Patents by Inventor Gérard Lang

Gérard Lang has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5364414
    Abstract: Oxidation tinctorial composition intended to be used for dyeing keratinous fibres, in particular human keratinous fibres and especially hair, characterized in that it contains, in a solvent medium appropriate for dyeing these fibres, at least one para oxidation dye precursor or at least one ortho oxidation dye precursor and at least one heterocyclic coupler corresponding to the formula (I): ##STR1## in which: R.sub.1 and R.sub.3, which may be identical or different, denote a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group;R.sub.2 denotes a hydrogen atom, a C.sub.1 -C.sub.4 alkyl group, a carboxyl group or an alkoxycarbonyl group; at least one of the radicals R.sub.2 or R.sub.3 denotes hydrogen;R.sub.4 denotes a hydrogen atom or a C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 hydroxyalkyl or C.sub.2 -C.sub.4 polyhydroxyalkyl group;the group NHR.sub.4 occupying the positions 4, 6 or 7 of the benzene ring, as well as their salts.
    Type: Grant
    Filed: July 22, 1992
    Date of Patent: November 15, 1994
    Assignee: L'Oreal
    Inventors: Gerard Lang, Alex Junino, Jean Cotteret, Jean J. Vandenbossche
  • Patent number: 5364413
    Abstract: 3-Substituted para-aminophenols, process for preparing them, their use for dyeing keratinous fibres and the intermediate compounds used in the process of preparation.3-Substituted para-aminophenols, of general formula: ##STR1## where X.dbd.H, halogen; Y.dbd.O--, --S--; R.dbd.alkyl, hydroxyalkyl, C.sub.1-4 aminoalkyl or C.sub.3 -C.sub.6 polyhydroxyalkyl;with the proviso that, when X.dbd.H, R is not methyl, and when X.dbd.H and Y.dbd.O, R is not ethyl;process #or preparing them, intermediate compounds of formula: ##STR2## where X.sup.1 .dbd.halogen, Y and R have the meaning stated above; with the proviso that, when Y.dbd.O, R is not methyl, and when R.dbd.aminoalkyl, X.sub.1 can also denote hydrogen;dyeing compositions containing one or more compounds of formula (I), and a process for dyeing human hair.
    Type: Grant
    Filed: November 12, 1992
    Date of Patent: November 15, 1994
    Assignee: L'Oreal
    Inventors: Alex Junino, Alain Genet, Gerard Lang
  • Patent number: 5354870
    Abstract: The invention concerns 4-hydroxy-5-methoxyindole and 5-ethoxy-4-hydroxy-2-methylindole which are useful as dyes for dyeing keratin materials.
    Type: Grant
    Filed: April 6, 1992
    Date of Patent: October 11, 1994
    Assignee: L'Oreal
    Inventors: Gerard Lang, Serge Forestier, Alex Junino, Herve Richard, Jean J. Vandenbossche
  • Patent number: 5340366
    Abstract: A process for dyeing keratinous fibers involves applying to the fibers, at least one compound of formula ##STR1## wherein R.sub.1 represents hydrogen, alkyl, acetyl, benzoyl, phenyl or carboxylalkyl and R.sub.2 and R.sub.3 represent hydrogen, alkyl, hydroxyl, halogen, nitro, alkyl phenyl, phenyl or alkoxy, and an aminopyrimidine of the formula ##STR2## wherein R.sub.5 represents hydrogen, hydroxyl or ##STR3## represents hydroxyl or ##STR4## R.sub.7 represents H or NH.sub.2, R.sub.8 represents ##STR5## and R.sub.9 and R.sub.10 represent hydrogen, alkyl, (CH.sub.2).sub.p -Z wherein p is 1 to 4 and Z represents OH, halogen, NH.sub.2, NHR' or NHR'R" wherein R' and R" represent alkyl or together form a heterocycle, with the proviso that one of R.sub.5 to R.sub.8 represents NH.sub.2.
