Patents by Inventor Grigorios Kolios
Grigorios Kolios has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20260199973Abstract: The present invention relates to the use of a tube furnace in a sintering and/or debinding process, wherein the tube furnace comprises a tube (T) comprising an oxide ceramic matrix composite (OCMC). In addition, the present invention relates to a tube furnace for the use in a sintering and/or debinding process, wherein the tube furnace comprises a tube (T) comprising an oxide ceramic matrix composite (OCMC). Moreover, the present invention relates to the use of the inventive tube furnace in a process for the treatment of at least one three-dimensional green body (GB).Type: ApplicationFiled: November 30, 2023Publication date: July 16, 2026Inventors: Tobias ROEDLMEIER, Grigorios KOLIOS
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Patent number: 12590379Abstract: An integrated process contains the following steps of: (i) pyrolysis of hydrocarbons to carbon and hydrogen, (iia) removal of at least a part of the produced carbon in step (i) and at least partly further processing of said carbon into a carbon containing electrode, and (iib) removal of the hydrogen produced in step (i) and at least partly using said hydrogen for providing energy, preferably electric energy or heat, for the electrode production in step (iia). A joint plant is also useful, which contains (a) at least one reactor for a pyrolysis process, (b) at least one reactor for the production of electrodes for an aluminum process, (c) a power plant and/or at least one gas-fired burner, and optionally, (d) at least one reactor for the electrolysis for producing aluminum.Type: GrantFiled: May 28, 2020Date of Patent: March 31, 2026Assignees: BASF SE, thyssenkrupp AG, thyssenkrupp Uhde GmbHInventors: Frederik Scheiff, Marc Leduc, Grigorios Kolios, William Daloz, Karsten Bueker, Nicolai Antweiler, Andreas Bode
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Patent number: 12491485Abstract: A reactor for carrying out an endothermic reaction, in particular a high-temperature reaction, in which a product gas is obtained from a feed gas, wherein: the reactor surrounds a reactor interior; the reactor is configured to provide a reactor bed in a reaction zone of the reactor interior, which reactor bed comprises a large number of solid material particles; the reactor is also configured to guide the feed gas into the reaction zone; in order to heat the feed gas, the reactor is designed to heat the solid material particles in the reaction zone such that, by transferring heat from the solid material particles to the feed gas, the feed gas in the reaction zone can be heated to a reaction temperature in order to participate as a starting product in the endothermic reaction for producing the product gas.Type: GrantFiled: March 31, 2020Date of Patent: December 9, 2025Assignees: BASF SE, thyssenkrupp AG, thyssenkrupp Uhde GmbHInventors: Hans-Jörg Zander, Markus Weikl, Andreas Bode, Dirk Klingler, Matthias Kern, Grigorios Kolios, Achim Wechsung, Frederik Scheiff, Dieter Flick, Nicolai Antweiler, Karsten Büker
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Publication number: 20250313465Abstract: The present invention relates to processes for recovering H2 from converting NH3 in an apparatus, the processes comprising one or more process stages, and an apparatus for these processes.Type: ApplicationFiled: May 24, 2023Publication date: October 9, 2025Inventors: Emiel Jan KAPPERT, Bastian OPITZ, Juergen Jose VARGAS SCHMITZ, Grigorios KOLIOS, David SCHLERETH
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Patent number: 12334741Abstract: A method of continuously performing one or more heat-consuming processes, where at least one heat-consuming process is electrically heated. The maximum temperature in the reaction zone of the heat-consuming process is higher than 500° C., at least 70% of products of the heat-consuming process are continuously processed further downstream and/or fed to a local energy carrier network, and the electrical energy required for the heat-consuming process is drawn from an external power grid and from at least one local power source. The local power source is fed by at least one local energy carrier network and by products from the heat-consuming process. The local energy carrier network stores natural gas, naphtha, hydrogen, synthesis gas, and/or steam as energy carrier, and has a total capacity of at least 5 GWh. The local energy carrier network is fed with at least one further product and/or by-product from at least one further chemical process.Type: GrantFiled: May 28, 2020Date of Patent: June 17, 2025Assignees: BASF SE, thyssenkrupp AG, thyssenkrupp Uhde GmbHInventors: Frederik Scheiff, Grigorios Kolios, Andreas Bode
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Publication number: 20250187918Abstract: The invention relates to a method for the production of nitric oxide from a gaseous reactant mixture containing oxygen and nitrogen in a reactor comprising a reaction zone (1) with a heat input device (2) and at least two regenerator zones (3, 4, 5, 6), each regenerator zone having a low temperature section on one end and a high temperature section at the other end of the regenerator zone, the high temperature sections being fluidically connected to the reaction zone (1), the method comprising the steps of: e) supplying heat through the heat input device (2) to the reaction zone (1) until a temperature of from 1500° C. to 2500° C.Type: ApplicationFiled: March 14, 2023Publication date: June 12, 2025Inventors: Kai Rainer EHRHARDT, Grigorios KOLIOS, Sven TITLBACH, Matthias Martin SENTKO
