Abstract: An electrochromic device includes: a first insulating substrate; a first conducting layer disposed over the first insulating substrate; an electrochromic layer disposed over the first conducting layer, wherein the electrochromic layer comprises an electrochromic polymer having a polymer backbone comprising one or more meta-conjugated linkers (MCLs) and one or more aromatic moieties (Ars), wherein each of the one or more MCLs is partially conjugated with one of the one or more Ars at a meta position of the one or more MCLs; an electrolyte layer disposed over the electrochromic layer; a second conducting layer disposed over the electrolyte layer; and a second insulating substrate disposed over the second conducting layer. A thickness of the electrochromic layer is from 10 nm to 1500 nm resulting in transmittance of 85%-99.9% at a wavelength of 550 nm at a neutral state of the electrochromic layer.

Abstract: An electrochromic device has a plurality of electrochromic layers stacked sequentially with underlying electrochromic layers crosslinked. The crosslinked electrochromic layers are solution-processable without compromising their optical and electrochromic performances. The disclosed electrochromic device can produce a full-color palette with a minimized intermediate color and show a multicolor capability. Multilayer electrochromic polymer patterns with surface texture information are made. The method for controlling electrochromism or multicolor electrochromism is discussed.

Abstract: An electrochromic device incorporating a high-energy absorbing polymer is presented to have an improved cycling stability. Various types of stable electrochromic devices are presented, including a highly stable yellow electrochromic device. Methods to improve the device cycling stability are also presented.

Abstract: An electrochromic device includes a charge balancing thin film comprised of a new vanadium oxide with a formula of VOx, which provides a high charge density, low coloration efficiency, an electroactive voltage in close proximity to those of some electrochromic materials, and high chemical and electrochromic stability. Vanadium oxide can be without doping or doped with others. The VOx charge balancing thin film has a porous nanostructure and is amorphous or a combination of amorphous and polycrystalline, and can work with electrochromic conjugated polymer in the device in a minimally color changing mode. A method to design a material for a charge balancing thin film to pair with a working electrode and obtain a low device voltage in an electrochromic device is disclosed. Methods to prepare related charge balancing thin films are also disclosed.

Abstract: An electrochromic polymer is comprised of a repeat unit comprising one or more meta-conjugated linkers (MCLs) and one or more aromatic moieties (Ars). Each of the one or more MCLs is partially conjugated with the one or more Ars at meta positions of the MCLs to form a polymer backbone of the electrochromic polymer. The electrochromic polymer undergoes an optical switching and a color change in an electrochromic device, which shows a high transparency and a high optical contrast.

Abstract: An electrochromic polymer is comprised of a repeat unit comprising one or more meta-conjugated linkers (MCLs) and one or more aromatic moieties (Ars). Each of the one or more MCLs is partially conjugated with the one or more Ars at meta positions of the MCLs to form a polymer backbone of the electrochromic polymer. The electrochromic polymer undergoes an optical switching and a color change in an electrochromic device, which shows a high transparency and a high optical contrast.

Abstract: A light-emitting electrochromic device with both electrochromic properties and light-emitting properties is disclosed. The light-emitting electrochromic device also shows multiple color-switching properties.

Abstract: This disclosure relates generally to electrochromic polymers that include a plurality of ?-conjugated chromophores in spaced relation with one another, and a plurality of conjugation-break spacers (CBSs), where at least one CBS separates adjacent chromophores. The chromophores may be colored in the neutral state, and multicolored to transmissive in different oxidization states.

Abstract: A new electrochromic polymer with yellow or orange or red color at neutral state and a method to form the new electrochromic polymer are disclosed. The disclosed electrochromic polymer has a low oxidation onset potential and a high optical contrast at the wavelength range of 400 nm to 550 nm.

Abstract: This disclosure relates generally to electrochromic polymers that include a plurality of ?-conjugated chromophores in spaced relation with one another, and a plurality of conjugation-break spacers (CBSs), where at least one CBS separates adjacent chromophores. The chromophores may be colored in the neutral state, and multicolored to transmissive in different oxidization states.

