Abstract: Disclosed is a polymer electrolyte having a protonic acid group that is excellent in thermal stability and dimensional stability. The polymer electrolyte includes copolymers having a sulfonic acid group which has a structure represented by the following formula: wherein X is a divalent electron-withdrawing group; Y is an oxygen or a sulfur; Z and Q are each a direct bond, —O—, —S—, —CO—, —SO2—, —[C(R?)2]g— (g: integer of from 1 to 8), etc.; R, R? and R1 to R16 are each a hydrogen, a fluorine, an alkyl, a fluorine-substituted alkyl, an aryl or a nitrile; m, n, p, q, r, s, t and u are each an integer of from 0 to 4 (with the proviso that p+q?1); and A is a group represented by Formula (5a) or (5b) below: wherein W is a divalent electron-withdrawing group; S is a protonic acid group; i is an integer of from 1 to 5; and j is an integer of from 1 to 7.

Abstract: The present invention provides a membrane-electrode assembly excellent in electric power generation performance and durability for use in a solid polymer electrolyte fuel cell and a solid polymer electrolyte fuel cell formed therefrom. The membrane-electrode assembly for use in a solid polymer electrolyte fuel cell has a solid polymer electrolyte membrane 1 sandwiched between a pair of electrodes 2 and 2 each containing a catalyst. The solid polymer electrolyte membrane 1 is formed of a polyarylene polymer including a repeating unit represented by the general formula (1), or a polyarylene copolymer including the repeating unit represented by the general formula (1) and a repeating unit represented by the general formula (2). The solid polymer electrolyte fuel cell includes the membrane-electrode assembly for use in a solid polymer electrolyte fuel cell.

Abstract: To provide a sulfonic acid group-containing polymer having improved hot water resistance and radical resistance (durability), a solid polymer electrolyte including the polymer, and a proton-conducting membrane including the electrolyte, the polymer electrolyte includes a sulfonated product of a polymer shown by the following general formula (I): wherein X, Y, and Z are bonded randomly, alternately, or in blocks, y represents an integer of two or more, and each of x and z represents an integer of zero or more, where x+z>2.

Abstract: A polymer electrolyte membrane obtained by subjecting a sulfonated polyarylene membrane having an initial water content of 80-300 weight % to a hot-water treatment. A composite polymer electrolyte membrane comprising a matrix made of a first sulfonated aromatic polymer having a high ion exchange capacity, and a reinforcing material constituted by a second sulfonated aromatic polymer having a low ion exchange capacity in the form of fibers or a porous membrane.

Abstract: A polymer electrolyte membrane obtained by subjecting a sulfonated polyarylene membrane having an initial water content of 80-300 weight % to a hot-water treatment. A composite polymer electrolyte membrane comprising a matrix made of a first sulfonated aromatic polymer having a high ion exchange capacity, and a reinforcing material constituted by a second sulfonated aromatic polymer having a low ion exchange capacity in the form of fibers or a porous membrane.

Abstract: A composite polymer electrolyte membrane is formed from a first polymer electrolyte comprising a sulfonated polyarytene polymer and a second polymer electrolyte comprising another hydrocarbon polymer electrolyte. In the first polymer electrolyte, 2-70 mol % constitutes an aromatic compound unit with an electron-attractive group in its principal chain, while 30-98 mol % constitutes an aromatic compound unit without an electron-attractive group in its principal chain. The second polymer electrolyte is a sulfonated polyether or sulfonated polysulfide polymer electrolyte.

Abstract: A polymer electrolyte membrane obtained by subjecting a sulfonated polyarylene membrane having an initial water content of 80-300 weight % to a hot-water treatment. A composite polymer electrolyte membrane comprising a matrix made of a first sulfonated aromatic polymer having a high ion exchange capacity, and a reinforcing material constituted by a second sulfonated aromatic polymer having a low ion exchange capacity in the form of fibers or a porous membrane.

