the glass ceramic converted therefrom are described. The glass or the glass ceramic has a composition (in % by weight based on oxide) of essentially SiO2 55-69, Al2O3 19-25, Li2O 3.2-5, Na2O 0-1.5, K2O 0-1.5, MgO 0-2.2, CaO 0-2.0, SrO 0-2.0, BaO 0-2.5, ZnO 0-<1.5, TiO2 1-3, ZrO2 1-2.5, 0.1-<1, ?TiO2+ZrO2+SnO2 2.5-5, P2O5 O-3, Nd2O3 0.01-0.6, CoO 0-0.005, F 0-1, B2O3 0-2.

Abstract: A lithium-aluminosilicate glass or a corresponding glass ceramic that has a content of 0-0.4 SnO2, 1.3-2.7% by weight of ?SnO2+TiO2, 1.3-2.5% by weight of ZrO2, 3.65-4.3% by weight of ?ZrO2+0.87 (TiO2+SnO2), ?0.04% by weight of Fe2O3, 50-4000 ppm of Nd2O3 and 0-50 ppm of CoO is described. The glass or the glass ceramic is color-neutral, has a turbidity of less than 1% HAZE and a high light transmission. The glazing time for conversion of the glass into glass ceramic is especially short with less than 2.5 hours.

Abstract: The colorless transparent colloid-former-containing glass that is convertible into a colorless transparent glass ceramic or a metal colloid-colored glass ceramic via respective heat treatments contains a combination of one or more metal colloid formers and one or more redox partners. The metal colloid formers are compounds containing Au, Ag, As, Bi, Nb, Cu, Fe, Pd, Pt, Sb and/or Sn. The redox partners are compounds containing As, Ce, Fe, Mn, Sb, Sn and/or W, with the proviso that the redox partner must be different from the metal colloid former.

Abstract: The glass ceramic panels are non-transparent and have at least one decoration. In order to fulfill the requirements for a glass ceramic panel that provides a cooking surface for a cooking unit in a variety of different pleasing colors, especially a creamy white color shade (BISQUE), in an economical manner, the glass ceramic panel has a predominant crystalline phase of keatite mixed crystals and a full-surface decorative coating that covers at least 80 percent of the upper smooth surface of the glass ceramic substrate. The full-surface decorative coating is provided in a different color from,the glass ceramic panel. Methods for making these glass ceramic panels are described.

Abstract: The fire-resistant window of fire resistance class E according to DIN EN 357 has a window frame system (1, 6) and at least one thermally or chemically pre-stressed monolithic fire-resistant glass pane (2) mounted in the window frame system (1, 6). The at least one thermally or chemically pre-stressed monolithic fire-resistant glass pane (2) is made of a high-temperature-melting aluminosilicate glass with a softening point (log ?=7.6) above 875° C., wherein ? is the viscosity, and with a bending strength of over 100 N/mm2. The glass pane (2) is also substantially impermeable to ultraviolet radiation.

Abstract: The invention proposes a method for producing glass ceramics which is particularly well suited as light conversion material, especially for down conversion. One initially produces a starting glass, containing (on an oxide basis) 5-50% by weight of SiO2, 5-50 % by weight of Al2O3 and 10-80% by weight of at least one oxide selected from the from the group formed by Y2O3, Lu2O3, Sc2O3, Gd2O3, Yb2O3, Ce2O3, as well as 0.1-30% by weight of at least one oxide selected from the group formed by B2O3, Th2O3, and oxides of the lanthanoids, except Lu2O3, Gd2O3, Yb2O3, Ce2O3. Thereafter, the material is heated up for ceramization at a heating rate of at least 100 K/min to a temperature in the range of between 1000° C. to 1400° C. until crystallites are formed that contain a garnet phase. Thereafter, the material is cooled down to room temperature. Alternatively, controlled cooling-down from the molten state is possible.

Abstract: The invention provides a method for producing a glass ceramic comprising the steps of melting a starting glass that is free from alkali, except for incidental contamination, and that contains at least one garnet-forming agent and at least one oxide of a lanthanoid; grinding the starting glass to produce a glass frit; molding by pressing and sintering the glass frit until at least one garnet phase containing lanthanoids is formed. A glass ceramic produced in this way may contain 5-50 % by weight of SiO2, 5-50 % by weight of Al2O3 and 10-80 % by weight of at least one oxide selected from the group formed by Y2O3, Lu2O3, Sc2O3, Gd2O3, Yb2O3, Ce2O3, as well least one oxide selected from the group formed by B2O3, Th2O3, and oxides of the lanthanoids, except Lu2O3, Gd2O3, Yb2O3, Ce2O3. Such a glass ceramic is suited especially for down conversion of excitation radiation in the blue and in the UV region of the spectrum.

Abstract: An optically detectable, floatable arsenic- and antimony-free, glazable lithium-aluminosilicate glass that can be prestressed and the glass ceramic converted therefrom are described. The glass or the glass ceramic has a composition (in % by weight based on oxide) of essentially SiO2 55-69, Al2O3 19-25, Li2O 3.2-5, Na2O 0-1.5, K2O 0-1.5, MgO 0-2.2, CaO 0-2.0, SrO 0-2.0, BaO 0-2.5, ZnO 0-<1.5, TiO2 1-3, ZrO2 1-2.5, SnO2 0.1-<1, ? TiO2+ZrO2+SnO2 2.5-5, P2O5 0-3, Nd2O3 0.01-0.6, CoO 0-0.005, F 0-1, B2O3 0-2.

