Abstract: A monitoring assembly for an electrochemical cell of a secondary lithium battery includes a porous sensory structure and a transducer. The porous sensory structure includes a sensory layer disposed on a major surface of a porous separator and a buffer layer disposed between the sensory layer and a facing surface of a negative electrode layer. The buffer layer electrically isolates the sensory layer from the facing surface of the negative electrode layer. The sensory layer includes an electrically conductive material and is configured to produce a response to an input signal or to a physical stimulus received within the electrochemical cell. The transducer is configured to process the response produced by the sensory layer to generate an output signal indicative of a diagnostic condition within the electrochemical cell.

Abstract: A method of making a reference electrode assembly for an electrochemical cell according to various aspects of the present disclosure includes providing a subassembly including a separator layer and a current collector layer coupled to the separator layer. The method further includes providing an electrode ink including an electroactive material, a binder, and a solvent. The method further includes creating a reference electrode precursor by applying an electroactive precursor layer to the current collector layer. The electroactive precursor layer covers greater than or equal to about 90% of a superficial surface area of a surface of the current collector layer. The electroactive precursor layer includes the electrode ink. The method further includes creating the reference electrode assembly by drying the electroactive precursor layer to remove at least a portion of the solvent, thereby forming an electroactive layer. The electroactive layer is solid and porous.

Abstract: An electrode for an electrochemical cell is provided. The electrode includes a carbon membrane having a first face and an opposing second face, wherein at least a portion of the carbon membrane is modified to include an elevated number of nucleation sites for lithium relative to the carbon membrane when unmodified.

Abstract: A reference electrode assembly for an electrochemical cell of a secondary lithium ion battery and methods of manufacturing the same. The reference electrode assembly includes a porous membrane having a major surface and a porous reference structure deposited on the major surface of the porous membrane. The porous reference structure includes a porous carbon layer and a porous reference electrode layer that at least partially overlaps the porous carbon layer on the major surface of the porous membrane.

Abstract: A system including a lithium-ion battery cell is disclosed. The lithium-ion battery cell includes a first electrode. The first electrode includes a current collector including a surface and an electrode coating formed from an electrode coating slurry and disposed on the current collector. The electrode coating slurry includes a plurality of flakes of flake graphite. Each of the plurality of flakes includes two parallel planar surfaces and an edge plane defined by the two parallel planar surfaces. The edge planes of the plurality of flakes are statistically facing toward the surface of the current collector. The first electrode further includes a conductive material including a high aspect ratio nano-sized carbon material. The carbon material is configured for providing attractive forces between components of the electrode coating. The lithium-ion battery cell further includes a second electrode, a separator disposed between the first electrode and the second electrode, and an electrolyte.

Abstract: A multifunctional self-cleaning surface layer and methods of preparing the multifunctional self-cleaning surface layer are provided. The multifunctional self-cleaning surface layer includes an inorganic matrix including silicon and oxygen; a plurality of photocatalytic active particles distributed within and bonded to the inorganic matrix; and a plurality of nanopores defined within the inorganic matrix in regions corresponding to bonds between the plurality of photocatalytic active particles and the inorganic matrix. Water molecules may be disposed within at least a portion of the plurality of nanopores. In the presence of water and electromagnetic radiation, the plurality of photocatalytic active particles may facilitate a decomposition reaction of any oil or organic residue on the multifunctional self-cleaning surface layer.

Abstract: A reference electrode assembly for an electrochemical cell includes a separator constructed from an electrically-insulating porous material. The reference electrode assembly also includes a current collector having a sputtered electrically-conducting porous layer arranged directly on the separator and a sputtered lithium iron phosphate (LFP) layer arranged directly on the electrically-conducting porous layer. The reference electrode assembly additionally includes an electrical contact connected to the current collector. A method using successive vacuum deposition of individual layers onto the separator is employed in fabricating the reference electrode assembly.

