Patents by Inventor James M. Valentine

James M. Valentine has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20140134061
    Abstract: A lean burn combustion source includes a first side stream comprising an inlet and an outlet, both positioned downstream of a furnace and upstream of a particulate control device, and a second side stream comprising: an inlet positioned downstream of the particulate control device and upstream of the catalyst, a heat exchanger section passing through the first side stream, whereby heat from hot exhaust gas flowing through the first side stream is transferred to hot exhaust gas flowing through the second side stream, an injector positioned in the second side stream injecting aqueous based reagent into the hot exhaust gas flowing through the second side stream such that the aqueous based reagent decomposes to ammonia gas, and an outlet in fluid communication with a reagent distribution device positioned in the primary exhaust gas stream downstream of the particulate control device and upstream of the catalyst.
    Type: Application
    Filed: November 12, 2013
    Publication date: May 15, 2014
    Inventors: R. Gifford Broderick, Jeffrey Michael Broderick, Kathryn V. O'Leary, Scott H. Lindemann, James M. Valentine
  • Publication number: 20140099248
    Abstract: A method of reducing NOx emissions from a lean burn combustion source employs an aqueous solution of reagent that is injected into a continuous decomposition duct at a rate of 0.2-10 gph with a flowing side stream of hot gas at a rate of 150-3000 scfm and a temperature of greater than 700° F. in the decomposition duct such that the aqueous reagent is converted to ammonia gas that is conveyed by the continuous decomposition duct to an ammonia injection grid that is placed in a primary exhaust stream from the combustion source upstream of a NOx reducing catalyst and NOx is reduced.
    Type: Application
    Filed: October 7, 2013
    Publication date: April 10, 2014
    Inventors: Jeffrey Michael Broderick, Scott H. Lindemann, James M. Valentine
  • Publication number: 20140099247
    Abstract: A method for reducing NOx emissions from a lean burn combustor equipped with a NOx reducing exhaust catalyst, includes at least the following steps: (i) generating a computer based model of the geometry of an exhaust system of the combustor; (ii) computing at least one of flue gas velocity profiles and mass flow stream lines for exhaust gas flow through the exhaust system; (iii) inputting injector data comprising at least droplet size and velocity; (iv) modeling droplet trajectories for a plurality of injector locations; (v) modeling at least one flow conditioning device in the exhaust system; and (vi) manipulating the computer based model until an injector location is identified that provides a predicted root mean square (RMS) of reagent at the face of the catalyst that is less than 15%.
    Type: Application
    Filed: October 4, 2013
    Publication date: April 10, 2014
    Inventors: Saiprasad Jangiti, Thomas V. Eldredge, Jeffrey Michael Broderick, James M. Valentine
  • Publication number: 20140096532
    Abstract: A method for reducing NOx emissions in the exhaust of a combined cycle gas turbine equipped with a heat recovery boiler and a catalyst effective for NOx reduction, wherein a slip stream of hot flowing exhaust gases is withdrawn from the primary gas flow after the catalyst at a temperature of 500° F. to 900° F. and directed through a fan to a continuous duct into which an aqueous based reagent is injected for decomposition to ammonia gas and the outlet of the continuous duct is connected to an injection grid positioned in the primary exhaust for injection of ammonia gas into the primary exhaust stream at a location upstream of the catalyst.
    Type: Application
    Filed: October 3, 2013
    Publication date: April 10, 2014
    Inventors: Jeffrey Michael Broderick, Kathryn V. O'Leary, R. Gifford Broderick, John N. Dale, James M. Valentine
  • Patent number: 8591849
    Abstract: A system and method for reducing NOx emissions from a lean burn combustion source is provided. The system includes a blower passing air through a continuous duct having a hot portion and a reaction portion. The hot portion of the duct is positioned in the convective zone of the combustion source to heat the passing air for the reaction portion of the duct. An injector attached to a urea storage container is positioned in the reaction portion of the duct and sprays urea from the storage container into the heated air in the reaction duct for evaporation and decomposition into ammonia gas. The ammonia gas is then supplied to an injection grid in the exhaust duct of the lean burn combustion source upstream of a NOx reduction catalyst. The injection grid supplies the ammonia gas to the exhaust gas in the exhaust duct.
    Type: Grant
    Filed: April 16, 2013
    Date of Patent: November 26, 2013
    Assignee: Combustion Components Associates, Inc.
