Abstract: This invention provides for an apparatus and a method for operation of a cryogenic hydrogen storage system that contains a porous medium configured to adsorb hydrogen. The hydrogen storage and supply system includes a hydrogen source apparatus and a cryosorptive storage apparatus. Methods and devices that allow for an energy efficient filling of the cryosorptive apparatus from the hydrogen source apparatus are described. The cryosorptive hydrogen storage apparatus is filled with cold, pressurized hydrogen. During the course of filling, heat is generated in the cryosorptive storage device by the process of hydrogen adsorption on to the host medium. Methods and devices are provided for the removal the generated heat and the warm hydrogen. Further provided are devices and methods for the capture and recycle of escaped hydrogen within the hydrogen source apparatus.

Abstract: An electronic system for selectively detecting and identifying a plurality of chemical species, which comprises an array of nanostructure sensing devices, is disclosed. Within the array, there are at least two different selectivities for sensing among the nanostructure sensing devices. Methods for fabricating the electronic system are also disclosed. The methods involve modifiying nanostructures within the devices to have different selectivity for sensing chemical species. Modification can involve chemical, electrochemical, and self-limiting point defect reactions. Reactants for these reactions can be supplied using a bath method or a chemical jet method. Methods for using the arrays of nanostructure sensing devices to detect and identify a plurality of chemical species are also provided.

Abstract: A nanostructure device is made up of a nanostructure, such as a single-walled carbon nanotube, spanning two electrical conductors, mounted on a substrate. A passivation layer may cover a portion of the conductors and the nanostructure. A thin polymer layer is deposited over an exposed portion of the nanotube. In this configuration, the device may perform like an n-type field effect transistor. The polymer material may be selected for interactivity with a particular chemical species or compound. The device may therefore be used as a resistive sensor that responds to the particular species or compound by exhibiting a change in resistivity.

Abstract: A capnometer adaptor includes a nanostructure sensor configured to selectively respond to a gaseous constituent of exhaled breath, such as to carbon dioxide. The sensor may be provided as a compact and solid-state device, and may be adapted for a variety of respiratory monitoring applications.

Abstract: A flexible electronic device is made up of nanostructures. Specifically, the device includes a flexible substrate, a film of nanostructures in contact with the flexible substrate, a first conducting element in contact with the film of nanostructures, and a second conducting element in contact with the film of nanostructures. The nanostructures may comprise nanotubes, such as carbon nanotubes disposed along the flexible substrate, such as an organic or polymer substrate. The first and second conductive elements may serve as electrical terminals, or as a source and drain. In addition, the electronic device may include a gate electrode that is in proximity to the nanotubes and not in electrical contact with the nanotubes. In this configuration, the device can operate as a transistor or a FET. The device may also be operated in a resistive mode as a chemical sensor (e.g., for sensing NH3).

Abstract: This invention provides for an apparatus and a method for operation of a cryogenic hydrogen storage system that contains a porous medium configured to adsorb hydrogen. The hydrogen storage and supply system includes a hydrogen source apparatus and a cryosorptive storage apparatus. Methods and devices that allow for an energy efficient filling of the cryosorptive apparatus from the hydrogen source apparatus are described. The cryosorptive hydrogen storage apparatus is filled with cold, pressurized hydrogen. During the course of filling, heat is generated in the cryosorptive storage device by the process of hydrogen adsorption on to the host medium. Methods and devices are provided for the removal the generated heat and the warm hydrogen. Further provided are devices and methods for the capture and recycle of escaped hydrogen within the hydrogen source apparatus.

Abstract: Nanostructure sensing devices for detecting an analyte are described. The devices include nanostructures connected to conductive elements, all on a substrate. Contact regions adjacent to points of contact between the nanostructures and the conductive elements are given special treatment. The proportion of nanostructure surface area within contact regions can be maximized to effect sensing at very low analyte concentrations. The contact regions can be passivated in an effort to prevent interaction between the environment and the contact regions for sensing at higher analyte concentrations and for reducing cross-sensing. Both contact regions and at least some portion of the nanostructures can be covered with a material that is at least partially permeable to the analyte of interest and impermeable to some other species to tune selectivity and sensitivity of the nanostructure sensing device.

