Abstract: A nanostructured article includes a substrate; a plurality of first nanostructures disposed on, and extending away from, the substrate; and a covalently crosslinked fluorinated polymeric layer disposed on the plurality of first nanostructures. The plurality of first nanostructures includes polyurethane. The polymeric layer at least partially fills spaces between the first nanostructures to an average minimum height above the substrate of at least 30 nm such that the polymeric layer has a nanostructured surface defined by, and facing away from, the plurality of first nanostructures.

Abstract: A nanostructured article includes a substrate; a plurality of first nanostructures disposed on, and extending away from, the substrate; and a covalently crosslinked fluorinated polymeric layer disposed on the plurality of first nanostructures. The plurality of first nanostructures includes polyurethane. The polymeric layer at least partially fills spaces between the first nanostructures to an average minimum height above the substrate of at least 30 nm such that the polymeric layer has a nanostructured surface defined by, and facing away from, the plurality of first nanostructures.

Abstract: A nanostructured article includes a substrate; a plurality of first nanostructures disposed on, and extending away from, the substrate; and a covalently crosslinked fluorinated polymeric layer disposed on the plurality of first nanostructures. The plurality of first nanostructures includes polyurethane. The polymeric layer at least partially fills spaces between the first nanostructures to an average minimum height above the substrate of at least 30 nm such that the polymeric layer has a nanostructured surface defined by, and facing away from, the plurality of first nanostructures.

Abstract: Dual-sided adhesive articles include a first crosslinked pressure sensitive adhesive layer with a first major surface and a second major surface, a second siloxane-based pressure sensitive adhesive layer with a first major surface and a second major surface, such that the first major surface of the second siloxane-based pressure sensitive adhesive layer is in contact with the second major surface of the first crosslinked pressure sensitive adhesive layer. The articles also include a release liner having a microstructured surface with an array of microstructures, where the microstructured surface is in contact with the second major surface of the second siloxane-based pressure sensitive adhesive layer. The microstructures of the microstructured surface of the second siloxane-based pressure sensitive adhesive layer are unstable when not in contact with the microstructured release liner, and disappear over time when in contact with a substrate.

Abstract: A polarizer including an oriented polymeric first layer is described. The oriented polymeric first layer is preparable from a mixture of polyvinyl alcohol and crosslinker where the crosslinker is included in the mixture at 5 to 40 percent by weight based on the total weight of the polyvinyl alcohol and crosslinker. The oriented polymeric first layer is a substantially uniaxially drawn layer, in that for U=(1/MDDR?1)/(TDDR1/2?1), U is at least 0.85, with MDDR being a machine direction draw ratio and TDDR being a transverse direction draw ratio.

Abstract: A vehicle sensor system is described comprising an exterior surface; and a repellent composition disposed on the exterior surface, wherein the repellent composition exhibits an increase in haze according to the Dirty Water Spray Test of less than 5, 4, 3, or 2%. In typical embodiments, the repellent composition exhibits an advancing water contact angle from 90° to 125°. In some embodiments, the sensor system comprises a camera, a laser, a LIDAR sensor, a sonar sensor, or a radar sensor. The exterior surface is typically a windshield surface, a protective housing, or a lens surface. In some favored embodiments, the repellent composition exhibits a roll-off angle of no greater than 25, 20, 15, 10 or 5 degrees.

Abstract: Articles and intermediates are described comprising an organic polymeric base member and a hardcoat layer disposed on the organic polymeric base member, wherein the hardcoat layer can be stretched 25-75% without cracking. A siliceous layer is disposed on the hardcoat layer. The siliceous layer has a porosity of no greater than 10% and a thickness no greater than 1 micron. In some embodiments, the article further comprises a surface layer comprising a zwitterionic compound bonded to the siliceous layer.

Abstract: Various embodiments disclosed relate to a surfacing film. The surfacing film includes a base layer. The base layer includes a thermoplastic polyurethane film comprising a reaction product of a reaction mixture of a diisocyanate, a polyester polyol having a melting temperature of at least about 30° C.; and a diol chain extender. There are many reasons to use the surfacing film including easier and more cost effective manufacturing of the surfacing film by directly extruding the base layer by mixing the reaction mixture in an extruder. Another reason to use the surfacing film is that the film has improved resistance to discoloration. Another reason to use the film is that the film shows good toughness.

Abstract: Waterborne suspensions include surface treated silica particles, a water dispersable binder resin, at least one surfactant, and an aqueous solvent. The surface treated silica particles have a mixture of hydrophobic and hydrophilic silane surface treatment agents, where the ratio of hydrophilic silane surface treatment agent to hydrophobic silane surface treatment agent is greater than 1. The waterborne suspensions can be coated and dried to form nanostructured tie layers, especially tie layers to silicone or (meth)acrylate layers.

Abstract: A composite article having a conductive layer on at least a portion of a flexible substrate. Electrical connectivity between various portions of the substrate can be obtained through this conductive layer. The conductive layer comprises a conductive surface, and there is a patterned layer on at least a portion of a first region of the conductive surface. The patterned layer comprises a conductive material having a surface roughness, and is in electrical contact with the conductive surface. An overcoat layer is present on at least a portion of the first region, such that the overcoat layer has a thickness less than the surface roughness, such that the conductive layer within the first region is covered by the overcoat layer, and such that at least a portion of the patterned layer substantially protrudes above the overcoat layer.

Abstract: A polarizer including an oriented polymeric first layer is described. The oriented polymeric first layer is preparable from a mixture of polyvinyl alcohol and crosslinker where the crosslinker is included in the mixture at 5 to 40 percent by weight based on the total weight of the polyvinyl alcohol and crosslinker. The oriented polymeric first layer is a substantially uniaxially drawn layer, in that for U=(1/MDDR?1)/(TDDR1/2?1), U is at least 0.85, with MDDR being a machine direction draw ratio and TDDR being a transverse direction draw ratio.

