Abstract: This application relates to an enclosure for a portable electronic device. The enclosure includes a metal substrate and a dehydrated anodized layer overlaying the metal substrate. The dehydrated anodized layer includes pores having openings that extend from an external surface of the dehydrated anodized layer and towards the metal substrate, and a metal oxide material that plugs the openings of the pores, where a concentration of the metal oxide material is between about 3 wt % to about 10 wt %.

Abstract: This application relates to an enclosure for a portable electronic device. The enclosure includes a titanium substrate having a textured surface that includes randomly distributed peaks separated from each other by valleys, where tops of the peaks are separated from bottoms of the valleys by at least a minimum separation distance such that the textured surface is characterized as having an Sq (root mean square height) that is greater than 0.3 micrometers.

Abstract: This application relates to an enclosure for a portable electronic device. The enclosure includes a titanium substrate having a textured surface that includes peaks separated by valleys, where the textured surface is characterized as having (i) an Sdq (root mean square gradient) that is greater than 0.2 micrometers, and (ii) a gloss value that is greater than 90 gloss units as measured at 60 degrees by a gloss meter.

Abstract: Techniques for forming an enclosure comprised of an aluminum alloy are disclosed. In some embodiments, aluminum ions and metal element ions can be dissolved in a non-aqueous ionic liquid in an electrolytic plating bath. A reverse pulsed electric current can facilitate in co-depositing the aluminum ions and the metal element ions onto a metal substrate. The resulting aluminum alloy layer can include nanocrystalline structures, which can impart the alloy layer with increased hardness and increased resistance to scratching, corrosion, and abrasion. In some embodiments, the metal element ion is chromium and the aluminum alloy layer includes a chromium oxide passivation layer formed via a passivation process. Subsequent to the passivation process, the formation of the chromium oxide layer does not impart a change in color to the aluminum alloy layer. In some embodiments, hafnium ions are co-deposited with aluminum ions to form an aluminum hafnium alloy.

Abstract: Techniques for forming an enclosure comprised of aluminum zirconium alloy layer are disclosed. In some embodiments, aluminum ions and zirconium ions can be dissolved in a non-aqueous ionic liquid in an electrolytic plating bath. A reverse pulsed electric current can facilitate in co-depositing the aluminum ions and the zirconium ions onto a metal substrate. The resulting aluminum zirconium alloy layer can include nanocrystalline grain structures, which can impart the alloy layer with increased hardness and increased resistance to scratching, denting, and abrasion. In some embodiments, the aluminum zirconium alloy layer can be anodized to form an aluminum oxide layer. Subsequent to the anodization operation, the oxidized layer is able to retain its substantially neutral color.

Abstract: Anodic oxide coatings that provide corrosion resistance to parts having protruding features, such as edges, corners and convex-shaped features, are described. According to some embodiments, the anodic oxide coatings include an inner porous layer and an outer porous layer. The inner layer is adjacent to an underlying metal substrate and is formed under compressive stress anodizing conditions that allow the inner porous layer to be formed generally crack-free. In this way, the inner porous layer acts as a barrier that prevents water or other corrosion-inducing agents from reaching the underlying metal substrate. The outer porous layer can be thicker and harder than the inner porous layer, thereby increasing the overall hardness of the anodic oxide coating.

Abstract: This application relates to an enclosure for a portable electronic device. The enclosure includes an aluminum alloy substrate and an anodized layer overlaying and formed from the aluminum alloy substrate. The anodized layer includes pores, where the pores include (i) dye particles that impart the anodized layer with a color, and (ii) divalent metal cations.

Abstract: This application relates to an enclosure for a portable electronic device. The enclosure includes an aluminum alloy substrate and an anodized layer overlaying and formed from the aluminum alloy substrate, wherein the anodized layer has an external surface that has a concentration of zinc that is between about 3 wt % to about 7 wt %.

Abstract: Techniques for forming a metal oxide from a metal substrate are disclosed. In some embodiments, the metal oxide can have an optical path difference between about 300 nm to about 1000 nm. The variations in optical path difference can impart the metal oxide to correspond to a range of pre-defined colors. In some embodiments, the optical path difference can impart the metal oxide to have an oxide color that is substantially similar to a color of a housing of a portable electronic device. In some embodiments, the metal oxide can be electrically conductive and the metal oxide can be utilized as an electrical contact of an electronic device to transmit and receive power and data from another electronic device.

Abstract: Treatments for anodic coatings that provide improved resistance to staining and cracking during various manufacturing processes are described. According to some embodiments, the methods include placing the anodic coatings in partially sealed states by sealing only the outermost portions of the anodic coatings, which protect the outer surfaces of the anodic coatings from contamination and staining. Inner portions of the anodic coatings are left unsealed, thereby making the anodic coatings more compliant and resistant to cracking when exposed to manufacturing processes, even those that involve exposure to high temperatures or high mechanical stress. Subsequent to the processing, another sealing process can be implemented to fully seal the anodic coatings so that they provide good corrosion and wear resistance.

Abstract: An ankle brace according to the present disclosure includes a medial pad, a lateral pad, a posterior wall, and at least one horizontal strap. The medial pad is configured to engage a medial side of an ankle. The lateral pad is configured to engage a lateral side of the ankle. The posterior wall is attached to the medial pad and is configured to engage a posterior side of the ankle. The at least one horizontal strap is configured to be secured to the lateral pad, secured to the posterior wall, and pulled in an anterior direction to apply an anterior force to a distal fibula of the ankle. The anterior force brings the distal fibula closer to a distal tibia of the ankle and thereby decreases stress on ligaments connecting the distal fibula and the distal tibia to one another.

