Abstract: According to one embodiment of the present disclosure, a redox flow battery is provided comprising an ionically conductive separator, a working side flowing electrolyte, a working electrode in ionic contact with the working side of the ionically conductive separator and the working side flowing electrolyte, a counter electrode, and an auxiliary electrode peripherally circumscribed by the working electrode in a common layer of the flow battery. The auxiliary electrode is in ionic contact with the working electrode, an electrically insulating peripheral gap separates the auxiliary electrode from the working electrode. A working electrode terminal is conductively coupled to the working electrode, an auxiliary electrode terminal is conductively coupled to the auxiliary electrode, and a counter electrode terminal is conductively coupled to the counter electrode.

Abstract: A cementitious print head and a cementitious printing methodology may include a feed barrel, a print head nozzle, a CO2 supply, a steam supply, a selective valve assembly in communication with the CO2 supply and the steam supply, a plurality of dual use extrusion head injectors, and a print head controller. The print head controller is operatively coupled to the selective valve assembly and is programmed to execute a CO2 and steam injection protocol where steam may be selected for injection by the extrusion head injectors into a cementitious composition as it is extruded from the print head nozzle to enhance a hydration reaction and formation of hydroxide in the cementitious composition before CO2 may be selected for injection by the extrusion head injectors into the cementitious composition as it is extruded from the print head nozzle to enhance a carbonation reaction in the cementitious composition.

Abstract: A system and method with a solid oxide electrolysis cell (SOEC), including feeding carbon dioxide and an olefin to the SOEC and discharging carbon monoxide and an olefin oxide from the SOEC, wherein the olefin oxide corresponds to the olefin.

Abstract: A system and method with a solid oxide electrolysis cell (SOEC), including feeding carbon dioxide and an olefin to the SOEC and discharging carbon monoxide and an olefin oxide from the SOEC, wherein the olefin oxide corresponds to the olefin.

Abstract: A system and method with a solid oxide electrolysis cell (SOEC), including feeding carbon dioxide and an olefin to the SOEC and discharging carbon monoxide and an olefin oxide from the SOEC, wherein the olefin oxide corresponds to the olefin.

Abstract: Systems and method for curing cementitious products are provided herein. In an example, a pressurized water saturator is used to create a CO2/H2O stream. The pressurized water saturator includes a carbon dioxide injection line disposed below a water level in the pressurized water saturator, an exit line disposed above the water level in the pressurized water saturator, and a pressure controller configured to hold a positive pressure of carbon dioxide in the pressurized water saturator.

Abstract: Embodiments provide a redox flow battery, an ion exchange membrane for use in the redox flow battery and a method for producing the ion exchanger membrane. The ion exchange membrane includes a base layer, a first hydrophobic layer, and a second hydrophobic layer. The base layer includes sulfonated poly(ether ether ketone). The base layer has a first surface and a second surface. The first hydrophobic layer includes a polydimethylsiloxane elastomer. The first hydrophobic layer is positioned on the first surface of the base layer. The second hydrophobic layer includes the polydimethylsiloxane elastomer. The second hydrophobic layer is positioned on the second surface of the base layer. The ion exchange membrane is configured to prevent cross contamination of the first electrolyte and the second electrolyte. The redox flow battery includes a first half-cell, a second half-cell, and the ion exchange membrane. The first half-cell includes a first electrolyte. The second half-cell includes a second electrolyte.

Abstract: A vehicle CO2 capture and utilization system includes a concrete mixer vehicle and a vehicle exhaust capture system. The concrete mixer vehicle comprises a vehicle exhaust and a mixer tank. The vehicle exhaust capture system is located onboard the concrete mixer vehicle. Additionally, the vehicle exhaust capture system includes one or more fluid pathways that fluidly couple the vehicle exhaust and the mixer tank.

Abstract: A method for curing cementitious articles includes flowing dry steam and carbon dioxide (CO2) simultaneously into a curing chamber containing a cementitious article. A relative humidity within the curing chamber may be between about 50% and about 70% and a temperature within the curing chamber may be between about 50° C. and about 70° C. A dry steam and CO2 mixture with a CO2 concentration between 2.5 vol % and 40 vol % is provided in the curing chamber and the cementitious article is cured for a duration between about 4 hours and 16 hours. Cementitious products cured with the method may have a CO2 uptake of greater than 15 wt % and a mechanical strength at least 10% greater than a cementitious product cured only in dry steam or CO2.

Abstract: Systems for accelerated carbonation curing of a pre-cast cementitious structure may include an ejector and a curing chamber downstream of the ejector. The ejector may be operable to combine a lesser-pressure carbon dioxide containing stream from a carbon dioxide source with a greater-pressure steam to produce a mixed stream including at least steam and carbon dioxide. The mixed stream may have a pressure greater than the pressure of the lesser-pressure carbon dioxide containing stream. The curing chamber may be operable to receive the mixed stream from the ejector and contact the mixed stream with the pre-cast cementitious structure to cure the pre-cast cementitious structure. Processes for accelerated carbonation curing of pre-cast cementitious structures using the systems are also disclosed.

Abstract: A vehicle CO2 capture and utilization system includes a concrete mixer vehicle and a vehicle exhaust capture system. The concrete mixer vehicle comprises a vehicle exhaust and a mixer tank. The vehicle exhaust capture system is located onboard the concrete mixer vehicle. Additionally, the vehicle exhaust capture system includes one or more fluid pathways that fluidly couple the vehicle exhaust and the mixer tank.

