Patents by Inventor Grant B. Jacobsen

Grant B. Jacobsen has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6344529
    Abstract: Disclosed are compounds useful as catalyst activators for olefin polymerization, comprising structures of the following formulae: wherein: L+ is a protonated derivative of an element of Group 15 of the Periodic Table of the Elements, additionally bearing two hydrocarbyl substituents of from 1 to 50 carbons each, or a positively charged derivative of an element of Group 14 of the Periodic Table of the Elements, said Group 14 element being substituted with three hydrocarbyl substituents of from 1 to 50 carbons each; R1 is a divalent linking group of from 1 to 40 non-hydrogen atoms; R2 independently each occurrence is a ligand group of from 1 to 50 nonhydrogen atoms with the proviso that in a sufficient number of occurrences to balance charge in the compound, R2 is L+—R1—; M1 is boron, aluminum or gallium; Arf independently each occurrence is a monovalent, fluorinated organic group containing from 6 to 100 non-hydrogen atoms; Y is a Group 15 element; and Z is a Grou
    Type: Grant
    Filed: December 6, 1999
    Date of Patent: February 5, 2002
    Assignee: The Dow Chemical Company
    Inventors: Edmund M. Carnahan, Grant B. Jacobsen, Jerzy Klosin, Peter N. Nickias, David J. Schwartz, David R. Neithamer
  • Publication number: 20010039320
    Abstract: Disclosed is a novel ethylene copolymer by copolymerizing an ethylene and at least one comonomer selected from a compound represented by the formula H2C═CHR wherein R is an alkyl group or an aryl group, and a diene, by slurry polymerization process in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex. The produced copolymer has a density of from 0.870 to 0.
    Type: Application
    Filed: May 16, 1997
    Publication date: November 8, 2001
    Inventors: GRANT B. JACOBSEN, FUMIO MATSUSHITA, LEE SPENCER, PETER L. WAUTERAERTS
  • Patent number: 6271165
    Abstract: This invention relates to supported and nonsupported catalyst components comprising (a) an ionic compound comprising (a)(1) a cation and (a)(2) an anion having up to 100 nonhydrogen atoms and the anion containing at least one subtituent comprising a moiety having an active hydrogen reacted with (c) an organometal or metalloid compound wherein the metal or metalloid is selected from Groups 2, 12, 13, or 14 of the Periodic Table of the Elements, and, optionally, (b) a transition metal compound, (d) a support material, and/or a diluent. Included are methods for preparation of the catalyst components, catalysts, reaction products and dispersions thereof, as well as polymerization process using the catalyst.
    Type: Grant
    Filed: June 21, 1999
    Date of Patent: August 7, 2001
    Assignee: The Dow Chemical Company
    Inventors: Grant B. Jacobsen, Pierre H. H. Loix, Theo J. P. Stevens
  • Patent number: 6043180
    Abstract: A supported catalyst component prepared from a support material and an alumoxane, containing 15-40 weight percent of aluminum from the alumoxane (based on the total weight of the support material and alumoxane), said supported catalyst component being obtained by heating said support material and alumoxane under an inert atmosphere at a temperature of from about 85 to about 250.degree. C. for a period sufficient to fix said alumoxane to the support material, to provide a supported catalyst component; wherein not more than about 10 percent aluminum from said alumoxane and present in the supported catalyst component is extractable in a one-hour extraction with toluene at 90.degree. C. using 10 ml toluene per gram of supported catalyst component; and a transition metal compound, and a process for the preparation of the supported catalyst.
    Type: Grant
    Filed: August 11, 1997
    Date of Patent: March 28, 2000
    Assignee: The Dow Chemical Company
    Inventors: Grant B. Jacobsen, Peter L. Wauteraerts, Lee Spencer
  • Patent number: 5783512
    Abstract: A non-supported solid catalyst comprising (a) an ionic compound comprising a.1) a cation and a.2) an anion having up to 100 nonhydrogen atoms and said anion containing at least one substituent comprising an active hydrogen moiety, (b) a transition metal compound, and (c) an organometal compound wherein the metal is selected from the Groups 1-14 of the Periodic Table of the Elements; a supported solid catalyst comprising (a), (b), (c), and (d) a support material, obtainable by combining components (a), (b), (c), and (d) in any order, and wherein during at least one step in the preparation of the solid catalyst, component (a) dissolved in a diluent in which (a) is soluble, is converted into solid form; a method for preparing the solid catalysts; and a process of polymerization using these solid catalysts.
    Type: Grant
    Filed: December 18, 1996
    Date of Patent: July 21, 1998
    Assignee: The Dow Chemical Company
    Inventors: Grant B. Jacobsen, Theo J. P. Stevens, Pierre H. H. Loix
  • Patent number: 5254782
    Abstract: Continuous process for the telomerization of conjugated dienes comprising reacting a conjugated diene with a compound containing an active hydrogen atom in the liquid phase in the presence of a Group VIII transition metal catalyst, a ligand compound of a tertiary phosphorous, arsenic or antimony, and a catalyst promoter compound having basic properties.
    Type: Grant
    Filed: August 16, 1991
    Date of Patent: October 19, 1993
    Assignee: The Dow Chemical Company
    Inventors: Barend J. Schaart, Hendrik L. Pelt, Grant B. Jacobsen