Patents by Inventor Gerardus Cornelis Overbeek
Gerardus Cornelis Overbeek has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20210332031Abstract: The present invention relates to a multi-aziridine compound having: a) from 2 to 6 of the following structural units (A): (A) whereby R?, R?, R1, R2, R3 and R4 are as defined herein m is an integer from 1 to 6; b) one or more linking chains wherein each one of these linking chains links two of the structural units A; and c) a molecular weight in the range from 600 Daltons to 5000 Daltons. The multi-aziridine compound can be used for example for crosslinking of for example carboxylic acid functional polymers dissolved and/or dispersed in an aqueous medium.Type: ApplicationFiled: July 17, 2019Publication date: October 28, 2021Inventors: Gerardus Cornelis OVERBEEK, Patrick Johannes Maria STALS, Daan VAN DER ZWAAG, Alfred Jean Paul BÜCKMANN
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Publication number: 20210317250Abstract: The present invention is directed to radiation-curable aqueous polyurethane dispersion, wherein the dispersion comprises aniomcally stabilized polyurethane A present in disperse form; and wherein said polyurethane A comprises 5 (meth)acrylamide functional groups in an amount of at least 0.2 mmol per g of the polyurethane A.Type: ApplicationFiled: July 9, 2019Publication date: October 14, 2021Inventors: Ilse VAN DER HOEVEN-VAN CASTEREN, Josephus Christiaan VAN OORSCHOT, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Harmanna HENDERIKS
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Patent number: 11124671Abstract: The present invention relates to a radiation-curable aqueous coating composition comprising a polyurethane A comprising as building blocks at least: (a) a polyisocyanate(s) containing at least one cyclic group, (b) a non-cyclic aliphatic diisocyanate(s) whereby the non-cyclic aliphatic group connecting the two isocyanate groups has 5 carbon atoms, and (c) a component(s) containing an isocyanate-reactive group(s), whereby the summed amount of (a) and (b) is 10 to 60 wt. %, relative to the total weight amount of components used to prepare the polyurethane A; and optionally radiation-curable diluent; whereby the weight ratio between (a) and (b) is in the range from 50:50 to 99:1; and whereby the ethylenically unsaturated bond concentration of the coating composition is in the range from 0.5 to 6 milliequivalents per g of polyurethane A and radiation-curable diluent.Type: GrantFiled: February 7, 2018Date of Patent: September 21, 2021Assignee: COVESTRO (NETHERLANDS) B.V.Inventors: Ilse Van Casteren, Ronald Tennebroek, Gerardus Cornelis Overbeek, Jourraine Celestijn, Jacobus Willem Griffioen
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Patent number: 11098223Abstract: The present invention relates to a radiation-curable aqueous coating composition comprising a polyurethane A comprising as building blocks at least: (a) a polyisocyanate(s) containing at least two cyclic groups, (b) a non-cyclic aliphatic diisocyanate(s) whereby the non-cyclic aliphatic group connecting the two isocyanate groups has from 4 to 36 carbon atoms, and (c) a component(s) containing an isocyanate-reactive group(s), whereby the summed amount of (a) and (b) is 10 to 60 wt. %, relative to the total weight amount of components used to prepare the polyurethane A; and optionally radiation-curable diluent; whereby the weight ratio between (a) and (b) is in the range from 50:50 to 99:1; and whereby the ethylenically unsaturated bond concentration of the coating composition is in the range from 0.5 to 6 milliequivalents per g of polyurethane A and radiation-curable diluent.Type: GrantFiled: February 7, 2018Date of Patent: August 24, 2021Assignee: COVESTRO (NETHERLANDS) B.V.Inventors: Ilse Van Casteren, Ronald Tennebroek, Gerardus Cornelis Overbeek, Jourraine Celestijn
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Patent number: 11001663Abstract: The present invention relates to an aqueous dispersion comprising dispersed particles of an acrylic copolymer having a volume average particle size diameter (d50) of from 1 to 50 ?m (microns), wherein the aqueous dispersion further comprises (i) an acrylic copolymer dispersant having an alkaline solubility higher than 50 wt. %, and being present in the dispersion in an amount of from 10 to 35% by weight, relative to the total amount of monomers used to prepare the acrylic copolymer of the dispersed polymeric particles; and (ii) decomposition products of an oil-soluble organic initiator.Type: GrantFiled: October 17, 2017Date of Patent: May 11, 2021Assignee: DSM IP ASSETS B.V.Inventors: Adrianus Antonius Johannes Van Geel, Franciscus Adrianus Johannes Suykerbuyk, Gerardus Cornelis Overbeek, Jurgen Scheerder
