Patents by Inventor Gérard Lang

Gérard Lang has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5190564
    Abstract: The invention relates to a process for dyeing keratinous fibres, comprising the simultaneous or sequential application of a composition (A) containing a compound of formula (I): ##STR1## in which: R.sub.1 denotes hydrogen, alkyl, acetyl, benzoyl, phenyl or C.sub.1 -C.sub.4 carboxyalyl (sic);R.sub.2 and R.sub.3 denote hydrogen, alkyl, alkoxy, hydroxyalkyl, amino, halogen, nitro, alkylphenyl, phenyl, alkylamino, hydroxyalkylamino;and a composition (B) containing at least one compound of formula (II): ##STR2## in which: R.sub.4 and R.sub.6 denote hydrogen, alkyl;R.sub.5 denotes hydrogen, alkyl, COOR' where R' is hydrogen or alkyl;Z.sub.1 represents hydrogen, halogen, alkyl, alkoxy or hydroxyl;Z.sub.2 represents hydrogen or alkyl or a compound of formula (III): ##STR3## in which: R.sub.7 and R.sub.8 denote hydrogen or alkyl;X.sub.1 and X.sub.2 represent hydrogen or an NH.sub.2 radical;R.sub.9 denotes hydrogen, alkyl, alkoxy;as well as the compositions used.
    Type: Grant
    Filed: January 30, 1992
    Date of Patent: March 2, 1993
    Assignee: L'Oreal
    Inventors: Gerard Lang, Jean Cotteret
  • Patent number: 5178852
    Abstract: The invention relates to cosmetic and pharmaceutical compositions containing the derivatives of benzylidenecamphor of formula: ##STR1## where R.sub.1 denotes H, OH, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.8 alkoxy, R.sub.3 denotes OH, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.8 alkoxy, or else when R.sub.1 denotes H or OH, R.sub.3 can represent C.sub.1 -C.sub.8 alkyl, R.sub.2 and R.sub.4 denote H or OH, at least one of the radicals R.sub.2 and R.sub.4 representing OH.The compounds (I) are wide-band sunscreens and antioxidants, and are utilized in the treatment of cutaneous inflammations and allergies.
    Type: Grant
    Filed: March 29, 1990
    Date of Patent: January 12, 1993
    Assignee: L'Oreal
    Inventors: Serge Forestier, Alain Lagrange, Gerard Lang, Andre Deflandre, Bernadette Luppi
  • Patent number: 5175340
    Abstract: The invention relates to an unsaturated benzalmalonate derivative of formula: ##STR1## in which: R.sub.1 and R.sub.2 denote a hydrogen atom, a hydroxyl, a trimethylsiloxy, a C.sub.1 -C.sub.6 straight or branched chain alkyl, C.sub.1 -C.sub.6 straight or branched chain alkoxy or a --(CH.sub.2).sub.p --C(R.sub.4).dbd.CH.sub.2 radical, where p is an integer between 1 and 10 and preferably between 1 and 4 and R.sub.4 denotes a hydrogen atom or a C.sub.1 -C.sub.4 straight or branched chain alkyl radical, one of the two radicals R.sub.1 or R.sub.2 denoting a residue --(CH.sub.2).sub.p --C(R.sub.4).dbd.CH.sub.2,R.sub.3 denotes a hydrogen atom, a C.sub.1 -C.sub.6 straight or branched chain alkyl radical or a C.sub.1 -C.sub.6 straight or branched chain alkoxy radical,R.sub.5 and R.sub.6, which are identical or different, denote a C.sub.1 -C.sub.8 straight or branched chain alkyl radical.Use as a sunscreen in cosmetic compositions.
    Type: Grant
    Filed: July 5, 1989
    Date of Patent: December 29, 1992
    Assignee: L'Oreal
    Inventors: Serge Forestier, Gerard Lang, Herve Richard
  • Patent number: 5158977
    Abstract: A 5,6,7,8-tetrahydro-1-naphthalenol derivative of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent lower alkyl,R.sub.5 and R.sub.6 represent hydrogen or lower alkyl,R represents hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.2 -C.sub.18 alkyl substituted by one or more hydroxyl groups, C.sub.3 -C.sub.18 alkenyl, C.sub.2 -C.sub.18 acyl, benzyl, benzoyl, carboxyl and carboxylic salts of an alkali or alkaline earth metal or of an organic amine.The derivative is useful as an antioxidant in cosmetic compositions and in pharmaceutical compositions for the preventive treatment of cutaneous inflammations and allergies or certain forms of cancer.