    Inventors: James M. Valentine, Jeffrey Michael Broderick, Scott H. Lindemann, R. Gifford Broderick, Edmund S. Schindler
  • Publication number: 20130272940
    Abstract: A system and method for reducing NOx emissions from a lean burn combustion source is provided. The system includes a blower passing air through a continuous duct having a hot portion and a reaction portion. The hot portion of the duct is positioned in the convective zone of the combustion source to heat the passing air for the reaction portion of the duct. An injector attached to a urea storage container is positioned in the reaction portion of the duct and sprays urea from the storage container into the heated air in the reaction duct for evaporation and decomposition into ammonia gas. The ammonia gas is then supplied to an injection grid in the exhaust duct of the lean burn combustion source upstream of a NOx reduction catalyst. The injection grid supplies the ammonia gas to the exhaust gas in the exhaust duct.
    Type: Application
    Filed: April 16, 2013
    Publication date: October 17, 2013
    Inventors: James M. Valentine, Jeffrey Michael Broderick, Scott H. Lindemann, R. Gifford Broderick, Edmund S. Schindler
  • Publication number: 20130152470
    Abstract: A system and method of reducing NOx emissions from a lean burn combustion source is provided. The system includes at least one injection lance having a elongated shaft with distal and proximal ends, a metering valve positioned at the distal end, an atomization chamber positioned between the metering valve and the distal end, a storage chamber for containing a reagent fluidly connected to the metering valve, an injection tip positioned at the proximal end for delivering the reagent, and at least one air port for supplying air to the atomization chamber. The injection lance is positioned in the combustion source, and the reagent is supplied from the storage chamber to the injection lance at an inlet pressure. The reagent is then injected into the combustion source via the injection lance, wherein a temperature of the reagent prior to the injection is maintained below a hydrolysis temperature of the reagent.
    Type: Application
    Filed: February 14, 2013
    Publication date: June 20, 2013
    Inventors: Scott H. Lindemann, Bruce E. Hartel, John N. Dale, Jeffrey Michael Broderick, James M. Valentine
  • Publication number: 20120177553
    Abstract: A system and method of reducing NOx emissions from a lean burn combustion source is provided. The system includes at least one injection lance having a elongated shaft with distal and proximal ends, a metering valve positioned at the distal end, an atomization chamber positioned between the metering valve and the distal end, a storage chamber for containing a reagent fluidly connected to the metering valve, an injection tip positioned at the proximal end for delivering the reagent, and at least one air port for supplying air to the atomization chamber. The injection lance is positioned in the combustion source, and the reagent is supplied from the storage chamber to the injection lance at an inlet pressure. The reagent is then injected into the combustion source via the injection lance, wherein a temperature of the reagent prior to the injection is maintained below a hydrolysis temperature of the reagent.
    Type: Application
    Filed: December 7, 2011
    Publication date: July 12, 2012
    Inventors: Scott H. Lindemann, Bruce E. Hartel, John N. Dale, Jeffrey Michael Broderick, James M. Valentine
  • Patent number: 8109077
    Abstract: The present invention provides methods and apparatus for injecting fluid, such as an aqueous urea solution, into an exhaust stream in order to reduce oxides of nitrogen (NOx) emissions from diesel engine exhaust. More particularly, the present invention provides a dual-injector system for diesel emissions control and corresponding methods.
    Type: Grant
    Filed: October 10, 2007
    Date of Patent: February 7, 2012
    Assignee: Tenneco Automotive Operating Company Inc.
    Inventors: Peter Joseph Reba, Gregory John Baccari, Thomas V. Eldredge, James M. Valentine
  • Patent number: 7743737
    Abstract: A safe, reliable system for automatically dosing diesel truck fuel tanks with a fuel additive is provided. The additive, such as a concentrated solution containing fuel borne catalyst (FBC), is fed by positive feed means in pulsed doses while the engine is on. The frequency and amount of FBC injection is controlled as a function of the time the engine is operated and predetermined values for rate of fuel consumption and intended additive concentrations in the fuel.
    Type: Grant
    Filed: December 22, 2005
    Date of Patent: June 29, 2010
    Assignee: Clean Diesel Technologies, Inc.
