Abstract: Composite wear layers that include a polyethylene terephthalate wear layer adhered to an organic/inorganic (O/I) top coat layer, and surface coverings and surface covering components including the wear layers, are disclosed. The organic/inorganic top coat layer is formed from a top coat formulation which comprises a coupling agent. The coupling agent is a molecule which includes an organic polymerizable moiety such as epoxy, acrylate and the like, as well as an inorganic polymerizable moiety such as a silanol. Top coat layers formed from the top coat formulation have both organic and inorganic character. Although not limited to these thickness ranges, the wear layer is typically in the range of about 1-20 mils thickness, and the top coat layer is typically in the range of 2 microns to 0.5 mils thickness. The composite wear layers can be included in surface coverings or surface covering components, such as floor and wall coverings.

Abstract: The invention comprises a composition and method for controlling the gloss of surface covering products through curing of the composition to create a wearlayer surface, and preferably on a floor covering product. The surface covering product preferably is prepared by application of an aromatic polyester acrylate composition including a flatting agent and/or hard particles, and at least one free-radical generating compound to a substrate, and then the coating is partially cured by exposure to low peak irradiance UV light in either ambient or inert air, followed by fully curing the coating with high peak irradiance UV light in preferably an inert atmosphere to form a low gloss abrasion resistant wearlayer surface. Alternatively, a high gloss wearlayer surface is obtained by solely exposing the preferred composition to high peak irradiance UV light in ambient atmosphere. Furthermore, a differential gloss flooring product is obtained by using the present inventive method described herein.

Abstract: The invention is a method for manufacturing a surface covering product having a gloss controlled surface wearlayer coating and a curable composition used in that method. The preferred curable composition is a polymerizable coating which includes a di-isocyanate and/or isocyanurate structure, a polyester polyol, a hydroxy and acrylyl functional polyester, mono, di, or tri-functional acrylates, and a flatting agent and/or hard particulates. The preferred surface covering product is a floor covering product produced as a vinyl film that is precoated with preferably a wearlayer coating that is adhered to the vinyl film, and the surface of the film is preferably embossed.

Abstract: A surface covering and a method of manufacturing such surface covering is disclosed. In one embodiment of the present invention, the surface covering includes a film having a print layer forming a pattern or design disposed on one side of the film. A discontinuous gloss layer is disposed on the other side of the film substantially in-register with at least a portion of the printed pattern or design. Additionally, the gloss layer has at least one portion thereof which has a gloss level different from the side upon which the gloss layer is disposed. In another embodiment, the surface covering has a film and a discontinuous gloss layer disposed on one side of the film. The gloss layer forms a pattern or design and at least one portion thereof has a gloss level different from the side upon which the gloss layer is disposed. A surface texture is mechanically embossed into the film substantially in-register with the pattern or design of the gloss layer. Optionally, a web may be laminated to the surface covering.

Abstract: Surface covering components that include a topcoat layer with different gloss levels in various regions on the top coat layer, and methods of manufacturing such surface covering components, are disclosed. The surface covering components include a coating layer that includes regions that have a relatively higher gloss, and regions with a relatively lower gloss. The differential gloss is provided by coating a substrate with a UV-curable coating composition, subjecting a first region of the surface coating to polymerization under a first set of conditions, and subjecting a second region of the surface coating to polymerization under a second set of conditions. The UV-curable coating compositions include UV-curable components and one or more flatting agents. The different polymerization conditions involve applying various photoinitiators, thermal initiators and/or cure altering agents to some regions of the coated substrate, and not applying these components to other regions of the substrate.

Abstract: A surface covering has a base to which is laminated a rigid vinyl film. The film is precoated with an electron beam cured wearlayer. The preferred wearlayer composition is a polymerizable organic urethane-polyester wearlayer coating. The coated printed film is prepared by application of a polyester urethane acrylate composition to a printed sheet of rigid vinyl film and the coating is exposed to a low accelerating energy Electro-curtain to form an abrasion resistant topcoat with no apparent degradation of printed rigid vinyl film.

