Patents by Inventor Grant B. Jacobsen

Grant B. Jacobsen has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20100292407
    Abstract: Disclosed is a novel ethylene copolymer by copolymerizing an ethylene and at least one comonomer selected from a compound represented by the formula H2C?CHR wherein R is, for example, an alkyl group or an aryl group, and a diene, by slurry polymerization process in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex.
    Type: Application
    Filed: March 16, 2010
    Publication date: November 18, 2010
    Applicant: Dow Global Technologies Inc.
    Inventors: Grant B. Jacobsen, Jozef J. Van Dun, Pak-Wing S. Chum, Larry A. Meiske, Fumio Matsushita, Akira Miyamoto
  • Patent number: 7714073
    Abstract: The invention provides blends comprising an ethylene copolymer formed from ethylene with at least one comonomer selected from (a) the group comprising compounds represented by the formula H2C?CHR wherein R represents a C1-C20 linear, branched or cyclic alkyl group or a C6-C20 aryl group, and (b) a C4-C20 linear, branched or cyclic diene. Each copolymer has a specific density, a specific molecular weight distribution, and a specific comonomer content distribution characteristic.
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: May 11, 2010
    Inventors: Grant B. Jacobsen, Jozef J. Van Dun, Pak-Wing S. Chum, Larry A. Meiske, Fumio Matsushita, Akira Miyamoto
  • Patent number: 7678726
    Abstract: A supported polymerization catalyst system is prepared by a method comprising the following steps: (i) addition of a cocatalyst to a porous support, (ii) mixing a polymerisation catalyst with a polymerisable monomer, and (iii) contacting together the components resulting from steps (i) and (ii). The porous support is preferably silica and the polymerisation catalyst is preferably a metallocene. The polymerisable monomer is typically 1-hexene and the supported catalyst system provides advantages a slowly decaying activity profile particularly when operating in the gas phase.
    Type: Grant
    Filed: August 4, 2004
    Date of Patent: March 16, 2010
    Assignee: Innovene Europe Limited
    Inventors: Grant B. Jacobsen, Brian S. Kimberley, Sergio Mastroianni
  • Patent number: 7645835
    Abstract: Blend compositions containing a novel homopolymer, the use of which allows the incorporation of more comonomer in the additional components of the blend (for the same overall density) resulting in increased tie molecule formation and improvement in properties such as ESCR, toughness and impact strength are disclosed. The homopolymers are important for applications where a high density is needed to ensure certain mechanical properties like abrasion resistance, indentation resistance, pressure resistance, topload resistance, modulus of elasticity, or morphology (for the chlorination of PE to CPE) and additional advantages such as melt processability. The blend can be obtained by dry or melt mixing the already produced components, or through in-situ production by in parallel and/or in series arranged reactors. These resins can be used in applications such as films, blow molded, injection molded, and rotomolded articles, fibers, and cable and wire coatings and jacketings and, various forms of pipe.
    Type: Grant
    Filed: June 21, 2006
    Date of Patent: January 12, 2010
    Assignee: Dow Global Technologies, Inc.
    Inventors: Jozef J. Van Dun, Akira Miyamoto, Grant B. Jacobsen, Fumio Matsushita, Patrick J. Schouterden, Lee Spencer, Pak-Wing S. Chum, Larry A. Meiske, Peter L. Wauteraerts
  • Patent number: 7521518
    Abstract: Disclosed is a novel ethylene copolymer by copolymerizing an ethylene and at least one comonomer selected from a compound represented by the formula H2C?CHR wherein R is an alkyl group or an aryl group, and a diene, by slurry polymerization process in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex.
    Type: Grant
    Filed: January 13, 2003
    Date of Patent: April 21, 2009
    Assignee: Dow Global Technologies, Inc.
    Inventors: Grant B. Jacobsen, Fumio Matsushita, Lee Spencer, Peter L. Wauteraerts
  • Patent number: 7166676
    Abstract: A process for the preparation of blends including an ethylene copolymer by copolymerizing ethylene and at least one comonomer selected from a compound represented by the formula H2C?CHR wherein R is an alkyl group or an aryl group, and a diene, in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex.
