Abstract: Catalyst systems and methods for making and using the same. A method of polymerizing olefins to produce a polyolefin polymer with a multimodal composition distribution, includes contacting ethylene and a comonomer with a catalyst system. The catalyst system includes a first catalyst compound and a second catalyst compound that are co-supported to form a commonly supported catalyst system. The first catalyst compound includes a compound with the general formula (C5HaR1b)(C5HcR2d)HfX2. The second catalyst compound includes at least one of the following general formulas: In both catalyst systems, the R groups can be independently selected from any number of substituents, including, for example, H, a hydrocarbyl group, a substituted hydrocarbyl group, or a heteroatom group, among others.

Abstract: A system and method of producing polyethylene, including: polymerizing ethylene in presence of a catalyst system in a reactor to form polyethylene, wherein the catalyst system includes a first catalyst and a second catalyst; and adjusting reactor conditions and an amount of the second catalyst fed to the reactor to control melt index (MI), density, and melt flow ratio (MFR) of the polyethylene.

Abstract: A method for protecting a phenol group on a precursor compound is provided. The method includes reacting the phenol group with dihydropyran in an acid catalyzed protection reaction and quenching the protection reaction with a strong base within less than about 60 seconds to form a protected precursor compound.

Abstract: An exercise apparatus includes a substantially flat, rigid platform for supporting a user during exercise. An inflatable tubular support having an upper portion with a first radial outside diameter, and a lower portion with a second radial outside diameter that is greater than the first radial outside diameter, is coupled to the platform by a fastener. The tubular support defines a central opening that communicates between the platform and a support surface. The platform includes a venting structure for releasing air from the central opening during use. The inflatable support includes an intermediate portion between the upper portion and the lower portion of the tubular support, the intermediate portion including a support feature to restrain the intermediate portion from radial expansion induced by an air pressure internal to the integral inflatable support.

Abstract: Disclosed herein are methods of preparing a catalyst system comprising a spray-dried activator and polymerization processes employing these catalyst systems.

Abstract: Disclosed herein are methods of preparing a catalyst system comprising a spray-dried activator and polymerization processes employing these catalyst systems.

Abstract: A method of synthesizing an alkyl cyclopentadiene compound is disclosed. The method includes contacting at least one cyclopentadienyl anion source and at least one alkyl group source to form at least one alkyl cyclopentadiene compound. The method further includes extracting the alkyl cyclopentadiene compound with a hydrocarbon solvent. The alkyl cyclopentadiene compound may be converted to a metallocene catalyst compound.

Abstract: An exercise apparatus includes a substantially flat, rigid platform for supporting a user during exercise. An inflatable tubular support having an upper portion with a first radial outside diameter, and a lower portion with a second radial outside diameter that is greater than the first radial outside diameter, is coupled to the platform by a fastener. The tubular support defines a central opening that communicates between the platform and a support surface. The platform includes a venting structure for releasing air from the central opening during use. The inflatable support includes an intermediate portion between the upper portion and the lower portion of the tubular support, the intermediate portion including a support feature to restrain the intermediate portion from radial expansion induced by an air pressure internal to the integral inflatable support.

Abstract: Catalyst systems and methods for making and using the same. The catalyst system can include a single site catalyst compound, a support comprising fluorinated alumina, and an aluminoxane. The aluminoxane can be present in an amount of about 10 mmol or less per gram of the support.

Abstract: An exercise apparatus includes a substantially flat, rigid platform for supporting a user during exercise. An inflatable tubular support having an upper portion with a first radial outside diameter, and a lower portion with a second radial outside diameter that is greater than the first radial outside diameter, is coupled to the platform by a fastener. The tubular support defines a central opening that communicates between the platform and a support surface. The platform includes a venting structure for releasing air from the central opening during use. The inflatable support includes an intermediate portion between the upper portion and the lower portion of the tubular support, the intermediate portion including a support feature to restrain the intermediate portion from radial expansion induced by an air pressure internal to the integral inflatable support.