Abstract: An electronic system and method for detecting carbon dioxide is provided, using a nanostructure sensing device (CO2 sensor). The CO2 sensor is made up of a substrate and a nanostructure disposed over the substrate. The nanostructure may comprise a carbon nanotube, or a network of nanotubes. Two conductive elements are disposed over the substrate and electrically connected to the nanotube. A gate electrode may be positioned opposite the nanostructure. A functionalization material reactive with carbon dioxide is disposed on CO2 sensor, and in particular, on the nanotube. The CO2 sensor may be connected to an electrical circuit, which will respond to changes in CO2 concentration in the ambient sensor environment.

Abstract: An electronic system for selectively detecting and identifying a plurality of chemical species, which comprises an array of nanostructure sensing devices, is disclosed. Within the array, there are at least two different selectivities for sensing among the nanostructure sensing devices. Methods for fabricating the electronic system are also disclosed. The methods involve modifiying nanostructures within the devices to have different selectivity for sensing chemical species. Modification can involve chemical, electrochemical, and self-limiting point defect reactions. Reactants for these reactions can be supplied using a bath method or a chemical jet method. Methods for using the arrays of nanostructure sensing devices to detect and identify a plurality of chemical species are also provided.

Abstract: Nanostructure sensing devices for detecting an analyte are described. The devices include nanostructures connected to conductive elements, all on a substrate. Contact regions adjacent to points of contact between the nanostructures and the conductive elements are given special treatment. The proportion of nanostructure surface area within contact regions can be maximized to effect sensing at very low analyte concentrations. The contact regions can be passivated in an effort to prevent interaction between the environment and the contact regions for sensing at higher analyte concentrations and for reducing cross-sensing. Both contact regions and at least some portion of the nanostructures can be covered with a material that is at least partially permeable to the analyte of interest and impermeable to some other species to tune selectivity and sensitivity of the nanostructure sensing device.

Abstract: This invention provides for an apparatus and a method for operation of a cryogenic hydrogen storage system that contains a porous medium configured to adsorb hydrogen. The hydrogen storage and supply system includes a hydrogen source apparatus and a cryosorptive storage apparatus. Methods and devices that allow for an energy efficient filling of the cryosorptive apparatus from the hydrogen source apparatus are described. The cryosorptive hydrogen storage apparatus is filled with cold, pressurized hydrogen. During the course of filling, heat is generated in the cryosorptive storage device by the process of hydrogen adsorption on to the host medium. Methods and devices are provided for the removal the generated heat and the warm hydrogen. Further provided are devices and methods for the capture and recycle of escaped hydrogen within the hydrogen source apparatus.

Abstract: Field-effect transistor (FET) devices with carbon nanotubes as the conducting channel detect chemicals in liquids are described. Chemical detection occurs primarily through analysis of conduction (l) as a function of the applied gate voltage (Vg). The conductivity of liquids is an important variable in the analysis of measurements of the device performance. In high-conducting liquids, screening and liquid conductance dominate in the device measurements; in low-conductive liquids (e.g., cyclohexane), the changes in the NTFET device performance upon exposure to different chemicals are similar to those found for the performance of the device in a gaseous environment. The influence of aromatic compounds on the device electronics can be correlated with their relative ability to donate or withdraw electrons from the carbon nanotube. A shift in the threshold of l-Vg was found to be linear with Hammett sigma values (&sgr;p) for mono-substituted benzene compounds.

Abstract: Nanoscale field effect transistor devices with carbon nanotubes as the conducting channel are used to detect protein-protein binding. A coating of an electron-donating polymer is applied to a nanotube device, and a receptor compound is bound to the polymer. The receptor compound is configured to bind a specific biological molecule or molecules. The device coated with the polymer coating and receptor compound may be operated as a p-type field-effect transducer. For example, upon exposure to biological molecules bound by the receptor, the conductance at negative voltage may be markedly reduced, thereby establishing an electronic signal response.

Abstract: A hydrogen storage and supply apparatus is described. The apparatus has a container that includes a cold enclosure. A porous material capable of occluding hydrogen pervades the cold enclosure. The porous material contains a plurality of light elements including Be, B, C, N, O, F, Mg, P, S, Li, Na, Al, Si and Cl. The cold enclosure can have a temperature in a range between about 30K and 270K and can withstand pressures up to about 50 bara. The container can have a layered wall structure with at least two walls, and there can be a cavity between the walls, which can provide thermal insulation. A hydrogen-consuming system is described in which the hydrogen storage and supply apparatus is used to provide hydrogen to a hydrogen-fueled device. A hydrogen production and distribution system, which used the hydrogen storage and supply apparatuses is described. Methods of storing, supplying and using hydrogen are also described.

