Abstract: A low refractive index composition that forms a low refractive index layer on an optical display is formed having a co-crosslinked interpenetrating polymer network of a fluoropolymer phase and an acrylate phase. The fluoropolymer phase is preferably formed from fluoropolymers based on THV or FKM and having either a degree of unsaturation and/or containing a reactive cure site monomer in its polymer backbone. The acrylate phase includes a multifunctional acrylate crosslinker, and more preferably includes a perfluoropolyether acrylate crosslinker. The formed low refractive index layer has improved interfacial adhesion to other layers or substrates contained in the optical display. Further, the mechanical strength and scratch resistance of the either of above low refractive index compositions can be further enhanced through the incorporation of surface functionalized inorganic particle into the formed layer.

Abstract: Presently described are optical substrates having a surface layer and optical displays comprising such optical substrates. The surface layer comprises the reaction product of a polymerizable mixture comprising at least one perfluoropolyether urethane polymeric material comprising at least two free-radically polymerizable groups and greater than 6 ethylene oxide repeat units and at least one non-fluorinated crosslinker comprising at least two free-radically polymerizable groups.

Abstract: An apparatus comprising a die having at least one application slot. The slot is in fluid communication with a die cavity. An expansible chamber device is disposed within the die cavity and changes volume in response to changes in pressure within the expansible chamber device. Another aspect of the invention is a method of translating a liquid through a die. A coating die is provided. The die comprises at least one applicator slot in fluid communication with a die cavity. An expansible chamber device is disposed within the cavity. The expansible chamber device is actuated by changes in the fluid pressure within the expansible chamber device. The liquid is translated through the die and delivered from the application slot at intervals corresponding to actuation of the expansible chamber device. Another aspect of the invention is a method for forming a die. An apparatus comprising a die having at least one applicator slot in fluid communication with the die cavity is provided.

Abstract: The present invention includes optical coatings containing ultraviolet curable monomers employing a bromine substituted fluorene structure. The fluorene backbone of the monomers of the present invention may also be functionalized with one or more polymerizable or reactive functionalities, and most readily at the 9 position. Compositions of the present invention include the reactive bromosubstituted fluorenes combined with inorganic nanoparticles, particularly nanoparticles with reactive surface modifiers exhibiting polymerizable functionality. Reactive high index nanoparticles such as surface modified zirconia are contemplated.

Abstract: A method of applying a material to a moving substrate is disclosed. The method includes providing a die comprising a die body having a cavity therein, wherein the cavity is in fluid communication with an applicator slot. The die is then oriented such that the applicator slot is positioned so as to dispense the material onto the substrate. The material is introduced into the die cavity such that the material is dispensed onto the substrate through the applicator slot. At least one end of the slot includes means for preventing lateral widening of the dispensed material. In another embodiment, means will be disposed at both ends of the applicator slot. The method is particularly useful when the capillary number characteristic of the coating process is less than 0.

Abstract: The present invention includes ultraviolet curable compositions preferably containing discrete, crystalline zirconia nanoparticles with reactive, or copolymerizable, surface modification, in a polymerizable monomer/oligomer resin mixture. It is believed that copolymerizable surface modification provides a functional group that enables the functionalized particle to co-polmerize with the reactive monomers, oligomers, and crosslinkers in the formulation. Relative to surface modification of the nanoparticles, acrylate functionality is preferred over methacrylate functionality. On the other hand, methacrylate functionality is preferred over non-reactive, or nonpolymerizable, functionality. As the nanocomposite cures, the resultant network is heavily crosslinked by selection of raw materials with substantial acrylate functionality.

Abstract: The invention is a die comprising a die body. The die body defines an internal cavity and an applicator slot. The cavity is in fluid communication with the applicator slot. A plurality of gas relief passages are in fluid communication with the internal cavity.

Abstract: The invention is a die comprising a die body. The die body defines an internal cavity and an applicator slot. The cavity is in fluid communication with the applicator slot. A plurality of gas relief passages are in fluid communication with the internal cavity.

Abstract: An apparatus comprising a die having at least one application slot. The slot is in fluid communication with a die cavity. An expansible chamber device is disposed within the die cavity and changes volume in response to changes in pressure within the expansible chamber device. Another aspect of the invention is a method of translating a liquid through a die. A coating die is provided. The die comprises at least one applicator slot in fluid communication with a die cavity. An expansible chamber device is disposed within the cavity. The expansible chamber device is actuated by changes in the fluid pressure within the expansible chamber device. The liquid is translated through the die and delivered from the application slot at intervals corresponding to actuation of the expansible chamber device. Another aspect of the invention is a method for forming a die. An apparatus comprising a die having at least one applicator slot in fluid communication with the die cavity is provided.

Abstract: A time-temperature indicator device provides a visually observable indication of the cumulative thermal exposure of an object. The device includes a substrate having a diffusely light-reflective porous matrix and a backing. The backing includes on its surface a viscoelastic indicator material for contacting the substrate and a barrier material for substantially inhibiting the lateral and longitudinal flow of viscoelastic indicator material between the substrate and the backing.

Abstract: A time-temperature indicator device provides a visually observable indication of the cumulative thermal exposure of an object. The device includes a substrate having a diffusely light-reflective porous matrix and a backing. The backing includes on its surface a viscoelastic indicator material for contacting the substrate and a barrier material for substantially inhibiting the lateral and longitudinal flow of viscoelastic indicator material between the substrate and the backing.

Abstract: A time-temperature indicator device provides a visually observable indication of the cumulative thermal exposure of an object. The device includes a substrate having a diffusely light-reflective porous matrix and a backing. The backing includes on its surface a viscoelastic indicator material for contacting the substrate and a barrier material for substantially inhibiting the lateral flow of viscoelastic indicator material between the substrate and the backing.