Abstract: A thermally stable and solvent resistant conductive polymer composite and its manufacturing friendly preparation method are disclosed. The disclosed composite presents great electrical conductivity with thermal stability and solvent resistance. A method of mixing a host thiophene conjugated polymer and a crosslinkable silane precursor simultaneously introduces both dopant and rigid cross-linked siloxane network into polymer system. The thin film made by the disclosed thermally stable and solvent resistant conductive polymer composite can be applied to fabricate various devices.

Abstract: An electrochromic polymer is comprised of a repeat unit comprising one or more meta-conjugated linkers (MCLs) and one or more aromatic moieties (Ars). Each of the one or more MCLs is partially conjugated with the one or more Ars at meta positions of the MCLs to form a polymer backbone of the electrochromic polymer. The electrochromic polymer undergoes an optical switching and a color change in an electrochromic device, which shows a high transparency and a high optical contrast.

Abstract: A new electrochromic polymer with high optical contrast and an electrochromic device incorporating the electrochromic polymer are presented. The electrochromic polymer includes side chains selected from C5-C20 linear or branched alkyl.

Abstract: The present disclosure presents a disulfide containing monomer, its reduced form, its derivative, the synthesis method of this disulfide containing monomer, and the polymer containing the monomers disclosed thereof

Abstract: An electrochromic polymer is comprised of a repeat unit comprising one or more meta-conjugated linkers (MCLs) and one or more aromatic moieties (Ars). Each of the one or more MCLs is partially conjugated with the one or more Ars at meta positions of the MCLs to form a polymer backbone of the electrochromic polymer. The electrochromic polymer undergoes an optical switching and a color change in an electrochromic device, which shows a high transparency and a high optical contrast.

Abstract: An electrochromic polymer is comprised of a repeat unit comprising one or more meta-conjugated linkers (MCLs) and one or more aromatic moieties (Ars). Each of the one or more MCLs is partially conjugated with the one or more Ars at meta positions of the MCLs to form a polymer backbone of the electrochromic polymer. The electrochromic polymer undergoes an optical switching and a color change in an electrochromic device, which shows a high transparency and a high optical contrast.

Abstract: A conjugated azopolymer and methods for making same. The azopolymer includes a plurality of monomer units containing isoindigo with R1 and R2 substituent groups, wherein R1 can be one or more C1 to 30 hydrocarbons; and R2 can be H or F. The azopolymer can have a number average molecular weight (Mn) of 4 to 20 kDa; a weight average molecular weight (Mw) of 12 to 50 kDa; and a poly dispersity index (PDI) of 2 to 3. The polymer can further have selected maximal wavelengths (?max) of 481 to 709 nm and electrochemical reduction events of ?0.4 to ?1.0 V against an Ag/AgCl reference electrode.

Abstract: A method of making an electrochromic device, includes: providing an electrochromic layer comprising a p-type electrochromic material; providing an ion-storage layer comprising an n-type metal oxide; and tuning the ion-storage layer, the electrochromic layer, or both the ion-storage layer and the electrochromic layer, so that when the electrochromic device is operating, the ion-storage layer operates in a minimally color changing mode.

Abstract: A composition for use as an electronic material. The composition contains at least one organic semiconducting material, and at least one electrically insulating polymer forming a semiconducting blend wherein the insulating polymer acts as a matrix for the organic semiconducting material resulting in an interpenetrating morphology of the polymer and the semiconductor material. The variation of charge carrier mobility with temperature in the semiconducting blend is less than 20 percent in a temperature range. A method of making a film of an electronic material. The method includes dissolving at least one organic semiconducting material and at least one insulating polymer into an organic solvent in a pre-determined ratio resulting in a semiconducting blend, depositing the blend onto a substrate to form a film comprising an interpenetrating morphology of the at least one insulating polymer and the at least one organic semiconductor material.

Abstract: A method for forming an electrochromic polymer block includes: forming each of reaction units by reacting two or more electron-donor groups, wherein each of the reaction units includes (i) a first backbone formed by the two or more electron-donor groups and (ii) at least one reactive functional group connected to each end of the first backbone; and forming the electrochromic polymer block by reacting at least two of the reaction units with acid-catalyzed cationic polymerization, wherein the electrochromic polymer block includes a second backbone formed by two or more of the first backbones.