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Publication number: 20240391765Abstract: The present invention provides a process of producing hydrogen comprising introducing methane and/or other light hydrocarbons into a reaction chamber and reacting said gases in said reaction chamber in a bed of solid carbonaceous materials to give hydrogen, wherein said carbonaceous materials are macro-structured carbonaceous materials, wherein the porosity of the carbonaceous material is in the range of 30 to 70 vol.-% and the carbonaceous material contains a content of carbon of 99 wt.-% to 100 wt.-% and a content of alkaline-earth metals, transition metals and metalloids of 0 and 1 wt.-% in relation to the total mass of the solid carbonaceous material, wherein the iron content is between 0 and 0.5 wt.-%, the magnesium content is between 0 and 0.005 wt.-%, the manganese content is between 0 and 0.01 wt.-%, the silicon content is between 0 and 0.01 wt.-% and the nickel content is between 0 and 0.025 wt.-%.Type: ApplicationFiled: September 26, 2022Publication date: November 28, 2024Inventors: Grigorios KOLIOS, Andreas BODE, Johannes BODE, Laila Raquel PASIN E MATOS, Michael REITZ, Frederik SCHEIFF, David SCHLERETH
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Patent number: 11904290Abstract: An apparatus contains at least one pressure-rated apparatus shell and at least one modular framework system containing ceramic fiber composite materials and arranged within the apparatus shell. A modular lining apparatus includes the modular framework system and refractory bricks. The apparatus can be used for high-temperature reactors, especially electrically heated high-temperature reactors.Type: GrantFiled: August 5, 2019Date of Patent: February 20, 2024Assignee: BASF SEInventors: Grigorios Kolios, Bernd Zoels, Hagen Appel, Jens Bernnat, Friedrich Glenk, Dieter Flick, Gerhard Olbert, Frederik Scheiff, Christopher Alec Anderlohr
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Patent number: 11882629Abstract: The present invention relates to an electrically heatable packed pressure-bearing apparatus for conducting endothermic reactions having an upper (3), middle (1) and lower (3) apparatus section, where at least one pair of electrodes (4, 5) in a vertical arrangement is installed in the middle section (1) and all electrodes are disposed in an electrically conductive solid-state packing (26), the upper and lower apparatus sections have a specific conductivity of 105 S/m to 108 S/m, and the middle apparatus section is electrically insulated against the solid-state packing, wherein the upper and lower apparatus sections are electrically insulated from the middle apparatus section, the upper electrode is connected via the upper apparatus section and the lower electrodes via the lower apparatus section or the electrodes are each connected via one or more connecting elements (10, 16) that are in electrical contact with these sections and the ratio of the cross-sectional areas of the upper and lower electrode to the crType: GrantFiled: January 22, 2019Date of Patent: January 23, 2024Assignee: BASF SEInventors: Hagen Appel, Jens Bernnat, Friedrich Glenk, Grigorios Kolios, Gerhard Olbert, Frederik Scheiff, Bernd Zoels, Matthias Kern, Dieter Flick, Christopher Alec Anderlohr, Dirk Klingler, Achim Wechsung
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Patent number: 11691115Abstract: The present invention relates to a process for conducting endothermic gas phase or gas-solid reactions, wherein the endothermic reaction is conducted in a production phase in a first reactor zone, the production zone, which is at least partly filled with solid particles, where the solid particles are in the form of a fixed bed, of a moving bed and in sections/or in the form of a fluidized bed, and the product-containing gas stream is drawn off from the production zone in the region of the highest temperature level plus/minus 200 K and the product-containing gas stream is guided through a second reactor zone, the heat recycling zone, which at least partly comprises a fixed bed, where the heat from the product-containing gas stream is stored in the fixed bed, and, in the subsequent purge step, a purge gas is guided through the production zone and the heat recycling zone in the same flow direction, and, in a heating zone disposed between the production zone and the heat recycling zone, the heat required for theType: GrantFiled: October 26, 2017Date of Patent: July 4, 2023Assignee: BASF SEInventors: Grigorios Kolios, Bernd Zoels, Matthias Kern, Jens Bernnat, Rene Koenig, Friedrich Glenk, Achim Wechsung