Abstract: A vehicle CO2 capture and utilization system includes a concrete mixer vehicle and a vehicle exhaust capture system. The concrete mixer vehicle comprises a vehicle exhaust and a mixer tank. The vehicle exhaust capture system is located onboard the concrete mixer vehicle. Additionally, the vehicle exhaust capture system includes one or more fluid pathways that fluidly couple the vehicle exhaust and the mixer tank.

Abstract: According to one embodiment of the present disclosure, a redox flow battery is provided comprising an ionically conductive separator, a working side flowing electrolyte, a working electrode in ionic contact with the working side of the ionically conductive separator and the working side flowing electrolyte, a counter electrode, and an auxiliary electrode peripherally circumscribed by the working electrode in a common layer of the flow battery. The auxiliary electrode is in ionic contact with the working electrode, an electrically insulating peripheral gap separates the auxiliary electrode from the working electrode. A working electrode terminal is conductively coupled to the working electrode, an auxiliary electrode terminal is conductively coupled to the auxiliary electrode, and a counter electrode terminal is conductively coupled to the counter electrode.

Abstract: A hybrid flow redox battery system includes an electrochemical cell with an ion-exchange membrane, an anode, and a cathode, an anolyte tank, a catholyte tank, one or more tank separators, a plurality of electrolyte pathways, one or more turbines, and one or more power generation circuits. The anolyte tank includes a lower anolyte opening positioned below an upper anolyte opening. The catholyte tank includes a lower catholyte opening positioned below an upper catholyte opening. The electrolyte pathways extend between the upper and lower anolyte openings and the anode and the upper and lower catholyte openings and the cathode. The turbines are fluidly coupled to the electrolyte pathways. The tank separators are positioned within one or both of the anolyte tank and the catholyte tank and are translatable in a downward direction to induce electrolyte flow from the lower anolyte and catholyte openings, through the turbines to hydroelectrically generate power.

Abstract: Embodiments of this disclosure are directed to a parking indicator comprising a vehicle contact body, a pivoting contact body support, an elongated visibility indicator, an indicator actuating mechanism, and an indicator retracting mechanism. The pivoting contact body support is attached to the vehicle contact body and is configured to permit the vehicle contact body to pivot to a horizontally-oriented position when the vehicle contact body is grounded via the pivoting contact body support and is contacted by a vehicle entering a parking space occupied by the parking indicator. The elongated visibility indicator is mechanically coupled to the vehicle contact body via the indicator actuating mechanism such that the indicator actuating mechanism upholds the elongated visibility indicator in an extended position.

Abstract: A method for curing cementitious articles includes flowing dry steam and carbon dioxide (CO2) simultaneously into a curing chamber containing a cementitious article. A relative humidity within the curing chamber may be between about 50% and about 70% and a temperature within the curing chamber may be between about 50° C. and about 70° C. A dry steam and CO2 mixture with a CO2 concentration between 2.5 vol % and 40 vol % is provided in the curing chamber and the cementitious article is cured for a duration between about 4 hours and 16 hours. Cementitious products cured with the method may have a CO2 uptake of greater than 15 wt % and a mechanical strength at least 10% greater than a cementitious product cured only in dry steam or CO2.

Abstract: A vehicle CO2 capture and utilization system includes a concrete mixer vehicle and a vehicle exhaust capture system. The concrete mixer vehicle comprises a vehicle exhaust and a mixer tank. The vehicle exhaust capture system is located onboard the concrete mixer vehicle. Additionally, the vehicle exhaust capture system includes one or more fluid pathways that fluidly couple the vehicle exhaust and the mixer tank.

Abstract: An electrochemical cell, electrochemical cell assembly and a method of assembling an electrochemical cell assembly. The cell includes a pair of current collectors that when joined together form a three-dimensional electrode assembly with an ion-exchange membrane disposed between the anode and cathode of the electrode assembly. The current collectors are sized and shaped such that a three-dimensional reactant chamber volume of one of the current collectors accepts nested placement of at least a portion of the three-dimensional reactant chamber volume of the other current collector. This design allows for easy and direct addition, removal or replacement of cells in a stack of such cells in a modular fashion. In addition, ease of mounting and unmounting of the cells on reactant manifolds promotes ease of assembly of two-dimensional or three-dimensional stack structures.

Abstract: An electrochemical cell, electrochemical cell assembly and a method of assembling an electrochemical cell assembly. The cell includes a pair of current collectors that when joined together form a three-dimensional electrode assembly with an ion-exchange membrane disposed between the anode and cathode of the electrode assembly. The current collectors are sized and shaped such that a three-dimensional reactant chamber volume of one of the current collectors accepts nested placement of at least a portion of the three-dimensional reactant chamber volume of the other current collector. This design allows for easy and direct addition, removal or replacement of cells in a stack of such cells in a modular fashion. In addition, ease of mounting and unmounting of the cells on reactant manifolds promotes ease of assembly of two-dimensional or three-dimensional stack structures.

Abstract: A hybrid flow redox battery system includes an electrochemical cell with an ion-exchange membrane, an anode, and a cathode, an anolyte tank, a catholyte tank, one or more tank separators, a plurality of electrolyte pathways, one or more turbines, and one or more power generation circuits. The anolyte tank includes a lower anolyte opening positioned below an upper anolyte opening. The catholyte tank includes a lower catholyte opening positioned below an upper catholyte opening. The electrolyte pathways extend between the upper and lower anolyte openings and the anode and the upper and lower catholyte openings and the cathode. The turbines are fluidly coupled to the electrolyte pathways. The tank separators are positioned within one or both of the anolyte tank and the catholyte tank and are translatable in a downward direction to induce electrolyte flow from the lower anolyte and catholyte openings, through the turbines to hydroelectrically generate power.