    Type: Grant
    Filed: October 15, 1993
    Date of Patent: August 23, 1994
    Assignee: L'Oreal
    Inventors: Gerard Lang, Jean Cotteret
  • Patent number: 5310959
    Abstract: Processes for preparing 5,8,11-eicosatriynoic acid as well as esters and amides thereof involves initially preparing the acid by reacting 1-decyne with 1,4-dihalo-2-butyne in the presence of a strong base to form 1-halo-2,5-tetradecadiyne which is then reacted with 5-hexynoic acid so as to form 5,8,11-eicosatriynoic acid. This acid can then be converted to the acid chloride form and reacted with an alcohol to form an ester or converted to a potassium salt and reacted with a halide also to form an ester, or after conversion to an acid chloride reacted with an amine in the presence of a tertiary amine to form an amide, or the acid can be reacted with carbonyldiimidazole in the presence of a solvent and excess amine to form an amide.
    Type: Grant
    Filed: May 17, 1993
    Date of Patent: May 10, 1994
    Assignee: Centre International de Recherches Dermatologiques Galderma (Cird Galderma)
    Inventors: Braham Shroot, Christopher Hensby, Jean Maignan, Gerard Lang, Serge Restle, Michel Colin
  • Patent number: 5279616
    Abstract: The invention relates to a process for dyeing keratinous fibers, comprising the simultaneous or sequential application of a component (A) containing at least one compound of formula (I): ##STR1## in which: R.sub.1 denotes hydrogen, alkyl, acetyl, benzoyl, phenyl or carboxyalyl;R.sub.2 and R.sub.3 denote a hydrogen, alkyl, hydroxyl, halogen, nitro, alkylphenyl, phenyl or alkoxy;and a component (B) containing at least one compound of formula (II): ##STR2## in which: R.sub.4 denotes a hydrogen atom or a .beta.-hydroxyethyl group;n=0, 1 or 2, and m=0 or 1;as well as its cosmetically acceptable salts; or one compound of formula (III): ##STR3## in which: R.sub.5 denotes a hydrogen atom, a hydroxyl group or a group ##STR4## R.sub.6 denotes a hydroxyl group or a group N ##STR5## R.sub.7 denotes H or NH.sub.2, R.sub.8 denotes a group ##STR6## R.sub.9 and R.sub.10, independently of one another, representing a hydrogen atom, a C.sub.1 -C.sub.4 alkyl, a group (CH.sub.2).sub.
    Type: Grant
    Filed: March 4, 1992
    Date of Patent: January 18, 1994
    Assignee: L'Oreal
    Inventors: Gerard Lang, Jean Cotteret
  • Patent number: 5279620
    Abstract: Tinctorial composition for keratin fibers, containing a para-type precursor of an oxidation colorant associated with a heterocyclic coupler of formula: ##STR1## where R.sub.1 .dbd.H, or C.sub.1 -C.sub.4 alkyl; R.sub.2 and R.sub.3, which may be identical or different, denote H, C.sub.1 -C.sub.4 alkyl, carboxyl or alkoxycarbonyl; OH is in position 6 or 7;and/or a salt of such a coupler.This composition allows the hair to be dyed with a color having a good resistance to light, washing, bad weather and perspiration.
    Type: Grant
    Filed: April 20, 1992
    Date of Patent: January 18, 1994
    Assignee: L'Oreal
    Inventors: Alex Junino, Gerard Lang
  • Patent number: 5268494
    Abstract: Compounds corresponding to the formula: ##STR1## wherein A represents --CH.sub.2).sub.2 or --C.tbd.C--;n is equal to 0, 1 or 2;R represents hydroxyl, alkoxy having the formula --OR.sub.1, or amino having the formula ##STR2## R.sub.1 represents alkyl, monohydroxyalkyl, polyhydroxyalkyl, aryl or aralkyl;R.sub.2 and R.sub.3 represent hydrogen, alkyl, monohydroxyalkyl, polyhydroxyalkyl, aryl or benzyl;R.sub.2 and R.sub.3 form, with the nitrogen atom, a heterocyclic ring.Application of these compounds in pharmacy and cosmetics.
    Type: Grant
    Filed: June 4, 1992
    Date of Patent: December 7, 1993
    Assignee: Centre International de Recherches Dermatologiques C.I.R.D.
