Patents by Inventor Hiroyuki Hirai
Hiroyuki Hirai has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4745043Abstract: A method for forming an image, which comprises heating a light-sensitive material comprising a support having thereon at least a light-sensitive silver halide, a binder, and a dye providing substance simultaneously with or after imagewise exposure thereof in the presence of water, a reducing agent, and at least one kind of intensifying agent. In accordance with the method of the present invention, images having a high density can be obtained in a short period of time using reduced amounts of silver and base. A heat-developable photographic material containing intensifying agent is also described.Type: GrantFiled: July 25, 1986Date of Patent: May 17, 1988Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroyuki Hirai
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Patent number: 4740445Abstract: A color image is formed in an image forming reaction system comprising a photographic heat-developable silver halide light-sensitive material by reacting a difficultly soluble metal compound, for example, calcium carbonate with a compound capable of water-mediated complexing reaction with the metal ion of the difficultly soluble metal compound and having an organic base, for example, guanidine oxalate in the presence of water to increase the pH of the system.Type: GrantFiled: July 30, 1986Date of Patent: April 26, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Hirai, Yoshiharu Yabuki, Kozo Sato
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Patent number: 4740363Abstract: Alkali is generated from two neutral parts by reacting a complexing agent such as sodium picolinate in one part with a slightly water-soluble metal compound such as zinc oxide in the other part in the presence of water.Type: GrantFiled: July 30, 1986Date of Patent: April 26, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Hirai, Yoshiharu Yabuki, Kozo Sato
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Patent number: 4731321Abstract: A heat developable light-sensitive material comprising a support having thereon at least one light-sensitive layer wherein at least one layer comprises a compound represented by the following general formula (I): ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, a heterocyclic group each of which may be substituted or unsubstituted; a carboxy group or a salt thereof; R.sub.3 and R.sub.Type: GrantFiled: December 16, 1986Date of Patent: March 15, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Sato, Yoshiharu Yabuki, Hiroyuki Hirai, Ken Kawata
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Patent number: 4716100Abstract: A heat developable light-sensitive material containing a novel base precursor (I), which is stable during storage and rapidly decomposes to release a basic component upon heating higher than a certain temperature, has excellent storability and provides an image having a good image quality, i.e., a low fog density and a high image density within a short period of developing time.Type: GrantFiled: August 26, 1985Date of Patent: December 29, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshiharu Yabuki, Kozo Sato, Ken Kawata, Hiroyuki Hirai
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Patent number: 4705737Abstract: A heat developable photographic material comprising a support having thereon at least a photosensitive silver halide, a binder, and at least on of base precursors represented by following formula (I) or (II): ##STR1## wherein R represents an alkyl group, an alkylene group, an aryl group, an arylene group, a monovalent or divalent heterocyclic group, each of which may be unsubstituted or substituted; B represents a mono- or di-acidic, nitrogen-containing, sulfur-free base having a pKa of not lower than about 7 and containing 12 carbon atoms or less; x is an integer of 1 when R represents a monovalent group or an integer of 2 when R represents a divalent group, y is the same as x when B represents the mono-acidic base or an integer of 1 when B represents the di-acidic base; and z is an integer of 2 when R represents a monovalent group and B represents the di-acidic base or otherwise an integer of 1; R' represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl gType: GrantFiled: August 20, 1985Date of Patent: November 10, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Hirai, Kozo Sato, Yoshiharu Yabuki, Ken Kawata
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Patent number: 4704345Abstract: A method of forming an image comprising heating a light-sensitive material having at least a light-sensitive silver halide, a binder and a dye releasing redox compound which is capable of reducing the light-sensitive silver halide and is capable of reacting with the light-sensitive silver halide by heating to release a hydrophilic diffusible dye on a support after or simultaneously with imagewise exposure in the presence of water and a base and/or a base precursor to form a mobile dye and transferring the mobile dye to a dye fixing layer at the time of heating for development.In accordance with the method of the present invention, a clear color image having a high density and low fog can be obtained in a short time by a simple procedure.Type: GrantFiled: July 31, 1986Date of Patent: November 3, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Hirai, Hideki Naito
