Patents by Inventor Itaru Asano

Itaru Asano has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240140026
    Abstract: A method of manufacturing a 3-dimensional model object by a powder bed fusion method using a resin granular material, in which the resin granular material comprises a resin powder (A) and a flow aid (B), a sphericity of the resin powder (A) is 80 or more and 100 or less, the resin powder (A) has a D80 particle size of 60 ?m or less and a D20 particle size of 1 ?m or more, the flow aid (B) is contained at an amount of more than 0.01 part by mass and less than 5 parts by mass with respect to 100 parts by mass of the resin powder (A), and steps (a) to (c) are performed in this order repeatedly.
    Type: Application
    Filed: February 22, 2022
    Publication date: May 2, 2024
    Inventors: Tomohiko Nakamura, Hirokazu Iwata, Yota Okuno, Itaru Asano
  • Publication number: 20240132666
    Abstract: A polymer powder includes a polyamide, wherein a melting point determined in differential scanning calorimetry is 190° C. or higher, a difference between the melting point and a melting onset temperature, which is defined in differential scanning calorimetry as a lowest temperature among temperatures at each of which a first temperature differential value of Heat Flow (W/g) observed between a peak top temperature of an endothermic peak, observed when 10 mg of powder is heated at a rate of 20° C./min from 30° C. in a nitrogen atmosphere, and a temperature point of ?50° C. from the peak top, becomes ?0.2 (W/g.° C.), is less than 30° C., and a D50 particle size is 1 ?m or more and 100 ?m or less.
    Type: Application
    Filed: February 22, 2022
    Publication date: April 25, 2024
    Inventors: Hirokazu Iwata, Tomohiko Nakamura, Yota Okuno, Kei Watanabe, Mikiya Nishida, Itaru Asano
  • Patent number: 11807717
    Abstract: A method produces polyamide fine particles by polymerizing a polyamide monomer (A) in the presence of a polymer (B) at a temperature equal to or higher than the crystallization temperature of a polyamide to be obtained, wherein the polyamide monomer (A) and the polymer (B) are homogeneously dissolved at the start of polymerization, and polyamide fine particles are precipitated after the polymerization. Polyamide fine particles have a number average particle size of 0.1 to 100 ?m, a sphericity of 90 or more, a particle size distribution index of 3.0 or less, a linseed oil absorption of 100 mL/100 g or less, and a crystallization temperature of 150° C. or more. In particular, a polyamide having a high crystallization temperature includes fine particles having a smooth surface, a narrow particle size distribution, and high sphericity.
    Type: Grant
    Filed: September 28, 2022
    Date of Patent: November 7, 2023
    Assignee: Toray Industries, Inc.
    Inventor: Itaru Asano
  • Patent number: 11685813
    Abstract: A method produces polyamide fine particles by polymerizing a polyamide monomer (A) in the presence of a polymer (B) at a temperature equal to or higher than the crystallization temperature of a polyamide to be obtained, wherein the polyamide monomer (A) and the polymer (B) are homogeneously dissolved at the start of polymerization, and polyamide fine particles are precipitated after the polymerization. Polyamide fine particles have a number average particle size of 0.1 to 100 ?m, a sphericity of 90 or more, a particle size distribution index of 3.0 or less, a linseed oil absorption of 100 mL/100 g or less, and a crystallization temperature of 150° C. or more.
    Type: Grant
    Filed: October 24, 2019
    Date of Patent: June 27, 2023
    Assignee: Toray Industries, Inc.
    Inventors: Itaru Asano, Tomohiko Nakamura, Yota Okuno, Nobuhiro Morioka
  • Publication number: 20230054021
    Abstract: A thermosetting resin composition contains at least: [A] a thermosetting resin; [B] a curing agent; and [C] polyamide particles satisfying following (c1) to (c6): (c1) a melting point of polyamide resin constituting the polyamide particles is 200 to 300° C.; (c2) a crystallization temperature of the polyamide resin constituting the polyamide particles is 150° C. to 250° C.; (c3) a number average particle size of the polyamide particles is 1 to 100 ?m; (c4) a sphericity of the polyamide particles is 80 to 100; and (c5) the linseed oil absorption of the polyamide particles is 10 to 100 mL/100 g. A thermosetting resin composition of the present invention enables suitable production of a fiber-reinforced composite material having sufficient compressive strength after impact and wet heat compression performance.