    Inventors: James M. Valentine, Curtis J. Knapper
  • Patent number: 7523722
    Abstract: A safe, reliable system for automatically dosing diesel truck fuel tanks with a fuel additive is provided. The additive, such as a concentrated solution containing fuel borne catalyst (FBC), is fed by gravity and dosing is controlled with a signal from a switch located on the ignition switch and/or the fuel tank cap and filler spout. When the ignition switch is in the on position and/or the cap is removed, a solenoid opens a valve and permits a timed or otherwise measured amount of additive to flow into the tank while the cap is off. Replacing the cap and/or turning off the ignition switch preferably stops the flow of additive, the flow rate being set to supply a predetermined amount of additive during an average refueling interval.
    Type: Grant
    Filed: July 1, 2005
    Date of Patent: April 28, 2009
    Assignee: Clean Diesel Technologies, Inc.
    Inventors: James M. Valentine, Curtis N. Knapper
  • Publication number: 20090004083
    Abstract: A multi-stage NOx reduction system employs catalysts effective at different temperature ranges and can have reagent injectors associated with each, for use in series or in parallel. A controller directs reagent introduction to one catalyst or the other as temperature and other conditions dictate. Valving can redirect exhaust to particular catalyst zones, if necessary.
    Type: Application
    Filed: June 17, 2005
    Publication date: January 1, 2009
    Inventors: James M. Valentine, Jeremy D. Peter-Hoblyn, John E. Hofmann
  • Publication number: 20080210184
    Abstract: A safe, reliable system for automatically dosing diesel truck fuel tanks with a fuel additive is provided. The additive, such as a concentrated solution containing fuel borne catalyst (FBC), is fed by gravity and dosing is controlled with a signal from a switch located on the ignition switch and/or the fuel tank cap and filler spout. When the ignition switch is in the on position and/or the cap is removed, a solenoid opens a valve and permits a timed or otherwise measured amount of additive to flow into the tank while the cap is off. Replacing the cap and/or turning off the ignition switch preferably stops the flow of additive, the flow rate being set to supply a predetermined amount of additive during an average refueling interval.
    Type: Application
    Filed: July 1, 2005
    Publication date: September 4, 2008
    Applicant: CLEAN DIESEL TECHNOLOGIES, INC.
    Inventors: James M. Valentine, Curtis J. Knapper
  • Publication number: 20080087008
    Abstract: The present invention provides methods and apparatus for injecting fluid, such as an aqueous urea solution, into an exhaust stream in order to reduce oxides of nitrogen (NOx) emissions from diesel engine exhaust. More particularly, the present invention provides a dual-injector system for diesel emissions control and corresponding methods.
    Type: Application
    Filed: October 10, 2007
    Publication date: April 17, 2008
    Inventors: Peter Joseph Reba, Gregory John Baccari, Thomas V. Eldredge, James M. Valentine
  • Patent number: 7285140
    Abstract: A low-emissions diesel fuel comprises a catalyzed blend of fatty acid esters, preferably derived from soybean oil and/or tallow and aviation kerosene. The catalyzed blend is effective in lowering regulated emission pollutants, among which are NOx, particulates, hydrocarbons and carbon monoxide. The catalyst will comprise fuel-soluble platinum and/or cerium or iron. The cerium or iron are typically employed at concentrations of from 2 to 25 ppm and the platinum from 0.05 to 2 ppm, with preferred levels of cerium or iron being from 5 to 10 ppm, e.g., 7.5 ppm, and the platinum being employed at a level of from 0.1 to 0.5 ppm, e.g., 0.15 ppm. A preferred ratio of cerium and/or iron to platinum is from 75:1 to 10:1. The jet fuel component will typically be employed at a volume ratio to the fatty acid esters of from about 2:1 to about 5:1, e.g., about 4:1. The full range of blends extends from 50:1 to 1:50 with some benefit.
    Type: Grant
    Filed: February 3, 2003
    Date of Patent: October 23, 2007
    Assignee: Clean Diesel Technologies, Inc.
    Inventor: James M. Valentine
  • Patent number: 7216681
    Abstract: A simple, reliable system is provided for automatically dosing vehicle fuel tanks with a fuel additive, particularly a concentrate containing a fuel borne catalyst (FBC), using gravity as the means of injection, preferably with no electronics or complex mechanical parts. The system includes a supply line for feeding fuel additive by gravity from an additive reservoir and opening into a filler spout of a fuel tank, a ball-in-seat valve at the end of the supply line biased in normally closed position and operable to an open position by mechanically pressing a release on the ball-in-seat valve, and a pivotable lever positioned within the filler spout and including a projection capable of mating with the ball-in-seat valve release upon pivotable movement. Upon insertion of a filler hose into the filler spout, the filler hose moves the lever and projection to press the release on the ball-in-seat valve thereby dispensing additive.