Abstract: The present disclosure provides an electrochemical cell that includes an electrically conductive material layer, a precursor material disposed on or adjacent to a first surface of the electrically conductive material layer, and an electroactive material layer disposed on or adjacent to the precursor material. In certain variations, the precursor material forms a continuous layer and a solid-electrolyte interface layer is disposed on or adjacent to an exposed surface of the electroactive material layer. In other variations, the precursor material forms a plurality of distinct precursor structures disposed on the first surface of the electrically conductive material layer in a predetermined pattern, such that at least a portion of each distinct precursor structure is unobstructed by the electroactive material layer. The distinct precursor structures are configured to form surface structures that chemically attach the solid-electrolyte interface layer and the electrically conductive material layer.

Abstract: A method of making a reference electrode assembly for an electrochemical cell according to various aspects of the present disclosure includes providing a subassembly including a separator layer and a current collector layer coupled to the separator layer. The method further includes providing an electrode ink including an electroactive material, a binder, and a solvent. The method further includes creating a reference electrode precursor by applying an electroactive precursor layer to the current collector layer. The electroactive precursor layer covers greater than or equal to about 90% of a superficial surface area of a surface of the current collector layer. The electroactive precursor layer includes the electrode ink. The method further includes creating the reference electrode assembly by drying the electroactive precursor layer to remove at least a portion of the solvent, thereby forming an electroactive layer. The electroactive layer is solid and porous.

Abstract: An adhesive-reinforced rotor for a rotary electric machine includes rotor lamination layers (“rotor lams”) having axial inner surfaces collectively defining rotor openings through the rotor lams. The rotor also includes reinforcement blocks disposed within a respective one of the rotor openings. A polymer primer/adhesive layer of the rotor having a bond line thickness of less than 1 mm is disposed between the one or more reinforcement blocks and the axial inner surfaces of the rotor lams. The reinforcement blocks and the primer/adhesive layer each have a tensile strength of at least 50 MPa. A modulus of elasticity of the reinforcement blocks is at least three times greater than that of the materials of the polymer primer/adhesive layer. A method of constructing an adhesive-reinforced rotor is also described herein.

Abstract: A system includes a display. The display includes an array of LEDs covered by a transparent material. The array of LEDs includes a plurality of first, second, third, and fourth LEDs respectively configured to emit red, green, blue, and violet light. The red, green, and blue light from the first, second, and third LEDs is visible to human eye. Violet light from the fourth LEDs is invisible to human eye. The system includes a photocatalytic coating disposed on the transparent material. The photocatalytic coating includes a photo-catalyst responsive to ultraviolet radiation present in sunlight and to the violet light emitted by the fourth LEDs in the array of LEDs. The system includes a controller configured to selectively turn on the fourth LEDs to activate the photo-catalyst in the photocatalytic coating disposed on the transparent material.

Abstract: A temperature sensor for a battery cell of a rechargeable battery is described, and includes a resistive sensing element, a first electrode, and a second electrode. The resistive sensing element, the first electrode, and the second electrode are affixed to a porous separator. The porous separator is interposed between an anode and a cathode of the battery cell. The resistive sensing element is electrically connected in series between the first electrode and the second electrode, and the resistive sensing element, the first electrode and the second electrode are affixed onto the separator as film layers, and are porous.

Abstract: The present disclosure provides an electrochemical cell that includes an electrically conductive material layer, a precursor material disposed on or adjacent to a first surface of the electrically conductive material layer, and an electroactive material layer disposed on or adjacent to the precursor material. In certain variations, the precursor material forms a continuous layer and a solid-electrolyte interface layer is disposed on or adjacent to an exposed surface of the electroactive material layer. In other variations, the precursor material forms a plurality of distinct precursor structures disposed on the first surface of the electrically conductive material layer in a predetermined pattern, such that at least a portion of each distinct precursor structure is unobstructed by the electroactive material layer. The distinct precursor structures are configured to form surface structures that chemically attach the solid-electrolyte interface layer and the electrically conductive material layer.