Abstract: To provide a sulfonic acid group-containing polymer having improved hot water resistance and radical resistance (durability), a solid polymer electrolyte including the polymer, and a proton-conducting membrane including the electrolyte, the polymer electrolyte includes a sulfonated product of a polymer shown by the following general formula (I): 1

Abstract: The present invention provides an electrode structure for a polymer electrolyte fuel cell comprising a pair of electrode catalyst layers 1, 1 and a polymer electrolyte membrane 2 held between the electrode catalyst layers 1, 1. The polymer electrolyte membrane 2 is a sulfonation product of a polymer, which comprises a main chain, wherein two or more divalent aromatic residues are bound to one another directly or through oxy groups or divalent groups other than aromatic residues, and side chains comprising aromatic groups to be sulfonated. Provided that the number of divalent aromatic residues comprised in the main chain of the above polymer is denoted by X, and the number of oxy groups comprised in the main chain of the above polymer is denoted by Y, the value X/Y is within the range of from 2.0 to 9.0.

Abstract: The present invention provides an electrode structure for polymer electrolyte fuel cells, inexpensive, and exhibiting excellent power production capacity and durability even under high temperature/low humidity conditions, and also provides a polymer electrolyte fuel cell which incorporates the same electrode structure. The present invention also provides an electrical device and transportation device, each incorporating the same polymer electrolyte fuel cell. The electrode structure comprises a pair of electrode catalyst layers 1,1, each containing a catalyst supported by carbon particles, and polymer electrolyte membrane 2 placed between these electrode catalyst layers 1,1. The polymer electrolyte membrane 2 is of a sulfonated polyarylene composed of 0.5 to 100% by mol of the first repeating unit represented by the general formula (1) and 0 to 99.

Abstract: The present invention provides an electrode structure having a pair of electrode catalyst layers and a polymer electrolyte membrane held between both the electrode catalyst layers. The polymer electrolyte membrane contains 5% or more by weight of the water coordinated to protons of sulfonic acid groups. The polymer electrolyte membrane comprises a fluorine-containing ion conducting polymer. The ratio of the fluorine content in the above polymer electrolyte membrane to the fluorine content in the above electrode catalyst layer is within the range of from 0.2 to 2.0. The polymer electrolyte membrane is a sulfonate of a copolymer general formulas (1) and (2). The electrode catalyst layer contains platinum within the range of from 0.01 to 0.8 mg/cm2, and the average particle diameter of a carbon particle as a carrier is within the range of from 10 to 100 nm. The polymer electrolyte membrane is produced by forming a membrane from the above sulfonate solution and drying the obtained membrane.

Abstract: The present invention provides a polymer electrolyte fuel cell, which is inexpensive and has an excellent efficiency of generating electric power, by using a material alternative to a perfluoroalkylene sulfonic acid polymer. The polymer electrolyte fuel cell comprises a pair of electrodes (2, 3) consisting of an oxygen electrode (2) and a fuel electrode (3) both having a catalyst layer (5) containing a catalyst and an ion conducting material; and a polymer electrolyte membrane (1) sandwiched between the two catalyst layers (5) of the both electrodes (2, 3).

Abstract: The present invention provides a polymer electrolyte fuel cell, which comprises: a pair of electrodes 2 and 3 both having a catalyst layer 5, where catalyst particles consisting of a catalyst carrier and a catalyst supported by the carrier are integrated by an ion-conductive polymer binder; and a polymer electrolyte membrane 1 sandwiched between the electrodes 2 and 3 on their sides having the catalyst layer 5. The polymer electrolyte fuel cell comprises: the polymer electrolyte membrane 1 having a coefficient of dynamic viscoelasticity at 110° C. in a range of 1×109 to 1×1011 Pa; and the catalyst layer 5 made of the ion-conductive polymer binder having a coefficient of dynamic viscoelasticity at 110° C. smaller than the polymer electrolyte membrane 1. The polymer electrolyte fuel cell further comprises a buffer layer 6, comprising an ion-conductive material having a coefficient of dynamic viscoelasticity at 110° C.