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Publication number: 20230010059Abstract: A process can be used for performing a pyrolysis of hydrocarbons in a rotary drum reactor at a temperature in the range of from 600 to 1800° C. The heat for the endothermic pyrolysis is provided by resistive heating of at least one particulate electrically conductive material introduced into said rotary drum reactor and moved through the rotary drum reactor with a flow of a hydrocarbon. The rotary drum reactor contains (A) an inner wall made of electrically insulated material, (B) a pressure-bearing outer wall, and (C) an electrical heating system attached to the inner wall and/or at least one integrated electrically conducting electrode pair. The at least one electrode pair is located at both ends of the inner wall of the rotary drum.Type: ApplicationFiled: November 30, 2020Publication date: January 12, 2023Applicant: BASF SEInventors: Frederik SCHEIFF, Dieter Flick, Lothar Seidemann, Jens Bernnat, Grigorios Kolios
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Publication number: 20220387954Abstract: A method can be used for operating a descending moving bed reactor with flowable granular material. The method involves: (i) filling an upper lock-hopper with granular material and/or emptying a lower lock-hopper, (ii) purging the lock-hoppers with purging gas, and (iii) filling the reaction chamber containing a descending moving bed from the upper lock-hopper and/or emptying the reaction chamber into the lower lock-hopper. The pressure equalization between the reaction chamber and lock-hopper is achieved with product gas. The method then involves: (iv) optionally, relieving the lock-hoppers and conveying the product gas flow into the product line, and (v) purging the lock-hoppers with purging gas.Type: ApplicationFiled: October 20, 2020Publication date: December 8, 2022Applicants: BASF SE, thyssenkrupp AG, thyssenkrupp Industrial Solutions AGInventors: Grigorios Kolios, Frederik Scheiff, Christopher Alec Anderlohr, Hagen Appel, Gerhard Olbert, Bernd Zoels, Dieter Flick, Achim Wechsung, Matthias Kern, Karsten Bueker, Nicolai Antweiler
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Publication number: 20220352721Abstract: A method of continuously performing one or more heat-consuming processes, where at least one heat-consuming process is electrically heated. The maximum temperature in the reaction zone of the heat-consuming process is higher than 500° C., at least 70% of products of the heat-consuming process are continuously processed further downstream and/or fed to a local energy carrier network, and the electrical energy required for the heat-consuming process is drawn from an external power grid and from at least one local power source. The local power source is fed by at least one local energy carrier network and by products from the heat-consuming process. The local energy carrier network stores natural gas, naphtha, hydrogen, synthesis gas, and/or steam as energy carrier, and has a total capacity of at least 5 GWh. The local energy carrier network is fed with at least one further product and/or by-product from at least one further chemical process.Type: ApplicationFiled: May 28, 2020Publication date: November 3, 2022Applicants: BASF SE, thyssenkrupp AG, thyssenkrupp Industrial Solutions AGInventors: Frederik SCHEIFF, Grigorios Kolios, Andreas Bode
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Publication number: 20220228280Abstract: An integrated process contains the following steps of: (i) pyrolysis of hydrocarbons to carbon and hydrogen, (iia) removal of at least a part of the produced carbon in step (i) and at least partly further processing of said carbon into a carbon containing electrode, and (iib) removal of the hydrogen produced in step (i) and at least partly using said hydrogen for providing energy, preferably electric energy or heat, for the electrode production in step (iia). A joint plant is also useful, which contains (a) at least one reactor for a pyrolysis process, (b) at least one reactor for the production of electrodes for an aluminum process, (c) a power plant and/or at least one gas-fired burner, and optionally, (d) at least one reactor for the electrolysis for producing aluminum.Type: ApplicationFiled: May 28, 2020Publication date: July 21, 2022Applicants: BASF SE, thyssenkrupp AG, thyssenkrupp Industrial Solutions AGInventors: Frederik Scheiff, Marc Leduc, Grigorios Kolios, William Daloz, Karsten Bueker, Nicolai Antweiler, Andreas Bode
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Publication number: 20220152584Abstract: Described herein is a gaslight multilayered composite tube having a heat transfer coefficient of >500 W/m2/K which in its construction over the cross section of the wall of the composite tube includes as an inner layer a nonporous monolithic oxide ceramic surrounded by an outer layer of oxidic fiber composite ceramic, where this outer layer has an open porosity of 5%<?<50%, and which on the inner surface of the composite tube includes a plurality of depressions oriented towards the outer wall of the composite tube. Also described herein is a method of using the multilayered composite tube as a reaction tube for endothermic reactions, jet tubes, flame tubes or rotary tubes.Type: ApplicationFiled: March 6, 2020Publication date: May 19, 2022Inventors: Grigorios Kolios, Heinrich Laib, Frederik Scheiff, Bernd Zoels, Matthias Kern