    Inventors: Braham Shroot, Christopher Hensby, Jean Maignan, Gerard Lang, Michel Colin
  • Patent number: 5261926
    Abstract: The invention relates to a process for dyeing keratinous fibres, comprising the simultaneous or sequential application of a component (A) containing at least one compound of formula (I): ##STR1## in which: R.sub.1 denotes hydrogen, alkyl, acetyl, benzoyl, phenyl or C.sub.1 -C.sub.4 carboxyalkyl,R.sub.2 and R.sub.3 denote hydrogen, alkyl, alkoxy, hydroxyalkyl, amino, halogen, nitro, alkylphenyl, phenyl, alkylamino or hydroxyalkylamino,and a component (B) containing at least(i) a compound of formula (II): ##STR2## in which: Y denotes OH or NR.sub.8 R.sub.9,R.sub.8 and R.sub.9, which are identical or different, denote hydrogen, aminoethyl, hydroxyethyl or C.sub.1 -C.sub.4 alkyl,R.sub.4 to R.sub.7 independently of each other denote a hydrogen atom, a C.sub.1 -C.sub.4 alkyl, a chlorine, a C.sub.1 -C.sub.4 alkoxy, an acetylamino, an aryloxy, not more than two of the groups R.sub.4 to R.sub.
    Type: Grant
    Filed: March 4, 1992
    Date of Patent: November 16, 1993
    Assignee: L'Oreal
    Inventors: Gerard Lang, Jean Cotteret
  • Patent number: 5254135
    Abstract: Method for dyeing keratinous fibres, in particular human keratinous fibres, such as hair, characterized in that a composition (A) containing, in a medium appropriate for dyeing, at least one aminoindole corresponding to the formula: ##STR1## in which: R.sub.1 and R.sub.3, independently of one another, represent a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group;R.sub.2 denotes hydrogen or a C.sub.1 -C.sub.4 alkyl group or COOR', R' being a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group;R.sub.4 represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 hydroxyalkyl or C.sub.2 -C.sub.4 polyhydroxyalkyl group;Z.sub.1 represents a hydrogen or halogen atom or a C.sub.1 -C.sub.4 alkyl group or OR;R being a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group; andZ.sub.2 represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group;and its saltsis applied to said fibres, the colour being developed with the aid of an oxidizing system.
    Type: Grant
    Filed: July 21, 1992
    Date of Patent: October 19, 1993
    Assignee: L'Oreal
    Inventors: Gerard Lang, Alex Junino, Jean Cotteret
  • Patent number: 5223249
    Abstract: Use in cosmetics, especially as UV screens, of diorganopolysiloxanes containing a 2-hydroxybenzophenone functional group of formula: ##STR1## where R is C.sub.1 -C.sub.10 alkyl, phenyl or 3,3,3-trifluoropropyl, B is R or A, r=0-200, s=0-50, or of formula: ##STR2## where u=1-20 and t=0-20 and t+u.gtoreq.3, A and/or B denoting a 4-alkyleneoxy-2-hydroxybenzophenone radical.
    Type: Grant
    Filed: March 22, 1990
    Date of Patent: June 29, 1993
    Assignee: L'Oreal
    Inventors: Serge Forestier, Gerard Lang, Herve Richard
  • Patent number: 5223533
    Abstract: The invention relates to the benzylcyclanone derivatives of formula: ##STR1## where R.sub.1 and R.sub.3 denote H, OH, linear or branched C.sub.1 -C.sub.8 alkyl or linear or branched C.sub.1 -C.sub.8 alkoxy, R.sub.2 and R.sub.4 represent H or OH, at least one of the two being OH, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 represent H, C.sub.1 -C.sub.18 alkyl, aralkyl or aryl, it being possible for R.sub.5 and R.sub.6 and/or R.sub.7 and R.sub.8 to form an optionally substituted, saturated C.sub.5 -C.sub.12 ring, X represents O or --(CR.sub.9 R.sub.10).sub.n with n=1 or 2 and R.sub.9 and R.sub.10 represent H or CH.sub.3 ; if X represents --(CR.sub.9 R.sub.10).sub.n, R.sub.6 and R.sub.8, with the atoms of the ring to which they are attached, form a bicyclic system having 7 or 8 carbon atoms; if X represents --(CR.sub.9 R.sub.10).sub.n with n=1, R.sub.9 and R.sub.10 =CH.sub.3, R.sub.5 =H and R.sub.6 and R.sub.8, with the atoms of the ring to which are attached, form a bicyclic system having 7 carbon atoms, R.sub.
