Abstract: Processes for making photosensitive organic pigments for use in imaging members, specifically processes for making a photosensitive phthalocyanine pigments having a specific crystal form, comprising dissolving the pigment in a mixture of a haloacetic acid and alkylene halide to form a solution, precipitating the pigment by adding the solution to a non-solvent system, the solution comprised of one or more organic solvents and a small amount of water, wherein the amount of water controls the crystal form of the pigment, followed by a treatment with a halobenzene to obtain a highly photosensitive second crystal form of the pigment.

Abstract: Processes for making organic pigments useful in imaging members, specifically for pigments that after further polymorphic conversion may be used in a charge generating layer of an imaging member. More specifically, there are described processes for producing titanyl phthalocyanine (TiOPc) in high yields using tetrahydronaphthalene as reaction solvent, such as TiOPc Type I. This pigment can be successfully converted to a high sensitivity crystal form useful as charge generating pigment in an imaging member.

Abstract: Processes for making photosensitive organic pigments for use in imaging members, specifically processes for making a photosensitive phthalocyanine pigments having a specific crystal form, comprising dissolving the pigment in a mixture of a haloacetic acid and alkylene halide to form a solution, precipitating the pigment by adding the solution to a non-solvent system, the solution comprised of one or more organic solvents and a small amount of water, wherein the amount of water controls the crystal form of the pigment, followed by a treatment with a halobenzene to obtain a highly photosensitive second crystal form of the pigment.

Abstract: Processes for making photosensitive organic pigments for use in imaging members, specifically processes for making a photosensitive phthalocyanine pigments having a specific crystal form, comprising dissolving the pigment in a mixture of a haloacetic acid and alkylene halide to form a solution, precipitating the pigment by adding the solution to a non-solvent system, the solution comprised of one or more organic solvents and a small amount of water, wherein the amount of water controls the crystal form of the pigment, followed by a treatment with a halobenzene to obtain a highly photosensitive second crystal form of the pigment.

Abstract: A process for preparing a curable polyester based emulsion is provided in embodiments, containing one or more unsaturated polyesters and one or more photoinitiators obtained by a phase inversion process, in which the particle size and particle size distribution is controlled by process parameters, such as solvent, solvent ratio, neutralization ratio of the resin and temperature.

Abstract: An emulsion polymerization process comprising polymerizing monomer in an emulsion in a reaction vessel at a first temperature to form a resin; cooling the reaction vessel to a second temperature that is above the softening point of the resin yet below the temperature required for significant depolymerization reaction to occur; and adding water to the cooled reaction vessel in an amount sufficient to effect phase inversion with mixing for a sufficient time to form an aqueous latex emulsion in the absence of a surfactant.

Abstract: An imaging member includes a charge generating layer and a charge transport layer. The charge transport layer includes a first surface in contact with the charge generating layer and a second surface. The charge transport layer includes a film forming polymer binder and a charge transport component dispersed therein. The concentration of the charge transport component in the charge transport layer is at a peak in a region of the charge transport intermediate the first and second surfaces of the charge transport layer.

Abstract: A process for preparing a curable polyester based emulsion is provided in embodiments, containing one or more unsaturated polyesters and one or more photoinitiators obtained by a phase inversion process, in which the particle size and particle size distribution is controlled by process parameters, such as solvent, solvent ratio, neutralization ratio of the resin and temperature.

Abstract: Processes for making photosensitive organic pigments for use in imaging members, specifically processes for making a photosensitive phthalocyanine pigments having a specific crystal form, comprising dissolving the pigment in a mixture of a haloacetic acid and alkylene halide to form a solution, precipitating the pigment by adding the solution to a non-solvent system, the solution comprised of one or more organic solvents and a small amount of water, wherein the amount of water controls the crystal form of the pigment, followed by a treatment with a halobenzene to obtain a highly photosensitive second crystal form of the pigment.

Abstract: Processes for making organic pigments useful in imaging members, specifically for pigments that after further polymorphic conversion may be used in a charge generating layer of an imaging member. More specifically, there are described processes for producing titanyl phthalocyanine (TiOPc) in high yields using tetrahydronaphthalene as reaction solvent, such as TiOPc Type I. This pigment can be successfully converted to a high sensitivity crystal form useful as charge generating pigment in an imaging member.