    Type: Application
    Filed: December 18, 2020
    Publication date: February 23, 2023
    Inventors: Itaru Asano, Atsuhito Arai, Ryohei Watari, Tomohiko Nakamura
  • Publication number: 20230034929
    Abstract: A method produces polyamide fine particles by polymerizing a polyamide monomer (A) in the presence of a polymer (B) at a temperature equal to or higher than the crystallization temperature of a polyamide to be obtained, wherein the polyamide monomer (A) and the polymer (B) are homogeneously dissolved at the start of polymerization, and polyamide fine particles are precipitated after the polymerization. Polyamide fine particles have a number average particle size of 0.1 to 100 ?m, a sphericity of 90 or more, a particle size distribution index of 3.0 or less, a linseed oil absorption of 100 mL/100 g or less, and a crystallization temperature of 150° C. or more. In particular, a polyamide having a high crystallization temperature includes fine particles having a smooth surface, a narrow particle size distribution, and high sphericity.
    Type: Application
    Filed: September 28, 2022
    Publication date: February 2, 2023
    Inventor: Itaru Asano
  • Patent number: 11485822
    Abstract: A method produces polyamide fine particles by polymerizing a polyamide monomer (A) in the presence of a polymer (B) at a temperature equal to or higher than the crystallization temperature of a polyamide to be obtained, wherein the polyamide monomer (A) and the polymer (B) are homogeneously dissolved at the start of polymerization, and polyamide fine particles are precipitated after the polymerization. Polyamide fine particles have a number average particle size of 0.1 to 100 ?m, a sphericity of 90 or more, a particle size distribution index of 3.0 or less, a linseed oil absorption of 100 mL/100 g or less, and a crystallization temperature of 150° C. or more. In particular, a polyamide having a high crystallization temperature includes fine particles having a smooth surface, a narrow particle size distribution, and high sphericity.
    Type: Grant
    Filed: May 7, 2018
    Date of Patent: November 1, 2022
    Assignee: Toray Industries, Inc.
    Inventor: Itaru Asano
  • Publication number: 20210403651
    Abstract: A method produces polyamide fine particles by polymerizing a polyamide monomer (A) in the presence of a polymer (B) at a temperature equal to or higher than the crystallization temperature of a polyamide to be obtained, wherein the polyamide monomer (A) and the polymer (B) are homogeneously dissolved at the start of polymerization, and polyamide fine particles are precipitated after the polymerization. Polyamide fine particles have a number average particle size of 0.1 to 100 ?m, a sphericity of 90 or more, a particle size distribution index of 3.0 or less, a linseed oil absorption of 100 mL/100 g or less, and a crystallization temperature of 150° C. or more.
    Type: Application
    Filed: October 24, 2019
    Publication date: December 30, 2021
    Inventors: Itaru Asano, Tomohiko Nakamura, Yota Okuno, Nobuhiro Morioka
  • Patent number: 11104766
    Abstract: A polysiloxane-polyalkylene glycol block copolymer is obtained by reacting a polysiloxane (A) having any functional group selected from a carboxylic anhydride group, a hydroxyl group, an epoxy group, a carboxyl group, and an amino group with a polyalkylene glycol (B) having any functional group selected from a carboxylic anhydride group, a hydroxyl group, a carboxyl group, an amino group, an epoxy group, a thiol group, and an isocyanate group, wherein a content of a structure derived from the polysiloxane (A) is 20% by mass or more and 90% by mass or less with respect to 100% by mass of the polysiloxane-polyalkylene glycol block copolymer.
    Type: Grant
    Filed: May 24, 2018
    Date of Patent: August 31, 2021
    Assignee: Toray Industries, Inc.
    Inventors: Hiroko Tanaka, Yuka Isago, Itaru Asano, Hiroshi Takezaki, Hisashi Miyama, Shiro Honda
  • Publication number: 20210221959
    Abstract: A polysiloxane-polyalkylene glycol block copolymer obtained by reacting a polysiloxane (A) having a functional group selected from the group consisting of a carboxylic anhydride group, a hydroxyl group, an epoxy group, an amino group, and a thiol group with a polyalkylene glycol (B) having a functional group selected from the group consisting of a carboxylic anhydride group, a hydroxyl group, an amino group, an epoxy group, and a thiol group to obtain a polysiloxane-polyalkylene glycol block copolymer intermediate, and further reacting a part of the carboxyl groups of the polysiloxane-polyalkylene glycol block copolymer intermediate with a compound reactive with a carboxyl group, wherein a content of a structure derived from the polysiloxane (A) is 30% by mass or more and 70% by mass or less with respect to 100% by mass of the entire polysiloxane-polyalkylene glycol block copolymer, and the polysiloxane-polyalkylene glycol block copolymer has a carboxyl group content of 0.1 mmol/g to 0.