    Type: Grant
    Filed: June 7, 1991
    Date of Patent: October 27, 1992
    Assignee: L'Oreal
    Inventors: Jean Maignan, Gerard Malle, Andre Deflandre, Gerard Lang
  • Patent number: 5151534
    Abstract: Compounds corresponding to the formula: ##STR1## wherein A represents --(CH.sub.2).sub.2 or --(C.tbd.C)--;n is equal to 0, 1 or 2;R represents hydroxyl, alkoxy having the formula --OR.sub.1, or amino having the formula ##STR2## R.sub.1 represents alkyl, monohydroxyalkyl, polyhydroxyalkyl, aryl or aralkyl;R.sub.2 and R.sub.3 represent hydrogen, alkyl, monohydroxyalkyl, polyhydroxyalkyl, aryl or benzyl;R.sub.2 and R.sub.3 form, with the nitrogen atom, a heterocyclic ring.Application of these compounds in pharmacy and cosmetics.
    Type: Grant
    Filed: May 10, 1989
    Date of Patent: September 29, 1992
    Assignee: Centre International de Recherches Dermatologiques (CIRD)
    Inventors: Braham Shroot, Christopher Hensby, Jean Maignan, Gerard Lang, Michel Colin
  • Patent number: 5145483
    Abstract: 5-Substituted ortho-aminophenols of formula: ##STR1## in which: R.sub.1 denotes a hydrogen atom, an alkyl radical having 1 to 4 carbon atoms or a hydroxyalkyl radical having 1 to 4 carbon atoms; andR.sub.2 denotes, independently of R.sub.1, an alkyl radical having 1 to 4 carbon atoms, an alkoxy radical having 1 to 4 carbon atoms or a benzyl radical;the addition salts with an acid and the phenates, anddyeing composition containing a compound of formula (I) or a salt or a phenate of such a compound.The 5-substituted ortho-aminophenols enable hair to be dyed in a rich spectrum of hues having good durability.
    Type: Grant
    Filed: October 27, 1989
    Date of Patent: September 8, 1992
    Assignee: L'Oreal
    Inventors: Alex Junino, Herve Andrean, Gerard Lang
  • Patent number: 5145662
    Abstract: The cosmetic use is described, for use as a UV filter, of dibenzoylmethane diorganopolysiloxanes having either formula: ##STR1## where R is C.sub.1 -C.sub.10 alkyl, phenyl or 3,3,3-trifluoropropyl, B is R or A, r=0-200, s=0-50, or formula: ##STR2## where u=1-20, t=0-20 and t+u.gtoreq.3. A and/or B represent an alkylene or alkyleneoxy-dibenzoylmethane which may be substituted.
    Type: Grant
    Filed: February 13, 1990
    Date of Patent: September 8, 1992
    Assignee: L'Oreal
    Inventors: Serge Forestier, Gerard Lang, Herve Richard
  • Patent number: 5131911
    Abstract: Process for dyeing keratin fibers by using derivatives of formula: ##STR1## where: R.sub.1 =H, lower alkyl or SiR.sub.11 R.sub.12 R.sub.13 ;R.sub.2 and R.sub.3, which may be identical or different, =H, alkyl, carboxyl, alkoxycarbonyl or --COOSiR.sub.11 R.sub.12 R.sub.13 ;R.sub.4 to R.sub.7, which may be identical or different, =H or an O--Z group, where Z=H, C.sub.1 -C.sub.20 alkyl, aralkyl, formyl, C.sub.2 -C.sub.20 acyl, C.sub.3 -C.sub.20 alkenyl, --SiR.sub.11 R.sub.12 R.sub.13, --P(O)(OR.sub.8).sub.2, R.sub.8 OSO.sub.2 ;or a heterocycle which may contain a P(O)(OR.sub.8) or CR.sub.9 R.sub.10 group;with the reservation that at least two of R.sub.4 to R.sub.7 denotes OZ or form a ring, and that at least one of R.sub.4 or R.sub.7 represents OZ;R.sub.8 and R.sub.9 =H, lower alkyl;R.sub.10 =alkoxy, mono- or dialkylamino;R.sub.11, R.sub.12 and R.sub.13, which may be identical or different, are alkyl groups;or their alkali metal, alkaline-earth metal, ammonium and amine salts.