Abstract: Surface covering components that include a topcoat layer with different gloss levels in various regions on the top coat layer, and methods of manufacturing such surface covering components, are disclosed. The surface covering components include a coating layer that includes regions that have a relatively higher gloss, and regions with a relatively lower gloss. The differential gloss is provided by coating a substrate with a UV-curable coating composition, subjecting a first region of the surface coating to polymerization under a first set of conditions, and subjecting a second region of the surface coating to polymerization under a second set of conditions. The UV-curable coating compositions include UV-curable components and one or more flatting agents. The different polymerization conditions involve applying various photoinitiators, thermal initiators and/or cure altering agents to some regions of the coated substrate, and not applying these components to other regions of the substrate.

Abstract: The invention comprises a composition and method for controlling the gloss of surface covering products through curing of the composition to create a wearlayer surface, and preferably on a floor covering product. The surface covering product preferably is prepared by application of an aromatic polyester acrylate composition including a flatting agent and/or hard particles, and at least one free-radical generating compound to a substrate, and then the coating is partially cured by exposure to low peak irradiance UV light in either ambient or inert air, followed by fully curing the coating with high peak irradiance UV light in preferably an inert atmosphere to form a low gloss abrasion resistant wearlayer surface. Alternatively, a high gloss wearlayer surface is obtained by solely exposing the preferred composition to high peak irradiance UV light in ambient atmosphere. Furthermore, a differential gloss flooring product is obtained by using the present inventive method described herein.

Abstract: The invention comprises a composition and method for controlling the gloss of surface covering products through curing of the composition to create a wearlayer surface, and preferably on a floor covering product. The surface covering product preferably is prepared by application of an aromatic polyester acrylate composition including a flatting agent and/or hard particles, and at least one free-radical generating compound to a substrate, and then the coating is partially cured by exposure to low peak irradiance UV light in either ambient or inert air, followed by fully curing the coating with high peak irradiance UV light in preferably an inert atmosphere to form a low gloss abrasion resistant wearlayer surface. Alternatively, a high gloss wearlayer surface is obtained by solely exposing the preferred composition to high peak irradiance UV light in ambient atmosphere. Furthermore, a differential gloss flooring product is obtained by using the present inventive method described herein.

Abstract: The invention is a method for manufacturing a surface covering product having a gloss controlled surface wearlayer coating and a curable composition used in that method. The preferred curable composition is a polymerizable coating which includes a di-isocyanate and/or isocyanurate structure, a polyester polyol, a hydroxy and acrylyl functional polyester, mono, di, or tri-functional acrylates, and a flatting agent and/or hard particulates. The preferred surface covering product is a floor covering product produced as a vinyl film that is precoated with preferably a wearlayer coating that is adhered to the vinyl film, and the surface of the film is preferably embossed.

Abstract: A surface covering has a base to which is laminated a rigid vinyl film. The film is precoated with an electron beam cured wearlayer. The preferred wearlayer composition is a polymerizable organic urethane-polyester wearlayer coating. The coated printed film is prepared by application of a polyester urethane acrylate composition to a printed sheet of rigid vinyl film and the coating is exposed to a low accelerating energy Electro-curtain to form an abrasion resistant topcoat with no apparent degradation of printed rigid vinyl film.

Abstract: The invention is a method for manufacturing a surface covering product having a gloss controlled surface wearlayer coating and a curable composition used in that method. The preferred curable composition is a polymerizable coating which includes a di-isocyanate and/or isocyanurate structure, a polyester polyol, a hydroxy and acrylyl functional polyester, mono, di, or tri-functional acrylates, and a flatting agent and/or hard particulates. The preferred surface covering product is a floor covering product produced as a vinyl film that is precoated with preferably a wearlayer coating that is adhered to the vinyl film, and the surface of the film is preferably embossed.

Abstract: Thermally insulative xerogels and their preparation are described. To obtain these xerogels, an inorganic gel having hydroxyl moieties is reacted with a silicon-nitrogen compound which has a C.sub.1-6 hydrocarbon moiety on the silicon. Shrinkage of the gel during drying the gel is reduced and a more highly porous xerogel is obtained. The more highly porous xerogel has a low thermal conductivity which makes it a good thermal insulation.