Abstract: An energy storage device comprising a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode comprises a self-supporting composite material film, a separator between the first electrode and the second electrode, and an electrolyte in contact with the first electrode, the second electrode, and the separator, wherein the electrolyte comprises at least one of a fluorine-containing cyclic carbonate, a fluorine-containing linear carbonate, and a fluoroether. The composite material film having greater than 0% and less than about 90% by weight of silicon particles, and greater than 0% and less than about 90% by weight of one or more types of carbon phases. At least one of the one or more types of carbon phases can be a substantially continuous phase that holds the composite material film together such that the silicon particles are distributed throughout the composite material film.

Abstract: Methods of detecting anomalies in and/or overcharge protection for secondary (rechargeable) electrochemical units, such as secondary cells and multicell secondary batteries. In some embodiments, the methods are based on a health measure referred to as “reverse coulombic efficiency” (RCE), which is based on a principle that the maximum amount of charge added to a secondary electrochemical unit during recharging should equal a net amount of charge discharged from the secondary electrochemical unit since a most recent fully charged state. An RCE-based health measure can be used to predict anomalies in secondary electrochemical units that can lead, for example, to overheating, explosion, and underperformance, among other things. Apparatuses and systems for implementing RCE-based anomaly detection and/or overcharge protection are also disclosed.

Abstract: An energy storage device comprising a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode comprises a self-supporting composite material film, a separator between the first electrode and the second electrode, and an electrolyte in contact with the first electrode, the second electrode, and the separator, wherein the electrolyte comprises at least one of a fluorine-containing cyclic carbonate, a fluorine-containing linear carbonate, and a fluoroether. The composite material film having greater than 0% and less than about 90% by weight of silicon particles, and greater than 0% and less than about 90% by weight of one or more types of carbon phases. At least one of the one or more types of carbon phases can be a substantially continuous phase that holds the composite material film together such that the silicon particles are distributed throughout the composite material film.

Abstract: Sulfonyl-based solvent systems for electrolytes used in electro-chemical devices, such as secondary batteries. In some embodiments, a solvent system of the disclosure includes a sulfonyl (—SO2—)-based solvent optionally in combination with one or more different sulfonyl-based solvents and/or one or more non-sulfonyl-based solvents. Five example chemical structures for a sulfonyl-based solvent usable in a sulfonyl-based solvent system of this disclosure are disclosed. Also disclosed are electrolytes that include one or more salts, such as one or more alkali-metal salts, dissolved in a sulfonyl-based solvent system of the present disclosure. Proper formulation of a disclosed electrolyte can lead to one or more benefits, including but not limited to, improved cycle life, improved low-temperature operation, and reduced flammability.

Abstract: Processes for producing a N,N-dialkyl perfluoroalkyl-sulfonamide product of the formula Rf—S(O)2—NRaRb (I) in which Rf represents fully or partially fluorinated alkyl groups with carbon 1 to 12 and Ra and Rb represents linear or branched or cyclic alkyl, alkene or alkyne groups with carbon 1 to 12, wherein Ra=Rb or Ra?Rb. In some embodiments, a reaction proceeds by contacting a perfluoroalkylsulfonyl halide of the formula: X—S(O)2—Rf, (II), in which X represents F, Cl, Br or I, with dialkylamine of the formula HNRaRb, under conditions sufficient to produce the desired N,N-dialkyl perfluoroalkylsulfonamide product of Formula I. In some embodiments, the reaction is carried out using a solvent of Formula I.

Abstract: Processes for producing a N,N-dialkyl perfluoroalkyl-sulfonamide product of the formula Rf—S(O)2—NRaRb (I) in which Rf represents fully or partially fluorinated alkyl groups with carbon 1 to 12 and Ra and Rb represents linear or branched or cyclic alkyl, alkene or alkyne groups with carbon 1 to 12, wherein Ra=Rb or Ra?Rb. In some embodiments, a reaction proceeds by contacting a perfluoroalkylsulfonyl halide of the formula: X—S(O)2—Rf, (II), in which X represents F, Cl, Br or I, with dialkylamine of the formula HNRaRb, under conditions sufficient to produce the desired N,N-dialkyl perfluoroalkylsulfonamide product of Formula I. In some embodiments, the reaction is carried out using a solvent of Formula I.