Abstract: A transparent, colorless lithium-aluminosilicate glass ceramic plate with high-quartz mixed crystals as the prevailing crystal phase, which is provided on one side with an opaque, colored, temperature-stable coating over the entire surface or over the entire surface to a large extent, is described, which has a content of Nd2O3 of 40 to 4000 ppm, a Yellowness Index of less than 10% with a 4 mm glass (ceramic) layer thickness, and a variegation of colors of the glass or the glass ceramic in the CIELAB color system of C* of less than 5. The glass ceramic plate preferably has a composition (in % by weight based on oxide) of: Li2O 3.0-4.5, Na2O 0-1.5, K2O 0-1.5, ?Na2O+K2O 0.2-2.0, MgO 0-2.0, CaO 0-1.5, SrO 0-1.5, BaO 0-2.5, ZnO 0-2.5, B2O3 0-1.0, Al2O3 19-25, SiO2 55-69, TiO2 1-3, ZrO2 1-2.5, SnO2 0-0.4, ?SnO2+TiO2<3, P2O5 0-3.0, Nd2O3 0.01-0.4, CoO 0.0-0.

Abstract: The method produces a glass-ceramic article substantially in the form of a plate with improved high temperature difference resistance or strength. The glass-ceramic article contains keatite mixed crystals (KMK) or high quartz mixed crystals (HQMK) as well as the keatite mixed crystals (KMK). The method includes heating a glass-ceramic in a high quartz mixed crystal state to form the keatite mixed crystals with a heating rate of 20 K/min to 150 K/min, preferably more than 15 K/min, especially preferably more than 20 K/min. These high heating rates increase the temperature difference resistance.

Abstract: A method for making a float glass convertible into a glass ceramic, by which a largely crystal fault-free glass can be produced. In this method the glass is cooled from a temperature (TKGmax), at which a crystal growth rate is at a maximum value (KGmax), to another temperature (TUEG), at which practically no more crystal growth occurs, with a cooling rate, KR, in ° C. min?1 according to: KR UEG KG max ? ? ? ? ? T UEG KG max 100 · KG max , wherein ?T=TKGmax?TUEG, and KGmax=maximum crystal growth rate in ?m min?1. The float glass has a thickness below an equilibrium thickness, a net width of at least 1 m and has no more than 50 crystals with a size of more than 50 ?m, especially no crystals with a size of more than 10 ?m, per kilogram of glass within the net width.

Abstract: This invention relates to a flat float glass that can be prestressed or transformed into a glass ceramic with high quartz mixed crystals or keatite mixed crystals. To eliminate undesirable surface defects during floating and to achieve superior characteristics of the glass or of the glass ceramic, in particular with regard to a low coefficient of thermal expansion and high light transmittance, the glass has a concentration of less than 300 ppb Pt, less than 30 ppb Rh, less than 1.5 wt. % ZnO and less than 1 wt. % SnO2, and is refined during melting without the use of the conventional fining agents arsenic oxide and/or antimony oxide.

Abstract: The support plate for transporting products during thermal treatment at firing temperatures is a nonporous keatite glass ceramic supporting member without a glassy surface layer. It has a nubby structure on an underside thereof and preferably C-shaped rounded edges. A method of making the keatite glass ceramic supporting member is described.

Abstract: The method produces a glass-ceramic article substantially in the form of a plate with improved high temperature difference resistance or strength. The glass-ceramic article contains keatite mixed crystals (KMK) or high quartz mixed crystals (HQMK) as well as the keatite mixed crystals (KMK). The method includes heating a glass-ceramic in a high quartz mixed crystal state to form the keatite mixed crystals with a heating rate of 20 K/min to 150 K/min, preferably more than 15 K/min, especially preferably more than 20 K/min. These high heating rates increase the temperature difference resistance.

Abstract: The translucent or opaque colored glass-ceramic article provides a cooking surface and has an adjustable light transmission in a visible range under 15%, as measured for a 4 mm sample thickness; a flaw-free upper surface with an impact resistance of greater than 18 cm breaking height, as tested with a 200 g steel ball in a falling ball test; a temperature difference resistance of greater than 500° C.; a high crystallinity with keatite mixed crystals as principal crystal phase in an interior of the glass-ceramic article and with a residual glass phase fraction of less than 8% by weight; a glassy upper surface layer of from 0.5 to 2.5 ?m thick, which is substantially free of high quartz mixed crystals and which inhibits chemical reactions, and a content of enriched ingredients in the residual glass phase in the interior of the glass-ceramic and in the glassy surface layer of ?Na2O+K2O+CaO+SrO+BaO+F+refining agents of from 0.2 to 1.6% by weight.

Abstract: Lithium-aluminosilicate flat float glass with a high thermal stability, which can be chemically and thermally tempered and is refined without using the standard refining agents arsenic oxide and/or antimony oxide, having a composition which, in % by weight based on the total composition, contains the following main constituents: Li2O ??2.5-6.0? ? Na2O + K2O <4 B2O3 ???0-<4 Al2O3 ??15-30? SiO2 ??55-75? ? TiO2 + ZrO2 <2 in order to avoid the crystallization of undesirable beta-quartz and/or keatite solid solutions and the use of this glass.