Abstract: Processes for cleaning anodic film pore structures are described. The processes employ methods for gas generation within the pores to flush out contamination within the anodic film. The pore cleaning processes can eliminate cosmetic defects related to anodic pore contamination during the manufacturing process. For example, an anodic film that is adjacent to a polymer piece can experience contamination originating from a gap between the anodic film and polymer piece, which can inhibit colorant uptake of the anodic film in areas proximate the polymer piece. In some cases, an alternating current anodizing process or a separate operation of cathodic polarization is implemented to generate hydrogen gas that bubbles out of the pores, forcing the contaminates out of the anodic film.

Abstract: Method, system and non-transitory computer-readable medium configured to store instructions for implementing a method for for providing automated collateral eligibility services implemented by one or more collateral management service (CMS) devices between a client and at least one other party. The method includes receiving a collateral eligibility schedule setup request from a client device. The collateral eligibility schedule setup request includes one or more attributes and one or more rules. The method further includes initiating a current collateral eligibility schedule based on the received collateral eligibility schedule setup request; transmitting a notification to the at least one other party to review the current collateral eligibility schedule; receiving approval of the current collateral eligibility schedule from the at least one other party; and activating the approved current collateral eligibility schedule.

Abstract: This application relates to a multi-piece enclosure for a portable electronic device. The enclosure includes a metal part including a metal substrate and a metal oxide layer overlaying the metal substrate, the metal oxide layer having an external surface that includes openings that lead into undercut regions. The openings are characterized as having a first width, and the undercut regions are characterized as having a second width that is greater than the first width. The enclosure further includes a non-metallic bulk layer including protruding portions that extend into the undercut regions such that the non-metallic bulk layer is interlocked with the metal part.

Abstract: This application relates to a part that includes a metal oxide layer having pore structures. In some embodiments, dye molecules having aromatic rings can be disposed within at least one of the pore structures. Additionally, the at least one pore structures can include dispersion molecules, where the dispersion molecules form non-covalent interactions with the dye molecules. By forming non-covalent interactions between the dye molecules and the dispersion molecules, the aromatic rings of the dye molecules are prevented from forming other non-covalent interactions with other dye molecules. Additionally, techniques for chemically stabilizing the color dye bath for dyeing anodized parts are also described.

Abstract: A method for providing a surface finish to a metal part includes both diffusion hardening a metal surface to form a diffusion-hardened layer, and oxidizing the diffusion-hardened layer to create an oxide coating thereon. The diffusion-hardened layer can be harder than an internal region of the metal part and might be ceramic, and the oxide coating can have a color that is different from the metal or ceramic, the color being unachievable only by diffusion hardening or only by oxidizing. The metal can be titanium or titanium alloy, the diffusion hardening can include carburizing or nitriding, and the oxidizing can include electrochemical oxidization. The oxide layer thickness can be controlled via the amount of voltage applied during oxidation, with the oxide coating color being a function of thickness. An enhanced hardness profile can extend to a depth of at least 20 microns below the top of the oxide coating.

Abstract: Treatments for anodic coatings that provide improved resistance to staining and cracking during various manufacturing processes are described. According to some embodiments, the methods include placing the anodic coatings in partially sealed states by sealing only the outermost portions of the anodic coatings, which protect the outer surfaces of the anodic coatings from contamination and staining. Inner portions of the anodic coatings are left unsealed, thereby making the anodic coatings more compliant and resistant to cracking when exposed to manufacturing processes, even those that involve exposure to high temperatures or high mechanical stress. Subsequent to the processing, another sealing process can be implemented to fully seal the anodic coatings so that they provide good corrosion and wear resistance.

Abstract: Anodized aluminum alloys that are resistant to corrosion are described. According to some embodiments, the anodized aluminum alloys include very small amounts, even trace levels, of corrosion resistant elements with higher Gibbs free energies for oxide formation than aluminum. If the aluminum alloy includes high levels of zinc, the corrosion resistant elements can also have higher Gibbs free energies for oxide formation than zinc. The corrosion resistant elements can accumulate at an interface region of the substrate near the anodic film during the anodizing process, thereby significantly changing the alloy composition in this interface region providing surprising high resistance to certain forms of corrosion. The type and amount of corrosion resistant elements can depend on particular application requirements. In some cases, the anodized aluminum alloys are used as cosmetic appealing housing for consumer electronic products.

Abstract: Processes for enhancing the corrosion resistance of anodized substrates are disclosed. In some embodiments, the process involves a second anodizing operation that targets an area of the substrate that is left inadequately protected by a first anodizing operation, and also targets defects that may have been arisen from intermediate processing operations such as laser-marking operations. The second anodizing operation can be conducted in a non-pore-forming electrolyte, and grows a thick protective barrier film over inadequately protected areas of the substrate, such as laser-marking treated areas.

Abstract: A method for providing a surface finish to a metal part includes both diffusion hardening a metal surface to form a diffusion-hardened layer, and oxidizing the diffusion-hardened layer to create an oxide coating thereon. The diffusion-hardened layer can be harder than an internal region of the metal part and might be ceramic, and the oxide coating can have a color that is different from the metal or ceramic, the color being unachievable only by diffusion hardening or only by oxidizing. The metal can be titanium or titanium alloy, the diffusion hardening can include carburizing or nitriding, and the oxidizing can include electrochemical oxidization. The oxide layer thickness can be controlled via the amount of voltage applied during oxidation, with the oxide coating color being a function of thickness. An enhanced hardness profile can extend to a depth of at least 20 microns below the top of the oxide coating.