Abstract: Localized high-salt-concentration electrolytes each containing a salt, a glyme as a solvent, and a fluorinated diluent. In some embodiments, the glyme has a chemical formula R1—(O—CH2—CH2)n—O—R2, wherein n=1 to 4 and at least one of R1 and R2 is a hydrocarbon sidechain having at least 2 carbon atoms and wherein the salt is soluble in the glyme. In some embodiments, the fluorinated diluent is selected from the group consisting of a fluorinated glyme and a fluorinated ether. In some embodiments, the salt includes an alkali-metal salt. In some embodiments, the salt includes an alkali-earth-metal salt. The salt may include a perfluorinated sulfonimide salt. Electrochemical devices that include localized high-salt-concentration electrolytes of the present disclosure are also disclosed.

Abstract: An energy storage device comprising a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode comprises a self-supporting composite material film, a separator between the first electrode and the second electrode, and an electrolyte in contact with the first electrode, the second electrode, and the separator, wherein the electrolyte comprises at least one of a fluorine-containing cyclic carbonate, a fluorine-containing linear carbonate, and a fluoroether. The composite material film having greater than 0% and less than about 90% by weight of silicon particles, and greater than 0% and less than about 90% by weight of one or more types of carbon phases. At least one of the one or more types of carbon phases can be a substantially continuous phase that holds the composite material film together such that the silicon particles are distributed throughout the composite material film.

Abstract: A dustproof test device includes a test box and a dust supply apparatus, where the test box includes a sample cabin, where the dust supply apparatus is connected to the test box through a dust tube, and where the dust supply apparatus is configured to transport dust into the sample cabin under the action of compressed air.

Abstract: Systems and associated methods for reducing Doppler shifts in the broadband signals between Unmanned Aerial Vehicles (UAVs) and ground stations are disclosed herein. In one embodiment, a method for reducing the Doppler shift of wireless signals includes estimating a velocity of the UAV based on a Global Positioning System (GPS) or an Inertial Measurement Unit (IMU) of the UAV and calculating the Doppler shift of an upload (UL) wireless signal based on the velocity of the UAV. The method further includes predistorting a frequency of the UL wireless signal at the ground station to reduce the Doppler shift at a UAV receiver (RX) and transmitting the UL wireless signal from a ground station transmitter (TX) to the UAV RX. In some embodiments, calculating the Doppler shift of the UL wireless signal is performed at the ground station.

Abstract: Localized high-salt-concentration electrolytes each containing a salt, a glyme as a solvent, and a fluorinated diluent. In some embodiments, the glyme has a chemical formula R1—(O—CH2—CH2)n—O—R2, wherein n=1 to 4 and at least one of R1 and R2 is a hydrocarbon sidechain having at least 2 carbon atoms and wherein the salt is soluble in the glyme. In some embodiments, the fluorinated diluent is selected from the group consisting of a fluorinated glyme and a fluorinated ether. In some embodiments, the salt includes an alkali-metal salt. In some embodiments, the salt includes an alkali-earth-metal salt. The salt may include a perfluorinated sulfonimide salt. Electrochemical devices that include localized high-salt-concentration electrolytes of the present disclosure are also disclosed.

Abstract: An energy storage device comprising a first electrode and a second electrode, a separator between the first electrode and the second electrode, and an electrolyte in contact with the first electrode, the second electrode, and the separator, wherein the electrolyte comprises at least one of a fluorine-containing cyclic carbonate, a fluorine-containing linear carbonate, and a fluoroether. The electrolyte may be substantially free of non-fluorine containing cyclic carbonates.

Abstract: Localized high-salt-concentration electrolytes each containing a salt, a glyme as a solvent, and a fluorinated diluent. In some embodiments, the glyme has a chemical formula R1—(O—CH2—CH2)n—O—R2, wherein n=1 to 4 and at least one of R1 and R2 is a hydrocarbon sidechain having at least 2 carbon atoms and wherein the salt is soluble in the glyme. In some embodiments, the fluorinated diluent is selected from the group consisting of a fluorinated glyme and a fluorinated ether. In some embodiments, the salt includes an alkali-metal salt. In some embodiments, the salt includes an alkali-earth-metal salt. The salt may include a perfluorinated sulfonimide salt. Electrochemical devices that include localized high-salt-concentration electrolytes of the present disclosure are also disclosed.