    Type: Grant
    Filed: June 7, 2002
    Date of Patent: January 23, 2007
    Assignee: Dow Global Technologies, Inc.
    Inventors: Grant B. Jacobsen, Jozef J. Van Dun, Pak-Wing S. Chum, Larry A. Meiske, Fumio Matsushita, Akira Miyamoto
  • Patent number: 7153909
    Abstract: Blend compositions containing a novel homopolymer, the use of which allows the incorporation of more comonomer in the additional components of the blend (for the same overall density) resulting in increased tie molecule formation and improvement in properties such as ESCR, toughness and impact strength are disclosed. The homopolymers are important for applications where a high density is needed to ensure certain mechanical properties like abrasion resistance, indentation resistance, pressure resistance, topload resistance, modulus of elasticity, or morphology (for the chlorination of PE to CPE) and additional advantages such as melt processability. The blend can be obtained by dry or melt mixing the already produced components, or through in-situ production by in parallel and/or in series arranged reactors. These resins can be used in applications such as films, blow molded, injection molded, and rotomolded articles, fibres, and cable and wire coatings and jacketings and, various forms of pipe.
    Type: Grant
    Filed: June 13, 2002
    Date of Patent: December 26, 2006
    Assignee: Dow Global Technologies Inc.
    Inventors: Jozef J. Van Dun, Akira Miyamoto, Grant B. Jacobsen, Fumio Matsushita, Patrick J. Schouterden, Lee Spencer, Pak-Wing S. Chum, Larry A. Meiski, Peter L. Wauteraerts
  • Patent number: 7094901
    Abstract: A cocatalyst or cocatalyst component, including a compound corresponding to the formula: (A*+a)b(Z*J*j)?cd, wherein: A* is a cation of from 1 to 80 atoms, not counting hydrogen atoms, Z* is an anion group of from 1 to 50 atoms, not counting hydrogen atoms, containing two or more Lewis base sites; J* is a Lewis acid of from 1 to 80, not counting hydrogen atoms, coordinated to at least one Lewis base site, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d, and provided further that one or more of A*, Z* or J* comprises a hydroxyl group or a polar group containing quiescent reactive functionality.
    Type: Grant
    Filed: June 24, 2004
    Date of Patent: August 22, 2006
    Assignee: Dow Global Michigan Technologies Inc.
    Inventors: David A. Babb, David R. Neithamer, Richard E. Campbell, Jr., Grant B. Jacobsen, Edmund M. Carnahan
  • Publication number: 20040077491
    Abstract: A cocatalyst or cocatalyst component, including a compound corresponding to the formula: (A*+a)b(Z*J*j)−cd, wherein: A* is a cation of from 1 to 80 atoms, not counting hydrogen atoms, Z* is an anion group of from 1 to 50 atoms, not counting hydrogen atoms, containing two or more Lewis base sites; J* is a Lewis acid of from 1 to 80, not counting hydrogen atoms, coordinated to at least one Lewis base site, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d, and provided further that one or more of A*, Z* or J* comprises a hydroxyl group or a polar group containing quiescent reactive functionality.
    Type: Application
    Filed: June 18, 2003
    Publication date: April 22, 2004
    Applicant: The Dow Chemical Company
    Inventors: David A. Babb, David R. Neithamer, Richard E. Campbell, Grant B. Jacobsen, Edmund M. Carnahan
  • Patent number: 6716786
    Abstract: A composition useful as an addition polymerization catalyst comprising: A) an inert support; B) a Group 3-10 or Lanthanide metal complex; and C) an activator compound capable of causing the metal complex B) to form an active polymerization catalyst, said compound corresponding to the formula: (A*+a)b(Z*J*j)−cd,  (I)  wherein: A* is a cation of charge +a, Z* is an anion group of from 1 to 50, preferably 1 to 30 atoms, not counting hydrogen atoms, further containing two or more Lewis base sites; J* independently each occurrence is a Lewis acid coordinated to at least one Lewis base-site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is a number from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d.