Abstract: An exercise apparatus includes a substantially flat, rigid platform for supporting a user during exercise. An inflatable tubular support having an upper portion with a first radial outside diameter, and a lower portion with a second radial outside diameter that is greater than the first radial outside diameter, is coupled to the platform by a fastener. The tubular support defines a central opening that communicates between the platform and a support surface. The platform includes a venting structure for releasing air from the central opening during use. The inflatable support includes an intermediate portion between the upper portion and the lower portion of the tubular support, the intermediate portion including a support feature to restrain the intermediate portion from radial expansion induced by an air pressure internal to the integral inflatable support.

Abstract: An exercise apparatus includes a substantially flat, rigid platform for supporting a user during exercise. An inflatable tubular support having an upper portion with a first radial outside diameter, and a lower portion with a second radial outside diameter that is greater than the first radial outside diameter, is coupled to the platform by a fastener. The tubular support defines a central opening that communicates between the platform and a support surface. The platform includes a venting structure for releasing air from the central opening during use. The inflatable support includes an intermediate portion between the upper portion and the lower portion of the tubular support, the intermediate portion including a support feature to restrain the intermediate portion from radial expansion induced by an air pressure internal to the integral inflatable support.

Abstract: A polymerization catalyst system and polymerization processes using the catalyst systems are disclosed. The polymerization catalyst systems may include a) a first catalyst compound, and b) a second catalyst compound, wherein the first catalyst compound includes an oxadiazole-containing compound. In some embodiments, the oxadiazole-containing compound has essentially no hydrogen response, thus allowing better and/or tailored control of product properties when producing polymers using the catalyst system.

Abstract: A method of synthesizing an alkyl cyclopentadiene compound is disclosed. The method includes contacting at least one cyclopentadienyl anion source and at least one alkyl group source to form at least one alkyl cyclopentadiene compound. The method further includes extracting the alkyl cyclopentadiene compound with a hydrocarbon solvent. The alkyl cyclopentadiene compound may be converted to a metallocene catalyst compound.

Abstract: Catalyst systems and methods for making and using the same. The catalyst system can include a single site catalyst compound, a support comprising fluorinated alumina, and an aluminoxane. The aluminoxane can be present in an amount of about 10 mmol or less per gram of the support.

Abstract: An adapter cap is configured to convert a plastic water or drinking bottle into a nasal washing device. The cap has a connector portion or mechanism configured for engagement with the neck of a plastic water bottle in place of a conventional bottle cap, and a tapered applicator or spout portion having a tip with an opening which is configured for placing into a nostril of a user during a nasal washing procedure.

Abstract: A polymerization catalyst system and polymerization processes using the catalyst systems are disclosed. The polymerization catalyst systems may include a) a first catalyst compound, and b) a second catalyst compound, wherein the first catalyst compound includes an oxadiazole-containing compound. In some embodiments, the oxadiazole-containing compound has essentially no hydrogen response, thus allowing better and/or tailored control of product properties when producing polymers using the catalyst system.

Abstract: An exercise apparatus includes a substantially flat, rigid platform for supporting a user during exercise. An inflatable tubular support having an upper portion with a first radial outside diameter, and a lower portion with a second radial outside diameter that is greater than the first radial outside diameter, is coupled to the platform by a fastener. The tubular support defines a central opening that communicates between the platform and a support surface. The platform includes a venting structure for releasing air from the central opening during use. The inflatable support includes an intermediate portion between the upper portion and the lower portion of the tubular support, the intermediate portion including a support feature to restrain the intermediate portion from radial expansion induced by an air pressure internal to the integral inflatable support.

Abstract: A method of using a nasal wash system includes providing a nasal washing device including a container including a saline solution, a cap for the container, a delivery tube carried by the cap for withdrawing saline solution from the container, an atomizing nozzle for spraying the saline solution, a conduit carrying the atomizing nozzle, the conduit including a malleable portion, and a pump mechanism coupled to the malleable conduit and including a movable pump member; adjusting the malleable portion of the conduit to a desired configuration to control a point of impact of a discharge mist from the atomizing nozzle; and moving the movable pump member of the pump mechanism so that saline solution is withdrawn from the container through the delivery tube, through the pump mechanism, through the conduit, and sprayed out of the atomizing nozzle as a discharge mist, while the atomizing nozzle remains stationary.