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Patent number: 4675277Abstract: A heat developable light-sensitive material comprising a support having provided thereon at least a light-sensitive silver halide, a binder, and a compound capable of ring-closure to produce a benzimidazole ring upon heat development can be developed to an increased maximum density with less fogging at a relatively low temperature in a short period of time.Type: GrantFiled: September 25, 1985Date of Patent: June 23, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Sato, Hiroshi Kitaguchi, Hiroyuki Hirai
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Patent number: 4668615Abstract: A heat developable light-sensitive material containing a compound represented by the general formula (I):[Ar.sub.n (R).sub.3-n CCO.sub.2 H].sub.l .multidot.B.sub.m (I)wherein ar represents an aryl group or a heterocyclic group; R represents a substituent other than an aryl group and a heterocyclic group; Ar and R may be bonded in a part thereof to form a ring; B represents a mono- or diacidic base which has a pKa of 7 or more and contains 12 or less carbon atoms; n represents an integer from 1 to 3; l and m each represents an integer of 1 or 2 and maintain a relationship in that a number of positive charge and a number of negative charge are equal; when n represents 1 or 2, two R's or Ar's may be the same or different, when n represents 3, three Ar's may be the same or different; and the substituent represented by Ar or R may be further substituted with a substituent.Type: GrantFiled: August 21, 1985Date of Patent: May 26, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Ken Kawata, Yoshiharu Yabuki, Kozo Sato, Hiroyuki Hirai
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Patent number: 4668612Abstract: A novel heat-developable color photosensitive material containing at least a light-sensitive silver halide, a binder, a dye providing substance capable of forming or releasing a diffusible dye by an oxidation-reduction reaction under heat and a transition metal ion, on a support.The present photosensitive materials provide a color image of high density with low fog in a short period of time, and have a good preservation-stability.Type: GrantFiled: September 4, 1985Date of Patent: May 26, 1987Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroyuki Hirai
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Patent number: 4659653Abstract: A heat developable light-sensitive material comprising a support having thereon at least a layer containing a novel compound having a group accelerating a reaction of decarboxylation, which releases a base by decarboxylation on heating. The heat developable light-sensitive material provides an image having a high density in a short time and has an improved storage stability.Type: GrantFiled: August 26, 1985Date of Patent: April 21, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazo Sato, Yoshiharu Yabuki, Hiroyuki Hirai, Ken Kawata
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Patent number: 4657848Abstract: A heat-developable light-sensitive material is described, containing a compound represented by formula (I) ##STR1## wherein R.sub.1 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkylene group, a substituted or unsubstituted cycloalkylene group, a substituted or unsubstituted alkenylene group, a substituted or unsubstituted alkynylene group, a substituted or unsubstituted aralkylene group, a substituted or unsubstituted arylene group, or a substituted or unsubstituted divalent heterocyclic group; R.sub.2 represents a hydrogen atom, a substituted or unsubstituted alkyl group; R.sub.Type: GrantFiled: October 2, 1985Date of Patent: April 14, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Sato, Yoshiharu Yabuki, Hiroyuki Hirai, Ken Kawata
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Patent number: 4650749Abstract: A heat developable light-sensitive material containing a compound represented by formula (I) or (II) ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, a heterocyclic group, a carboxyl group or a salt thereof, a halogen atom, a cyano group, an alkylsulfonyl or arylsulfonyl group, a sulfamoyl group, a carbamoyl group, an alkoxycarbonyl or aryloxycarbonyl group, a di- or mono-alkylphosphoryl or arylphosphoryl group, a di- or mono-alkylphosphinyl or arylphosphinyl group, an alkylsulfinyl or arylsulfinyl group, an acyl group, an amino group, an acylamino group, an acyloxy group or a group represented by X; X represents a decarboxylation accelerating group; or any two of R.sub.1, R.sub.2, and X may combine to form a ring; and the groups represented by R.sub.1, R.sub.Type: GrantFiled: August 26, 1985Date of Patent: March 17, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Sato, Yoshiharu Yabuki, Hiroyuki Hirai, Ken Kawata
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Patent number: 4649104Abstract: A heat developable light-sensitive material is described, comprising a polymer containing as a constituent a repeating unit represented by formula (I) ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituted or unsubstituted alkyl group having from 1 to 6 carbon atoms; L represents a divalent connecting group having from 1 to 20 carbon atoms; M represents a cation and x represents a number which is the same as the charge number of the cation represented by M.The polymer containing the repeating unit represented by formula (I) is a base precursor which is stable at normal temperature, but rapidly decomposes to release a base by heating; therefore, the heat developable light-sensitive material containing the base precursor has excellent preservability and provides images having good image quality, i.e., low fog density and high image density, upon a short period of developing time.Type: GrantFiled: October 30, 1985Date of Patent: March 10, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Taku Nakamura, Hiroyuki Hirai