Abstract: The present invention relates to protection films comprising an optical film suitably sized for an illuminated display device, the optical film having perimeter surface portions defining a central region. The protection film further comprises a pressure sensitive adhesive layer at the perimeter surface portions of the optical film. The optical film and/or pressure sensitive adhesive layer has been adapted such that the at least the central region of the optical film contacts the illuminated display device or the central region of the optical film is bonded to the illuminated display device by means of a self-wetting layer. The protection film may be preassembled or may be provided as a kit, the kit comprising an optical film and a double-faced pressure sensitive tape.

Abstract: Adhesive composition including an elastomeric silicone-based copolymer selected from the group consisting of urea-based silicone copolymers, oxamide-based silicone copolymers, amide-based silicone copolymers, urethane-based silicone copolymers and mixtures thereof; and greater than 0% by weight and no more than 20% by weight of MQ resin. In certain embodiments, the adhesive compositions includes less than 10% by weight of MQ resin. In some illustrative embodiments, the adhesive composition is a pressure-sensitive adhesive. In certain illustrative embodiments, the pressure sensitive adhesive is optically clear, self-wetting to the end-use substrate, and stretch releasable. In certain such embodiments, the adhesive article exhibits a 180° PEEL ADHESION to a glass substrate no greater than about 500 N/dm after aging for seven days at 85° C. The pressure sensitive adhesive compositions may be used to form adhesive articles and adhesive assemblies.

Abstract: A composite article having a conductive layer on at least a portion of a flexible substrate. Electrical connectivity between various portions of the substrate can be obtained through this conductive layer. The conductive layer comprises a conductive surface, and there is a patterned layer on at least a portion of a first region of the conductive surface. The patterned layer comprises a conductive material having a surface roughness, and is in electrical contact with the conductive surface. An overcoat layer is present on at least a portion of the first region, such that the overcoat layer has a thickness less than the surface roughness, such that the conductive layer within the first region is covered by the overcoat layer, and such that at least a portion of the patterned layer substantially protrudes above the overcoat layer.

Abstract: Waterborne suspensions include surface treated silica particles, a water dispersable binder resin, at least one surfactant, and an aqueous solvent. The surface treated silica particles have a mixture of hydrophobic and hydrophilic silane surface treatment agents, where the ratio of hydrophilic silane surface treatment agent to hydrophobic silane surface treatment agent is greater than 1. The waterborne suspensions can be coated and dried to form nanostructured tie layers, especially tie layers to silicone or (meth)acrylate layers.

Abstract: Dual-sided adhesive articles include a first crosslinked pressure sensitive adhesive layer with a first major surface and a second major surface, a second siloxane-based pressure sensitive adhesive layer with a first major surface and a second major surface, such that the first major surface of the second siloxane-based pressure sensitive adhesive layer is in contact with the second major surface of the first crosslinked pressure sensitive adhesive layer. The articles also include a release liner having a microstructured surface with an array of microstructures, where the microstructured surface is in contact with the second major surface of the second siloxane-based pressure sensitive adhesive layer. The microstructures of the microstructured surface of the second siloxane-based pressure sensitive adhesive layer are unstable when not in contact with the microstructured release liner, and disappear over time when in contact with a substrate.

Abstract: Optically clear adhesive or coating layers can be prepared by preparing a curable mixture, coating the curable mixture to form a layer, partially curing the curable mixture, drying the coated layer, and fully curing the curable mixture. The curable mixture may also be partially cured and then coated, dried and fully cured. The curable mixture includes two free radically polymerizable monomer compositions that are relatively incompatible and a transient compatibilizer, such as a solvent. Polymers of the two monomer compositions, if polymerized separately and blended, form phase separated domains. The curable mixture provides for adhesive or coating layers that are optically clear.

Abstract: Adhesive compositions include a blend of a non-siloxane polyurea-based polymer, a non-siloxane polyurethane-based polymer, or a blend of a non-siloxane polyurea-based and non-siloxane polyurethane-based with at least one (meth)acrylate-based pressure sensitive adhesive. The non-siloxane polyurea-based polymer or non-siloxane polyurethane-based polymer is free of free radically polymerized groups. The adhesive composition is a self-wetting, optically clear pressure sensitive adhesive. The adhesive compositions can be coated on substrates to form adhesive articles.

Abstract: The present invention relates to protection films comprising an optical film suitably sized for an illuminated display device, the optical film having perimeter surface portions defining a central region. The protection film further comprises a pressure sensitive adhesive layer at the perimeter surface portions of the optical film. The optical film and/or pressure sensitive adhesive layer has been adapted such that the at least the central region of the optical film contacts the illuminated display device or the central region of the optical film is bonded to the illuminated display device by means of a self-wetting layer. The protection film may be preassembled or may be provided as a kit, the kit comprising an optical film and a double-faced pressure sensitive tape.

Abstract: Presently described are coating compositions comprising a polymerizable resin composition and a non-ionic unpolymerizable surfactant. In some embodiments, the coating comprises greater than 10 wt-% of non-ionic unpolymerizable surfactant. In other embodiments, the coating composition comprises an an additive comprising a silicone group or a fluorinated group and a hydrophobic group. Also described are articles comprising the cured coating compositions. In one embodiment, an article is described comprising a cured coating wherein the cured coating exhibits a property of an initially visible simulated fingerprint reducing in visibility in 1-20 minutes. Also described is a method of determining the fingerprint visibility of a coating composition and a polyacylate composition useful as an additive. In another embodiment a coated surface is described comprising a polymeric organic material comprising a plurality of pores wherein a portion of the pores are interconnected and comprise a lipophilic liquid.