Abstract: This invention provides for an apparatus and a method for operation of a cryogenic hydrogen storage system that contains a porous medium configured to adsorb hydrogen. The hydrogen storage and supply system includes a hydrogen source apparatus and a cryosorptive storage apparatus. Methods and devices that allow for an energy efficient filling of the cryosorptive apparatus from the hydrogen source apparatus are described. The cryosorptive hydrogen storage apparatus is filled with cold, pressurized hydrogen. During the course of filling, heat is generated in the cryosorptive storage device by the process of hydrogen adsorption on to the host medium. Methods and devices are provided for the removal the generated heat and the warm hydrogen. Further provided are devices and methods for the capture and recycle of escaped hydrogen within the hydrogen source apparatus.

Abstract: The disclosure provided herein describes methods for the detection of conformational changes and/or interactions between biomolecules and molecules which bind to the biomolecules. The method is based on detection of alterations in resistance of a semiconductor nanostructured material coupled to a biomolecule where the resistance is modulated by the conformational state of biomolecules such that a change in the level of resistance so measured provides an indication of a change in the conformation of the biomolecule.

Abstract: Nanostructure sensing devices for detecting an analyte are described. The devices include nanostructures connected to conductive elements, all on a substrate. Contact regions adjacent to points of contact between the nanostructures and the conductive elements are given special treatment. The proportion of nanostructure surface area within contact regions can be maximized to effect sensing at very low analyte concentrations. The contact regions can be passivated in an effort to prevent interaction between the environment and the contact regions for sensing at higher analyte concentrations and for reducing cross-sensing. Both contact regions and at least some portion of the nanostructures can be covered with a material that is at least partially permeable to the analyte of interest and impermeable to some other species to tune selectivity and sensitivity of the nanostructure sensing device.

Abstract: A hydrogen containing nanostructure is provided, where the hydrogen is adsorbed to the nanostructure by physisorption. The nanostructure includes light elements, selected from the second and third rows of the periodic table. The nanostructure is formed as a layered network of light elements coupled with covalent sp2 bonds. The chemical composition of the nanostructure can be such that the desorption temperature of hydrogen is greater than the liquefaction temperature of nitrogen, 77 K. Further, a hydrogen storage system is provided, including a container and a nanostructured storage material within the container, wherein the nanostructured storage material includes light elements, and the nanostructured storage material is capable of adsorbing hydrogen by physisorption. The hydrogen storage system can include a liquid nitrogen based cooling system, capable of cooling the nanostructured storage material below the desorption temperature of hydrogen.

Abstract: A hydrogen storage and supply apparatus is described. The apparatus has a container that includes a cold enclosure. A porous material capable of occluding hydrogen pervades the cold enclosure. The porous material contains a plurality of light elements including Be, B, C, N, O, F, Mg, P, S, Li, Na, Al, Si and Cl. The cold enclosure can have a temperature in a range between about 30K and 270K and can withstand pressures up to about 50 bara. The container can have a layered wall structure with at least two walls, and there can be a cavity between the walls, which can provide thermal insulation. A hydrogen-consuming system is described in which the hydrogen storage and supply apparatus is used to provide hydrogen to a hydrogen-fueled device. A hydrogen production and distribution system, which used the hydrogen storage and supply apparatuses is described. Methods of storing, supplying and using hydrogen are also described.

Abstract: An electronic system for selectively detecting and identifying a plurality of chemical species, which comprises an array of nanostructure sensing devices, is disclosed. Within the array, there are at least two different selectivities for sensing among the nanostructure sensing devices. Methods for fabricating the electronic system are also disclosed. The methods involve modifiying nanostructures within the devices to have different selectivity for sensing chemical species. Modification can involve chemical, electrochemical, and self-limiting point defect reactions. Reactants for these reactions can be supplied using a bath method or a chemical jet method. Methods for using the arrays of nanostructure sensing devices to detect and identify a plurality of chemical species are also provided.