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Patent number: 4649103Abstract: A heat-developable light-sensitive material is disclosed, comprising a support and at least one layer containing a novel base precursor releasing a base by thermal decomposition. The heat-developable light-sensitive material of the invention has an improved long-term stability and can provide a high density image in a short time.Type: GrantFiled: August 26, 1985Date of Patent: March 10, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshiharu Yabuki, Kozo Sato, Ken Kawata, Hiroyuki Hirai
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Patent number: 4647526Abstract: A heat-developable light-sensitive material is described which is capable of providing images of high density and low fog in a short period of time, and which is excellent in stability. The heat-developable light-sensitive material comprises a support and formed thereon a heat developable light-sensitive layer, wherein said light-sensitive material contains at least one compound selected from the group consisting of compounds represented by formulae (I), (II), (III) and (IV) as a base precursor ##STR1## wherein symbols represent the same groups as defined in claim 1.Type: GrantFiled: August 22, 1985Date of Patent: March 3, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Ken Kawata, Yoshiharu Yabuki, Kozo Sato, Hiroyuki Hirai
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Patent number: 4640891Abstract: A heat developable light-sensitive material having an excellent stability with time and capable of providing a high quality image is disclosed, which contains a base precursor represented by the following general formula (I): ##STR1## wherein A represents an organic residue represented by the following formula (II): ##STR2## X represents an electron attractive substituent having a Hammett's sigma value of more than 0;l represents an integer of 1 to 5 and, when l represents 2 or more, a plurality of Xs may be the same or different;Y represents a substituent having a Hammett's sigma value of 0 or less;k represents an integer of 0 to 5 and, when k represents 2 or more, a plurality of Ys may be the same or different;Z represents a divalent organic residue selected from the group consisting of --C.dbd.Type: GrantFiled: August 23, 1985Date of Patent: February 3, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshiharu Yabuki, Kozo Sato, Ken Kawata, Hiroyuki Hirai
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Patent number: 4640892Abstract: A heat-developable color photographic light-sensitive material comprises a support having thereon at least one layer containing the novel base precursor. This heat-developable color photographic light-sensitive material provides a high maximum density and low fog by heat-developing at a relatively low temperature and for a short period of time.Type: GrantFiled: August 26, 1985Date of Patent: February 3, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Ken Kawata, Yoshiharu Yabuki, Kozo Sato, Hiroyuki Hirai
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Patent number: 4639418Abstract: A heat developable photosensitive material comprising a support having thereon at least one light-sensitive layer comprising light-sensitive silver halide and a binder, wherein at least one layer contains a base precursor represented by the following general formula (I): ##STR1## wherein at least one of X, Y and Z, which may be the same or different, represents an electron-attractive substituent selected from the group (a) consisting of a halogen atom, a nitro group, an alkysulfinyl group, an arylsulfinyl group, an acyl group, a sulfamoyl group, a sulfamoyl group substituted with an aryl group, a substituted aryl group, an alkyl group or a substituted alkyl group, a carbamoyl group, a substituted carbamoyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an aryloxysulfonyl groups ##STR2## a nitroso group, ##STR3## wherein B is defined as in general formula (I), and R, R.sup.1 and R.sup.Type: GrantFiled: August 22, 1985Date of Patent: January 27, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshiharu Yabuki, Kozo Sato, Ken Kawata, Hiroyuki Hirai
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Patent number: 4637902Abstract: A base precursor represented by the following general formula (A) or (B): ##STR1## wherein A.sub.1, A.sub.2, A.sub.5, A.sub.6, A.sub.7, and A.sub.8 each represents a hydrogen atom, an alkyl group, a substituted alkyl group, a cycloalkyl group, an alkenyl group, an aralkyl group, an aryl group, a substituted aryl group, an acyl group, or a heterocyclic group, and A.sub.1 and A.sub.2 can combine to form a ring and two of A.sub.5, A.sub.6, A.sub.7, and A.sub.8 can combine to form a ring, A.sub.3 and A.sub.4 each represents a hydrogen atom, an alkyl group, a substituted alkyl group, a cycloalkyl group, or an aralkyl group, and A.sub.3 and A.sub.4 can combine to form a ring or A.sub.3 and A.sub.4 can be a double bond forming an imino group from ##STR2## and X represents a nucleophilic group.Type: GrantFiled: March 14, 1984Date of Patent: January 20, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Hirai, Ken Kawata