Abstract: A composition comprised of a charge transport compound and a crosslinked polymer composition generated from the curing of a solution of a hydroxyl pendant polycarbonate, a hydroxylated charge transport compound, a curing agent and a solvent.

Abstract: An emulsion polymerization process comprising polymerizing monomer in an emulsion in a reaction vessel at a first temperature to form a resin; cooling the reaction vessel to a second temperature that is above the softening point of the resin yet below the temperature required for significant depolymerization reaction to occur; and adding water to the cooled reaction vessel in an amount sufficient to effect phase inversion with mixing for a sufficient time to form an aqueous latex emulsion in the absence of a surfactant.

Abstract: An imaging member includes a conductive substrate, a SiOx layer coated over the conductive substrate, a charge generating layer coated over the SiOx layer, and a charge transport layer

Abstract: A method of making a multichromal sphere includes the steps of preparing a composition of at least (1) a matrix material and (2) at least two sets of particles, each of the sets of particles having a color different from at least one of another of the sets of particles and a segregation (e.g., an electrical or magnetic) property different from at least one of another of the sets of particles, encapsulating the composition within a shell to form an encapsulated sphere, immobilizing the encapsulated sphere in a manner to restrict at least rotation of the encapsulated sphere, subjecting the immobilized encapsulated sphere to an external field associated with the segregation property different among the sets of particles, under conditions in which the sets of particles are able to migrate within the matrix material, thereby producing color segregation in the immobilized encapsulated sphere, and solidifying the matrix material while substantially maintaining the color segregation.

Abstract: An imaging member includes a charge generating layer and a charge transport layer. The charge transport layer includes a first surface in contact with the charge generating layer and a second surface. The charge transport layer includes a film forming polymer binder and a charge transport component dispersed therein. The concentration of the charge transport component in the charge transport layer is at a peak in a region of the charge transport intermediate the first and second surfaces of the charge transport layer.

Abstract: A toner process comprising the aggregation and coalescence of a sulfonated polyester and a colorant, and wherein said polyester possesses a degree of sulfonation or a sulfonation percentage of from about 0.5 to about 3 mol percent.

Abstract: A toner process comprising the aggregation and coalescence of a sulfonated polyester and a colorant, and wherein said polyester possesses a degree of sulfonation or a sulfonation percentage of from about 0.5 to about 3 mol percent.

Abstract: A method of making a multichromal sphere includes the steps of preparing a composition of at least (1) a matrix material and (2) at least two sets of particles, each of the sets of particles having a color different from at least one of another of the sets of particles and a segregation (e.g., an electrical or magnetic) property different from at least one of another of the sets of particles, encapsulating the composition within a shell to form an encapsulated sphere, immobilizing the encapsulated sphere in a manner to restrict at least rotation of the encapsulated sphere, subjecting the immobilized encapsulated sphere to an external field associated with the segregation property different among the sets of particles, under conditions in which the sets of particles are able to migrate within the matrix material, thereby producing color segregation in the immobilized encapsulated sphere, and solidifying the matrix material while substantially maintaining the color segregation.

Abstract: A process which comprises admixing in the absence of a solvent an amine of the formula R1—NH2 and a first ester of the formula wherein R2 is an electron withdrawing group and R3 is an alkyl group; heating the mixture containing the amine and the first ester to form an intermediate compound of the formula admixing the intermediate compound with a base and a second ester of the formula said second ester being present in a molar excess relative to the intermediate compound, said base being present in a molar excess relative to the intermediate compound, and heating the mixture to form a pyridone compound of the formula or a salt thereof. Also disclosed is a process for preparing diazopyridone colorants which comprises preparing a pyridone compound by the above process and reacting the pyridone compound with a diazonium salt to form a diazopyridone compound.

Abstract: Disclosed is a process for preparing substituted pyridone compounds which comprises (a) admixing in the absence of a solvent (1) an amine of the formula R1—NH2 wherein R1 is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, and (2) a first ester of the formula 1