    Type: Application
    Filed: August 6, 2019
    Publication date: July 22, 2021
    Inventors: Yuka Isago, Kenshi Miyaura, Itaru Asano
  • Publication number: 20200377670
    Abstract: A polysiloxane-polyalkylene glycol block copolymer is obtained by reacting a polysiloxane (A) having any functional group selected from a carboxylic anhydride group, a hydroxyl group, an epoxy group, a carboxyl group, and an amino group with a polyalkylene glycol (B) having any functional group selected from a carboxylic anhydride group, a hydroxyl group, a carboxyl group, an amino group, an epoxy group, a thiol group, and an isocyanate group, wherein a content of a structure derived from the polysiloxane (A) is 20% by mass or more and 90% by mass or less with respect to 100% by mass of the polysiloxane-polyalkylene glycol block copolymer.
    Type: Application
    Filed: May 24, 2018
    Publication date: December 3, 2020
    Inventors: Hiroko Tanaka, Yuka Isago, Itaru Asano, Hiroshi Takezaki, Hisashi Miyama, Shiro Honda
  • Publication number: 20200048413
    Abstract: A method produces polyamide fine particles by polymerizing a polyamide monomer (A) in the presence of a polymer (B) at a temperature equal to or higher than the crystallization temperature of a polyamide to be obtained, wherein the polyamide monomer (A) and the polymer (B) are homogeneously dissolved at the start of polymerization, and polyamide fine particles are precipitated after the polymerization. Polyamide fine particles have a number average particle size of 0.1 to 100 ?m, a sphericity of 90 or more, a particle size distribution index of 3.0 or less, a linseed oil absorption of 100 mL/100 g or less, and a crystallization temperature of 150° C. or more. In particular, a polyamide having a high crystallization temperature includes fine particles having a smooth surface, a narrow particle size distribution, and high sphericity.
    Type: Application
    Filed: May 7, 2018
    Publication date: February 13, 2020
    Inventor: Itaru Asano
  • Patent number: 10239970
    Abstract: Fine polymer particles made by a method include producing an emulsion in a liquid prepared by dissolving and mixing a polymer A and a polymer B in organic solvents in which a solution phase composed primarily of the polymer A and a solution phase composed primarily of the polymer B are formed as separate phases, wherein the solvents in the two phases resulting from the phase separation are substantially identical to each other, and contacting the emulsion with a poor solvent for the polymer A to precipitate the polymer A, wherein the particles have a glass transition point of 150° C. or more and 400° C. or less, an average particle diameter of 1 ?m or more to 100 ?m or less, and a particle diameter distribution index of the particles is 2 or less, wherein the polymer A is nonvinyl type polymer.
    Type: Grant
    Filed: June 30, 2016
    Date of Patent: March 26, 2019
    Assignee: Toray Industries, Inc.
    Inventors: Itaru Asano, Yuji Echigo, Hiroshi Takezaki
  • Patent number: 10125252
    Abstract: By first forming an emulsion in a system that separates into two phases which include a solution phase containing an ethylene-vinyl alcohol copolymer (A) as the main component and a solution phase containing a polymer (B) different from the ethylene-vinyl alcohol copolymer (A) as the main component when the copolymer (A), the polymer (B), and an organic solvent (C) having an SP value of 20 (J/cm3)1/2 to 30 (J/cm3)1/2 are dissolved and mixed together, and then causing the ethylene-vinyl alcohol copolymer (A) to precipitate as microparticles by bringing a poor solvent (D) of the ethylene-vinyl alcohol copolymer (A) into contact with the emulsion, it is possible to obtain ethylene-vinyl alcohol copolymer microparticles that have a narrow particle size distribution wherein the particle size distribution index in a dry-powder state is 2 or less, have a true spherical particle shape, and exhibit excellent re-dispersibility into liquid.
    Type: Grant
    Filed: May 21, 2014
    Date of Patent: November 13, 2018
    Assignee: Toray Industries, Inc.
    Inventors: Takahiko Otsubo, Itaru Asano, Hiroshi Takezaki
  • Patent number: 9920193
    Abstract: Provided are: fine vinylidene fluoride resin particles which are solid and have an average particle diameter of 0.3 ?m or more but less than 100 ?m, a particle diameter distribution index of 1-2, a repose angle of less than 40°, and an average sphericity of 80 or more said fine vinylidene fluoride particles being suitable for coating materials and coating applications; and a method for producing the fine vinylidene fluoride resin particles.