    Type: Grant
    Filed: August 3, 2000
    Date of Patent: April 6, 2004
    Assignee: The Dow Chemical Company
    Inventors: Richard E. Campbell, Jr., Grant B. Jacobsen, David D. Devore, Robert E. LaPointe, David R. Neithamer
  • Patent number: 6696379
    Abstract: A supported catalyst composition comprising: A1) a mixture of aluminum containing Lewis acids of the formulas: [(—AlQ1—O—)z(—AlArf—O—)z′] and (Arfz″Al2Q16−z″)  where; Q1 independently each occurrence is C1-20 alkyl; Arf is a fluorinated aromatic hydrocarbyl moiety of from 6 to 30 carbon atoms; z is a number from 1 to 50; z′ is a number from 1 to 50; and z″ is an number from 0 to 6; or A2) a fluorohydrocarbyl-substituted alumoxane compound corresponding to the formula: R1—(AlR3O)m—R2,  wherein: R1 and R2 independently each occurrence is a C1-40 aliphatic or aromatic group or a fluorinated derivative thereof or R1 and R2 together form a covalent bond; R3 independently each occurrence is a monovalent, fluorinated organic group containing from 1 to 100 carbon atoms or R1, with the proviso that in at least one occurrence per molecule, R3 is a monovalent, fluorinated organic group containing from 1
    Type: Grant
    Filed: February 11, 2000
    Date of Patent: February 24, 2004
    Assignee: The Dow Chemical Company
    Inventors: Edmund M. Carnahan, Grant B. Jacobsen, Eugene Y. Chen, James C. Stevens
  • Patent number: 6627573
    Abstract: A compound useful as a cocatalyst or cocatalyst component, especially for use as an addition polymerization catalyst compound, corresponding to the formula: (A*+a)b(Z*J*j)−cd, wherein: A* is a cation of from 1 to 80, preferably 1 to 60 atoms, not counting hydrogen atoms, said A* having a charge +a, Z* is an anion group of from 1 to 50, preferably 1 to 30 atoms, not counting hydrogen atoms, further containing two or more Lewis base sites; J* independently each occurrence is a Lewis acid of from 1 to 80, preferably 1 to 60 atoms, not counting hydrogen atoms, coordinated to at least one Lewis base site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is a number from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d, and provided further that one or more of A*, Z* or J* comprises a hydroxyl group or a polar group containing quiescent reactive functionali
    Type: Grant
    Filed: July 12, 2001
    Date of Patent: September 30, 2003
    Assignee: The Dow Chemical Company
    Inventors: David A. Babb, Richard E. Campbell, Jr., David R. Neithamer, Grant B. Jacobsen, Edmund M. Carnahan
  • Publication number: 20030120013
    Abstract: Disclosed is a novel ethylene copolymer by copolymerizing an ethylene and at least one comonomer selected from a compound represented by the formula H2C═CHR wherein R is an alkyl group or an aryl group, and a diene, by slurry polymerization process in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex.
    Type: Application
    Filed: January 13, 2003
    Publication date: June 26, 2003
    Applicant: Dow Global Technologies, Inc.
    Inventors: Grant B. Jacobsen, Fumio Matsushita, Lee Spencer, Peter L. Wauteraerts
  • Publication number: 20030088021
    Abstract: Blend compositions containing a novel homopolymer, the use of which allows the incorporation of more comonomer in the additional components of the blend (for the same overall density) resulting in increased tie molecule formation and improvement in properties such as ESCR, toughness and impact strength are disclosed. The homopolymers are important for applications where a high density is needed to ensure certain mechanical properties like abrasion resistance, indentation resistance, pressure resistance, topload resistance, modulus of elasticity, or morphology (for the chlorination of PE to CPE) and additional advantages such as melt processability. The blend can be obtained by dry or melt mixing the already produced components, or through in-situ production by in parallel and/or in series arranged reactors. These resins can be used in applications such as films, blow molded, injection molded, and rotomolded articles, fibres, and cable and wire coatings and jacketings and, various forms of pipe.
    Type: Application
    Filed: June 13, 2002
    Publication date: May 8, 2003
    Applicant: The Dow Chemical Company
    Inventors: Jozef J. Van Dun, Akira Miyamoto, Grant B. Jacobsen, Fumio Matsushita, Schouterden J. Patrick, Spencer Lee, Pak-Wing S. Chum, Larry A. Meiske, Wauteraerts L. Peter
  • Publication number: 20030055176
    Abstract: A process for the preparation of blends including an ethylene copolymer by copolymerizing ethylene and at least one comonomer selected from a compound represented by the formula H2C═CHR wherein R is an alkyl group or an aryl group, and a diene, in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound.
