Abstract: Provided is fluoroalkyl silicone of the formula (I): wherein each R1 is independently an alkyl or aryl; Rf is a perfluoroalkyl group, optionally substituted by one or more in-chain —O-, —S- or —NRf1-heteroatoms, where Rf1 is a perfluoroalkyl preferably a C1-C6 perfluoroalkyl; R3 is —H, —OR4; where R4 is a C1-C4 alkyl n is 0 to 2000; m may be zero; p may be zero, n+ m+ p is at least one; q is at least 3; R5 is H, alkyl, aryl-(CH2)n—CF2CHF—O—Rf; or R3; wherein the fluoroalkyl silicone has at least one fluorinated group of the formula (CH2)q—O—CF2CHF—O—Rf.

Abstract: Novel fluoroalkysilanes of the following formula are described; Rf—O—CHFCF2—O—(CH2)n—Si(R)xX3?x, wherein Rf is a perfluoroalkyl group, optionally substituted by one or more in-chain -Q-, —S—or —NRf1-heteroatoms, where Rf1 is a -perfluoroalkyl; X is a hydrolysable group; R is a C1C4 alkyl group; n is at least 3; and x is 1 to 3.

Abstract: Presently described are linerless sheeting articles comprising a substrate, a pressure sensitive adhesive layer disposed on the substrate, and a water soluble protective layer disposed on the pressure sensitive adhesive layer. The water soluble protective layer comprises at least 50 wt-% solids of a water soluble polymer and a polymer additive comprising a fluorinated-group, a silane group, or a combination thereof. The polymer additive is typically present in an amount no greater than 5 wt-% solids. In a favored embodiment, the polymer additive is an oligomer. Methods of making and applying the sheeting article are also described.

Abstract: Described herein is a method of making silsesquioxane-like particles using polyhydrosiloxanes and a water soluble base. The silsesquioxane-like particles have an average particle diameter of less than 100 micrometers and are substantially free of —OH bonds. In one embodiment, the silsesquioxane-like particles may be used in films.

Abstract: Novel fluoroalkyl silicones, and use thereof in release coatings, are described.

Abstract: Described herein is a method of making silsesquioxane-like particles using polyhydrosiloxanes and a water soluble base. The silsesquioxane-like particles have an average particle diameter of less than 100 micrometers and are substantially free of —OH bonds. In one embodiment, the silsesquioxane-like particles may be used in films.

Abstract: A composition comprises (a) a resin component comprising at least one liquid resin; (b) a reinforcing modifier comprising short fibers that are flexible; and (c) a flow modifier comprising hybrid organic-inorganic particles bearing organic or heteroorganic groups that comprise substantially non-interacting groups; wherein the reinforcing modifier and the flow modifier are dispersed in the resin component.

Abstract: A curable silsesquioxane polymer, a composition including such polymer, an article having a layer disposed thereon that includes the curable polymer and/or the cured polymer, and a method of forming a cured coating, wherein the curable silsesquioxane polymer includes a three-dimensional branched network having the formula: (I), or (II) wherein: the oxygen atom at the * is bonded to another Si atom within the three-dimensional branched network; R is an organic group comprising an ethylenically unsaturated group; R2 is an organic group that is not an ethylenically unsaturated group, and n or n+m is an integer of greater than 3; and the —OH groups are present in an amount of at least 15 wt-% of the polymer.

Abstract: An interconnect structure includes a patterned and cured dielectric layer located directly on a surface of a patterned permanent antireflective coating. The patterned and cured dielectric layer and the permanent antireflective coating form shaped openings. The shaped openings include an inverse profile which narrows towards a top of the shaped openings. A conductive structure fills the shaped openings wherein the patterned and cured dielectric layer and the permanent antireflective coating each have a conductively filled region.

Abstract: A curable composition comprising a silicone, a halomethyl-1,3,5-triazine and optionally a silicate tackifier is disclosed. The compositions are useful in the preparation of pressure-sensitive adhesives and release coatings.