    Type: Grant
    Filed: August 26, 2013
    Date of Patent: March 20, 2018
    Assignee: TORAY INDUSTRIES, INC.
    Inventors: Yuji Echigo, Makiko Saito, Itaru Asano, Yoko Wakahara, Hiroshi Takezaki
  • Patent number: 9777130
    Abstract: Polyphenylene sulfide microparticles have a linseed oil absorption amount of 40 to 1,000 mL/100 g and a number average particle diameter of 1 to 200 ?m. The porous PPS microparticles have a large specific surface area and therefore promote fusion of particles when molded into various molded bodies by applying thermal energy, thus enabling formation or molding of a coating layer of particles at a lower temperature in a shorter time. The porous PPS microparticles have a porous shape and therefore enable scattering light in multiple directions and suppression of specific reflection of reflected light in a specific direction, thus making it possible to impart shading effect and matte effect when added to a medium.
    Type: Grant
    Filed: December 17, 2014
    Date of Patent: October 3, 2017
    Assignee: Toray Industries, Inc.
    Inventors: Takahiko Otsubo, Itaru Asano, Yoko Wakahara, Hiroshi Takezaki
  • Patent number: 9567443
    Abstract: A method of producing polycarbonate-based polymer microparticles including forming an emulsion in a system in which a polycarbonate-based polymer (A), a polymer (B) different from the polycarbonate-based polymer (A) and an organic solvent (C) are dissolved and mixed together and which causes phase separation into two phases of a solution phase having the polycarbonate-based polymer (A) as its main component and a solution phase having the polymer (B) different from the polycarbonate-based polymer (a) as its main component, and contacting a poor solvent for the polycarbonate-based polymer (A) with the emulsion at a temperature of 80° C. or higher to thereby precipitate microparticles of the polycarbonate-based polymer (A).
    Type: Grant
    Filed: January 18, 2013
    Date of Patent: February 14, 2017
    Assignee: Toray Industries, Inc.
    Inventors: Itaru Asano, Hiroshi Takezaki
  • Publication number: 20160311995
    Abstract: Polyphenylene sulfide microparticles have a linseed oil absorption amount of 40 to 1,000 mL/100 g and a number average particle diameter of 1 to 200 ?m. The porous PPS microparticles have a large specific surface area and therefore promote fusion of particles when molded into various molded bodies by applying thermal energy, thus enabling formation or molding of a coating layer of particles at a lower temperature in a shorter time. The porous PPS microparticles have a porous shape and therefore enable scattering light in multiple directions and suppression of specific reflection of reflected light in a specific direction, thus making it possible to impart shading effect and matte effect when added to a medium.
    Type: Application
    Filed: December 17, 2014
    Publication date: October 27, 2016
    Inventors: Takahiko Otsubo, Itaru Asano, Yoko Wakahara, Hiroshi Takezaki
  • Publication number: 20160304714
    Abstract: Fine polymer particles made by a method include producing an emulsion in a liquid prepared by dissolving and mixing a polymer A and a polymer B in organic solvents in which a solution phase composed primarily of the polymer A and a solution phase composed primarily of the polymer B are formed as separate phases, wherein the solvents in the two phases resulting from the phase separation are substantially identical to each other, and contacting the emulsion with a poor solvent for the polymer A to precipitate the polymer A, wherein the particles have a glass transition point of 150° C. or more and 400° C. or less, an average particle diameter of 1 ?m or more to 100 ?m or less, and a particle diameter distribution index of the particles is 2 or less, wherein the polymer A is nonvinyl type polymer.
    Type: Application
    Filed: June 30, 2016
    Publication date: October 20, 2016
    Inventors: Itaru Asano, Yuji Echigo, Hiroshi Takezaki
  • Patent number: 9410004
    Abstract: A fine polymer particle production method includes producing an emulsion in a liquid prepared by dissolving and mixing a polymer A and a polymer B in organic solvents in which a solution phase composed primarily of the polymer A and a solution phase composed primarily of the polymer B are formed as separate phases, and bringing it into contact with a poor solvent for the polymer A to precipitate the polymer A. This method serves for easy synthesis of fine polymer particles with a narrow particle size distribution and the method can be effectively applied to production of highly heat-resistant polymers that have been difficult to produce with the conventional methods.
    Type: Grant
    Filed: August 8, 2013
    Date of Patent: August 9, 2016
    Assignee: Toray Industries, Inc.
    Inventors: Itaru Asano, Yuji Echigo, Hiroshi Takezaki