    Type: Application
    Filed: June 7, 2002
    Publication date: March 20, 2003
    Inventors: Grant B. Jacobsen, Jozef J. Van Dun, Pak-Wing S. Chum, Larry A. Meiske, Fumio Matsushita, Akira Miyamoto
  • Patent number: 6506866
    Abstract: Disclosed is a novel ethylene copolymer by copolymerizing an ethylene and at least one comonomer selected from a compound represented by the formula H2C═CHR wherein R is an alkyl group or an aryl group, and a diene, by slurry polymerization process in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex. The produced copolymer has a density of from 0.870 to 0.
    Type: Grant
    Filed: May 16, 1997
    Date of Patent: January 14, 2003
    Assignee: Dow Global Technologies Inc.
    Inventors: Grant B. Jacobsen, Fumio Matsushita, Lee Spencer, Peter L. Wauteraerts
  • Publication number: 20020169262
    Abstract: Functionalized catalyst supports useful in formation of supported catalyst systems for the polymerization of olefins are disclosed. Methods for preparing functionalized catalyst supports and supported catalyst compositions therefrom as well as polymerization processes utilizing such supported catalysts are also disclosed. The functionalized catalyst support comprises a particulated support material having chemically bonded thereto a plurality of non-ionic, Lewis acid, aluminum-containing groups containing at least one fluoro-substituted hydrocarbyl ligand containing from 1 to 20 carbons bonded to the aluminum, said support being capable of activating a Group 3-10 metal complex for the addition polymerization of one or more addition polymerizable monomers.
    Type: Application
    Filed: June 27, 2002
    Publication date: November 14, 2002
    Applicant: The Dow Chemical Company
    Inventors: Edmund M. Carnahan, Grant B. Jacobsen
  • Patent number: 6475945
    Abstract: The present invention relates to functionalized catalyst supports that are useful in the formation of supported polymerization catalysts, supported catalysts derived from such functionalized catalyst supports, methods for preparing such functionalized catalyst supports and supported catalysts, and polymerization processes utilizing such supported catalysts. The functionalized catalyst support comprises a particulated support material having chemically bonded thereto a plurality of aluminum-containing groups derived from a non-ionic Lewis acid, said aluminum-containing groups: containing at least one fluoro-substituted hydrocarbyl ligand containing from 1 to 20 carbons, said hydrocarbyl ligand being bonded to aluminum, and being bonded to said support material, optionally through a bridging moiety, said composition being capable of activating a Group 3-10 metal complex for the addition polymerization of one or more addition polymerizable monomers.
    Type: Grant
    Filed: May 18, 2000
    Date of Patent: November 5, 2002
    Assignee: The Dow Chemical Company
    Inventors: Edmund M. Carnahan, Grant B. Jacobsen
  • Publication number: 20020072577
    Abstract: The present invention relates to supported catalyst composition for an addition polymerization, a process to prepare the same and the use thereof in an addition polymerization, wherein the composition comprises: (A) a particulated, solid support material; (B) an activator which is an ammonium salt of a compatible, noncoordinating anion, A−, said anion, A− containing a remnant formed by reaction of a non-ionic Lewis acid and a moiety containing an active hydrogen; and (C) a Group 4 metal complex catalyst.
    Type: Application
    Filed: October 1, 2001
    Publication date: June 13, 2002
    Applicant: The Dow Chemical Company
    Inventors: Grant B. Jacobsen, Marc A. Springs, Lawrence D. Wilson
  • Publication number: 20020032120
    Abstract: A compound useful as a cocatalyst or cocatalyst component, especially for use as an addition polymerization catalyst compound, corresponding to the formula:
    Type: Application
    Filed: July 12, 2001
    Publication date: March 14, 2002
    Inventors: David A. Babb, Richard E. Campbell, David R. Neithamer, Grant B. Jacobsen, Edmund M. Carnahan