Abstract: Dual condensation cure silicone systems are described. Such systems include hydroxyl-functional(s), hydride-functional silane(s), Fe(III) catalyst(s) and Ti(W) complex(es). Articles, including adhesive articles included the cured reaction product of such dual condensation cure silicone systems are also described.

Abstract: A curable composition comprising a silicone, a halomethyl-1,3,5-triazine and optionally a silicate tackifier is disclosed. The compositions are useful in the preparation of pressure-sensitive adhesives and release coatings.

Abstract: An interconnect structure includes a patterned and cured dielectric layer located directly on a surface of a patterned permanent antireflective coating. The patterned and cured dielectric layer and the permanent antireflective coating form shaped openings. The shaped openings include an inverse profile which narrows towards a top of the shaped openings. A conductive structure fills the shaped openings wherein the patterned and cured dielectric layer and the permanent antireflective coating each have a conductively filled region.

Abstract: Silsesquioxane polymers that cure to porous silsesquioxane polymers, silsesquioxane polymers that cure to porous silsesquioxane polymers in negative tone photo-patternable dielectric formulations, methods of forming structures using negative tone photo-patternable dielectric formulations containing silsesquioxane polymers that cure to porous silsesquioxane polymers, structures containing porous silsesquioxane polymers and monomers and method of preparing monomers for silsesquioxane polymers that cure to porous silsesquioxane polymers.

Abstract: Silsesquioxane polymers that cure to porous silsesquioxane polymers, silsesquioxane polymers that cure to porous silsesquioxane polymers in negative tone photo-patternable dielectric formulations, methods of forming structures using negative tone photo-patternable dielectric formulations containing silsesquioxane polymers that cure to porous silsesquioxane polymers, structures containing porous silsesquioxane polymers and monomers and method of preparing monomers for silsesquioxane polymers that cure to porous silsesquioxane polymers.

Abstract: Silsesquioxane polymers that cure to porous silsesquioxane polymers, silsesquioxane polymers that cure to porous silsesquioxane polymers in negative tone photo-patternable dielectric formulations, methods of forming structures using negative tone photo-patternable dielectric formulations containing silsesquioxane polymers that cure to porous silsesquioxane polymers, structures containing porous silsesquioxane polymers and monomers and method of preparing monomers for silsesquioxane polymers that cure to porous silsesquioxane polymers.

Abstract: Dual condensation cure silicone systems are described. Such systems include hydroxyl-functional(s), hydride-functional silane(s), platinum catalyst(s) and Ti(W) complex(es). Systems including alkoxy-functional crosslinker(s) are also described. Articles, including adhesive articles included the cured reaction product of such dual condensation cure silicone systems are also described.

Abstract: Photoactivated, precious metal catalysts in combination with condensation-cure silicone systems are described. Curable compositions including hydroxyl-functional polyorganosiloxanes, hydride-functional silanes, and a catalyst comprising a precious metal complexed with an actinic-radiation-displaceable ligand are described. Methods of curing such compositions and the resulting cured compositions are also discussed.

Abstract: Condensation-cure systems comprising at least one silanol-functional polyorganosiloxane and a platinum catalyst are described. The platinum catalysts include Pt(0) complexes, a Pt(II) complexes, and a Pt(IV) complexes. Condensation-cure systems comprising two or more silanol-functional polyorganosiloxanes are described, as are systems comprising a silanol functional polyorganosiloxane in combination with hydride-functional silanes or alkoxy-functional silanes. Articles incorporating cured condensation-cure systems are also disclosed.

Abstract: A curable silsesquioxane polymer, a composition including such polymer, an article having a layer disposed thereon that includes the curable polymer and/or the cured polymer, and a method of forming a cured coating, wherein the curable silsesquioxane polymer includes a three-dimensional branched network having the formula: wherein: the oxygen atom at the * is bonded to another Si atom within the three-dimensional branched network; R is an organic group comprising an ethylenically unsaturated group; n is an integer of greater than 3; and the —OH groups are present in an amount of at least 15 wt-% of the polymer.