Abstract: The present disclosure provides a detergent additives and methods for preparing a sulfurized alkyl phenate product from polyalphaolefins.

Abstract: This disclosure relates to a film layer for use in flexible metal clad laminates. The film layer comprises a thermosetting composition comprising: a copolymer of (a) a diisoalkenylarene (DIAEA) and (b) a divinylarene (DVA) containing a mixture of m-divinylarene and p-divinylarene, in a mole ratio of (a) to (b) of 15:1 to 1:15; a second polymer; a filler and optional additives. Flexible metal clad laminates made with the film further comprises a metal foil bonded to the surface of the film. The thermosetting composition containing the DIAEA-DVA copolymer provides improved thermal stability at high temperature, excellent processability, and electrical properties, e.g., Dk and Df.

Abstract: Polymers are obtained by polymerizing in the presence of a Bronsted acid or a Lewis acid catalyst, a monomer comprising a 1,3-diisoalkenylarene, a 1,4-diisoalkenylarene, or mixtures thereof. The polymer comprises at least one of repeat units (A), (B), (C), and (D); wherein R1 is H or a C1-C8 alkyl group. The polymers have high Tg and exhibit good solubility in non-polar solvents, forming substantially gel-free solutions. The polymers are useful for producing crosslinked materials having good physical properties. The crosslinked materials are valuable for further downstream uses, such as copper clad laminates.

Abstract: The disclosure relates to a curable polymer composition comprising (i) a copolymer of a diisoalkenylarene (DIAEA) and a divinylarene (DVA), and (ii) at least one anti-scorching agent. The copolymer has a solubility in a hydrocarbon solvent at 25° C. for a period of less than 4 hours of at least 10 wt. %, a glass transition temperature (Tg) of 50 to 300° C., and a Gel Content of less than 5 wt. %. The curable polymer composition is cured at a temperature of greater than 140° C. to obtain a cured polymer composition having a Gel Content in a hydrocarbon solvent of >90%, and low Dk and Df values. The curable polymer composition does not cross-link or has minimal premature cross-linking in steps such as processing, storage, etc., and can be used in copper clad lamination applications.

Abstract: The disclosure relates to a thermosetting composition comprising a copolymer of (a) a diisoalkenylarene (DIAEA), and (b) a divinylarene (DVA) comprising m-DVB, p-DVB, m-EVB, p-EVB, and mixtures thereof. A mole ratio of DIAEA to DVA is from 15:1 to 1:15. The thermosetting composition after curing at a temperature of ?120° C. is characterized as having: a Gel Content of >90%, a Dk of <2.6 and Df of <0.002, both measured at 10 GHz, according to ASTM D2520. The thermosetting composition provides improved thermal stability at high temperature and excellent processability when used electronic applications as metal-clad laminates and build-up films.

Abstract: The disclosure relates to methods for producing poly(cyclohexadiene) homopolymers (PCHD). The PCHD is formed by polymerizing a 1,3-cyclohexadiene monomer in the presence of a catalyst, in a hydrocarbon solvent, and at a temperature of ?100° C. to 120° C. The catalyst is selected from the group consisting of a Bronsted acid, a Lewis acid, and combinations thereof. PCHD produced under these conditions has good solubility in non-polar solvents, and a number average molecular weight of 300 to 5,000 Dalton; a weight average molecular weight of 5,000 to 15,000 Delton; and a polydispersity index of 3.0 to 8.0. The PCHD is useful for producing crosslinked materials having good physical properties. The crosslinked materials can be combined with a rubbery polymer to produce compositions valuable for further downstream uses.

Abstract: The disclosure relates to a hydrogenated styrene-based multiblock copolymer composition, having selectively quaternized midblock, for forming anion-exchange membranes (AEMs). The quaternized hydrogenated styrene-based multiblock copolymer is characterized as having a high glass transition temperature from the hydrophobic end-blocks, low vinyl (rubber) content, and quaternized mid-block. AEMs made from the composition have improved thermal and dimensional stability in electrolyzer operations.