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Publication number: 20210087427Abstract: Aqueous coating compositions include dispersed polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane. The polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, and the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt. % of at least one active-hydrogen chain extending compound with a functionality of at least 2 other than water, (e) from 0 to 10 wt. % of at least one diol having a molecular weight below 500 g/mol.Type: ApplicationFiled: December 1, 2020Publication date: March 25, 2021Inventors: Roel Johannes Marinus SWAANS, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Paul de KOK
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Publication number: 20210079209Abstract: The present invention relates to a waterborne dispersion comprising (A) amphiphilic block copolymer obtained with a controlled radical polymerization process and comprising at least blocks [A] and [B], whereby block [A] comprises ethylenically unsaturated monomer(s) bearing water-soluble and/or water-dispersible functional groups (monomer(s) (i)), and block [B] comprises ethylenically unsaturated monomer(s) different from monomer(s) (i) (monomer(s) (ii)); and (B) polymer P comprising ethylenically unsaturated monomer(s) different from (i) (monomer(s) (ii)), characterized in that the amount of block copolymer is higher than 1 and lower than 30 wt. %, based on the total weight of monomers used to prepare the block copolymer and polymer P; the acid value of the composition consisting of block copolymer and polymer P is higher than 1 and at most 35 mg KOH per g of the block copolymer-polymer P composition; the block copolymer has a calculated glass transition temperature of higher than 10° C.Type: ApplicationFiled: December 18, 2018Publication date: March 18, 2021Inventors: Michael Arnoldus Jacobus SCHELLEKENS, Johannes Hendrikus DE BONT, John BARBOSA, Jon Andrew CRONIN, Charles SHEARER, Matthew Stewart GEBHARD, Gerardus Cornelis OVERBEEK
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Publication number: 20210070977Abstract: The present invention further relates to a waterborne dispersion comprising (A) polymer P; (B) amphiphilic block copolymer obtained with a controlled radical polymerization process and comprising at least blocks [A] and [B], whereby block [A] comprises ethylenically unsaturated monomer(s) bearing water-soluble and/or water-dispersible functional groups (monomer(s) (i)), and block [B] comprises ethylenically unsaturated monomer(s) different from monomer(s) (i) (monomer(s) (ii)); and (C) crosslinker, characterized in that the polymer P is crosslinkable and comprises ethylenically unsaturated monomer(s) bearing crosslinkable functional groups different from monomer(s) (i) and monomer(s) (ii) (monomer(s) (iii)) in an amount of from 1 to 10 wt. %, based on the total weight of monomers used to prepare the polymer P, the amount of lock copolymer is higher than 1 wt. % and lower than 30 wt.Type: ApplicationFiled: December 18, 2018Publication date: March 11, 2021Inventors: Michael Arnoldus Jacobus SCHELLEKENS, Johannes Hendrikus DE BONT, John BARBOSA, Jon Andrew CRONIN, Charles SHEARER, Matthew Stewart GEBHARD, Gerardus Cornelis OVERBEEK
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Patent number: 10883015Abstract: Aqueous coating compositions include dispersed polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane. The polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, and the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt. % of at least one active-hydrogen chain extending compound with a functionality of at least 2 other than water, (e) from 0 to 10 wt. % of at least one diol having a molecular weight below 500 g/mol.Type: GrantFiled: August 15, 2019Date of Patent: January 5, 2021Assignee: DSM IP ASSETS B.V.Inventors: Roel Johannes Marinus Swaans, Ronald Tennebroek, Gerardus Cornelis Overbeek, Paul de Kok
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Publication number: 20200317842Abstract: The present invention relates to an aqueous dispersion comprising dispersed particles of an acrylic copolymer having a volume average particle size diameter (d50) of from 1 to 50 ?m (microns), wherein the aqueous dispersion further comprises (i) an acrylic copolymer dispersant having an alkaline solubility higher than 50 wt. %, and being present in the dispersion in an amount of from 10 to 35% by weight, relative to the total amount of monomers used to prepare the acrylic copolymer of the dispersed polymeric particles; and (ii) decomposition products of an oil-soluble organic initiator.Type: ApplicationFiled: October 17, 2017Publication date: October 8, 2020Inventors: Adrianus Antonius Johannes VAN GEEL, Franciscus Adrianus Johannes SUYKERBUYK, Gerardus Cornelis OVERBEEK, Jurgen SCHEERDER