    Type: Grant
    Filed: March 29, 1990
    Date of Patent: June 29, 1993
    Assignee: L'Oreal
    Inventors: Serge Forestier, Alain LaGrange, Gerard Lang, Andre Deflandre, Bernadette Luppi
  • Patent number: 5217709
    Abstract: Cosmetic composition containing, by way of a compound screening cut UV of wavelengths 280-380 nm, a 5-benzylidene-3-oxacyclopentanone of formula (I): ##STR1## where R.sub.1, R.sub.2, R.sub.3 and R.sub.4 denote C.sub.1 -C.sub.8 alkyl, aralkyl or aryl, or alternatively R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 form, with the carbon to which they are attached, a saturated 5- or 6-membered ring, andR.sub.5, R.sub.6 and R.sub.7 denote H, C.sub.1 -C.sub.8 alkyl, C.sub.2 -C.sub.8 alkenyl, C.sub.1 -C.sub.12 alkoxy, C.sub.2 -C.sub.8 alkenyloxy, C.sub.2 -C.sub.12 acyloxy, benzyloxy or --COOR.sub.10 where R.sub.10 is a C.sub.1 --C.sub.8 alkyl, hydrogen, an alkali metal or alkaline earth metal or a radical derived from an amine, it also being possible for one of the substituents R.sub.5, R.sub.6 and R.sub.7 to denote a radical ##STR2## where R.sub.1, R.sub.2, R.sub.3 and R.sub.4 have the above meanings. This composition can be a protective composition for the human epidermis or the hair or an antisun composition.
    Type: Grant
    Filed: October 24, 1989
    Date of Patent: June 8, 1993
    Assignee: L'Oreal
    Inventors: Alain Lagrange, Serge Forestier, Gerard Lang, Bernadette Luppi
  • Patent number: 5202487
    Abstract: 2-Substituted para-aminophenols of general formula: ##STR1## where Y denotes oxygen or sulphur and R denotes a C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 hydroxyalkyl or C.sub.1 -C.sub.6 haloalkyl or a C.sub.2 -C.sub.6 polyhydroxyalkyl, provided that when Y=O, R is not methyl or ethyl and when Y=S, R is not ethyl; anddye composition containing one or more compounds of formula (I) where Y denotes an oxygen or sulphur atom and R is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 hydroxyalkyl, C.sub.1 -C.sub.6 haloalkyl or C.sub.2 -C.sub.6 polyhydroxyalkyl.
    Type: Grant
    Filed: August 24, 1992
    Date of Patent: April 13, 1993
    Assignee: L'Oreal
    Inventors: Alex Junino, Gerard Lang, Alain Genet
  • Patent number: 5198567
    Abstract: A compound of formula (I) ##STR1## its isomers and its salts in which R.sub.1, R.sub.3 and R.sub.4 are each independently hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, halogen, C.sub.1 -C.sub.8 -acyloxy or hydroxyl;R' is hydrogen or C.sub.1 -C.sub.6 -alkyl;R" is either a polyene chain or a benzene ringare useful in cosmetics and in the treatment of various dermatological and other complaints.
    Type: Grant
    Filed: July 23, 1991
    Date of Patent: March 30, 1993
    Assignee: L'Oreal
    Inventors: Gerard Lang, Jean Maignan, Serge Restle, Braham Shroot
  • Patent number: 5196189
    Abstract: A quaternized polymer for use as a cosmetic agent, has recurring units of the formula ##STR1## wherein R is lower alkyl or --CH.sub.2 --CH.sub.2 OH;R' is an aliphatic, alicyclic or arylaliphatic radical containing a maximum of 20 carbon atoms, or R and R' together with the nitrogen atom to which they are attached form a heterocycle capable of containing a heteroatom other than nitrogen;A is a divalent group selected from ##STR2## wherein x, y and t are whole numbers ranging from 0 to 11 such that the sum (x+y+t) is greater than or equal to 0 and lower than 18, and E and K represent hydrogen or an aliphatic radical having less than 18 carbon atoms,--(CH.sub.2).sub.n --S--(CH.sub.2).sub.n --, (3)--(CH.sub.2).sub.n --O--(CH.sub.2).sub.n --, (4)--(CH.sub.2).sub.n --S--S--(CH.sub.2).sub.n --, (5)--(CH.sub.2).sub.n --SO--(CH.sub.2).sub.n --, (6)--(CH.sub.2).sub.n --SO.sub.2 --(CH.sub.2).sub.