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Publication number: 20220152568Abstract: A reactor for carrying out an endothermic reaction, in particular a high-temperature reaction, in which a product gas is obtained from a feed gas, wherein: the reactor surrounds a reactor interior; the reactor is configured to provide a reactor bed in a reaction zone of the reactor interior, which reactor bed comprises a large number of solid material particles; the reactor is also configured to guide the feed gas into the reaction zone; in order to heat the feed gas, the reactor is designed to heat the solid material particles in the reaction zone such that, by transferring heat from the solid material particles to the feed gas, the feed gas in the reaction zone can be heated to a reaction temperature in order to participate as a starting product in the endothermic reaction for producing the product gas.Type: ApplicationFiled: March 31, 2020Publication date: May 19, 2022Inventors: Hans-Jörg ZANDER, Markus WEIKL, Andreas BODE, Dirk KLINGLER, Matthias KERN, Grigorios KOLIOS, Achim WECHSUNG, Frederik SCHEIFF, Dieter FLICK, Nicolai ANTWEILER, Karsten BÜKER
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Patent number: 11078077Abstract: A method for producing synthesis gas may involve introducing a hydrocarbon-containing coke-oven gas and a carbon dioxide-containing converter gas into a first reaction zone where hydrogen present in the hydrocarbon-containing coke-oven gas reacts at least partly with carbon dioxide to form water, which reacts thermally with hydrocarbon to form synthesis gas containing carbon monoxide and hydrogen. The method may further involve introducing an oxygen-containing gas in a second reaction zone, and using the oxygen-containing gas and some hydrogen from the first reaction zone to produce thermal energy. Still further, the method may involve supplying the thermal energy produced in the second reaction zone to the first reaction zone.Type: GrantFiled: November 28, 2016Date of Patent: August 3, 2021Assignees: THYSSENKRUPP INDUSTRIAL SOLUTIONS AG, THYSSENKRUPP AGInventors: Hans-Jürgen Maass, Volker Göke, Otto Machhammer, Andreas Bode, Grigorios Kolios, Karsten Büker
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Publication number: 20210162359Abstract: An apparatus contains at least one pressure-rated apparatus shell and at least one modular framework system containing ceramic fiber composite materials and arranged within the apparatus shell. A modular lining apparatus includes the modular framework system and. refractory bricks. The apparatus can be used for high-temperature reactors, especially electrically heated high-temperature reactors.Type: ApplicationFiled: August 5, 2019Publication date: June 3, 2021Applicant: BASF SEInventors: Grigorios Kolios, Bernd Zoels, Hagen Appel, Jens Bernnat, Friedrich Glenk, Dieter Flick, Gerhard Olbert, Frederik Scheiff, Christopher Alec Anderlohr
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Publication number: 20210051770Abstract: The present invention relates to an electrically heatable packed pressure-bearing apparatus for conducting endothermic reactions having an upper (3), middle (1) and lower (3) apparatus section, where at least one pair of electrodes (4, 5) in a vertical arrangement is installed in the middle section (1) and all electrodes are disposed in an electrically conductive solid-state packing (26), the upper and lower apparatus sections have a specific conductivity of 105 S/m to 108 S/m, and the middle apparatus section is electrically insulated against the solid-state packing, wherein the upper and lower apparatus sections are electrically insulated from the middle apparatus section, the upper electrode is connected via the upper apparatus section and the lower electrodes via the lower apparatus section or the electrodes are each connected via one or more connecting elements (10, 16) that are in electrical contact with these sections and the ratio of the cross-sectional areas of the upper and lower electrode to the crType: ApplicationFiled: January 22, 2019Publication date: February 18, 2021Applicant: BASF SEInventors: Hagen APPEL, Jens BERNNAT, Friedrich GLENK, Grigorios KOLIOS, Gergard OLBERT, Frederik SCHEIFF, Berd ZOELS, Matthias Kern, Dieter FLICKde, Christopher Alec ANDERLOHR, Dirk KLINGLER, Achim WECSUNG
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Patent number: 10865151Abstract: The present invention relates to a gastight multilayer composite tube having a heat transfer coefficient of >500 W/m2/K and comprising at least two layers, namely a layer of nonporous monolithic oxide ceramic and a layer of oxidic fiber composite ceramic, a connecting piece comprising at least one metallic gas-conducting conduit which in the longitudinal direction of the composite tube overlaps in a region at least two ceramic layers, where the one ceramic layer comprises a nonporous monolithic ceramic and the other ceramic layer comprises a fiber composite ceramic, and also the use of the multilayer composite tube as reaction tube for endothermic reactions, radiation tubes, flame tubes or rotary tubes.Type: GrantFiled: May 12, 2016Date of Patent: December 15, 2020Assignee: BASF SEInventors: Grigorios Kolios, Sven Thate, Carlos Tellaeche Herranz, Bernd Zoels