Abstract: A multi-block polyolefin copolymer (MBPC) is disclosed comprising: i) a combination of a semicrystalline polymer block and an amorphous polymer block, or ii) at least two amorphous polymer blocks, or iii) at least two semicrystalline polymer blocks. The semicrystalline polymer blocks A and C are independently derived from 1,3-butadiene monomer with 80 to 97 wt. % of 1,4 addition, based on weight of the polymerized 1,3-butadiene monomer in each block A and C. The amorphous polymer block B is derived from at least one monomer selected from isoprene monomer, 1,3-butadiene monomer with 21 to 85 wt. % incorporation by 1,2 addition, and mixtures thereof. The MBPC can be used as a compatibilizer for compatibilization of blends of two or more polyolefins different from each other. Such polyolefin blends provide improved mechanical properties and processability for producing various articles.

Abstract: Disclosed herein are copolymers formed by cationic polymerization of one or more cyclic dienes and a comonomer selected from the group consisting of a monoterpene, a branched styrene, and combinations thereof, in the presence of a catalyst. Random copolymers having repeat units derived from a cyclic conjugated diene, such as 1,3-cyclohexadiene, and a comonomer such as a monoterpene, can be prepared as soluble products in hydrocarbon solvents. The copolymers can be crosslinked with various crosslinking agents to form materials having good oxidative stability and fire retardancy. The uncrosslinked and crosslinked copolymers have useful properties such as a low dissipation factor, low dielectric constants, and a good balance of thermomechanical and electrical properties that make them valuable in electronic applications.

Abstract: An associative rheology modifier is obtained by coupling of a rheology modifier precursor with a coupling agent. The rheology modifier precursor is formed by reacting a rosin acid with a polyether at a mole ratio of the rosin acid to the polyether of >2:1, at a temperature from 180-350° C. and in the presence of an acid catalyst. The polyether has a molecular weight of 500-10,000 g/mol and the rheology modifier precursor has a water solubility of >10 wt. % concentration. The associative rheology modifier has a molecular weight (Mw) from 1500-25,000 g/mol. The associative rheology modifier shows a high shear thinning effect at low shear rate. A composition is also provided comprising the associative rheology modifier.

Abstract: This application relates to a wafer transfer method and a mechanical arm. The method includes: providing a first wafer to a finger portion front end of a mechanical arm; extending the mechanical arm to a first length to move the finger portion front end of the mechanical arm to a first processing position in a first processing chamber; placing the first wafer at the first processing position; contracting the mechanical arm to move the finger portion front end of the mechanical arm out of the first processing chamber; providing a second wafer to the finger portion front end of the mechanical arm; extending the mechanical arm to a second length to move the finger portion front end of the mechanical arm to a second processing position in the first processing chamber, wherein the second length is different from the first length; and placing the second wafer at the second processing position.

Abstract: The disclosure relates to polymers obtained by polymerizing in the presence of a Bronsted acid or a Lewis acid catalyst, a monomer comprising a 1,3-diisoalkenylarene, a 1,4-diisoalkenylarene, or mixtures thereof. The polymer comprises at least one of repeat units (A), (B), (C), and (D); wherein R1 is H or a C1-C8 alkyl group. The polymers have high Tg and exhibit good solubility in non-polar solvents, forming substantially gel-free solutions. The polymers are useful for producing crosslinked materials having good physical properties. The crosslinked materials are valuable for further downstream uses, such as copper clad laminates.

Abstract: A process for deodorizing a rosin ester composition is disclosed. The process employs an adsorptive bed containing an adsorbent material. The adsorbent material comprises silica adsorbent having an average pore size between 50-200 ?, BET surface area of at least 300 m2/g, pore volume of 1.20 to 3.00 cc/g, and a silanol [Si—OH] level of 0.5 to 5 unit/nm2. The deodorized rosin ester composition has an odor intensity reduction of at least 1 unit on odor intensity scale of Offensive Odor Control Act as compared to the rosin ester feedstock. In embodiment, the deodorizing treatment comprises using multi-staged adsorbent system with an adsorbent column having multiple layers of different adsorbent materials.

Abstract: A plasticized PVC composition free of phthalate and having low color is disclosed. The composition comprises a morpholide plasticizer prepared from a fatty acid selected from a tall oil fatty acid, a tall oil fatty acid monomer derived therefrom, and mixtures thereof. The fatty acid has a total carbon footprint of <95% of the total carbon footprint of a fatty acid obtained from a vegetable oil. The morpholide is prepared from the reaction of a tall oil fatty acid with morpholine in the presence of a catalyst.