    Type: Grant
    Filed: March 7, 2005
    Date of Patent: May 15, 2007
    Assignee: Clean Diesel Technologies, Inc.
    Inventors: James M. Valentine, Laura K. Valentine
  • Patent number: 7063729
    Abstract: A low-emissions diesel fuel comprises fungible aviation kerosene grade 55, 50–300 ppm detergent, 25–500 ppm lubricity additive and a bimetallic, fuel soluble platinum and cerium fuel borne catalyst (e.g., 0.1–2.0 ppm platinum COD and 5–20 ppm cerium oleate). The fuel can be used as is or in the form of an emulsion. A method of reducing the emissions of pollutants from a diesel engine, comprising running the engine on a fuel as defined. Retarding engine timing can further reduce NOx and the use of a diesel particulate filter and/or diesel oxidation catalyst can provide further reductions in carbon monoxide, unburned hydrocarbons and particulates.
    Type: Grant
    Filed: November 8, 2002
    Date of Patent: June 20, 2006
    Assignee: Clean Diesel Technologies, Inc.
    Inventors: James M. Valentine, Barry N. Sprague, Jeremy D. Peter-Hoblyn
  • Patent number: 6948926
    Abstract: Residual fuels, as well as lighter distillate fuels, are combusted with greater efficiency by utilizing low concentrations of specific bimetallic or trimetallic fuel-borne catalysts. The catalysts reduce fouling of heat transfer surfaces by unburned carbon while limiting the amount of secondary additive ash which may itself cause overloading of particulate collector devices or emissions of toxic ultra fine particles when used in forms and quantities typically employed. By utilizing a fuel containing a fuel-soluble catalyst comprised of platinum and at least one additional metal comprising cerium and/or iron, production of pollutants of the type generated by incomplete combustion is reduced. Ultra low levels of nontoxic metal combustion catalysts are able to be employed for improved heat recovery and lower emissions of regulated pollutants.
    Type: Grant
    Filed: November 29, 2002
    Date of Patent: September 27, 2005
    Assignee: Clean Diesel Technologies, Inc.
    Inventors: James M. Valentine, Barry N. Sprague
  • Publication number: 20040172876
    Abstract: Delivery of metallic combustion catalysts to internal combustion engines and other combustion devices is improved by dosing units that have the ability to effect the slow and positive supply of metallic additives, including platinum and/or cerium containing catalyst compositions, to fuel. The invention provides additive dosing materials and methods for simply and effectively supplying catalytic metal fuel additives to fuel in suitable low concentrations as are effective. The dosing units can be used with devices made to contact diesel fuel. In one approach, a catalytic metal additive concentrate (CMAC) is prepared in normally solid, semisolid or viscous form. The CMAC will preferably be encapsulated with a solid polymer. The encapsulation can be accomplished by embedding or dispersing the CMAC in a suitable polymer. If desired, the CMAC can be dispersed in one polymer and then the resulting composite can be embedded in the same or a different polymer.
    Type: Application
    Filed: March 21, 2003
    Publication date: September 9, 2004
    Inventors: Barry N. Sprague, James M. Valentine
  • Publication number: 20040098905
    Abstract: A low-emissions diesel fuel comprises fungible aviation kerosene emulsified with from 1 to 30% water, and preferably contains 50-300 ppm detergent and 25-500 ppm lubricity additive. Improved results can be achieved by also employing a fuel-soluble platinum group metal compound, such as 0.1-2.0 ppm platinum COD and a fuel-soluble cerium compound, such as 5-20 ppm cerium oleate. A method of reducing the emissions of pollutants from a diesel engine, comprising running the engine on a fuel as defined. The method is improved by also employing another pollution-reducing technique selected from timing changes, exhaust gas recirculation, oxidation catalysts, lean NOx catalysts and particulate filters for enhanced emissions control.
    Type: Application
    Filed: March 28, 2003
    Publication date: May 27, 2004
    Inventors: James M. Valentine, Barry N. Sprague