Abstract: A composite polymer electrolyte membrane is formed from a first polymer electrolyte comprising a sulfonated polyarylene polymer and a second polymer electrolyte comprising another hydrocarbon polymer electrolyte. In the first polymer electrolyte, 2-70 mol % constitutes an aromatic compound unit with an electron-attractive group in its principal chain, while 30-98 mol % constitutes an aromatic compound unit without an electron-attractive group in its principal chain. The second polymer electrolyte is a sulfonated polyether or sulfonated polysulfide polymer electrolyte. The composite polymer electrolyte membrane is formed from a matrix comprising the first polymer electrolyte selected from among sulfonated polyarylene polymers and having an ion exchange capacity in excess of 1.5 meq/g but less than 3.0 meq/g, which is supported on a reinforcement comprising the second polymer electrolyte having an ion exchange capacity in excess of 0.5 meq/g but less than 1.5 meq/g.

Abstract: A polymer electrolyte membrane obtained by subjecting a sulfonated polyarylene membrane having an initial water content of 80-300 weight % to a hot-water treatment. A composite polymer electrolyte membrane comprising a matrix made of a first sulfonated aromatic polymer having a high ion exchange capacity, and a reinforcing material constituted by a second sulfonated aromatic polymer having a low ion exchange capacity in the form of fibers or a porous membrane.

Abstract: The membrane electrode assembly comprising a pair of opposing electrodes each having a catalytic layer, and a polymer electrolyte membrane sandwiched by the electrodes, part of the catalytic layers being projecting into the polymer electrolyte membrane is produced by (1) coating a catalytic layer of one electrode with a solution of a polymer electrolyte in an organic solvent, (2) coating the resultant polymer electrolyte membrane with a catalyst slurry for the other electrode, while the amount of the organic solvent remaining in the polymer electrolyte membrane is 5-20 weight % based on the polymer electrolyte membrane, and (3) after drying, hot-pressing the polymer electrolyte membrane and the electrodes formed on both sides of the membrane.

Abstract: A field frame for use with a finder which provides arbitrary or stepwise switches of an aspect ratio of the finder. The field frame is made up of a standard field frame, a first L-shaped field switch frame having a dowel pin and two elongated holes, and a second L-shaped field switch frame having a dowel pin and two elongated holes. These two L-shaped field switch frames are piled up one on top of the other in such a manner that dowel pins standing on the main body of the standard field frame fit into the laminated elongated holes of the L-shaped field switch frames. A driving wheel having engaging cutouts is also laminated on the L-shaped field switch frames so that the engaging cutouts can engage with the dowel pins of the field switch frames. The driving wheel is also provided with a lever.

Abstract: A camera having a sprocket with a pair of cogs formed on a periphery for engaging a filmstrip having a row of perforations separated at alternate short and long intervals. The periphery is divided by the cogs into a frictional engaging section which provides frictional engagement of the periphery with the filmstrip and a mechanical engaging section which provides mechanical engagement of the cogs with the perforations. A shutter charging mechanism is operated by rotation of the sprocket driven by the filmstrip through the mechanical engagement between the filmstrip and at least part of the mechanically engaging section of the sprocket. A switch over mechanism disconnects the sprocket and the shutter mechanism in response to rewinding the filmstrip and a locking mechanism prevents reverse rotation of the sprocket in a specific position.

Abstract: A camera for use with a filmstrip having a row of perforations separated at alternate short and long intervals has a film winding mechanism which includes a sprocket and a locking mechanism for locking the sprocket in a specific position when an exposure counter returns its start point.

Abstract: A field frame for use with a finder which provides arbitrary or stepwise switches of an aspect ratio of the finder. The field frame is made up of a standard field frame, a first L-shaped field switch frame having a dowel pin and two elongated holes, and a second L-shaped field switch frame having a dowel pin and two elongated holes. These two L-shaped field switch frames are piled up one on top of the other in such a manner that dowel pins standing on the main body of the standard field frame fit into the superposed elongated holes of the L-shaped field switch frames. A driving wheel having engaging cutouts is also superposed on the L-shaped field switch frames so that the engaging cutouts can engage with the dowel pins of the field switch frames. The driving wheel is also provided with a lever.