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Patent number: 10767072Abstract: The current invention relates to a process for preparing an aqueous binder composition free of organic solvent, the process comprising at least the following steps: A) preparing a hydrophilic vinyl polymer (Polymer A) by polymerisation of a monomer composition A that contains: Ai) at least one carboxylic acid functional olefinically unsaturated monomer; and Aii) at least one olefinically unsaturated monomer different than Ai); and Aiii) optionally at least one wet adhesion promoting olefinically unsaturated monomer different than Ai and Aii); where Polymer A has an acid value (AV) from 32 to 98 mg KOH/g of solid Polymer A; B) preparing a hydrophobic vinyl polymer (Polymer B) by emulsion polymerization of a monomer composition B in the presence of Polymer A where the monomer composition B contains: Bi) at least one olefinically unsaturated monomer; Bii) optionally carboxylic acid functional olefinically unsaturated monomer different than Bi); and Biii) optionally wet adhesion promoting olefinically unsaturatedType: GrantFiled: October 21, 2015Date of Patent: September 8, 2020Assignee: DSM IP ASSETS B.V.Inventors: Tijs Nabuurs, Willem-Jan Soer, Gerardus Cornelis Overbeek
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Publication number: 20200239731Abstract: The present invention relates to a radiation-curable aqueous coating composition comprising a polyurethane A comprising as building blocks at least: (a) a polyisocyanate(s) containing at least two cyclic groups, (b) a non-cyclic aliphatic diisocyanate(s) whereby the non-cyclic aliphatic group connecting the two isocyanate groups has from 4 to 36 carbon atoms, and (c) a component(s) containing an isocyanate-reactive group(s), whereby the summed amount of (a) and (b) is 10 to 60 wt. %, relative to the total weight amount of components used to prepare the polyurethane A; and optionally radiation-curable diluent; whereby the weight ratio between (a) and (b) is in the range from 50:50 to 99:1; and whereby the ethylenically unsaturated bond concentration of the coating composition is in the range from 0.5 to 6 milliequivalents per g of polyurethane A and radiation-curable diluent.Type: ApplicationFiled: February 7, 2018Publication date: July 30, 2020Inventors: Ilse VAN CASTEREN, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Jourraine CELESTIJN
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Publication number: 20200207994Abstract: The current invention relates to an one-pack aqueous coating composition comprising dispersed carbonyl functional vinyl polymer(s) particles, characterized in that the coating composition further comprises carbodihydrazide, whereby (i) the equivalent molar ratio of hydrazide groups to carbonyl groups is from 0.1 to 0.95, (ii) the ratio of number-average molecular weight of the carbonyl functional vinyl polymer(s) to acid value of the carbonyl functional vinyl polymer(s) is higher than 400, and (iii) the acid value of the carbonyl functional vinyl polymer(s) is from 2 to 100 mg KOH/gram carbonyl functional vinyl polymer.Type: ApplicationFiled: July 16, 2018Publication date: July 2, 2020Inventors: Gerardus Cornelis OVERBEEK, Alfred Jean Paul BÜCKMANN, Patrick Johannes Maria STALS, Daan VAN DER ZWAAG, Jurgen SCHEERDER, Stella Josette VAN DIJK
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Publication number: 20200095460Abstract: The present invention relates to an aqueous coating composition comprising polyurethane A and vinyl polymer, wherein the polyurethane A comprising as building blocks at least: (a) a polyisocyanate(s) containing at least one cyclic group, (b) a non-cyclic aliphatic diisocyanate(s) whereby the non-cyclic aliphatic group connecting the two isocyanate groups has 5 carbon atoms, and (c) a component(s) containing an isocyanate-reactive group(s), whereby the summed amount of (a) and (b) is 10 to 60 wt. %, relative to the total weight amount of components used to prepare the polyurethane A; and whereby the weight ratio between (a) and (b) is in the range from 50:50 to 99:1.Type: ApplicationFiled: February 7, 2018Publication date: March 26, 2020Inventors: Ilse VAN CASTEREN, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Jourraine CELESTIJN, Jacobus Willem GRIFFIOEN