    Type: Grant
    Filed: June 12, 1992
    Date of Patent: March 23, 1993
    Assignee: Societe Anonyme dite: l'Oreal
    Inventors: Bernard Jacquet, Gerard Lang
  • Patent number: 5194663
    Abstract: An aromatic derivative of butyric acid has the formula ##STR1## These aromatic derivatives of butyric acid are useful in human and veterinary medicines as well as in cosmetic compositions.
    Type: Grant
    Filed: August 9, 1991
    Date of Patent: March 16, 1993
    Assignee: Societe Anonyme Dite: L'Oreal
    Inventors: Jean Maignan, Gerard Malle, Gerard Lang
  • Patent number: 5192332
    Abstract: The present invention provides a cosmetic temporary coloring composition which comprises a cosmetically acceptable support and, as an active ingredient, at least one chemically modified protein derivative which contains residues of molecules of dye grafted onto the protein chain. Thus, certain of the side chains of the protein derivative having amine, alcohol or thiol functions are substituted by residues of dye molecules. The present invention further provides a process for the temporary coloring of human hair, nails or skin comprising applying thereto in an amount effective to color the human hair, nails or skin a composition containing a solution in water, a lower mono-alcohol or polyol or an aqueous alcoholic mixture wherein the alcohol is present in an amount ranging from 0.5 to 50 percent by weight of the chemically modified protein derivative.
    Type: Grant
    Filed: October 7, 1991
    Date of Patent: March 9, 1993
    Assignee: L'Oreal
    Inventors: Gerard Lang, Serge Forestier, Gerard Malle, Alex Junino
  • Patent number: 5191110
    Abstract: According to this process, one effects a stereospecific reduction of the two hydroxyl groups of an ether-diol by a mixture (titanium trichloride, lithium aluminum hydride) at a temperature between 5.degree. C. and about 40.degree. C. and that optionally, one converts the resulting ether into vitamin A, retinol or retinoic acid.Application to the synthesis of all-trans compounds selected from the group consisting of vitamin A and its ethers, retinol and retinoic acid, and their 13-cis isomers.
    Type: Grant
    Filed: April 21, 1992
    Date of Patent: March 2, 1993
    Assignee: L'Oreal
    Inventors: Guy Solladie, Serge Forestier, Gerard Lang
  • Patent number: RE34300
    Abstract: New chloro-meta-phenylenediamines, their use as couplers in the oxidation dyeing of keratinous fibres, dyeing compositions for hair containing these compounds and dyeing process using the said compositions.The invention relates to the compounds of formula: ##STR1## in which Z and Z' denote, independently of one another, an alkyl radical having from 1 to 4 carbon atoms or a hydroxyalkyl radical having from 2 to 4 carbon atoms, andR.sub.1 and R.sub.2 denote, independently of one another, a hydrogen atom, an alkyl radical having from 1 to 4 carbon atoms or a mono- or polyhydroxyalkyl radical having 2 or 3 carbon atoms, to their addition salts with an acid, and to their use by way of couplers for the oxidation dyeing of keratinous fibres, especially human hair.These compounds, when they are combined with paraphenylenediamines, surprisingly give beige to light brown hues or purple hues of greater of lesser redness, depending on the substitution of the 5-amino group of the chlorobenzene.
    Type: Grant
    Filed: August 13, 1990
    Date of Patent: July 6, 1993
    Assignee: L'Oreal
    Inventors: Alex Junino, Jean J. Vandenbossche, Herve Borowiak, Gerard Lang