Abstract: Aspects of the present disclosure include methods of charging secondary lithium metal batteries that include selectively and intentionally overcharging the battery to activate redox shuttling additives in order to reactivate dead lithium. Aspects of the present disclosure also include control systems for determining when to initiate a lithium reactivation charging process and for determining one or more parameters of a lithium reactivation charging protocol.

Abstract: Systems and associated methods for reducing Doppler shifts in the broadband signals between Unmanned Aerial Vehicles (UAVs) and ground stations are disclosed herein. In one embodiment, a method for reducing the Doppler shift of wireless signals includes estimating a velocity of the UAV based on a Global Positioning System (GPS) or an Inertial Measurement Unit (IMU) of the UAV and calculating the Doppler shift of an upload (UL) wireless signal based on the velocity of the UAV. The method further includes predistorting a frequency of the UL wireless signal at the ground station to reduce the Doppler shift at a UAV receiver (RX) and transmitting the UL wireless signal from a ground station transmitter (TX) to the UAV RX. In some embodiments, calculating the Doppler shift of the UL wireless signal is performed at the ground station.

Abstract: A dustproof test device includes a test box and a dust supply apparatus, where the test box includes a sample cabin, where the dust supply apparatus is connected to the test box through a dust tube, and where the dust supply apparatus is configured to transport dust into the sample cabin under the action of compressed air.

Abstract: An energy storage device comprising a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode comprises a self-supporting composite material film, a separator between the first electrode and the second electrode, and an electrolyte in contact with the first electrode, the second electrode, and the separator, wherein the electrolyte comprises at least one of a fluorine-containing cyclic carbonate, a fluorine-containing linear carbonate, and a fluoroether. The composite material film having greater than 0% and less than about 90% by weight of silicon particles, and greater than 0% and less than about 90% by weight of one or more types of carbon phases. At least one of the one or more types of carbon phases can be a substantially continuous phase that holds the composite material film together such that the silicon particles are distributed throughout the composite material film.

Abstract: An energy storage device includes a first electrode and a second electrode, a separator between the first electrode and the second electrode, and an electrolyte in contact with the first electrode, the second electrode, and the separator. The electrolyte includes at least one of a fluorine-containing cyclic carbonate, a fluorine-containing linear carbonate, and a fluoroether. At least one of the first electrode and the second electrode includes a self-supporting composite material film. The composite material film has greater than 0% and less than about 90% by weight of silicon particles, and greater than 0% and less than about 90% by weight of one or more types of carbon phases. At least one of the one or more types of carbon phases can be a substantially continuous phase that holds the composite material film together such that the silicon particles are distributed throughout the composite material film.

Abstract: Systems and associated methods for adaptive beam aggregation in wireless communications between unmanned aerial vehicles (UAVs) and ground-based stations are disclosed herein. In some embodiments, a method for transmitting wireless data between an unmanned aerial vehicle (UAV) and a customer premise equipment (CPE) station includes transmitting a first wireless data between a first antenna array and a first CPE station and transmitting a second wireless data between a second antenna array and a second CPE station. The first and second antenna arrays can include one or more individual antennas of the UAV.

Abstract: Systems and associated methods for reducing Doppler shifts in the broadband signals between Unmanned Aerial Vehicles (UAVs) and ground stations are disclosed herein. In one embodiment, a method for reducing the Doppler shift of wireless signals includes estimating a velocity of the UAV based on a Global Positioning System (GPS) or an Inertial Measurement Unit (IMU) of the UAV and calculating the Doppler shift of an upload (UL) wireless signal based on the velocity of the UAV. The method further includes predistorting a frequency of the UL wireless signal at the ground station to reduce the Doppler shift at a UAV receiver (RX) and transmitting the UL wireless signal from a ground station transmitter (TX) to the UAV RX. In some embodiments, calculating the Doppler shift of the UL wireless signal is performed at the ground station.