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Publication number: 20200024474Abstract: The present invention relates to a radiation-curable aqueous coating composition comprising a polyurethane A comprising as building blocks at least: (a) a polyisocyanate(s) containing at least one cyclic group, (b) a non-cyclic aliphatic diisocyanate(s) whereby the non-cyclic aliphatic group connecting the two isocyanate groups has 5 carbon atoms, and (c) a component(s) containing an isocyanate-reactive group(s), whereby the summed amount of (a) and (b) is 10 to 60 wt. %, relative to the total weight amount of components used to prepare the polyurethane A; and optionally radiation-curable diluent; whereby the weight ratio between (a) and (b) is in the range from 50:50 to 99:1; and whereby the ethylenically unsaturated bond concentration of the coating composition is in the range from 0.5 to 6 milliequivalents per g of polyurethane A and radiation-curable diluent.Type: ApplicationFiled: February 7, 2018Publication date: January 23, 2020Inventors: Ilse VAN CASTEREN, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Jourraine CELESTIJN, Jacobus Willem GRIFFIOEN
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Publication number: 20200024473Abstract: The present invention relates to an aqueous coating composition comprising polyurethane A and vinyl polymer, wherein the polyurethane A comprises as building blocks at least: (a) a polyisocyanate(s) containing at least two cyclic groups, (b) a non-cyclic aliphatic diisocyanate(s) whereby the non-cyclic aliphatic group connecting the two isocyanate groups has from 4 to 36 carbon atoms, and (c) a component(s) containing an isocyanate-reactive group(s), whereby the summed amount of (a) and (b) is 10 to 60 wt. %, relative to the total weight amount of components used to prepare the polyurethane A; and whereby the weight ratio between (a) and (b) is in the range from 50:50 to 99:1.Type: ApplicationFiled: February 7, 2018Publication date: January 23, 2020Inventors: Ilse VAN CASTEREN, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Jourraine CELESTIJN
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Publication number: 20190367772Abstract: The present invention relates to an aqueous coating composition comprising dispersed polymer particles, wherein (i) the dispersed polymer particles are polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane, (ii) the polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, (iii) the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt.Type: ApplicationFiled: August 15, 2019Publication date: December 5, 2019Inventors: Roel Johannes Marinus SWAANS, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Paul de KOK
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Publication number: 20190367644Abstract: The present invention relates to an aqueous emulsion comprising at least 30 wt. % of vinyl copolymer(s) (A), said vinyl copolymer(s) (A) containing the following monomers: (I) isobornyl methacrylate and 2-octyl acrylate in a summed amount of at least 30 wt. %, in a weight ratio of isobornyl methacrylate to 2-octyl acrylate from 5:95 to 95:5; (II) no more than 70 wt. % of at least one ethylenically unsaturated monomer other than 2-octyl acrylate and isobornyl methacrylate, whereby the summed amount of (I) and (II) is 100 wt. % and whereby the amount of vinyl copolymer(s) (A) is given relative to the total weight amount of binder present in the emulsion.Type: ApplicationFiled: July 3, 2017Publication date: December 5, 2019Inventors: Tijs NABUURS, Maud KASTELIJN, Johannes Hendrikus DE BONT, Gerardus Cornelis OVERBEEK, Saskia Carolien VAN DER SLOT, Ronald TENNEBROEK, Addy MOLHOEK
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Patent number: 10457763Abstract: The present invention relates to an aqueous polymer emulsion comprising at least 30 wt. % of a vinyl copolymer (A), said vinyl copolymer comprising: (I) from 10 to 90 wt. % of 2-octyl acrylate monomer; (II) from 10 to 90 wt. % of at least one itaconate ester monomer according to formula (1) in which A and B may be different or the same and A and B are independently an alkyl group or an aryl group; and (III) from 0 to 80 wt. % of ethylenically unsaturated monomer other than (I) and (II); whereby the summed amount of (I), (II) and (III) is 100 wt. % and whereby the amount of vinyl copolymer (A) is given relative to the total weight amount of the polymers present in the emulsion.Type: GrantFiled: February 12, 2016Date of Patent: October 29, 2019Assignee: DSM IP ASSETS B.V.Inventors: Tijs Nabuurs, Jeffrey Stubbs, Johannes Hendrikus De Bont, Gerardus Cornelis Overbeek
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Patent number: 10428237Abstract: The present invention relates to an aqueous coating composition comprising dispersed polymer particles, wherein (i) the dispersed polymer particles are polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane, (ii) the polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, (iii) the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt.Type: GrantFiled: December 22, 2015Date of Patent: October 1, 2019Assignee: DSM IP ASSETS B.V.Inventors: Roel Johannes Marinus Swaans, Ronald Tennebroek, Gerardus Cornelis Overbeek, Paul De Kok