    Type: Grant
    Filed: October 2, 1991
    Date of Patent: July 21, 1992
    Assignee: L'Oreal
    Inventors: Gerard Lang, Serge Forestier, Alex Junino, Herve Richard, Jean Jacques Van den Bossche
  • Patent number: 5126453
    Abstract: In a first stage of a process for the preparation of 6-piperidino-2,4-diaminopyrimidine-3-oxide at least one of the two amino groups of a compound having formula (1): ##STR1## where X represents a halogen atom or OH group, is protected by an addition reaction with an isocyanate having formula:R--N=C=OIn this formula R represents an alkyl group, or one of the amino groups. The resulting urea derivative is then oxidized to produce the corresponding N-oxide which is then reacted with piperidine. The protective group(s) are then eliminated by reaction with an organic or inorganic base.
    Type: Grant
    Filed: December 31, 1990
    Date of Patent: June 30, 1992
    Assignee: L'Oreal
    Inventors: Jean Maignan, Serge Restle, Gerard Lang
  • Patent number: 5114429
    Abstract: The invention relates to the new compounds consisting of N,N'-bis(.beta.-hydroxyethyl)-N,N'-bis(4'-aminophenyl)-1,3-diamino-2-propa nol and N,N'-bis(ethyl)-N,N'-bis(4'-amino-3'-methylphenyl)ethylenediamine, and their use in keratinous fiber dyeing compositions and processes.
    Type: Grant
    Filed: September 6, 1989
    Date of Patent: May 19, 1992
    Assignee: L'oreal
    Inventors: Alex Junino, Alain Genet, Gerard Lang
  • Patent number: 5114716
    Abstract: An anti-oxidant system contains, in combination, at least one stabilized ascorbyl ester, at least one tocopherol or a mixture of tocopherols, or cafeic acid or a derivative thereof, at least one complexing agent and at least one non-thiol polypeptide. The anti-oxidant system is employed to stabilize fatty bodies and cosmetic compositions.
    Type: Grant
    Filed: July 28, 1989
    Date of Patent: May 19, 1992
    Assignee: Societe Anonyme Dite: L'Oreal
    Inventors: Quang L. N'Guyen, Jacqueline Griat, Francois Millecamps, Gerard Lang, Serge Forestier
  • Patent number: 5106611
    Abstract: Use of modified diorganopolysiloxanes as antioxidants in cosmetics or in dermatology.Use, as an antioxidizing agent in cosmetics or in dermatology, of diorganopolysiloxanes (i) of formula (I): ##STR1## in which the symbols R denote alkyl or phenyl, B are chosen from the radicals R and A, a an integer chosen between 0 and 200 inclusive, b an integer chosen between 0 and 50 inclusive, and if b is equal to 0, at least one of the two symbols B is A,A is of formula: ##STR2## where: R.sub.1 denotes hydrogen or an alkyl,R.sub.2 denotes hydrogen, hydroxyl, alkyl or alkoxy,R.sub.3 denotes hydrogen, hydroxyl or alkyl,R.sub.4 denotes hydrogen or alkyl,R.sub.5 denotes hydrogen, hydroxyl or alkoxy,Y denotes:(O).sub.n --CH.sub.2 --CH(R.sub.6)--CH.sub.2 --whereR.sub.6 denotes hydrogen or alkyl and n has the value of 0 or 1,or (ii) of formula (II): ##STR3## where c is an integer between 1 and 20 inclusive,d is an integer between 2 and 20 inclusive, andc+d equal to or greater than 3.
    Type: Grant
    Filed: November 20, 1989
    Date of Patent: April 21, 1992
    Assignee: L'Oreal
    Inventors: Serge Forestier, Gerard Lang, Herve Richard
  • Patent number: 5106612
    Abstract: An N-(mercaptoalkyl).omega.-hydroxyalkylamide having the formula, ##STR1## wherein n is 2 or 3 and m is 2 or 5 inclusive is employed as a reducing agent in the first stage reducing operation of permanently deforming hair.
    Type: Grant
    Filed: March 5, 1991
    Date of Patent: April 21, 1992
    Assignee: Societe Anonyme dite: l'Oreal
    Inventors: Jean Maignan, Gerard Lang, Gerard Malle
  • Patent number: 5102660
    Abstract: New polyaminoamides which filter ultraviolet radiation, process for their preparation and their use for protecting the skin and hair.
    Type: Grant
    Filed: October 12, 1990
    Date of Patent: April 7, 1992
    Assignee: L'Oreal
    Inventors: Serge Forestier, Gerard Lang, Edith Sainte Beuve
  • Patent number: 5102707
    Abstract: Linear and cyclic diorganopolysiloxanes containing benzotriazole functional groups are well suited for the coating of optical fibers and for lubricating plastics, e.g., PVC.