Abstract: A process for deodorizing a rosin ester composition is disclosed. The process employs an adsorptive bed containing an adsorbent material. The adsorbent material comprises silica adsorbent having an average pore size between 50-200 ?, BET surface area of at least 300 mm2/g, pore volume of 1.20 to 3.00 cc/g, and a silanol [Si—OH] level of 0.5 to 5 unit/nm2. The deodorized rosin ester composition has an odor intensity reduction of at least 1 unit on odor intensity scale of Offensive Odor Control Act as compared to the rosin ester feedstock. In embodiment, the deodorizing treatment comprises using multi-staged adsorbent system with an adsorbent column having multiple layers of different adsorbent materials.

Abstract: Disclosed herein are copolymers formed by cationic polymerfization of one or more cyclic dienes and a comonomer selected from the group consisting of a monoterpene, a branched styrene, and combinations thereof, in the presence of a catalyst. Random copolymers having repeat units derived from a cyclic conjugated diene, such as 1,3-cyclohexadiene, and a comonomer such as a monoterpene, can be prepared as soluble products in hydrocarbon solvents. The copolymers can be crosslinked with various crosslinking agents to form materials having good oxidative stability and fire retardancy. The uncrosslinked and crosslinked copolymers have useful properties such as a low dissipation factor, low dielectric constants, and a good balance of thermomechanical and electrical properties that make them valuable in electronic applications.

Abstract: The disclosure relates to methods for producing poly(cyclohexadiene) homopolymers (PCHD). The PCHD is formed by polymerizing a 1,3-cyclohexadiene monomer in the presence of a catalyst, in a hydrocarbon solvent, and at a temperature of ?100° C. to 120° C. The catalyst is selected from the group consisting of a Bronsted acid, a Lewis acid, and combinations thereof. PCHD produced under these conditions has good solubility in non-polar solvents, and a number average molecular weight of 300 to 5,000 Dalton; a weight average molecular weight of 5,000 to 15,000 Delton; and a polydispersity index of 3.0 to 8.0. The PCHD is useful for producing crosslinked materials having good physical properties. The crosslinked materials can be combined with a rubbery polymer to produce compositions valuable for further downstream uses.

Abstract: A process for reducing or removing at least 90% of sulfur in a tall oil composition, e.g., to a level of 15 ppm or less is disclosed. The process employs at least a first desulfurization and a second desulfurization treatment in parallel or in series. The first treatment comprises adsorptive desulfurization, wherein the adsorbent material comprises silica adsorbent having an average pore size between 50-200 ?, BET surface area of at least 300 m2/g, pore volume of 1.20 to 3.00 cc/g, and a silanol [Si—OH] level of 0.5 to 5 unit/nm2. The second desulfurization treatment is selected from adsorptive treatment, heat treatment, distillation, extraction, oxidation, reduction, hydrogenation, and sulfur scavenging for a reduced sulfur content.

Abstract: A process for reducing or removing at least 90% of sulfur in a tall oil composition, e.g., to a level of 15 ppm or less is disclosed. The process employs at least a first desulfurization and a second desulfurization treatment in parallel or in series. The first treatment comprises adsorptive desulfurization, wherein the adsorbent material comprises silica adsorbent having an average pore size between 50-200 ?, BET surface area of at least 300 mm2/, pore volume of 1.20 to 3.00 cc/g, and a silanol [Si—OH] level of 0.5 to 5 unit/nm2. The second desulfurization treatment is selected from adsorptive treatment, heat treatment, distillation, extraction, oxidation, reduction, hydrogenation, and sulfur scavenging for a reduced sulfur content.

Abstract: A plasticized PVC composition free of phthalate and having low color is disclosed. The composition comprises a morpholide plasticizer prepared from a fatty acid selected from a tall oil fatty acid, a tall oil fatty acid monomer derived therefrom, and mixtures thereof. The fatty acid has a total carbon footprint of <95% of the total carbon footprint of a fatty acid obtained from a vegetable oil. The morpholide is prepared from the reaction of a tall oil fatty acid with morpholine in the presence of a catalyst.