Abstract: A self-cleaning film system includes a substrate and a film. The film includes a monolayer formed from a fluorinated material, and a first plurality of regions disposed within the monolayer and spaced apart from one another such that each of the regions abuts, is surrounded by, and is not covered by the fluorinated material. Each of the regions includes a photocatalytic material. The system may include a wave guide disposed adjacent the substrate. The wave guide includes a first light source configured for emitting a first portion of electromagnetic radiation towards the film having an ultraviolet wavelength of from 10 nm to 400 nm, and a second light source configured for emitting a second portion of electromagnetic radiation towards the film having an infrared wavelength of from 700 nm to 1 mm. A method of forming a self-cleaning film system configured for reducing a visibility of a contaminant is disclosed.

Abstract: A method of making a reference electrode assembly for an electrochemical cell according to various aspects of the present disclosure includes providing a subassembly including a separator layer and a current collector layer coupled to the separator layer. The method further includes providing an electrode ink including an electroactive material, a binder, and a solvent. The method further includes creating a reference electrode precursor by applying an electroactive precursor layer to the current collector layer. The electroactive precursor layer covers greater than or equal to about 90% of a superficial surface area of a surface of the current collector layer. The electroactive precursor layer includes the electrode ink. The method further includes creating the reference electrode assembly by drying the electroactive precursor layer to remove at least a portion of the solvent, thereby forming an electroactive layer. The electroactive layer is solid and porous.

Abstract: A method of making a reference electrode assembly for an electrochemical cell according to various aspects of the present disclosure includes providing a subassembly including a separator layer and a current collector layer coupled to the separator layer. The method further includes providing an electrode ink including an electroactive material, a binder, and a solvent. The method further includes creating a reference electrode precursor by applying an electroactive precursor layer to the current collector layer. The electroactive precursor layer covers greater than or equal to about 90% of a superficial surface area of a surface of the current collector layer. The electroactive precursor layer includes the electrode ink. The method further includes creating the reference electrode assembly by drying the electroactive precursor layer to remove at least a portion of the solvent, thereby forming an electroactive layer. The electroactive layer is solid and porous.

Abstract: A method of making a reference electrode assembly for an electrochemical cell according to various aspects of the present disclosure includes providing a subassembly including a separator layer and a current collector layer coupled to the separator layer. The method further includes providing an electrode ink including an electroactive material, a binder, and a solvent. The method further includes creating a reference electrode precursor by applying an electroactive precursor layer to the current collector layer. The electroactive precursor layer covers greater than or equal to about 90% of a superficial surface area of a surface of the current collector layer. The electroactive precursor layer includes the electrode ink. The method further includes creating the reference electrode assembly by drying the electroactive precursor layer to remove at least a portion of the solvent, thereby forming an electroactive layer. The electroactive layer is solid and porous.

Abstract: A monitoring assembly for an electrochemical cell of a secondary lithium battery includes a porous sensory structure and a transducer. The porous sensory structure includes a sensory layer disposed on a major surface of a porous separator and a buffer layer disposed between the sensory layer and a facing surface of a negative electrode layer. The buffer layer electrically isolates the sensory layer from the facing surface of the negative electrode layer. The sensory layer includes an electrically conductive material and is configured to produce a response to an input signal or to a physical stimulus received within the electrochemical cell. The transducer is configured to process the response produced by the sensory layer to generate an output signal indicative of a diagnostic condition within the electrochemical cell.

Abstract: A method of making a reference electrode assembly for an electrochemical cell according to various aspects of the present disclosure includes providing a subassembly including a separator layer and a current collector layer coupled to the separator layer. The method further includes providing an electrode ink including an electroactive material, a binder, and a solvent. The method further includes creating a reference electrode precursor by applying an electroactive precursor layer to the current collector layer. The electroactive precursor layer covers greater than or equal to about 90% of a superficial surface area of a surface of the current collector layer. The electroactive precursor layer includes the electrode ink. The method further includes creating the reference electrode assembly by drying the electroactive precursor layer to remove at least a portion of the solvent, thereby forming an electroactive layer. The electroactive layer is solid and porous.

Abstract: A reference electrode assembly for an electrochemical cell of a secondary lithium ion battery and methods of manufacturing the same. The reference electrode assembly includes a porous membrane having a major surface and a porous reference structure deposited on the major surface of the porous membrane. The porous reference structure includes a porous carbon layer and a porous reference electrode layer that at least partially overlaps the porous carbon layer on the major surface of the porous membrane.