    Type: Grant
    Filed: August 4, 1989
    Date of Patent: April 7, 1992
    Assignee: Rhone-Poulenc Chimie
    Inventors: Edith Canivenc, Serge Forestier, Michel Gay, Gerard Lang, Herve Richard
  • Patent number: 5093516
    Abstract: An aromatic compound of the formula ##STR1## wherein n is 0 or 1,(1) when n is 1,R' represents hydrogen or C.sub.1 -C.sub.4 alkoxy,R" represents hydrogen, OH, C.sub.1 -C.sub.4 acyloxy, C.sub.1 -C.sub.4 alkoxy or amino,or R' and R" taken together form an oxo, methano or hydroxy-imino radical,R.sub.1 represents--CH.sub.2 OH or --COR.sub.10,R.sub.10 represents hydrogen, OR.sub.11 or ##STR2## R.sub.11 represents hydrogen, C.sub.1 -C.sub.20 alkyl, monohydroxyalkyl, polyhydroxy alkyl, aryl, aralkyl, the residue of a sugar or ##STR3## p is 1,2 or 3, r' and r" represent hydrogen, lower alkyl, monohydroxyalkyl, polyhydroxyalkyl, aryl, benzyl, the residue of an amino acid or the residue of an aminated sugar, of r' and r" taken together form a heterocycle,R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 represent hydrogen, OH, C.sub.1 -C.sub.12 alkyl, cycloalkyl, cycloalkenyl, phenyl or a radical of the formulas (i)--X--C.sub.6 H.sub.5, (ii)--X--R.sub.12 or (iii)--NHCOR.sub.13,X is --0--,--S--,--SO--,--SO.sub.
    Type: Grant
    Filed: April 3, 1987
    Date of Patent: March 3, 1992
    Assignee: L'Oreal
    Inventors: Jean Maignan, Gerard Lang, Gerard Malle, Serge Restle, Braham Shroot
  • Patent number: 5089250
    Abstract: The cosmetic use is described, in particular for use as a UV filter, of benzotriazole diorganopolysiloxanes having either formula: ##STR1## where R is C.sub.1 -C.sub.10 alkyl, phenyl or 3,3,3-trifluoropropyl, B is R or A, r=0-200, s=0-50, or formulas: ##STR2## where u=1-20, t=0-20 and t+u.gtoreq.3.A and/or B represent a benzotriazole C.sub.3 -C.sub.12 alkylene which may be substituted.
    Type: Grant
    Filed: February 13, 1990
    Date of Patent: February 18, 1992
    Assignee: L'Oreal
    Inventors: Serge Forestier, Gerard Lang, Herve Richard, Jean C. Grognet
  • Patent number: 5084579
    Abstract: A benzofuran compound of the formula ##STR1## wherein A represents ##STR2## wherein R.sub.1, R.sub.2, R.sub.3, B and D have various meanings. The benzofuran compound is usefully employed in pharmaceutical and cosmetic compositions.
    Type: Grant
    Filed: March 14, 1991
    Date of Patent: January 28, 1992
    Assignee: L'Oreal
    Inventors: Gerard Lang, Serge Forestier, Alain Lagrange, Jean Maignan, Gerard Malle
  • Patent number: 5084067
    Abstract: 3-Substituted para-aminophenols of general formula: ##STR1## where X.dbd.H, halogen; Y.dbd.O--, --S--; R.dbd.alkyl, hydroxyalkyl, C.sub.1-4 aminoalkyl or C.sub.3 -C.sub.6 polyhydroxyalkyl;with the proviso that, when X.dbd.H, R is not methyl, and when X.dbd.H and Y.dbd.O, R is not ethyl;process for preparing them, intermediate compounds of formula: ##STR2## where X.sub.1 =halogen, Y and R have the meaning stated above; with the proviso that, when Y.dbd.O, R is not methyl, and when R=aminoalkyl, X.sub.1 can also denote hydrogen;dyeing compositions containing one or more compounds of formula (I), and a process for dyeing human hair.
    Type: Grant
    Filed: February 28, 1989
    Date of Patent: January 28, 1992
    Assignee: L'Oreal
    Inventors: Alex Junino, Alain Genet, Gerard Lang
  • Patent number: 5075331
    Abstract: A benzofuran compound of the formula ##STR1## wherein A represents ##STR2## wherein R.sub.1, R.sub.2, R.sub.3, B and D have various meanings. The benzofuran compound is usefully employed in pharmaceutical and cosmetic compositions.
    Type: Grant
    Filed: September 14, 1989
    Date of Patent: December 24, 1991
    Assignee: L'Oreal
    Inventors: Gerard Lang, Serge Forestier, Alain Lagrange, Jean Maignan, Gerard Malle